CN105130369A - Aqueous internal wall inorganic coating and preparation method thereof - Google Patents

Aqueous internal wall inorganic coating and preparation method thereof Download PDF

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Publication number
CN105130369A
CN105130369A CN201510435893.7A CN201510435893A CN105130369A CN 105130369 A CN105130369 A CN 105130369A CN 201510435893 A CN201510435893 A CN 201510435893A CN 105130369 A CN105130369 A CN 105130369A
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water
agent
inorganic
speed
cementitious material
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CN201510435893.7A
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Chinese (zh)
Inventor
刘善江
花东栓
董立志
刘洪亮
薛小倩
郭京林
刘艳菲
李幕英
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Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Industry and Trade Group Co Ltd
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Priority to CN201510435893.7A priority Critical patent/CN105130369A/en
Publication of CN105130369A publication Critical patent/CN105130369A/en
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Abstract

The invention relates to an aqueous internal wall inorganic coating and a preparation method thereof. The coating is prepared from following raw materials, by weight, 3-8 parts of an aqueous emulsion, 10-25 parts of an inorganic bonding material, 0.5-2.5 parts of a stabilizing agent, 10-40 parts of deionized water, 0.1-0.3 parts of an amine neutralizing agent, 0.1-0.5 parts of a macromolecular surfactant, 0.2-0.6 parts of a molecule-grade defoaming agent, 0.2-0.4 parts of a dispersing agent, 0.5-1 part of a thickening agent, 0.3-0.8 parts of a flatting agent and 32.3-55 parts of a pigment filling material. The aqueous internal wall inorganic coating is good in stability, is high in hardness, is good in adhesion resistance, allows thick coating, is strong in adhesive force, is quick to dry, is excellent in anti-aging property and water-proof performance, is breathable and is alkali-resistant.

Description

A kind of water-based inner wall inorganic paint and preparation method thereof
Technical field
The present invention relates to building coating field, particularly relate to a kind of aqueous aluminum powder plastic paint and preparation method thereof.
Background technology
Along with the worsening shortages of natural resources, and people become large day by day to the demand of resource, much apply steel, the field of timber replaced by the plastics of recoverable.Therefore, the application of society plastics is more and more extensive, and the protection of frosting is also more and more important with decoration.Because the surface energy of plastics is low, there is certain difficulty in the attachment on its surface in coating, be solvent based coating for the coating majority of frosting.Significant proportion composition in solvent based coating is volatilizable solvent, will evaporate in air after application, causes pollute significantly air, and these organic solvents are mainly derived from oil, is also a kind of very large waste to petroleum resources.Water-borne coatings not containing or only containing a small amount of organic solvent, take water as dispersion medium, this point is the incomparable advantage of solvent based coating.
Existing domestic aqueous plastic paint is more difficult embodiment metallic appearance effect in aqueous aluminum powder arrangement, the stability less stable in water-based, and physical and chemical performance performance is poor.
In view of above-mentioned defect, creator of the present invention obtains this creation finally through long research and practice.
Summary of the invention
The object of the present invention is to provide a kind of water-based inner wall inorganic paint and preparation method thereof, in order to overcome above-mentioned technological deficiency.
For achieving the above object, the invention provides a kind of water-based inner wall inorganic paint, be made up of following raw material ratio, by weight calculating: water-based emulsion 3-8, inorganic cementitious material 10-25, stablizer 0.5-2.5, deionized water 10-40, amine neutralizing agent 0.1-0.3, molecules surfactant 0.1-0.5, molecular antifoaming agent 0.2-0.6, dispersion agent 0.2-0.4, thickening material 0.5-1, flow agent 0.3-0.8, color stuffing 32.3-55.
Further, be by weight: water-based emulsion 5.7, inorganic cementitious material 25, stablizer 2.5, deionized water 10, amine neutralizing agent 0.3, molecules surfactant 0.5, molecular antifoaming agent 0.2, dispersion agent 0.4, thickening material 1, flow agent 0.8, titanium dioxide 10, calcium carbonate 30, process white 7.5, kaolin 7.5;
Inorganic cementitious material comprises potassium 6.25, lithium silicate 6.25, silicon sol 12.5.
Further, be by weight: water-based emulsion 8, inorganic cementitious material 10, stablizer 0.5, deionized water 35, amine neutralizing agent 0.1, molecules surfactant 0.1, molecular antifoaming agent 0.6, dispersion agent 0.2, thickening material 0.5, flow agent 0.3, titanium dioxide 15, calcium carbonate 24.7, process white 7.5, kaolin 7.5;
Inorganic cementitious material comprises potassium silicate 2.5, lithium silicate 2.5, silicon sol 5.
Further, be by weight: water-based emulsion 3, inorganic cementitious material 20, stablizer 2.0, deionized water 40, amine neutralizing agent 0.2, molecules surfactant 0.3, molecular antifoaming agent 0.5, dispersion agent 0.3, thickening material 0.8, flow agent 0.6, titanium dioxide 22.3, calcium carbonate 10.
Further, described inorganic cementitious material is that lithium silicate potassium, silicon sol are wherein a kind of or composite according to a certain percentage.
Further, inorganic cementitious material adopts potassium silicate, lithium silicate 1: 1 composite, the silicon sol that the employing γ-glycidyl ether propyl trimethoxy silicane of the quality such as rear interpolation is crossed as stabilizer treatment.
Further, described water-based emulsion be non-plasticizing based on ethylene and vinyl acetate copolymer water-dispersion emulsion; Defoamer is hub-and-spoke configuration molecular antifoaming agent.
Further, described dispersion agent is the anionic compound of polyphosphate and polyether phosphate system; Stablizer is Trimethoxy silane or derivatives thereof.
Further, described amine neutralizing agent is alcamines organism; Molecules surfactant is fatty alcohol-polyoxyethylene ether or its derivative; Thickening material be organic modified bentonite, pure Natvosol wherein one or both; Flow agent is fluorine-containing alcohol ether modified acrylate class flow agent; Color stuffing is that wherein one or several are composite for titanium dioxide, calcium carbonate, process white, kaolin.
The present invention also provides a kind of preparation method of water-based inner wall inorganic paint, and making processes is:
Step a, according to formula ratio, adds silicon sol in paint mixing cylinder A successively, stirs, be warming up to 35-45 DEG C, slowly add stablizer with the speed of 400-600rpm, stirs 15min with the speed of 400-600rpm;
Step b, according to formula ratio, slowly adds lithium silicate and potassium silicate successively, stirs 15min, obtain inorganic cementitious material at A cylinder with the speed of 500-800rpm, for subsequent use;
Step c according to formula ratio, successively by deionized water, amine neutralizing agent, dispersion agent, defoamer, molecules surfactant, thickening material enters in paint mixing cylinder B, stirs 10 minutes with the speed of 800-1200rpm;
Steps d, according to formula, adds in paint mixing cylinder B by color stuffing, improve the speed stirring 30min of mixing speed to 1200-1500rpm, measure mill base fineness≤55 μm;
Step e is according to dosage, slowly inorganic cementitious material in paint mixing cylinder A is added in paint mixing cylinder B, 5 minutes are stirred with the speed of 800-1200rpm, add water-based emulsion, flow agent, stirs 5 minutes with the speed of 800-1200rpm, surveys initial viscosity, according to initial viscosity, the part thickening material adding formula ratio carries out being thickened to 25 DEG C, stormer viscosity meter 80-100KU.
Beneficial effect of the present invention is compared with prior art: water-based inner wall inorganic paint good stability of the present invention, hardness is high, resistance to blocking good, can thickly be coated with, strong adhesion, fast drying, ageing resistance excellent, water-tolerant, ventilative alkali resistant.
Also there is convenient and quick construction, Diamond Search, organic binder matter content be extremely low, A level is not fired, the feature such as asepsis environment-protecting.
Embodiment
Below, to above-mentioned being described in more detail with other technical characteristic and advantage of the present invention.
The water-based inner wall inorganic paint of the embodiment of the present invention is made up of following raw material ratio, by weight calculating: water-based emulsion 3-8, inorganic cementitious material 10-25, stablizer 0.5-2.5, deionized water 10-40, amine neutralizing agent 0.1-0.3, molecules surfactant 0.1-0.5, molecular antifoaming agent 0.2-0.6, dispersion agent 0.2-0.4, thickening material 0.5-1, flow agent 0.3-0.8, color stuffing 32.3-55.
Wherein, water-based emulsion be non-plasticizing based on ethylene and vinyl acetate copolymer water-dispersion emulsion; Defoamer is hub-and-spoke configuration molecular antifoaming agent; Dispersion agent is the anionic compound of polyphosphate and polyether phosphate system; Inorganic cementitious material is that lithium silicate potassium, silicon sol are wherein a kind of or composite according to a certain percentage; Stablizer is Trimethoxy silane or derivatives thereof; Amine neutralizing agent is alcamines organism; Molecules surfactant is fatty alcohol-polyoxyethylene ether or its derivative; Thickening material be organic modified bentonite, pure Natvosol wherein one or both; Flow agent is fluorine-containing alcohol ether modified acrylate class flow agent; Color stuffing is that wherein one or several are composite for titanium dioxide, calcium carbonate, process white, kaolin.
In the embodiment of the present invention, inorganic cementitious material adopts potassium silicate, lithium silicate 1: 1 composite, the mode of the silicon sol that the employing γ-glycidyl ether propyl trimethoxy silicane of the quality such as rear interpolation is crossed as stabilizer treatment, obtains high stability, high bond strength inorganic cementitious material.
Adopt improving the fragility of paint film based on ethylene and vinyl acetate copolymer water-dispersion emulsion and improving paint film flexibility and film-formation result of non-plasticizing, ultralow organic binder matter, ensures fire performance and the stain resistant ability of paint film to greatest extent.
By adopting organic modified bentonite and modified hydroxyethylcellulosadsorbing to arrange in pairs or groups, improve application property and stability in storage.
Select primary amine type organic as neutralizing agent, while stable prod PH, improve the stability of inorganic cementitious material.
Select the anionic compound of polyphosphoric acid salt and polyether phosphate system as dispersion agent, improve dispersion effect and the system stability of color stuffing, finished product paint 50 DEG C of thermmal storages more than 35 days phenomenons without exception.
The making processes of water-based inner wall inorganic paint is:
Step a, according to formula ratio, adds silicon sol in paint mixing cylinder A successively, stirs, be warming up to 35-45 DEG C, slowly add stablizer with the speed of 400-600rpm, stirs 15min with the speed of 400-600rpm;
Step b, according to formula ratio, slowly adds lithium silicate and potassium silicate successively, stirs 15min, obtain inorganic cementitious material at A cylinder with the speed of 500-800rpm, for subsequent use;
Step c according to formula ratio, successively by deionized water, amine neutralizing agent, dispersion agent, defoamer, molecules surfactant, thickening material enters in paint mixing cylinder B, stirs 10 minutes with the speed of 800-1200rpm;
Steps d, according to formula, adds in paint mixing cylinder B by color stuffing, improve the speed stirring 30min of mixing speed to 1200-1500rpm, measure mill base fineness≤55 μm;
Step e is according to dosage, slowly inorganic cementitious material in paint mixing cylinder A is added in paint mixing cylinder B, 5 minutes are stirred with the speed of 800-1200rpm, add water-based emulsion, flow agent, stirs 5 minutes with the speed of 800-1200rpm, surveys initial viscosity, according to initial viscosity, the part thickening material adding formula ratio carries out being thickened to 25 DEG C, stormer viscosity meter 80-100KU.
Embodiment one
Water-based inner wall inorganic paint, according to weight, comprising:
Water-based emulsion 5.7, inorganic cementitious material 25 (potassium silicate 6.25, lithium silicate 6.25, silicon sol 12.5), stablizer 2.5, deionized water 10, amine neutralizing agent 0.3, molecules surfactant 0.5, molecular antifoaming agent 0.2, dispersion agent 0.4, thickening material 1, flow agent 0.8, titanium dioxide 10, calcium carbonate 30, process white 7.5, kaolin 7.5.
Its preparation method, comprises the following steps:
According to formula ratio, silicon sol is added in paint mixing cylinder A successively, stir with the speed of 400-600rpm, be warming up to 35-45 DEG C, slowly add stablizer, stir 15min with the speed of 400-600rpm;
According to formula ratio, slowly add lithium silicate and potassium silicate successively, stir 15min with the speed of 500-800rpm, obtain inorganic cementitious material at A cylinder, for subsequent use;
According to formula ratio, successively by deionized water, amine neutralizing agent, dispersion agent, defoamer, molecules surfactant, thickening material enters in paint mixing cylinder B, stirs 10 minutes with the speed of 800-1200rpm;
According to having filled a prescription, color stuffing being added in paint mixing cylinder B, improving the speed stirring 30min of mixing speed to 1200-1500rpm, measuring mill base fineness≤55 μm;
According to dosage, slowly inorganic cementitious material in paint mixing cylinder A is added in paint mixing cylinder B, 5 minutes are stirred with the speed of 800-1200rpm, add water-based emulsion, flow agent, stirs 5 minutes with the speed of 800-1200rpm, surveys initial viscosity, according to initial viscosity, the part thickening material adding formula ratio carries out being thickened to 25 DEG C, stormer viscosity meter 100KU.
Embodiment two
Water-based inner wall inorganic paint, according to weight, comprising:
Water-based emulsion 8, inorganic cementitious material 10 (potassium silicate 2.5, lithium silicate 2.5, silicon sol 5), stablizer 0.5, deionized water 35, amine neutralizing agent 0.1, molecules surfactant 0.1, molecular antifoaming agent 0.6, dispersion agent 0.2, thickening material 0.5, flow agent 0.3, titanium dioxide 15, calcium carbonate 24.7, process white 7.5, kaolin 7.5.
Its preparation method, comprises the following steps:
According to formula ratio, silicon sol is added in paint mixing cylinder A successively, stir with the speed of 400-600rpm, be warming up to 35-45 DEG C, slowly add stablizer, stir 15min with the speed of 400-600rpm;
According to formula ratio, slowly add lithium silicate and potassium silicate successively, stir 15min with the speed of 500-800rpm, obtain inorganic cementitious material at A cylinder, for subsequent use;
According to formula ratio, successively by deionized water, amine neutralizing agent, dispersion agent, defoamer, molecules surfactant, thickening material enters in paint mixing cylinder B, stirs 10 minutes with the speed of 800-1200rpm;
According to having filled a prescription, color stuffing being added in paint mixing cylinder B, improving the speed stirring 30min of mixing speed to 1200-1500rpm, measuring mill base fineness≤55 μm;
According to dosage, slowly inorganic cementitious material in paint mixing cylinder A is added in paint mixing cylinder B, 5 minutes are stirred with the speed of 800-1200rpm, add water-based emulsion, flow agent, stirs 5 minutes with the speed of 800-1200rpm, surveys initial viscosity, according to initial viscosity, the part thickening material adding formula ratio carries out being thickened to 25 DEG C, stormer viscosity meter 90KU.
Embodiment three
Water-based inner wall inorganic paint, according to weight, comprising:
Water-based emulsion 3, inorganic cementitious material 20, stablizer 2.0, deionized water 40, amine neutralizing agent 0.2, molecules surfactant 0.3, molecular antifoaming agent 0.5, dispersion agent 0.3, thickening material 0.8, flow agent 0.6, titanium dioxide 22.3, calcium carbonate 10.
Its preparation method, comprises the following steps:
According to formula ratio, silicon sol is added in paint mixing cylinder A successively, stir with the speed of 400-600rpm, be warming up to 35-45 DEG C, slowly add stablizer, stir 15min with the speed of 400-600rpm;
According to formula ratio, slowly add lithium silicate and potassium silicate successively, stir 15min with the speed of 500-800rpm, obtain inorganic cementitious material at A cylinder, for subsequent use;
According to formula ratio, successively by deionized water, amine neutralizing agent, dispersion agent, defoamer, molecules surfactant, thickening material enters in paint mixing cylinder B, stirs 10 minutes with the speed of 800-1200rpm;
According to having filled a prescription, color stuffing being added in paint mixing cylinder B, improving the speed stirring 30min of mixing speed to 1200-1500rpm, measuring mill base fineness≤55 μm;
According to dosage, slowly inorganic cementitious material in paint mixing cylinder A is added in paint mixing cylinder B, 5 minutes are stirred with the speed of 800-1200rpm, add water-based emulsion, flow agent, stirs 5 minutes with the speed of 800-1200rpm, surveys initial viscosity, according to initial viscosity, the part thickening material adding formula ratio carries out being thickened to 25 DEG C, stormer viscosity meter 80KU.
The all technical that table 1 interior wall inorganic paint records
The foregoing is only preferred embodiment of the present invention, is only illustrative for invention, and nonrestrictive.Those skilled in the art is understood, and can carry out many changes in the spirit and scope that invention claim limits to it, amendment, even equivalence, but all will fall within the scope of protection of the present invention.

Claims (10)

1. a water-based inner wall inorganic paint, it is characterized in that, be made up of following raw material ratio, by weight calculating: water-based emulsion 3-8, inorganic cementitious material 10-25, stablizer 0.5-2.5, deionized water 10-40, amine neutralizing agent 0.1-0.3, molecules surfactant 0.1-0.5, molecular antifoaming agent 0.2-0.6, dispersion agent 0.2-0.4, thickening material 0.5-1, flow agent 0.3-0.8, color stuffing 32.3-55.
2. water-based inner wall inorganic paint according to claim 1, it is characterized in that, be by weight: water-based emulsion 5.7, inorganic cementitious material 25, stablizer 2.5, deionized water 10, amine neutralizing agent 0.3, molecules surfactant 0.5, molecular antifoaming agent 0.2, dispersion agent 0.4, thickening material 1, flow agent 0.8, titanium dioxide 10, calcium carbonate 30, process white 7.5, kaolin 7.5;
Inorganic cementitious material comprises potassium 6.25, lithium silicate 6.25, silicon sol 12.5.
3. water-based inner wall inorganic paint according to claim 1, it is characterized in that, be by weight: water-based emulsion 8, inorganic cementitious material 10, stablizer 0.5, deionized water 35, amine neutralizing agent 0.1, molecules surfactant 0.1, molecular antifoaming agent 0.6, dispersion agent 0.2, thickening material 0.5, flow agent 0.3, titanium dioxide 15, calcium carbonate 24.7, process white 7.5, kaolin 7.5;
Inorganic cementitious material comprises potassium silicate 2.5, lithium silicate 2.5, silicon sol 5.
4. water-based inner wall inorganic paint according to claim 1, it is characterized in that, be by weight: water-based emulsion 3, inorganic cementitious material 20, stablizer 2.0, deionized water 40, amine neutralizing agent 0.2, molecules surfactant 0.3, molecular antifoaming agent 0.5, dispersion agent 0.3, thickening material 0.8, flow agent 0.6, titanium dioxide 22.3, calcium carbonate 10.
5. the water-based inner wall inorganic paint according to the arbitrary claim of claim 1-5, is characterized in that, described inorganic cementitious material is that lithium silicate potassium, silicon sol are wherein a kind of or composite according to a certain percentage.
6. water-based inner wall inorganic paint according to claim 5, it is characterized in that, inorganic cementitious material adopts potassium silicate, lithium silicate 1: 1 composite, the silicon sol that the employing γ-glycidyl ether propyl trimethoxy silicane of the quality such as rear interpolation is crossed as stabilizer treatment.
7. the water-based inner wall inorganic paint according to the arbitrary claim of claim 1-5, is characterized in that, described water-based emulsion be non-plasticizing based on ethylene and vinyl acetate copolymer water-dispersion emulsion; Defoamer is hub-and-spoke configuration molecular antifoaming agent.
8. water-based inner wall inorganic paint according to claim 7, is characterized in that, described dispersion agent is the anionic compound of polyphosphate and polyether phosphate system; Stablizer is Trimethoxy silane or derivatives thereof.
9. water-based inner wall inorganic paint according to claim 7, is characterized in that, described amine neutralizing agent is alcamines organism; Molecules surfactant is fatty alcohol-polyoxyethylene ether or its derivative; Thickening material be organic modified bentonite, pure Natvosol wherein one or both; Flow agent is fluorine-containing alcohol ether modified acrylate class flow agent; Color stuffing is that wherein one or several are composite for titanium dioxide, calcium carbonate, process white, kaolin.
10. a preparation method for water-based inner wall inorganic paint, is characterized in that, making processes is:
Step a, according to formula ratio, adds silicon sol in paint mixing cylinder A successively, stirs, be warming up to 35-45 DEG C, slowly add stablizer with the speed of 400-600rpm, stirs 15min with the speed of 400-600rpm;
Step b, according to formula ratio, slowly adds lithium silicate and potassium silicate successively, stirs 15min, obtain inorganic cementitious material at A cylinder with the speed of 500-800rpm, for subsequent use;
Step c according to formula ratio, successively by deionized water, amine neutralizing agent, dispersion agent, defoamer, molecules surfactant, thickening material enters in paint mixing cylinder B, stirs 10 minutes with the speed of 800-1200rpm;
Steps d, according to formula, adds in paint mixing cylinder B by color stuffing, improve the speed stirring 30min of mixing speed to 1200-1500rpm, measure mill base fineness≤55 μm;
Step e is according to dosage, slowly inorganic cementitious material in paint mixing cylinder A is added in paint mixing cylinder B, 5 minutes are stirred with the speed of 800-1200rpm, add water-based emulsion, flow agent, stirs 5 minutes with the speed of 800-1200rpm, surveys initial viscosity, according to initial viscosity, the part thickening material adding formula ratio carries out being thickened to 25 DEG C, stormer viscosity meter 80-100KU.
CN201510435893.7A 2015-07-22 2015-07-22 Aqueous internal wall inorganic coating and preparation method thereof Pending CN105130369A (en)

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Cited By (12)

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CN105694550A (en) * 2016-03-16 2016-06-22 陈威 Single-component waterborne inorganic terrace paint formula and manufacturing technology
CN105925024A (en) * 2016-05-11 2016-09-07 上海嘉柏丽实业有限公司 Inorganic mineral environment-friendly fire-retardant coating and preparation method thereof
CN106007633A (en) * 2016-05-24 2016-10-12 杨景松 Air-purification diatomite internal wall decoration powder paint and preparation method thereof
CN106893377A (en) * 2017-02-21 2017-06-27 河北晨阳工贸集团有限公司 A kind of interior wall sealing wax with air purification function and preparation method thereof
CN106905781A (en) * 2017-02-20 2017-06-30 河北晨阳工贸集团有限公司 Excellent color-adjustable base paint of color development and preparation method thereof
CN108587263A (en) * 2018-05-14 2018-09-28 青岛瑞利特新材料科技有限公司 A kind of graphene inorganic interior wall coating and preparation method thereof
CN111410552A (en) * 2020-04-30 2020-07-14 上海中南建筑材料有限公司 Fire-resistant aerogel thermal insulation coating and preparation method thereof
CN111439985A (en) * 2020-03-23 2020-07-24 石家庄市油漆厂 Inorganic interior wall coating and preparation method thereof
CN111619258A (en) * 2020-05-29 2020-09-04 乐凯医疗科技有限公司 Thermosensitive recording material and preparation method thereof
CN112300643A (en) * 2020-11-06 2021-02-02 河北嘉宝莉涂料有限公司 Fireproof and insect-proof interior wall coating and preparation method thereof
CN112759955A (en) * 2020-12-29 2021-05-07 广西经正涂料有限公司 Water-based inorganic primer for interior walls and preparation method thereof
CN114672179A (en) * 2022-03-16 2022-06-28 山东省泥博士新型材料有限公司 Preparation method of water-based inorganic egg gloss glaze

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105694550A (en) * 2016-03-16 2016-06-22 陈威 Single-component waterborne inorganic terrace paint formula and manufacturing technology
CN105925024A (en) * 2016-05-11 2016-09-07 上海嘉柏丽实业有限公司 Inorganic mineral environment-friendly fire-retardant coating and preparation method thereof
CN106007633A (en) * 2016-05-24 2016-10-12 杨景松 Air-purification diatomite internal wall decoration powder paint and preparation method thereof
CN106007633B (en) * 2016-05-24 2018-01-16 广东马斯柯新型建材有限公司 A kind of purification of air diatomite inner wall decoration powder coating and preparation method thereof
CN106905781A (en) * 2017-02-20 2017-06-30 河北晨阳工贸集团有限公司 Excellent color-adjustable base paint of color development and preparation method thereof
CN106893377A (en) * 2017-02-21 2017-06-27 河北晨阳工贸集团有限公司 A kind of interior wall sealing wax with air purification function and preparation method thereof
CN108587263A (en) * 2018-05-14 2018-09-28 青岛瑞利特新材料科技有限公司 A kind of graphene inorganic interior wall coating and preparation method thereof
CN111439985A (en) * 2020-03-23 2020-07-24 石家庄市油漆厂 Inorganic interior wall coating and preparation method thereof
CN111439985B (en) * 2020-03-23 2022-02-25 石家庄市油漆厂 Inorganic interior wall coating and preparation method thereof
CN111410552A (en) * 2020-04-30 2020-07-14 上海中南建筑材料有限公司 Fire-resistant aerogel thermal insulation coating and preparation method thereof
CN111619258A (en) * 2020-05-29 2020-09-04 乐凯医疗科技有限公司 Thermosensitive recording material and preparation method thereof
CN111619258B (en) * 2020-05-29 2021-10-19 乐凯医疗科技有限公司 Thermosensitive recording material and preparation method thereof
CN112300643A (en) * 2020-11-06 2021-02-02 河北嘉宝莉涂料有限公司 Fireproof and insect-proof interior wall coating and preparation method thereof
CN112759955A (en) * 2020-12-29 2021-05-07 广西经正涂料有限公司 Water-based inorganic primer for interior walls and preparation method thereof
CN112759955B (en) * 2020-12-29 2022-02-11 广西经正涂料有限公司 Water-based inorganic primer for interior walls and preparation method thereof
CN114672179A (en) * 2022-03-16 2022-06-28 山东省泥博士新型材料有限公司 Preparation method of water-based inorganic egg gloss glaze

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Application publication date: 20151209