CN104293167B - The high rigidity of a kind of PVC floor tile, high glaze ultraviolet-curing paint - Google Patents
The high rigidity of a kind of PVC floor tile, high glaze ultraviolet-curing paint Download PDFInfo
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- CN104293167B CN104293167B CN201410584676.XA CN201410584676A CN104293167B CN 104293167 B CN104293167 B CN 104293167B CN 201410584676 A CN201410584676 A CN 201410584676A CN 104293167 B CN104293167 B CN 104293167B
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- ultraviolet
- floor tile
- pvc floor
- curing paint
- high rigidity
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention relates to paint field, particularly relate to the high rigidity of a kind of PVC floor tile, high glaze ultraviolet-curing paint, it is characterised in that be prepared from by the raw material of following mass percent: aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture: 30% ~ 45%；Graphitization nano carbon fiber: 3 5%；Initiator: 5% ~ 12%；Surface modifier: 1% ~ 3%；Cosolvent: 5% ~ 10%；Reactive diluent: 10% ~ 20%；Polyacrylate or organosilicon levelling agent: 1% ~ 2%；Atent solvent: 10% ~ 30%；Pigment: 0% ~ 2%.While the present invention possesses high rigidity, high tenacity, high glaze performance, also there is higher salt fog resistance, resistance to ag(e)ing, wearability, scratch resistance, adhesive force, cold-and-heat resistent impact capacity.
Description
Technical field
The present invention relates to paint field, particularly relate to the high rigidity of a kind of PVC floor tile, high glaze ultraviolet-curing paint.
Background technology
Ultraviolet-curing paint is since coming out, because it has the feature of 5E, i.e. efficiently (Efficient), applicable wide (Enabling), economical (Economical), energy-conservation (Energy Saying), environmental friendliness (Environmental-friendly).In the prior art, ultraviolet-curing paint has been widely used in by people and has lived closely bound up field, beautifies object and the effect of protection object to play.
Materials for construction is the nova risen up slowly in building materials industry, swift and violent along with China's real estate in recent years increases, to infrastructure input increasing, the materials for construction of China had become in plastic industry the second largest pillar industry being only second to packaging already, and average annual growth rate is more than 15%.In recent years, Chinese Plastics building material industry accelerated research and development and popularization and application paces, and industry production scale constantly expands, and technical merit steadily improves.
PVC floor tile, compared to tradition floor tile, has the characteristic such as low cost, environment-friendly and green, is the most gradually welcome by people, become the typical development projects in materials for construction.
Coating can effectively protect PVC tile surface not to be corroded, thus extends the service life of PVC floor tile, and PVC floor tile seems more attractive in appearance under the covering with paint of coating in addition.But existing general PVC floor tile coating effect is the best, and hardness and gloss do not possess high standard demand, therefore outward appearance and service life receive strong influence.
Summary of the invention
It is an object of the invention to solve the defect of prior art, the high rigidity of a kind of PVC floor tile, high glaze ultraviolet-curing paint are provided, while the present invention possesses high rigidity, high tenacity, high glaze performance, also there is higher salt fog resistance, resistance to ag(e)ing, wearability, scratch resistance, adhesive force, cold-and-heat resistent impact capacity.
For realizing the object of the invention, the technical solution used in the present invention is as follows:
The high rigidity of a kind of PVC floor tile, high glaze ultraviolet-curing paint, it is characterised in that: it is prepared from by the raw material of following mass percent:
Aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture: 30% ~ 45%；
Graphitization nano carbon fiber: 3-5%；
Initiator: 5% ~ 12%；
Surface modifier: 1% ~ 3%；
Cosolvent: 5% ~ 10%；
Reactive diluent: 10% ~ 20%；
Polyacrylate or organosilicon levelling agent: 1% ~ 2%；
Atent solvent: 10% ~ 30%；
Pigment: 0% ~ 2%.
Further, the high rigidity of described a kind of PVC floor tile, high glaze ultraviolet-curing paint are prepared from by the raw material of following mass percent:
Aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture: 40%；
Graphitization nano carbon fiber: 5%；
Initiator: 8%；
Surface modifier: 1.5%；
Cosolvent: 7.5%；
Reactive diluent: 16.5%；
Polyacrylate or organosilicon levelling agent: 1.5%；
Atent solvent: 19%;
Pigment: 1%.
Further, the high rigidity of described a kind of PVC floor tile, the preparation method of high glaze ultraviolet-curing paint, comprise the following steps:
(1) being mixed with initiator with Photosensitive Phenolic Epoxy Acrylate mixture by aliphatic urethane diacrylate, mix homogeneously is placed 1 ~ 2 hour；
(2) material mixing graphitization nano carbon fiber, surface modifier, cosolvent, reactive diluent and (1st) step obtained, it is warming up to 30 ~ 50 DEG C, stir 25 ~ 30 minutes under 600 ~ 800 revs/min, cool to less than 30 DEG C and add polyacrylate or organosilicon levelling agent and atent solvent, to obtain final product.
Further, described aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture, mass ratio is 3 ~ 5:1.
Further, described reactive diluent is salicylic acid ester stupid to the tert-butyl group and diacrylate ester admixture, and mass ratio is 1.5 ~ 2.5:1.
Further, described initiator is benzophenone, alpha-alcohol ketone or said mixture.
Further, described surface modifier is silicone, Organic fluoride class or said mixture.
Further, described cosolvent is alcohol ether solvents.
Further, described atent solvent is methylpentanolone.
The invention provides the high rigidity of a kind of PVC floor tile, high glaze ultraviolet-curing paint, have the beneficial effect that:
The high rigidity of the present invention a kind of PVC floor tile, high glaze ultraviolet-curing paint are not only fully able to meet that coating has beautifies and defencive function, also have splendid hardness, gloss and pliability.Additionally, other physical propertys of the present invention are unaffected, there is more preferable resistance to soiling, salt fog resistance, resistance to ag(e)ing, scratch resistance, adhesive force and anti-cold shock performance the most further.
The present invention selects two kinds of reactive diluents, for salicylic acid ester stupid to the tert-butyl group and diacrylate.Salicylic acid ester stupid to the tert-butyl group can provide reasonable hardness and relatively low fragility to compositions, and the flexibility that diacrylate has had, composition viscosity can be reduced, also having and well adhere to facilitation, two kinds of reactive diluents nor affect on the performance of integral formula with the use of the cost both controlling compositions simultaneously.
The aliphatic urethane diacrylate that the present invention uses and Photosensitive Phenolic Epoxy Acrylate mixture, there is the advantage that hardness is high, gloss is high, chemical-resistant is good, surface cure performance is good, again polyacrylate or organosilicon levelling agent are had good synergism.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1:
The high rigidity of described a kind of PVC floor tile, high glaze ultraviolet-curing paint are prepared from by the raw material of following mass percent:
Aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture: 40%；
Graphitization nano carbon fiber: 5%；
Benzophenone: 8%；
Organic fluoride class: 1.5%；
Glycol ether: 7.5%；
Salicylic acid ester stupid to the tert-butyl group, diacrylate ester admixture: 16.5%；
Polyacrylate or organosilicon levelling agent: 1.5%；
Methylpentanolone: 19%；
Pigment: 1%.
Wherein, aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture quality are than for 3:1；Salicylic acid ester stupid to the tert-butyl group, diacrylate mixture quality are than for 2:1.
Embodiment 2:
The high rigidity of described a kind of PVC floor tile, high glaze ultraviolet-curing paint are prepared from by the raw material of following mass percent:
Aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture: 40%；
Graphitization nano carbon fiber: 4%；
Alpha-alcohol ketone: 10%；
Silicone: 2%；
Glycol ether: 9%；
Salicylic acid ester stupid to the tert-butyl group, diacrylate ester admixture: 18%；
Polyacrylate or organosilicon levelling agent: 1%；
Methylpentanolone: 14%
Pigment: 2%.
Wherein, aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture quality are than for 3.5:1；Salicylic acid ester stupid to the tert-butyl group, diacrylate mixture quality are than for 2.5:1.
Embodiment 3:
The high rigidity of described a kind of PVC floor tile, high glaze ultraviolet-curing paint are prepared from by the raw material of following mass percent:
Aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture: 35%；
Graphitization nano carbon fiber: 3%；
Benzophenone, alpha-alcohol ketone mixture: 12%；
Silicone, Organic fluoride class mixture: 3%；
Glycol ether: 8.5%；
Salicylic acid ester stupid to the tert-butyl group, diacrylate ester admixture: 12%；
Polyacrylate or organosilicon levelling agent: 2%；
Methylpentanolone: 23%
Pigment: 1.5%.
Wherein, aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture quality are than for 4:1；Benzophenone, alpha-alcohol ketone mixture quality are than for 2.2:1；Salicylic acid ester stupid to the tert-butyl group, diacrylate mixture quality are than for 1.8:1.
Claims (9)
1. the high rigidity of a PVC floor tile, high glaze ultraviolet-curing paint, it is characterised in that: it is prepared from by the raw material of following mass percent:
Aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture: 30% ~ 45%；
Graphitization nano carbon fiber: 3-5%；
Initiator: 5% ~ 12%；
Surface modifier: 1% ~ 3%；
Cosolvent: 5% ~ 10%；
Reactive diluent: 10% ~ 20%；
Polyacrylate or organosilicon levelling agent: 1% ~ 2%；
Atent solvent: 10% ~ 30%；
Pigment: 0% ~ 2%.
The high rigidity of a kind of PVC floor tile the most according to claim 1, high glaze ultraviolet-curing paint, it is characterised in that: the high rigidity of described a kind of PVC floor tile, high glaze ultraviolet-curing paint are prepared from by the raw material of following mass percent:
Aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture: 40%；
Graphitization nano carbon fiber: 5%；
Initiator: 8%；
Surface modifier: 1.5%；
Cosolvent: 7.5%；
Reactive diluent: 16.5%；
Polyacrylate or organosilicon levelling agent: 1.5%；
Atent solvent: 19%；
Pigment: 1%.
The high rigidity of a kind of PVC floor tile the most according to claim 1 and 2, high glaze ultraviolet-curing paint, it is characterised in that: the high rigidity of described a kind of PVC floor tile, the preparation method of high glaze ultraviolet-curing paint, comprise the following steps:
(1) being mixed with initiator with Photosensitive Phenolic Epoxy Acrylate mixture by aliphatic urethane diacrylate, mix homogeneously is placed 1 ~ 2 hour；
(2) material mixing graphitization nano carbon fiber, surface modifier, cosolvent, reactive diluent and (1st) step obtained, it is warming up to 30 ~ 50 DEG C, stir 25 ~ 30 minutes under 600 ~ 800 revs/min, cool to less than 30 DEG C and add polyacrylate or organosilicon levelling agent and atent solvent, to obtain final product.
The high rigidity of a kind of PVC floor tile the most according to claim 1 and 2, high glaze ultraviolet-curing paint, it is characterised in that: described aliphatic urethane diacrylate and Photosensitive Phenolic Epoxy Acrylate mixture, mass ratio is 3 ~ 5:1.
The high rigidity of a kind of PVC floor tile the most according to claim 1 and 2, high glaze ultraviolet-curing paint, it is characterised in that: described reactive diluent is TBS. and diacrylate ester admixture, and mass ratio is 1.5 ~ 2.5:1.
The high rigidity of a kind of PVC floor tile the most according to claim 1 and 2, high glaze ultraviolet-curing paint, it is characterised in that: described initiator is benzophenone, alpha-alcohol ketone or said mixture.
The high rigidity of a kind of PVC floor tile the most according to claim 1 and 2, high glaze ultraviolet-curing paint, it is characterised in that: described surface modifier is silicone, Organic fluoride class or said mixture.
The high rigidity of a kind of PVC floor tile the most according to claim 1 and 2, high glaze ultraviolet-curing paint, it is characterised in that: described cosolvent is alcohol ether solvents.
The high rigidity of a kind of PVC floor tile the most according to claim 1 and 2, high glaze ultraviolet-curing paint, it is characterised in that: described atent solvent is methylpentanolone.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410584676.XA CN104293167B (en) | 2014-10-28 | 2014-10-28 | The high rigidity of a kind of PVC floor tile, high glaze ultraviolet-curing paint |
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| CN201410584676.XA CN104293167B (en) | 2014-10-28 | 2014-10-28 | The high rigidity of a kind of PVC floor tile, high glaze ultraviolet-curing paint |
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| CN104293167A CN104293167A (en) | 2015-01-21 |
| CN104293167B true CN104293167B (en) | 2016-10-26 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101583521B1 (en) * | 2015-07-31 | 2016-01-08 | (주) 엘림비엠에스 | The method of coating for PVC flooring tile |
| CN105925170A (en) * | 2016-06-29 | 2016-09-07 | 海盐三田科技有限公司 | Solvent-free ultraviolet photocuring anti-flouring easily cleaned paint as well as preparation method and application thereof |
| TW201946945A (en) * | 2018-05-15 | 2019-12-16 | 日商Ｄｉｃ股份有限公司 | Epoxy (meth) acrylate resin composition, curable resin composition, cured product, and article |
| KR20230109621A (en) * | 2020-10-21 | 2023-07-20 | 아르끄마 프랑스 | Actinic radiation curable compositions for abrasive carbon-bonded composites and additive manufacturing methods using such compositions |
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| CN101260253A (en) * | 2008-04-22 | 2008-09-10 | 惠州市长润发涂料有限公司 | Ultraviolet solidifying protection paint applied for polyester substrate surface |
| CN102051115A (en) * | 2010-12-14 | 2011-05-11 | 惠州市凯辉化工有限公司 | Ultraviolet light curing colored paint and preparation method thereof |
| CN102516866A (en) * | 2011-12-19 | 2012-06-27 | 烟台德邦科技有限公司 | Ultraviolet light curing material |
| CN103009756A (en) * | 2012-12-10 | 2013-04-03 | 广东天安新材料股份有限公司 | Composite basement membrane with surface solidifying coating and manufacturing method of composite basement membrane |
| CN103059697A (en) * | 2012-12-28 | 2013-04-24 | 上海乘鹰新材料有限公司 | Ultraviolet curing coating composition for metallic yarn protective layer |
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2014
- 2014-10-28 CN CN201410584676.XA patent/CN104293167B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101260253A (en) * | 2008-04-22 | 2008-09-10 | 惠州市长润发涂料有限公司 | Ultraviolet solidifying protection paint applied for polyester substrate surface |
| CN102051115A (en) * | 2010-12-14 | 2011-05-11 | 惠州市凯辉化工有限公司 | Ultraviolet light curing colored paint and preparation method thereof |
| CN102516866A (en) * | 2011-12-19 | 2012-06-27 | 烟台德邦科技有限公司 | Ultraviolet light curing material |
| CN103009756A (en) * | 2012-12-10 | 2013-04-03 | 广东天安新材料股份有限公司 | Composite basement membrane with surface solidifying coating and manufacturing method of composite basement membrane |
| CN103059697A (en) * | 2012-12-28 | 2013-04-24 | 上海乘鹰新材料有限公司 | Ultraviolet curing coating composition for metallic yarn protective layer |
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Effective date of registration: 20190313 Address after: 313000 South Side of No. 18 Road, Lianshi Town Industrial Park, Nanxun District, Huzhou City, Zhejiang Province Patentee after: HUZHOU LONGZHU POLYMER NEW MATERIAL CO., LTD. Address before: 610000 Chengdu hi tech Zone Shiyang Industrial Park, Sichuan Patentee before: Chengdu Nashuo Technology Co., Ltd. |
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Denomination of invention: A high hardness and high gloss UV curing coating for PVC floor tiles Effective date of registration: 20210420 Granted publication date: 20161026 Pledgee: Nanxun Rural Commercial Bank of Zhejiang, Limited by Share Ltd. Pledgor: HUZHOU LONGZHU POLYMER NEW MATERIAL Co.,Ltd. Registration number: Y2021330000321 |
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