CN104817946A - Single-component water-based wood paint - Google Patents
Single-component water-based wood paint Download PDFInfo
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- CN104817946A CN104817946A CN201510249728.2A CN201510249728A CN104817946A CN 104817946 A CN104817946 A CN 104817946A CN 201510249728 A CN201510249728 A CN 201510249728A CN 104817946 A CN104817946 A CN 104817946A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a single-component water-based wood paint which comprises the following components in parts by weight: 30-40 parts of water-based epoxy modified polyurethane emulsion, 30-40 parts of water-based acrylic resin, 2-30 parts of filler, 1-6 parts of nano aluminum dioxide, 0.1-1.0 part of wetting agent, 1-5 parts of dispersing agent, 0.1-0.5 part of defoaming agent, 1-6 parts of film-forming assistant and the balance of water. The water-based acrylic resin is a hydroxy acrylic resin in which the mass content of hydroxy group is 0-2-0.4 part. The film-forming assistant is prepared by mixing the following components in parts by weight: 60-90 parts of tripropylene glycol monobutyl ether and 10-40 parts of alcohol ester-12. The single-component water-based wood paint has the advantages of excellent water resistance, excellent wear resistance, excellent adhesive force, favorable film effect, high film hardness, high drying speed and low cost.
Description
Technical field
The present invention relates to technical field of aqueous paint, be specifically related to mono-component aqueous woodwork coating.
Background technology
Water-borne wood coating has environmental protection, energy-conservation, safety, without advantages such as Health hazards, under the overall situation advocating environmental protection at present, its advantage is further obvious.Current water-borne wood coating on the market has the broad variety such as mono-component aqueous alkydpaints, acrylic coating, aqueous polyurethane coating, waterborne polyurethane modified acrylic coating, aqueous epoxy coating, but it is low all to there is hardness of film, the film effect problems such as solid content is low, poor solvent resistance.Bicomponent polyurethane coating can reach good paint film effect, but price is higher, and use range is limited.The water-borne coatings of development high-performance and low-cost is the important topic of current water-borne coatings research field.
Summary of the invention
The object of the invention is the defect existed to overcome prior art, provide a kind of mono-component aqueous woodwork coating, have excellent water tolerance, wear resistance, sticking power, film effect is good, and hardness of film is high, fast drying, and cost is low.
The present invention also provides the preparation method of mono-component aqueous woodwork coating.
In order to realize object of the present invention, the present invention by the following technical solutions:
A kind of mono-component aqueous woodwork coating, it comprises the component of following weight part:
Wherein in an embodiment, described mono-component aqueous woodwork coating comprises the component of following weight part:
Wherein in an embodiment, described mono-component aqueous woodwork coating comprises the component of following weight part:
Wherein in an embodiment, described mono-component aqueous woodwork coating comprises the component of following weight part:
Wherein in an embodiment, described film coalescence aid is mixed by the component of following weight part: tripropylene glycol butyl ether 60%-90%, alcohol ester-12 10%-40%.
Wherein in an embodiment, described water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.2%-0.4%.
Wherein in an embodiment, the solid content of described waterborne epoxy modified polyaminoester emulsion is greater than 40%.
Wherein in an embodiment, the solid content of described water-borne acrylic resin is greater than 40%.
Wherein in an embodiment, described anti-settling agent is the water-based anti-settling agent of model XH-301.
Wherein in an embodiment, described wetting agent is polyether-modified dimethyl siloxane series wetting agent; Described dispersion agent is vinylformic acid sodium salt Series Dispersant; Described defoamer is aqueous mineral oil defoamer.
Mono-component aqueous woodwork coating of the present invention, its beneficial effect is compared to existing technology:
1) the present invention adopts epoxy modified aqueous urethane as resin, there is high glass transition temperature, aqueous polyurethane dispersion itself is block polymer, there is the hard segment that the soft chain segment of ether chain and ester chain formation and isocyanic ester etc. are formed, soft chain segment makes film have good elongation, elasticity, low film-forming temperature, hard section makes resin have higher second-order transition temperature, such that hardness of film is high, intensity good; The cohesive force that recycling epoxy resin is outstanding, the advantages such as excellent water tolerance, wear resistance and sticking power, in conjunction with acrylic resin fast drying, the features such as base material wetting effect is good, this onepot coating is had, and hardness is high, the advantage of solvent resistance, good heat resistance; Nanometer titanium dioxide aluminium add the mechanical property that effectively can improve film, strengthen film scratch resistance performance; On the whole, this coating, with lower cost, achieves good film performance.
2) mix the use of film coalescence aid and make the minimum auxiliary agent of this formula, reduce the film-forming temperature of film efficiently, coating in film forming under comparatively low temperature, can be able to be reduced costs again.
Embodiment
For feature of the present invention, technique means and the specific purposes reached, function can be understood further, below in conjunction with embodiment, the present invention is described in further detail.
Mono-component aqueous woodwork coating of the present invention, comprises the component of following weight part:
Further, described mono-component aqueous woodwork coating, comprises the component of following weight part:
Wherein, film coalescence aid can be mixed by the component of following weight part: tripropylene glycol butyl ether 60%-90%, alcohol ester-12 10%-40%; Tripropylene glycol methyl ether 60%-90%, DALPAD D 10%-40%; Tripropylene glycol methyl ether 60%-90%, tripropylene glycol butyl ether 10%-40%; DALPAD H 20%-50%; Propylene glycol 50%-80%; Butyl and ethylene glycol are with the ratio compound of 3:1; Propandiol butyl ether and butyl are with the ratio compound of 2:1;
Or: the DALPAD H of single component; DALPAD D; DALPAD C; Propylene glycol monomethyl ether; Propandiol butyl ether etc.
Waterborne epoxy modified polyaminoester emulsion is purchased from cloud Qinghua, Yantai work, and solid content is greater than 40%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.2%-0.4%, and the solid content of water-borne acrylic resin is greater than 40%.
Further again, described mono-component aqueous woodwork coating, comprises the component of following weight part:
Wherein, film coalescence aid is mixed by the component of following weight part: tripropylene glycol butyl ether 60%-90%, alcohol ester-12 10%-40%; Waterborne epoxy modified polyaminoester emulsion is purchased from cloud Qinghua, Yantai work, and solid content is greater than 40%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.2%-0.4%, and the solid content of water-borne acrylic resin is greater than 40%.
Anti-settling agent is the water-based anti-settling agent of model XH-301; Wetting agent is Bi Ke company polyether-modified dimethyl siloxane series wetting agent; Dispersion agent is high Supreme Being Si company vinylformic acid sodium salt Series Dispersant; Defoamer is Bi Ke company aqueous mineral oil defoamer; PH adjusting agent is Tao Shi AMP-95.
Above-mentioned filler talcum powder, calcium carbonate, nanometer titanium dioxide aluminium are domestic, and granularity is respectively 325 orders, 800 orders, 1250 orders.
In this formula, epoxy modified aqueous urethane is as resin, there is high glass transition temperature, aqueous polyurethane dispersion itself is block polymer, there is the hard segment that the soft chain segment of ether chain and ester chain formation and isocyanic ester etc. are formed, soft chain segment makes film have good elongation, elasticity, low film-forming temperature, and hard section makes resin have higher second-order transition temperature, such that hardness of film is high, intensity good; The cohesive force that recycling epoxy resin is outstanding, the advantages such as excellent water tolerance, wear resistance and sticking power, in conjunction with acrylic resin fast drying, the features such as base material wetting effect is good, rational proportion between filmogen, this onepot coating is had, and hardness is high, the advantage of solvent resistance, good heat resistance, while reaching this effect, as far as possible with minimum raw material, reach the object reduced costs.As not having rational proportion between various raw material, dispersion system too much may be caused uneven because of raw material, film effect does not reach the defects such as requirement.
Provide several specific embodiment more below.
Embodiment 1:
Mono-component aqueous woodwork coating of the present invention, comprises the component of following weight part:
Wherein, film coalescence aid is mixed by the component of following weight part: tripropylene glycol butyl ether 80%, alcohol ester-12 20%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.4%.
Waterborne epoxy modified polyaminoester emulsion is purchased from cloud Qinghua, Yantai work, and solid content is greater than 40%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.4%, and the solid content of water-borne acrylic resin is greater than 40%.
Anti-settling agent is the water-based anti-settling agent of model XH-301; Wetting agent is Bi Ke company polyether-modified dimethyl siloxane series wetting agent; Dispersion agent is high Supreme Being Si company vinylformic acid sodium salt Series Dispersant; Defoamer is Bi Ke company aqueous mineral oil defoamer; PH adjusting agent is Tao Shi AMP-95.
Above-mentioned filler talcum powder, calcium carbonate, nanometer titanium dioxide aluminium are domestic, and granularity is respectively 325 orders, 800 orders, 1250 orders.
The method utilizing this formula to prepare above-mentioned mono-component aqueous woodwork coating is:
Water, talcum powder, calcium carbonate, nanometer titanium dioxide aluminium, wetting agent, dispersion agent and defoamer, anti-settling agent are mixed, dispersed with stirring, obtains slurry; In this slurry, add waterborne epoxy modified polyaminoester emulsion, water-borne acrylic resin and film coalescence aid, dispersed with stirring, obtain finished product, add pH adjusting agent adjust ph to 7-8.
Embodiment 2:
As different from Example 1, mono-component aqueous woodwork coating of the present invention, comprises the component of following weight part:
Wherein, film coalescence aid is mixed by the component of following weight part: tripropylene glycol butyl ether 60 parts, alcohol ester-12 40 parts; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.2 part.
Waterborne epoxy modified polyaminoester emulsion solid content is greater than 40%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.2%, and the solid content of water-borne acrylic resin is greater than 40%.
Anti-settling agent is organobentonite; Wetting agent is polyoxyethylene alkanisation ethers wetting agent; Dispersion agent is high Supreme Being Si company vinylformic acid sodium salt Series Dispersant; Defoamer is Bi Ke company aqueous mineral oil defoamer; PH adjusting agent is disodium bicarbonate.
Above-mentioned filler talcum powder, calcium carbonate, nanometer titanium dioxide aluminium are domestic, and granularity is respectively 300 orders, 600 orders, 1000 orders.
Embodiment 3:
As different from Example 1, mono-component aqueous woodwork coating of the present invention, comprises the component of following weight part:
Wherein, film coalescence aid is mixed by the component of following weight part: tripropylene glycol butyl ether 90%, alcohol ester-12 10%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.3%.
Waterborne epoxy modified polyaminoester emulsion is purchased from cloud Qinghua, Yantai work, and solid content is greater than 40%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.4%, and the solid content of water-borne acrylic resin is greater than 40%.
Anti-settling agent is the YH-C water-based anti-settling agent of Jinan Hai De Chemical Co., Ltd.; Wetting agent is Nekal BX; Dispersion agent is high Supreme Being Si company vinylformic acid sodium salt Series Dispersant; Defoamer is Bi Ke company aqueous mineral oil defoamer; PH adjusting agent is Tao Shi AMP-95.
Above-mentioned filler talcum powder, calcium carbonate, nanometer titanium dioxide aluminium are domestic, and granularity is respectively 350 orders, 800 orders, 1000 orders.
Embodiment 4:
As different from Example 1, mono-component aqueous woodwork coating of the present invention, comprises the component of following weight part:
Wherein, film coalescence aid is mixed by the component of following weight part: tripropylene glycol butyl ether 70%, alcohol ester-12 30%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.2%.
Waterborne epoxy modified polyaminoester emulsion is purchased from cloud Qinghua, Yantai work, and solid content is greater than 40%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.4%, and the solid content of water-borne acrylic resin is greater than 40%.
Anti-settling agent adopts the water-based anti-settling agent of model XH-301; Wetting agent adopts Bi Ke company polyether-modified dimethyl siloxane series wetting agent; Dispersion agent adopts high Supreme Being Si company vinylformic acid sodium salt Series Dispersant; Defoamer adopts polydimethylsiloxane; PH adjusting agent is Tao Shi AMP-95.
Above-mentioned filler talcum powder, calcium carbonate, nanometer titanium dioxide aluminium are domestic, and granularity is respectively 300 orders, 600 orders, 1250 orders.
Embodiment 5:
As different from Example 1, mono-component aqueous woodwork coating of the present invention, comprises the component of following weight part:
Wherein, film coalescence aid by tripropylene glycol methyl ether 60%, DALPAD D 40% is composite forms.
Waterborne epoxy modified polyaminoester emulsion is purchased from cloud Qinghua, Yantai work, and solid content is greater than 40%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.3%, and the solid content of water-borne acrylic resin is greater than 40%.
Anti-settling agent adopts polyamide wax series anti-settling agent; Wetting agent is Bi Ke company polyether-modified dimethyl siloxane series wetting agent; Dispersion agent adopts Tristearoylglycerol class dispersion agent; Defoamer is Bi Ke company aqueous mineral oil defoamer; PH adjusting agent adopts disodium bicarbonate.
Above-mentioned filler talcum powder, calcium carbonate, nanometer titanium dioxide aluminium are domestic, and granularity is respectively 325 orders, 800 orders, 1250 orders.
Embodiment 6:
As different from Example 1, mono-component aqueous woodwork coating of the present invention, comprises the component of following weight part:
Wherein, film coalescence aid is tripropylene glycol methyl ether 70%, DALPAD H 30% is composite forms.
Waterborne epoxy modified polyaminoester emulsion is purchased from cloud Qinghua, Yantai work, and solid content is greater than 40%; Water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.3%, and the solid content of water-borne acrylic resin is greater than 40%.
Anti-settling agent adopts polyamide wax series anti-settling agent; Wetting agent is Bi Ke company polyether-modified dimethyl siloxane series wetting agent; Dispersion agent adopts Tristearoylglycerol class dispersion agent; Defoamer is Bi Ke company aqueous mineral oil defoamer; PH adjusting agent adopts Tao Shi AMP-95.
Above-mentioned filler talcum powder, calcium carbonate, nanometer titanium dioxide aluminium are domestic, and granularity is respectively 250 orders, 800 orders, 1200 orders.
According to mono-component aqueous woodwork coating of the present invention, the coating be made into and common mono-component aqueous woodwork coating contrast, and verify advance of the present invention.
Comparative example 1
Single component woodwork coating formula 1 more general at present, comprises the component of following weight part:
Comparative example 2
Single component woodwork coating formula 2 more general at present, comprises the component of following weight part:
Detect the coating properties of above-mentioned comparative example and embodiment 1 ~ embodiment 3 respectively, comparing result is as table one.
Table one
As can be seen from Table I, mono-component aqueous woodwork coating of the present invention, relative to the acrylic coating of prior art, good film effect, excellent water tolerance, wear resistance, sticking power and higher hardness, and the dried coating film time (surface drying time) is far below such coating existing.
The above embodiment only have expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (10)
1. a mono-component aqueous woodwork coating, is characterized in that, comprises the component of following weight part:
2. mono-component aqueous woodwork coating according to claim 1, is characterized in that, comprises the component of following weight part:
3. mono-component aqueous woodwork coating according to claim 2, is characterized in that, comprises the component of following weight part:
4. the mono-component aqueous woodwork coating according to any one of claims 1 to 3, is characterized in that, comprises the component of following weight part:
5. the mono-component aqueous woodwork coating according to any one of claims 1 to 3, is characterized in that, described film coalescence aid is mixed by the component of following weight part: tripropylene glycol butyl ether 60%-90%, alcohol ester-12 10%-40%.
6. the mono-component aqueous woodwork coating according to any one of claims 1 to 3, is characterized in that, described water-borne acrylic resin is Hydroxylated acrylic resin, and wherein the mass content of hydroxyl is 0.2%-0.4%.
7. mono-component aqueous woodwork coating according to claim 6, is characterized in that, the solid content of described waterborne epoxy modified polyaminoester emulsion is greater than 40%.
8. the mono-component aqueous woodwork coating according to any one of claims 1 to 3, is characterized in that, the solid content of described water-borne acrylic resin is greater than 40%.
9. the mono-component aqueous woodwork coating according to any one of claims 1 to 3, is characterized in that, described anti-settling agent is the water-based anti-settling agent of model XH-301.
10. the mono-component aqueous woodwork coating according to any one of claims 1 to 3, is characterized in that, described wetting agent is polyether-modified dimethyl siloxane series wetting agent; Described dispersion agent is vinylformic acid sodium salt Series Dispersant; Described defoamer is aqueous mineral oil defoamer.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510249728.2A CN104817946A (en) | 2015-05-14 | 2015-05-14 | Single-component water-based wood paint |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510249728.2A CN104817946A (en) | 2015-05-14 | 2015-05-14 | Single-component water-based wood paint |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647362A (en) * | 2016-04-12 | 2016-06-08 | 湖州新奥克化工有限公司 | High-durability high-efficiency nano antimicrobial water-based wood paint and preparation method thereof |
| CN106675262A (en) * | 2016-12-20 | 2017-05-17 | 东来涂料技术（上海）有限公司 | Safe eco-friendly waterborne hot foil die-stamping primer used for plastic part and preparation method of primer |
| CN106893468A (en) * | 2017-03-30 | 2017-06-27 | 木涂（深圳）化工科技有限公司 | Water-borne wood coating and preparation method thereof |
| CN107312422A (en) * | 2015-11-24 | 2017-11-03 | 三棵树涂料股份有限公司 | Water-borne wood coating containing modified polyurethane emulsion and preparation method thereof |
| CN106433440B (en) * | 2016-11-29 | 2018-06-01 | 滁州市瑞景园林建设有限公司 | A kind of fire resistant water-based coating |
| CN108912774A (en) * | 2018-06-28 | 2018-11-30 | 湖南冠艺家居股份有限公司 | It is covered with the wood furniture and its manufacturing method of paint film |
| CN111826070A (en) * | 2020-07-31 | 2020-10-27 | 马鞍山市金韩防水保温工程有限责任公司 | Wear-resistant water-based paint and preparation method thereof |
| CN112094548A (en) * | 2020-05-27 | 2020-12-18 | 慧瑞环保涂料(上海)有限公司 | Sanding-free hot-pressing type coating |
| AU2021204656A1 (en) * | 2020-12-16 | 2022-06-30 | Changzhou Bemate Home Technology Co., Ltd. | Scratch-resistant floor and method for producing same, and floor coating |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107312422A (en) * | 2015-11-24 | 2017-11-03 | 三棵树涂料股份有限公司 | Water-borne wood coating containing modified polyurethane emulsion and preparation method thereof |
| CN105647362A (en) * | 2016-04-12 | 2016-06-08 | 湖州新奥克化工有限公司 | High-durability high-efficiency nano antimicrobial water-based wood paint and preparation method thereof |
| CN106433440B (en) * | 2016-11-29 | 2018-06-01 | 滁州市瑞景园林建设有限公司 | A kind of fire resistant water-based coating |
| CN106675262A (en) * | 2016-12-20 | 2017-05-17 | 东来涂料技术（上海）有限公司 | Safe eco-friendly waterborne hot foil die-stamping primer used for plastic part and preparation method of primer |
| CN106893468A (en) * | 2017-03-30 | 2017-06-27 | 木涂（深圳）化工科技有限公司 | Water-borne wood coating and preparation method thereof |
| CN106893468B (en) * | 2017-03-30 | 2019-07-16 | 惠州市臻旺新材料有限公司 | Water-borne wood coating and preparation method thereof |
| CN108912774A (en) * | 2018-06-28 | 2018-11-30 | 湖南冠艺家居股份有限公司 | It is covered with the wood furniture and its manufacturing method of paint film |
| CN112094548A (en) * | 2020-05-27 | 2020-12-18 | 慧瑞环保涂料(上海)有限公司 | Sanding-free hot-pressing type coating |
| CN111826070A (en) * | 2020-07-31 | 2020-10-27 | 马鞍山市金韩防水保温工程有限责任公司 | Wear-resistant water-based paint and preparation method thereof |
| AU2021204656A1 (en) * | 2020-12-16 | 2022-06-30 | Changzhou Bemate Home Technology Co., Ltd. | Scratch-resistant floor and method for producing same, and floor coating |
| AU2021204656B2 (en) * | 2020-12-16 | 2022-07-21 | Changzhou Bemate Home Technology Co., Ltd. | Scratch-resistant floor and method for producing same, and floor coating |
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