CN104263146A - Water-soluble electroplating glazing oil and manufacturing method thereof - Google Patents
Water-soluble electroplating glazing oil and manufacturing method thereof Download PDFInfo
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- CN104263146A CN104263146A CN201410443229.2A CN201410443229A CN104263146A CN 104263146 A CN104263146 A CN 104263146A CN 201410443229 A CN201410443229 A CN 201410443229A CN 104263146 A CN104263146 A CN 104263146A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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Abstract
The invention discloses a water-soluble electroplating glazing oil and a manufacturing method thereof. The water-soluble electroplating glazing oil comprises the following components in percentage by weight: 32-35% of water-soluble acrylic resin, 15-17% of water-soluble amino resin, 5-8% of film formation assistant, 0.2-0.5% of neutralizer, 3-5% of adhesion promoter, 35-45% of deionized water, 0.3-1% of wetting and leveling agent and 0.2-0.5% of defoaming agent. The manufacturing method comprises the following steps: adding the water-soluble acrylic resin, water-soluble amino resin and adhesion promoter into a dispersion cylinder, dispersing at the speed of 550 rpm, adding the film formation assistant and neutralizer, and dispersing for 25-30 minutes until the resin solution is dispersed uniformly; regulating the speed of the dispersion machine to 700 rpm, adding the neutralizer and deionized water, and dispersing the resin solution again; adding the assistant, and stirring for 30-60 minutes until the resin solution is completely uniform; and adding the rest of deionized water, regulating the speed of the dispersion machine to 550 rpm, dispersing for 10-15 minutes, and regulating the viscosity and solid content. The product has the advantages of favorable glazing effect, high glossiness, favorable transparency, excellent acid resistance, excellent salt spray resistance and the like.
Description
Technical field
The present invention relates to a kind of five metals plate surface protecting materials and manufacture craft, be specifically related to a kind of water-soluble plating coating oil and preparation method thereof.
Background technology
Hardware industry now, people more and more focus on the perfection of product, and plating five metals parts out all can be used for not oxidized after the plating of protection five metals parts, variable color and getting rusty by the transparent coating oil of cover last layer.At present, market being used for the gloss oil of Lacquer finish is all with the coating oil of the production of resins oiliness of high acid value substantially.The condition of cure of its coating oil is baking 120 degree, and the time is 50 minutes.This product is owing to having a large amount of benzene classes and hazardous and noxious substances volatilization when producing and use.Irritating smell is large, and environmental pollution is serious, and the direct labor's of serious threat simultaneously is healthy, is unfavorable for shipping storage and safety in production.
And along with social development, people also improve constantly the protective awareness of living environment, environmental protection has been not only economic problems.But be related to the large problem of whole human survival.Hardware products is infiltration human lives one of product the most widely, naturally by society and people are paid close attention to, under this megatrend, makes great efforts pollution-free, the non-harmful green material of Application and Development and is determined to win.
Application number is in the Chinese patent of " 201310340346.1 ", disclose the patent of invention that name is called " a kind of Lacquer finish ink ", its technical scheme is as follows: in mass parts containing following composition: epoxy acrylic oligopolymer resin 35 ~ 50 mass parts, hexanediyl ester 10 ~ 15 mass parts, dibutyl phthalate 1 ~ 4 mass parts, trimethylol propane trimethyl propionic ester 15 ~ 30 mass parts, butyl glycol ether 10 ~ 20 mass parts, 2-hydroxyl-2-toluene acetone 5 ~ 10 mass parts, wax 2 ~ 4 mass parts, diethanolamine 1 ~ 4 mass parts, vinyl acetic monomer 25 ~ 30 mass parts, methyl-silicone oil 0.1 ~ 0.8 mass parts, pure water 10 ~ 15 mass parts.Lacquer finish ink provided by the invention, rub resistance, thermotolerance, resistance to adhesive are strong, prevent set-off and adhesion, and the Lacquer finish that can pile up, also there is not yellowing, low smelly advantage; But it contains " triphen " toxic ingredient such as dibutyl phthalate and 2-hydroxyl-2-toluene acetone, is unfavorable for storage and the use of product, meanwhile, easily causes the pollution to environment, do not reach the environmental requirement of product.
Application number is in the Chinese patent of " 201010557452.1 ", disclose the patent of invention that name is called " water-based gloss oil ", its technical scheme is as follows: formula comprises 15 ~ 30 parts, water, acrylate copolymer 10 ~ 20 parts, titanium dioxide 10 ~ 20 parts, huge sum of money stone flour 3 ~ 5 parts, water-ground limestone 5 ~ 15 parts, kaolin 3 ~ 5 parts, mica powder 3 ~ 5 parts, wetting dispersing agent 0.4 ~ 0.8 part, defoamer 0.3 ~ 0.4 part, flow agent 0.3 ~ 0.6 part, thickening material 0.5 ~ 2 part, multifunctional assistant 0.2 part, film coalescence aid 0.8 ~ 1 part, biocide mildewcide 0.8 ~ 2 part.Features such as although this product has at the bottom of environment-protecting asepsis, alkali resistant, mildew-resistant, solid underseal, cracking resistance, energy-conservation, fire-retardant, sound insulation, protection against the tide, leak stopping, strong adhesion, hardness are high, resistance to metal to-metal contact, but, its composition kind is too complicated, the bad control of content proportioning of each composition, thus product quality is affected in certain limit, simultaneously, its construction technology is too complicated, need the parameter of control many, the qualification rate being directed at product declines, and affects the production efficiency of product simultaneously.
Summary of the invention
In order to solve the problem, the invention discloses a kind of water-soluble plating coating oil and preparation method thereof, this product has the advantages such as polishing effect is good, glossiness is high, transparency is good, acidproof, salt spray resistance is excellent, and this product is nontoxic simultaneously, environmentally safe, meets environmental requirement.
A kind of water-soluble plating coating oil, raw material comprises following component (by weight percentage):
Water soluble acrylic resin 32-35, water soluble amino resin 15-17, film coalescence aid 5-8, adhesion promoter 3-5, neutralizing agent 0.2-0.5, deionized water 35-45, moistening flatting agent 0.3-1, defoamer 0.2-0.5.
Further, described water soluble amino resin is height methyl-etherified melamine resin, and described adhesion promoter is ADP.
Further, described film coalescence aid is two hexylene glycol monobutyl ether and propyl carbinols, and described flow agent is BYK333(modified organic silicon or acrylate).
Further, described neutralizing agent is dimethylethanolamine.
A making method for water-soluble plating coating oil, comprises following processing step:
(1) water soluble acrylic resin, water soluble amino resin and adhesion promoter are added to dispersion cylinder together, open dispersion machine, turn speed to 550 revs/min of dispersions;
(2) keep dispersing speed constant, and add film coalescence aid, dispersion 25-30 minute, until resin solution is uniformly dispersed;
(3) dispersing speed is adjusted to 700 revs/min, and adds neutralizing agent and portions of de-ionized water, resin solution is disperseed again;
(4) add auxiliary agent (moistening flatting agent, defoamer) respectively, after adding, stir 30-60 minute, until stir completely;
(5) add remaining deionized water, and dispersion machine is transferred to 550 revs/min, and disperse 10-15 minute, adjustment viscosity and solid part.
The invention has the advantages that: (1) this product, using water as solvent, in use only has moisture evaporation, does not pollute environment, and not containing benezene and hazardous and noxious substances.(2) this product is main body base-material with water soluble acrylic resin, is equipped with high light water soluble amino resin, make product spray polishing effect good, gloss is high, transparency good, acidproof, salt spray resistance is excellent, nondiscoloration, friction resistant; (3) this product is more energy-conservation, condition of cure be 100 degree 30 minutes, because of the time and energy consumption cost less, thus improve the production efficiency of product; (4) this product in use can direct spraying construction, and therefore, the construction technology of product is simple, in addition, and product cheap; (5) product does not have corrodibility, non-combustible, and product uses transport storage safety.
Embodiment
The invention discloses a kind of water-soluble plating coating oil and preparation method thereof, this product has the advantages such as polishing effect is good, glossiness is high, transparency is good, acidproof, salt spray resistance is excellent, and this product is nontoxic simultaneously, and environmentally safe, meets environmental requirement.
Be clearly and completely described to the technical scheme in the present invention below, obviously, described is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under the prerequisite of not making creative work, all belongs to the scope of protection of the invention.
Embodiment
In following examples, used raw material is commercially available, and when not illustrated especially, consumption unit is (kg).
A kind of water-soluble plating coating oil, raw material comprises following component (by weight percentage):
Water soluble acrylic resin 32-35, water soluble amino resin 15-17, film coalescence aid 5-8, adhesion promoter 3-5, deionized water 35-45, moistening flatting agent 0.3-1, defoamer 0.2-0.5, neutralizing agent 0.2-0.5.
Described water soluble acrylic resin is height methyl-etherified melamine resin, and described film coalescence aid is
Table 1
Embodiment 1
(1) 32 parts of water soluble acrylic resins, 15 parts of water soluble amino resins and 5 parts of adhesion promoters are added to dispersion cylinder together, open dispersion machine, turn speed to 550 revs/min of dispersions;
(2) keep dispersing speed constant, and add 5 parts of film coalescence aid and 0.2 part of neutralizing agent, disperse 25 minutes, until resin solution is uniformly dispersed;
(3) dispersing speed is adjusted to 700 revs/min, and adds 21 parts of deionized waters, resin solution is disperseed again;
(4) add auxiliary agent (0.5 part of moistening flatting agent, 0.3 part of defoamer) respectively, after adding, stir 45 minutes, until stir completely;
(5) add 21.2 parts of remaining deionized waters, and dispersing speed is transferred to 550 revs/min, and disperse 12 minutes, adjustment viscosity and solid part.
Embodiment 2
(1) 32 parts of water soluble acrylic resins, 16 parts of water soluble amino resins and 3 parts of adhesion promoters are added to dispersion cylinder together, open dispersion machine, turn speed to 550 revs/min of dispersions;
(2) keep dispersing speed constant, and add 5 parts of film coalescence aid and 0.2 part of neutralizing agent, disperse 28 minutes, until resin solution is uniformly dispersed;
(3) dispersing speed is adjusted to 700 revs/min, and adds 22 parts of deionized waters, resin solution is disperseed again;
(4) add auxiliary agent (0.8 part of moistening flatting agent, 0.2 part of defoamer) respectively, after adding, stir 40 minutes, until stir completely;
(5) add 21 parts of remaining deionized waters, and dispersing speed is transferred to 550 revs/min, and disperse 15 minutes, adjustment viscosity and solid part.
Embodiment 3
(1) 33 parts of water soluble acrylic resins, 16 parts of water soluble amino resins and 4 parts of adhesion promoters are added to dispersion cylinder together, open dispersion machine, turn speed to 550 revs/min of dispersions;
(2) keep dispersing speed constant, and add 5 parts of film coalescence aid and 0.3 part of neutralizing agent, disperse 30 minutes, until resin solution is uniformly dispersed;
(3) dispersing speed is adjusted to 700 revs/min, and adds 22 parts of deionized waters, resin solution is disperseed again;
(4) add auxiliary agent (0.8 part of moistening flatting agent, 0.3 part of defoamer) respectively, after adding, stir 45 minutes, until stir completely;
(5) add 18.9 parts of remaining deionized waters, and dispersing speed is transferred to 550 revs/min, and disperse 12 minutes, adjustment viscosity and solid part.
Embodiment 4
(1) 35 parts of water soluble acrylic resins, 16.3 parts of water soluble amino resins and 4 parts of adhesion promoters are added to dispersion cylinder together, open dispersion machine, turn speed to 550 revs/min of dispersions;
(2) keep dispersing speed constant, and add 8 parts of film coalescence aid, 0.3 part of neutralizing agent, disperse 25 minutes, until resin solution is uniformly dispersed;
(3) dispersing speed is adjusted to 700 revs/min, and adds 22 parts of deionized waters, resin solution is disperseed again;
(4) add auxiliary agent (1 part of moistening flatting agent, 0.5 part of defoamer) respectively, after adding, stir 40 minutes, until stir completely;
(5) add 14.2 parts of remaining deionized waters, and dispersing speed is transferred to 550 revs/min, and disperse 15 minutes, adjustment viscosity and solid part.
As follows with the correlated performance test index of the present embodiment product:
Known by above test item, the amount of solid content of this product all reaches the standard-required of client, and as can be seen from test result, the transparent dress liquid of this product form and aspect, therefore have higher clarity, and have higher sticking power, therefore the spraying effect of product is good; As can be seen from salt spray resistance and resistance to nitric acid test data, this product has higher acidproof and salt spray resistance, and in addition, the hardness of this product is higher, has good friction resistant performance.
Known by describing above, the invention has the advantages that: (1) this product, using water as solvent, in use only has moisture evaporation, does not pollute environment, and not containing benezene and hazardous and noxious substances.(2) this product is main body base-material with water soluble acrylic resin, is equipped with high light water soluble amino resin, make product spray polishing effect good, gloss is high, transparency good, acidproof, salt spray resistance is excellent, nondiscoloration, friction resistant; (3) this product is more energy-conservation, condition of cure be 100 degree 30 minutes, because of the time and energy consumption cost less, thus improve the production efficiency of product; (4) this product in use can direct spraying construction, and therefore, the construction technology of product is simple, in addition, and product cheap; (5) product does not have corrodibility, non-combustible, and product uses transport storage safety.
Above content is in conjunction with concrete preferred implementation further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, some simple deduction or replace can also be made, all should be considered as belonging to protection scope of the present invention.
Claims (5)
1. a water-soluble plating coating oil, is characterized in that, raw material comprises following component (by weight percentage):
Water soluble acrylic resin 32-35, water soluble amino resin 15-17, film coalescence aid 5-8, adhesion promoter 3-5, neutralizing agent 0.2-0.5, deionized water 35-45, moistening flatting agent 0.3-1, defoamer 0.2-0.5.
2. the water-soluble plating coating oil of one according to claim 1, is characterized in that, described water soluble amino resin is height methyl-etherified melamine resin, and described adhesion promoter is ADP.
3. the water-soluble plating coating oil of one according to claim 1, is characterized in that, described film coalescence aid is two hexylene glycol monobutyl ether and propyl carbinols, and described flow agent is BYK333(modified organic silicon or acrylate).
4. the water-soluble plating coating oil of one according to claim 1, is characterized in that, described neutralizing agent is dimethylethanolamine.
5. a making method for water-soluble plating coating oil, is characterized in that, comprises following processing step:
Water soluble acrylic resin, water soluble amino resin and adhesion promoter are added to dispersion cylinder together, open dispersion machine, turn speed to 550 revs/min of dispersions;
Keep dispersing speed constant, and add film coalescence aid and neutralizing agent, dispersion 25-30 minute, until resin solution is uniformly dispersed;
Dispersing speed is adjusted to 700 revs/min, and adds portions of de-ionized water, resin solution is disperseed again;
Add auxiliary agent (moistening flatting agent, defoamer) respectively, after adding, stir 30-60 minute, until stir completely;
Add remaining deionized water, and dispersion machine is transferred to 550 revs/min, and disperse 10-15 minute, adjustment viscosity and solid part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410443229.2A CN104263146A (en) | 2014-09-02 | 2014-09-02 | Water-soluble electroplating glazing oil and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410443229.2A CN104263146A (en) | 2014-09-02 | 2014-09-02 | Water-soluble electroplating glazing oil and manufacturing method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105670465A (en) * | 2016-02-02 | 2016-06-15 | 中山市柏顿涂料有限公司 | Waterborne overprinting varnish for tin-plated electric cooker casing and preparation method of waterborne overprinting varnish |
| CN106010009A (en) * | 2016-07-08 | 2016-10-12 | 英德市邦士化工实业有限公司 | Environment-friendly water-based gloss oil |
| CN106634288A (en) * | 2016-09-22 | 2017-05-10 | 佛山市美联涂料有限公司 | Waterborne industrial paint |
| CN110903728A (en) * | 2019-12-17 | 2020-03-24 | 湖北和乐门业有限公司 | Ink migration resistant water-based varnish for transfer steel door and preparation method thereof |
| CN111234631A (en) * | 2020-03-12 | 2020-06-05 | 上海安美特铝业有限公司 | High-tolerance water-based gloss oil for aluminum products and preparation method thereof |
| CN111454656A (en) * | 2020-04-29 | 2020-07-28 | 杭州临安兴旺电镀有限公司 | Environment-friendly electroplating paint and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5955063A (en) * | 1997-01-03 | 1999-09-21 | Brody; Donald E. | Water-based fingernail coating |
| CN102618133A (en) * | 2012-03-31 | 2012-08-01 | 广州集泰化工有限公司 | High-temperature resistant and strong corrosive resistant water-based baking varnish for metal and preparation method for baking varnish |
-
2014
- 2014-09-02 CN CN201410443229.2A patent/CN104263146A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5955063A (en) * | 1997-01-03 | 1999-09-21 | Brody; Donald E. | Water-based fingernail coating |
| CN102618133A (en) * | 2012-03-31 | 2012-08-01 | 广州集泰化工有限公司 | High-temperature resistant and strong corrosive resistant water-based baking varnish for metal and preparation method for baking varnish |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105670465A (en) * | 2016-02-02 | 2016-06-15 | 中山市柏顿涂料有限公司 | Waterborne overprinting varnish for tin-plated electric cooker casing and preparation method of waterborne overprinting varnish |
| CN106010009A (en) * | 2016-07-08 | 2016-10-12 | 英德市邦士化工实业有限公司 | Environment-friendly water-based gloss oil |
| CN106634288A (en) * | 2016-09-22 | 2017-05-10 | 佛山市美联涂料有限公司 | Waterborne industrial paint |
| CN110903728A (en) * | 2019-12-17 | 2020-03-24 | 湖北和乐门业有限公司 | Ink migration resistant water-based varnish for transfer steel door and preparation method thereof |
| CN111234631A (en) * | 2020-03-12 | 2020-06-05 | 上海安美特铝业有限公司 | High-tolerance water-based gloss oil for aluminum products and preparation method thereof |
| CN111454656A (en) * | 2020-04-29 | 2020-07-28 | 杭州临安兴旺电镀有限公司 | Environment-friendly electroplating paint and preparation method thereof |
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