CN103664023A - Surface treatment method for glass flake in preparation of glass flake coating - Google Patents
Surface treatment method for glass flake in preparation of glass flake coating Download PDFInfo
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- CN103664023A CN103664023A CN201310580633.XA CN201310580633A CN103664023A CN 103664023 A CN103664023 A CN 103664023A CN 201310580633 A CN201310580633 A CN 201310580633A CN 103664023 A CN103664023 A CN 103664023A
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Abstract
The invention relates to a surface treatment method for a glass flake in the preparation of a glass flake coating. The prepared glass flake coating relates to epoxy resin, talcum powder, thixotropic agent, titanium dioxide, pigment and the glass flake mixture, blending is carried in the preparation of the glass flake coating, wherein the glass flake mixture contains the glass flake and treating fluid, the treating fluid contains active diluting agent, coupling agent, flake directional arrangement agent and defoaming agent, the treating fluid used by per 100g of glass flake comprises the following ingredients by mass: 30.0-180.0g of active diluting agent, 0.6-12.0g of coupling agent, 0.6-12.0g of flake directional arrangement agent and 0.6-4.5g of defoaming agent. The surface treatment method has the characteristics of being short in time, and high in efficiency, the content of bubbles in the glass flake coating can be reduced, the formed coating film is parallel to a substrate metal, the diffusion path of a permeable medium can be prolonged, and the shielding property of the glass flake coating film can be improved.
Description
Technical field
The invention belongs to technical field of coatings, especially a kind of surface treatment method to glass flake while preparing glass-flake coating.
Background technology
It is glass flake structure that glass-flake coating can form multilayer chip structure after coating film forming in coating, and this structure can effectively extend the evolving path of corrosive medium in coating, thereby effectively delays the corrosion of base metal.Glass-flake coating utilizes These characteristics to obtain application more and more widely at weight corrosion-resistant fields such as boats and ships, metallurgy, petrochemical industry, offshore platforms.
But the wetting ability of glass flake is poor, in addition with the poor adhesion of epoxy resin, glass flake as undressed in direct employing is prepared glass-flake coating, the effect of its coating shield water vapour and corrosive medium will be poor, water vapour can produce on the surface of glass flake and resin epoxy infiltration, migration, thereby reduces impermeability and the solidity to corrosion of glass flake coatings.
At present the surface treatment of glass flake is mainly contained to following two kinds of modes:
One, with the epoxy resin that is mixed with coupling agent, glass flake is carried out to bulk treatment, but prepared glass-flake coating in use can produce water-intake rate and raise, cause producing that coating expands within the shorter military service phase, cracking and with the phenomenon such as ground desorption, shorten work-ing life of glass-flake coating;
Two, silane coupling agent is sprayed directly on the surface of glass flake and processes, make the surface treatment of glass flake inhomogeneous, easily cause the solidity to corrosion heterogeneity of its coating, differential expansion, cracking and failure phenomenon easily occurred in the military service phase.
In addition, aforesaid way is longer to the treatment time of glass flake, and production efficiency is low.
Summary of the invention
For addressing the above problem, the invention provides a kind of surface treatment method to glass flake while preparing glass-flake coating, this surface treatment method is short to the treatment time of glass flake, processing efficiency is high, extended the work-ing life of prepared glass-flake coating, greatly reduced the air bubble content in glass-flake coating, formation is filmed parallel with base metal, effectively extend the evolving path of permeating medium, improved the shielding properties of filming.
For achieving the above object, the present invention adopts following technical scheme:
A kind of surface treatment method to glass flake while preparing glass-flake coating, prepare glass-flake coating and relate to epoxy resin, talcum powder, thixotropic agent, titanium dioxide, pigment and glass flake mixture, prepare glass-flake coating routinely compounding process blend, but wherein said glass flake mixture contains glass flake and treatment solution, described treatment solution comprises reactive thinner, coupling agent, scale and aligns agent and deaerating agent; Feature of the present invention is as follows:
(1) described reactive thinner is the mixed solution containing reactive pattern thinner and non-response type thinner, described response type thinner or glycidyl ether, or petroleum resin modified dose; Described non-response type thinner or be any in varsol, alcoholic solvent, or its two kinds of combinations;
Above-mentioned glycidyl ether in (1) or be any in butylglycidyl ether, glycidyl allyl ether, 2-ethyl-hexyl glycidyl ether, methyl propenoic acid glycidyl ether, or its any two combination, or its any two above combination;
Above-mentioned in (1) petroleum resin modified dose adopts LR600;
Above-mentioned varsol in (1) or be any in toluene, dimethylbenzene, trimethylbenzene, or its any two combination, or its three kinds of combinations;
Above-mentioned alcoholic solvent in (1) or be propyl carbinol, phenylcarbinol, any in phenylethyl alcohol, or its any two combination, or its three kinds of combinations;
Above-mentioned (1) described in the quality configuration proportion of response type thinner and described non-response type thinner be controlled at: described response type thinner: described non-response type thinner=1～99:99～1;
(2) described coupling agent or be any in silane coupling agent, titanate coupling agent, or its two kinds of combinations;
Above-mentioned silane coupling agent in (2) or be γ-aminopropyl triethoxysilane, γ-(2,3-glycidoxy) any in propyl trimethoxy silicane, γ-propyl methacrylate base Trimethoxy silane, or its any two combination, or its three kinds of combinations;
Above-mentioned titanate coupling agent in (2) or be any in stearyl-titanic acid ester, hydroxyl vaccenic acid-9-acyl titanate, Witco 1298 Soft Acid acyl titanate, methacryloyl titanic acid ester, N-β-(aminoethyl)-β-ammonia ethanolato-titanium acid esters, sec.-propyl dimethoxy acryl diisooctyl pyrophosphoryl base titanic acid ester, different capryloyl titanic acid ester, diisooctyl pyrophosphoryl base titanic acid ester, diisooctyl phosphoryl titanic acid ester, diisooctyl pyrophosphoryl base titanic acid ester, or its any two combination, or its any two above combination;
Described scale align agent or for modified siloxane compounds, modification acrylate block interpolymers compounds, there is any in the interpolymer compounds of acidic-group, or its any two combination, or its three kinds of combinations;
(4) described deaerating agent or silicone based deaerating agent, or non-organic silicon polymer class deaerating agent, or organosilicon and polymer class deaerating agent;
Above-mentioned described silicone based deaerating agent in (4) adopts BYK-066N, BYK-067N that Bi Ke company produces, any in BYK-020, BYK-065, or its any two combination, or its any two above combination;
Above-mentioned described non-organic silicon polymer class deaerating agent in (4) adopts any in BYK-052, BYK-1752, BYK-A560, BYK-A550, BYK-054, BYK-A535 and the BYK-1790 that Bi Ke company produces, or its any two combination, or its any two above combination;
Above-mentioned described organosilicon in (4) and polymer class deaerating agent adopt BYK-A530, BYK-070 that Bi Ke company produces, any in BYK-085, or its any two combination, or its three kinds of combinations;
The described treatment solution that every 100g glass flake is used is as follows by its proportioning of mass parts:
Described reactive thinner 30.0～180.0g, described coupling agent 0.6～12.0g, described scale align agent 0.6～12.0g, described deaerating agent 0.6～4.5g;
100g glass flake is joined in the described treatment solution of said ratio and at room temperature stir 10min～1.5h and can obtain described glass flake mixture, in described glass flake mixture, compounding process adds epoxy resin, talcum powder, thixotropic agent, titanium dioxide and pigment just can prepare glass-flake coating routinely afterwards.
Described glass flake adopts RCF-016.
Described response type thinner and the preferred quality configuration proportion of described non-response type thinner are controlled at: described response type thinner: described non-response type thinner=1～9:9～1.
Described scale aligns any in BYK-110, BYK-111 that agent adopts Bi Ke company to produce, BYK-108, BYK-300, BYK-301, BYK-302, BYK-306, BYK-320, BYK-321, or its any two combination, or its any two above combination.
Described scale aligns any in Levaslip 411, Levaslip 432 that agent adopts this special chemical of hamming to produce, Levaslip 466, Levaslip 810, Levaslip 876, Levelol 835, Disponer 903, Disponer 904S, or its any two combination, or its any two above combination.
Guaranteeing described treatment solution under said ratio, it preferably forms and is:
Described reactive thinner is the mixed solution of dimethylbenzene, propyl carbinol and butylglycidyl ether, described coupling agent is γ-(2,3-glycidoxy) propyl trimethoxy silicane, it is modified siloxane and the composition with the interpolymer compounds of acidic-group that described scale aligns agent, and described deaerating agent is organosilicon and polymer class deaerating agent.
Owing to adopting technical scheme as mentioned above, the present invention produces following beneficial effect:
1, the invention solves the long problem of surface treatment problem, glass-flake coating preparation time cycle of glass flake, the problem such as the more and difficult froth breaking of air bubble content in the more mixed and disorderly problem of arrangement of glass flake and glass-flake coating.
2, the present invention can significantly reduce the surface treatment time of glass flake, owing to having reduced air bubble content and the formation in glass-flake coating, film parallel with base metal, thereby effectively extended the evolving path of permeating medium, on the basis of the shielding properties of filming in raising, improve the production efficiency of glass-flake coating, extended the work-ing life of glass-flake coating.
3, the present invention has shortened the glass flake surface-treated time, and processing efficiency is greatly improved.
Embodiment
The present invention is a kind of surface treatment method to glass flake while preparing glass-flake coating, this surface treatment method is the processing problem before preparing glass-flake coating mainly for glass flake, background technology surface treatment method of the present invention has the advantages that the time is short, efficiency is high relatively, the air bubble content and the formation that reduce in glass-flake coating are filmed parallel with base metal, extend the evolving path of permeating medium, improve the shielding properties of filming.
By the following examples, can explain in more detail the present invention, the present invention is not limited to the following examples, discloses object of the present invention and is intended to protect all changes and improvements in the scope of the invention.
Prepare glass-flake coating and relate to epoxy resin, talcum powder, thixotropic agent, titanium dioxide, pigment and glass flake mixture, prepare glass-flake coating routinely compounding process blend, the color of pigment and its colourity are determined voluntarily according to the requirement of base metal, but wherein described glass flake mixture of the present invention contains glass flake and treatment solution, described glass flake suggestion adopts RCF-016, and RCF-016 is that trade(brand)name Qie You NHTechno company produces.
Treatment solution of the present invention comprises reactive thinner, coupling agent, scale and aligns agent and deaerating agent:
(1) described reactive thinner is the mixed solution containing reactive pattern thinner and non-response type thinner, described response type thinner or glycidyl ether, or petroleum resin modified dose; Described non-response type thinner or be any in varsol, alcoholic solvent, or its two kinds of combinations.
Above-mentioned glycidyl ether in (1) or be any in butylglycidyl ether, glycidyl allyl ether, 2-ethyl-hexyl glycidyl ether, methyl propenoic acid glycidyl ether, or its any two combination, or its any two above combination.
The above any two combination or described any two above combinations and following two kinds of combinations or three kinds of combinations all do not comprise concrete proportioning, concrete proportioning is grasped voluntarily, such as 1:1 preparation is pressed in any two combinations, such as 1:1:1 preparation is pressed in any two above combinations, all the other separately do not explain it.
Above-mentioned in (1) petroleum resin modified dose adopts LR600, and LR600 is that trade(brand)name Qie You Johanna Lüttge company produces.
Above-mentioned varsol in (1) or be any in toluene, dimethylbenzene, trimethylbenzene, or its any two combination, or its three kinds of combinations.
Above-mentioned alcoholic solvent in (1) or be propyl carbinol, phenylcarbinol, any in phenylethyl alcohol, or its any two combination, or its three kinds of combinations.
Above-mentioned (1) described in the quality configuration proportion of response type thinner and described non-response type thinner be controlled at: described response type thinner: described non-response type thinner=1～99:99～1.
Described response type thinner and the preferred quality configuration proportion of described non-response type thinner are controlled at: described response type thinner: described non-response type thinner=1～9:9～1.
Take described response type thinner: described non-response type thinner=1～99:99～1 is example, the present invention's suggestion:
When described response type thinner get large value as 99 time as described in non-response type thinner get the small value as 1;
When non-response type thinner as described in described response type thinner gets the small value as 1 time is got large value as 99;
When described response type thinner get intermediate value as 50 time as described in non-response type thinner also get intermediate value as 50;
The total value that response type thinner described above adds described non-response type thinner is as the criterion with 100 mass parts, in like manner described response type thinner: described non-response type thinner=1～9:9～1 is as the criterion with 10 mass parts.
Described reactive thinner of the present invention is the mixed solution containing reactive pattern thinner and non-response type thinner, in described reactive thinner, add non-response type thinner not only to reduce the viscosity of described treatment solution, and effectively increased the wetting ability of described treatment solution to glass flake, can effectively reduce the viscosity of glass-flake coating, increase the wettability of glass flake to base metal, improve the sticking power of glass flake to base metal.
(2) described coupling agent or be any in silane coupling agent, titanate coupling agent, or its two kinds of combinations.
Above-mentioned silane coupling agent in (2) or be γ-aminopropyl triethoxysilane, γ-(2, 3-glycidoxy) propyl trimethoxy silicane, any in γ-propyl methacrylate base Trimethoxy silane, or its any two combinations, or its three kinds of combinations, wherein the reference commodity of γ-aminopropyl triethoxysilane are called KH-550, γ-(2, 3-glycidoxy) the reference commodity of propyl trimethoxy silicane KH-560 by name, the reference commodity KH-570 by name of γ-propyl methacrylate base Trimethoxy silane, KH-550, KH-560 and KH-570 produce by Nanjing dawn.
Above-mentioned titanate coupling agent in (2) or be stearyl-titanic acid ester, hydroxyl vaccenic acid-9-acyl titanate, Witco 1298 Soft Acid acyl titanate, methacryloyl titanic acid ester, N-β-(aminoethyl)-β-ammonia ethanolato-titanium acid esters, sec.-propyl dimethoxy acryl diisooctyl pyrophosphoryl base titanic acid ester, different capryloyl titanic acid ester, diisooctyl pyrophosphoryl base titanic acid ester, diisooctyl phosphoryl titanic acid ester, any in diisooctyl pyrophosphoryl base titanic acid ester, or its any two combinations, or combination more than its any two, above-mentioned have belong to monoalkoxytitanates class, what have belongs to phosphate type titanate ester, monoalkoxytitanates class and phosphate type titanate ester are all attributed to titanate coupling agent.
Described scale align agent or for modified siloxane compounds, modification acrylate block interpolymers compounds, there is any in the interpolymer compounds of acidic-group, or its any two combination, or its three kinds of combinations.
Above-mentioned described scale in (3) aligns any in BYK-110, BYK-111 that agent suggestion adopts Bi Ke company to produce, BYK-108, BYK-300, BYK-301, BYK-302, BYK-306, BYK-320, BYK-321, or its any two combinations, or combination more than its any two, the said products that Bi Ke company produces all belongs to the interpolymer compounds with acidic-group.
Above-mentioned described scale in (3) aligns any in Levaslip 411, Levaslip 432 that agent suggestion adopts this special chemical of hamming to produce, Levaslip 466, Levaslip 810, Levaslip 876, Levelol 835, Disponer 903, Disponer 904S, or its any two combinations, or combination more than its any two, the said products that this special chemical of hamming is produced all belongs to modified siloxane compounds or modification acrylate block interpolymers compounds.
Described scale aligns agent and has the wetting ability of the described treatment solution of improvement to glass flake surface, can also improve the dispersing property of glass flake in described treatment solution and coating, what is more important can improve the align ability of glass flake in filming, or make glass flake and base metal keeping parallelism, improve the ability of the resistance to various corrosive mediums of filming.
(4) described deaerating agent or silicone based deaerating agent, or non-organic silicon polymer class deaerating agent, or organosilicon and polymer class deaerating agent, above-mentioned three kind deaerating agents all can be bought in market.
Above-mentioned described silicone based deaerating agent suggestion in (4) adopts BYK-066N, BYK-067N that Bi Ke company produces, any in BYK-020, BYK-065, or its any two combination, or its any two above combination.
Above-mentioned described non-organic silicon polymer class deaerating agent suggestion in (4) adopts any in BYK-052, BYK-1752, BYK-A560, BYK-A550, BYK-054, BYK-A535 and the BYK-1790 that Bi Ke company produces, or its any two combination, or its any two above combination.
Above-mentioned described organosilicon in (4) and the suggestion of polymer class deaerating agent adopt BYK-A530, BYK-070 that Bi Ke company produces, any in BYK-085, or its any two combination, or its three kinds of combinations.
Described deaerating agent of the present invention can break bubble in time by the bubble producing in glass flake treating processes, on increase glass flake wetting ability basis, avoid its surface adsorption bubble and cause unnecessary surface treatment defect, improve glass flake surface-treated efficiency, shorten the treatment time.
Secondly, the present invention has just added deaerating agent in described treatment solution, not only can eliminate in advance a large amount of bubbles of glass flake surface adsorption, and in preparing glass-flake coating process, can greatly reduce the generation of bubbles volume, effectively avoid the surface imperfection of glass-flake coating generation when construction, greatly improve the shielding properties of coating.
After completing above-mentioned every preparation, the described treatment solution that every 100g glass flake is used is as follows by its proportioning of mass parts:
Described reactive thinner 30.0～180.0g, described coupling agent 0.6～12.0g, described scale align agent 0.6～12.0g, described deaerating agent 0.6～4.5g.
Guaranteeing described treatment solution under said ratio, it preferably forms and is:
Described reactive thinner is the mixed solution of dimethylbenzene, propyl carbinol and butylglycidyl ether, described coupling agent is γ-(2,3-glycidoxy) propyl trimethoxy silicane, it is modified siloxane and the composition with the interpolymer compounds of acidic-group that described scale aligns agent, and described deaerating agent is organosilicon and polymer class deaerating agent.
Guaranteeing that its preferred composition of described treatment solution under said ratio is:
Described reactive thinner is the mixed solution of dimethylbenzene, propyl carbinol and butylglycidyl ether, and described coupling agent is KH-560, and described scale aligns the combination that agent is Levaslip 432 and BYK-110, and described deaerating agent is BYK-085.
100g glass flake is joined in the described treatment solution of said ratio and at room temperature stir 10min～1.5h and can obtain described glass flake mixture, in described glass flake mixture, compounding process adds epoxy resin, talcum powder, thixotropic agent, titanium dioxide and pigment just can prepare glass-flake coating routinely afterwards.
In normal compound technology and with 30g glass flake, be as the criterion, in the described glass flake mixture of preparing after described treatment solution is processed, can add:
30g epoxy resin, 30g talcum powder, 1g thixotropic agent Ultra, 10g titanium dioxide and appropriate pigment can be prepared epoxy glass scale coating after 3000r/min high speed dispersion 45min.
If add all substances of said ratio and also can prepare epoxy glass scale coating through high speed dispersion and refinement in scuffing of cylinder bore.
Following table is to adopt different methods and by the present invention, is the contrast of 1 required material consumption of fundamental unit and preparation time.
| The present invention | Other method | |
| Deaerating agent add-on | 1 | 2～3 |
| Scale aligns agent add-on | 1 | 3～6 |
| Prepare glass-flake coating required time | 1 | 6～30 |
By upper table, can find out: the usage quantity that deaerating agent and scale align agent has all obtained minimizing, but
Prepare the required time of glass-flake coating and also shortened.
Glass-flake coating relatively seeing the following form in performance prepared by the glass-flake coating that the present invention is prepared after glass flake surface treatment and other method.
Claims (6)
1. the surface treatment method to glass flake while preparing glass-flake coating, prepare glass-flake coating and relate to epoxy resin, talcum powder, thixotropic agent, titanium dioxide, pigment and glass flake mixture, prepare glass-flake coating routinely compounding process blend, but wherein said glass flake mixture contains glass flake and treatment solution, described treatment solution comprises reactive thinner, coupling agent, scale and aligns agent and deaerating agent; It is characterized in that:
(1) described reactive thinner is the mixed solution containing reactive pattern thinner and non-response type thinner, described response type thinner or glycidyl ether, or petroleum resin modified dose; Described non-response type thinner or be any in varsol, alcoholic solvent, or its two kinds of combinations;
Above-mentioned glycidyl ether in (1) or be any in butylglycidyl ether, glycidyl allyl ether, 2-ethyl-hexyl glycidyl ether, methyl propenoic acid glycidyl ether, or its any two combination, or its any two above combination;
Above-mentioned in (1) petroleum resin modified dose adopts LR600;
Above-mentioned varsol in (1) or be any in toluene, dimethylbenzene, trimethylbenzene, or its any two combination, or its three kinds of combinations;
Above-mentioned alcoholic solvent in (1) or be propyl carbinol, phenylcarbinol, any in phenylethyl alcohol, or its any two combination, or its three kinds of combinations;
Above-mentioned (1) described in the quality configuration proportion of response type thinner and described non-response type thinner be controlled at: described response type thinner: described non-response type thinner=1～99:99～1;
(2) described coupling agent or be any in silane coupling agent, titanate coupling agent, or its two kinds of combinations;
Above-mentioned silane coupling agent in (2) or be γ-aminopropyl triethoxysilane, γ-(2,3-glycidoxy) any in propyl trimethoxy silicane, γ-propyl methacrylate base Trimethoxy silane, or its any two combination, or its three kinds of combinations;
Above-mentioned titanate coupling agent in (2) or be any in stearyl-titanic acid ester, hydroxyl vaccenic acid-9-acyl titanate, Witco 1298 Soft Acid acyl titanate, methacryloyl titanic acid ester, N-β-(aminoethyl)-β-ammonia ethanolato-titanium acid esters, sec.-propyl dimethoxy acryl diisooctyl pyrophosphoryl base titanic acid ester, different capryloyl titanic acid ester, diisooctyl pyrophosphoryl base titanic acid ester, diisooctyl phosphoryl titanic acid ester, diisooctyl pyrophosphoryl base titanic acid ester, or its any two combination, or its any two above combination;
Described scale align agent or for modified siloxane compounds, modification acrylate block interpolymers compounds, there is any in the interpolymer compounds of acidic-group, or its any two combination, or its three kinds of combinations;
(4) described deaerating agent or silicone based deaerating agent, or non-organic silicon polymer class deaerating agent, or organosilicon and polymer class deaerating agent;
Above-mentioned described silicone based deaerating agent in (4) adopts BYK-066N, BYK-067N that Bi Ke company produces, any in BYK-020, BYK-065, or its any two combination, or its any two above combination;
Above-mentioned described non-organic silicon polymer class deaerating agent in (4) adopts any in BYK-052, BYK-1752, BYK-A560, BYK-A550, BYK-054, BYK-A535 and the BYK-1790 that Bi Ke company produces, or its any two combination, or its any two above combination;
Above-mentioned described organosilicon in (4) and polymer class deaerating agent adopt BYK-A530, BYK-070 that Bi Ke company produces, any in BYK-085, or its any two combination, or its three kinds of combinations;
The described treatment solution that every 100g glass flake is used is as follows by its proportioning of mass parts:
Described reactive thinner 30.0～180.0g, described coupling agent 0.6～12.0g, described scale align agent 0.6～12.0g, described deaerating agent 0.6～4.5g;
100g glass flake is joined in the described treatment solution of said ratio and at room temperature stir 10min～1.5h and can obtain described glass flake mixture, in described glass flake mixture, compounding process adds epoxy resin, talcum powder, thixotropic agent, titanium dioxide and pigment just can prepare glass-flake coating routinely afterwards.
2. a kind of surface treatment method to glass flake while preparing glass-flake coating according to claim 1, is characterized in that: described glass flake adopts RCF-016.
3. a kind of surface treatment method to glass flake while preparing glass-flake coating according to claim 1, is characterized in that: described response type thinner and the preferred quality configuration proportion of described non-response type thinner are: described response type thinner: described non-response type thinner=1～9:9～1.
4. a kind of surface treatment method to glass flake while preparing glass-flake coating according to claim 1, it is characterized in that: described scale aligns any in BYK-110, BYK-111 that agent adopts Bi Ke company to produce, BYK-108, BYK-300, BYK-301, BYK-302, BYK-306, BYK-320, BYK-321, or its any two combination, or its any two above combination.
5. a kind of surface treatment method to glass flake while preparing glass-flake coating according to claim 1, it is characterized in that: described scale aligns any in Levaslip 411, Levaslip 432 that agent adopts this special chemical of hamming to produce, Levaslip 466, Levaslip 810, Levaslip 876, Levelol 835, Disponer 903, Disponer 904S, or its any two combination, or its any two above combination.
6. a kind of surface treatment method to glass flake while preparing glass-flake coating according to claim 1, is characterized in that: the preferred composition of described treatment solution is:
Described reactive thinner is the mixed solution of dimethylbenzene, propyl carbinol and butylglycidyl ether, described coupling agent is γ-(2,3-glycidoxy) propyl trimethoxy silicane, it is modified siloxane and the composition with the interpolymer compounds of acidic-group that described scale aligns agent, and described deaerating agent is organosilicon and polymer class deaerating agent.
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| CN107384118A (en) * | 2017-06-15 | 2017-11-24 | 东南大学 | Modified basalt scale solvent-free epoxy resin anticorrosive paint and preparation method thereof |
| CN110117449A (en) * | 2019-04-25 | 2019-08-13 | 首钢集团有限公司 | A kind of glass flake varnish and preparation method thereof |
| CN112608660A (en) * | 2020-12-04 | 2021-04-06 | 厦门双瑞船舶涂料有限公司 | Low-surface-treatment epoxy glass flake coating and preparation method thereof |
| CN113388312A (en) * | 2021-06-18 | 2021-09-14 | 中国船舶重工集团公司第七二五研究所 | High-performance ceramic-based epoxy modified organic silicon coating and preparation and application methods thereof |
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| CN105713472A (en) * | 2016-05-03 | 2016-06-29 | 青岛爱尔家佳新材料有限公司 | Water soluble damping coating with micro-binding damping structure and preparation method thereof |
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| CN110117449A (en) * | 2019-04-25 | 2019-08-13 | 首钢集团有限公司 | A kind of glass flake varnish and preparation method thereof |
| CN112608660A (en) * | 2020-12-04 | 2021-04-06 | 厦门双瑞船舶涂料有限公司 | Low-surface-treatment epoxy glass flake coating and preparation method thereof |
| CN112608660B (en) * | 2020-12-04 | 2022-07-19 | 厦门双瑞船舶涂料有限公司 | Low-surface-treatment epoxy glass flake coating and preparation method thereof |
| CN113388312A (en) * | 2021-06-18 | 2021-09-14 | 中国船舶重工集团公司第七二五研究所 | High-performance ceramic-based epoxy modified organic silicon coating and preparation and application methods thereof |
| CN113388312B (en) * | 2021-06-18 | 2022-07-08 | 中国船舶重工集团公司第七二五研究所 | High-performance ceramic-based epoxy modified organic silicon coating and preparation and application methods thereof |
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