CN105925170A - Solvent-free ultraviolet photocuring anti-flouring easily cleaned paint as well as preparation method and application thereof - Google Patents
Solvent-free ultraviolet photocuring anti-flouring easily cleaned paint as well as preparation method and application thereof Download PDFInfo
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- CN105925170A CN105925170A CN201610519245.4A CN201610519245A CN105925170A CN 105925170 A CN105925170 A CN 105925170A CN 201610519245 A CN201610519245 A CN 201610519245A CN 105925170 A CN105925170 A CN 105925170A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a solvent-free ultraviolet photocuring anti-flouring easily cleaned paint as well as a preparation method and application thereof. The solvent-free ultraviolet photocuring anti-flouring easily cleaned paint comprises 25-35 parts of aromatic polyurethane hexa-functional crylic acid oligomer, 8-12 parts of aliphatic polyurethane trifunctional crylic acid oligomer, 5-7 parts of bisphenol A epoxy bifunctional crylic acid oligomer, 35-45 parts of a tripropylene glycol acrylic ester monomer, 4-6 parts of 1,6-hexylene glycol acrylic ester monomer (HDDA), 7-9 parts of pentaerythritol triacrylate monomer (PET3A), 2.5-3.5 parts of a 2-hydroxyl-2-methyl-1-phenyl-1-acetone photoinitiator (1173), 3-5 parts of a reactive type tertiary amine co-initiator and 0.4-0.6 part of a polyether modified polydimethylsiloxane leveling agent. After being used, the solvent-free ultraviolet photocuring anti-flouring easily cleaned paint disclosed by the invention has very good resistance to oil and sweat stains, is resistant to dust absorption and scrawling, and can be cleaned easily, dirt can be easily wiped off by using cleaning cloth without trace left.
Description
[technical field]
The invention belongs to the technical field of chemistry painting industry, relate in particular to a kind of no-solvent type ultraviolet (UV)
Photocuring anti-soil paint easy to clean, preparation method and its usage.
[background technology]
Civilian coating is widely used in the internal and external ornament of master builder room.Traditional coating is to be coated with on cloth base material
Form layer protecting film, it is impossible to formed and there is the functional effect that anti-soil is easy to clean.
For meeting people, coating being decorated the Functional Requirement day by day promoted, has arisen at the historic moment various function in market
Property coating, the invention provides a kind of anti-soil function easy to clean to meet the demand of people.
[summary of the invention]
The problem to be solved in the present invention is to provide a kind of energy-conserving and environment-protective, simple to operation, formation anti-soil is the most clear
No-solvent type ultraviolet (UV) photocuring anti-soil paint easy to clean and preparation thereof that solidification clean, rapid is dried, make
By method, by simple roller coat coating method be particularly suited for building hotel and hotel and the indoor room of household,
The use of the PVC pad pasting body of wall flat board decoration in parlor.
For achieving the above object, the present invention proposes a kind of no-solvent type ultraviolet photo-curing anti-soil paint easy to clean,
Including following components and each constituent mass ratio it is:
Aromatic urethane 6 functional group's acrylated oligomer: 25～35 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 8～12 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 5～7 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 35～45 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA) 4～6 parts；
Pentaerythritol triacrylate monomer (PET3A): 7～9 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 2.5～3.5 parts；
Response type tertiary amine aided initiating: 3～5 parts
Polyether-modified polydimethylsiloxane levelling agent: 0.4～0.6 part.
As preferably, each constituent mass ratio is:
Aromatic urethane 6 functional group's acrylated oligomer: 30 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 10 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 6 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 40 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA) 5 parts；
Pentaerythritol triacrylate monomer (PET3A): 8 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 3 parts；
Response type tertiary amine aided initiating: 4 parts
Polyether-modified polydimethylsiloxane levelling agent: 0.5 part.
As preferably, each constituent mass ratio is:
Aromatic urethane 6 functional group's acrylated oligomer: 33 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 8 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 5 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 36 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA): 6 parts；
Pentaerythritol triacrylate monomer (PET3A): 9 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 2.5 parts；
Response type tertiary amine aided initiating: 5 parts
Polyether-modified polydimethylsiloxane levelling agent: 0.6 part.
As preferably, each constituent mass ratio is:
Aromatic urethane 6 functional group's acrylated oligomer: 27 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 12 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 7 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 43 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA): 4 parts；
Pentaerythritol triacrylate monomer (PET3A): 7 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 3.5 parts；
Response type tertiary amine aided initiating: 3 parts
Polyether-modified polydimethylsiloxane levelling agent: 0.4 part.
For achieving the above object, the present invention proposes a kind of no-solvent type ultraviolet photo-curing anti-soil paint easy to clean
Preparation method, in turn include the following steps:
1) press formula proportion and add tripropylene glycol diacrylate monomer (TPGDA), and open stirring dispersion machine
Setting speed is 300 revs/min, slowly stirs；
2) in the ratio addition 1 in formula, 6-hexylene glycol two acrylic ester monomer (HDDA), it is kept stirring for dispersion
Machine setting speed is 300 revs/min, slowly stirs；
3) add pentaerythritol triacrylate monomer (PET3A) in the ratio in formula, be kept stirring for dispersion
Machine setting speed is 300 revs/min, slowly stirs；
4) add diphenyl ketone photo initiator (BP) in the ratio in formula, improve stirring dispersion machine rotating speed and set
Be set to 600 revs/min, middling speed agitation dissolve diphenyl ketone photo initiator (BP) till being completely dissolved,
The diphenyl ketone photo initiator stirring dispersion machine speed setting that slows down after being completely dissolved is 300 revs/min；
5) aliphatic polyurethane 6 functional group's acrylated oligomer is added in the ratio in formula；And be kept stirring for
Dispersing speed is set as 300 revs/min；
6) aliphatic polyurethane 6 functional group's acrylated oligomer is added in the ratio in formula；And be kept stirring for
Dispersing speed is set as 300 revs/min；
7) aliphatic polyurethane 3 functional group's acrylated oligomer is added in the ratio in formula；And be kept stirring for
Dispersing speed is set as 300 revs/min；
8) bisphenol-A epoxy 2 functional group's acrylated oligomer is added in the ratio in formula；And it is kept stirring for dispersion
Machine speed setting is 300 revs/min；
9) response type tertiary amine aided initiating is added in the ratio in formula；And be kept stirring for dispersing speed and set
It is set to 300 revs/min；
10) polyether-modified polydimethylsiloxane levelling agent is added in the ratio in formula；And be kept stirring for point
Dissipating machine speed setting is 300 revs/min；
11) 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173) is added in the ratio in formula；
Improving stirring dispersion machine speed setting is 1000 revs/min, stir 20 minutes to uniform, temperature is less than
50℃；
13) filter and package with grenadine and obtain that no-solvent type ultraviolet photo-curing anti-soil is easy to clean paints product.
For achieving the above object, the present invention proposes a kind of no-solvent type ultraviolet photo-curing anti-soil paint easy to clean
Purposes, for indoor PVC pad pasting body of wall flat board, coating weight control is at 20～25 grams/every square metre.
Beneficial effects of the present invention: no-solvent type ultraviolet (UV) photocuring anti-soil paint easy to clean of the present invention leads to
Cross roller coat coating method simple to operate and be suitable to building hotel and household indoor room and the PVC in parlor
The use of pad pasting body of wall flat board decoration, the photocuring anti-soil paint easy to clean after coating, launch through medium pressure mercury lamp
Ultraviolet photo-curing dried, there is the anti-sweat stain of superpower oil rub resistance, anti-suction dust, anti-graffiti, Yi Qing
Clean, dirt only just can be wiped easily with rag one brush gently, and the function left no trace.In being particularly suited for
Child likes the family scribbled everywhere, and decoration material surface is after scribble, as long as just can easily wipe with rag.
Inventive feature and advantage will be combined by embodiment and be described in detail.
[detailed description of the invention]
Embodiment one:
A kind of no-solvent type ultraviolet (UV) photocuring anti-soil paint easy to clean, described no-solvent type ultraviolet (UV) photocuring
The composition of anti-soil paint easy to clean is as follows:
Aromatic urethane 6 functional group's acrylated oligomer: 30 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 10 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 6 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 40 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA) 5 parts；
Pentaerythritol triacrylate monomer (PET3A): 8 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 3 parts；
Response type tertiary amine aided initiating: 4 parts, uses the response type tertiary amine aided initiating that the name of an article is 6420 of Changxing chemical company；
Polyether-modified polydimethylsiloxane levelling agent: 0.5 part, uses the name of an article is L-333 polyether-modified poly-the two of Ou Li chemical industry
Methylsiloxane levelling agent；
Described no-solvent type ultraviolet (UV) photocuring anti-soil paint easy to clean to prepare equipment needed thereby as follows:
1) 380v27kw stirring dispersion machine one；
2) one, cylinder of capacity 1000 liters material；
The preparation method of no-solvent type ultraviolet (UV) photocuring anti-soil paint easy to clean, process flow steps is as follows:
1) add tripropylene glycol diacrylate monomer (TPGDA) in the ratio in formula, and open stirring dispersion machine setting turn
Speed is 300 revs/min, slowly stirs；
2) in the ratio addition 1 in formula, 6-hexylene glycol two acrylic ester monomer (HDDA), it is kept stirring for dispersion machine setting speed
It is 300 revs/min, slowly stirs；
3) add pentaerythritol triacrylate monomer (PET3A) in the ratio in formula, be kept stirring for dispersion machine setting speed
It is 300 revs/min, slowly stirs；
4) adding diphenyl ketone photo initiator (BP) in the ratio in formula, improving stirring dispersion machine speed setting is 600 revs/min
Clock, middling speed agitation dissolving diphenyl ketone photo initiator (BP) is till being completely dissolved, and the stirring dispersion machine speed setting that slows down
It it is 300 revs/min；
5) aliphatic polyurethane 6 functional group's acrylated oligomer is added in the ratio in formula；And be kept stirring for dispersing speed and set
It is set to 300 revs/min；
6) aliphatic polyurethane 6 functional group's acrylated oligomer is added in the ratio in formula；And be kept stirring for dispersing speed and set
It is set to 300 revs/min；
7) aliphatic polyurethane 3 functional group's acrylated oligomer is added in the ratio in formula；；And be kept stirring for dispersing speed and set
It is set to 300 revs/min；
8) bisphenol-A epoxy 2 functional group's acrylated oligomer is added in the ratio in formula；And it is kept stirring for dispersing speed setting
It it is 300 revs/min；
9) response type tertiary amine aided initiating is added in the ratio in formula；And be kept stirring for dispersing speed and be set as 300 revs/min
Clock；
10) polyether-modified polydimethylsiloxane levelling agent is added in the ratio in formula；And it is kept stirring for dispersing speed setting
It it is 300 revs/min；
11) 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173) is added in the ratio in formula；Improve dispersed with stirring
Machine speed setting is 1000 revs/min, stir 20 minutes to uniformly, temperature is less than 50 DEG C；
13) filter and package with grenadine.
Wherein, no-solvent type ultraviolet (UV) photocuring anti-soil enamel-cover easy to clean reload request is:
Packing container is black plastic bucket or metal metal bucket；
Packing specification: 20Kg/ bucket, 200Kg/ bucket.
The storage request of described no-solvent type ultraviolet (UV) photocuring anti-soil paint easy to clean is:
Leave at shady and cool ventilation, keep fire away, store against sunshine waterproof.
Storage period: 25 DEG C of storage periods are 6 months, and expired reinspection is qualified, may continue to use.
The use coating method of described no-solvent type ultraviolet (UV) photocuring anti-soil paint easy to clean is as follows:
The roll coater using double roller is coated；Coating weight control is at 20～25 grams/every square metre；The base material of coating is indoor PVC
Pad pasting body of wall flat board.
The using method of no-solvent type ultraviolet (UV) photocuring anti-soil paint easy to clean, comprises the steps:
1) coating substrate sizes size is the indoor PVC pad pasting body of wall flat board of 1220mm × 2400mm；
2) described no-solvent type ultraviolet (UV) photocuring anti-soil paint easy to clean presses coating weight control at 20～25 grams/every square metre,
Double rollers are coated on PVC pad pasting body of wall flat board；
3) no-solvent type ultraviolet (UV) photocuring anti-soil paint easy to clean PVC pad pasting ash wall body plate enters with two medium pressure mercury lamps
Photo solidification machine, carry out photocuring and be completely dried, photocuring energy ensures 350～450mJ/cm2, obtain described no-solvent type purple
Outside line (UV) photocuring anti-soil paint easy to clean.
No-solvent type ultraviolet (UV) photocuring anti-soil of the present invention paint easy to clean is selected containing unsaturated carbon carbon double
Key (C=C) acrylated oligomer and monomer, light trigger is main body raw material, and leveling auxiliary agent is for assisting former material
Material, by physical compounding mix homogeneously, simple to operation, solidification is dried rapidly, energy-conservation without poison ring
Protect；No-solvent type ultraviolet (UV) photocuring anti-soil of the present invention paint easy to clean particular make-up composition is acrylic acid
Oligomer, acrylic monomers, light trigger, organosilicon levelling agent.No-solvent type ultraviolet (UV) of the present invention
Photocuring anti-soil paint easy to clean is suitable to building hotel and household by roller coat coating method simple to operate
The use of the PVC pad pasting body of wall flat board decoration in indoor room and parlor, the photocuring anti-soil after coating is easy to clean
Paint, the ultraviolet photo-curing launched through medium pressure mercury lamp is dried, has the anti-sweat stain of superpower oil rub resistance, anti-
Inhale dust, anti-graffiti, easy to clean, only just can wipe dirt with rag one brush gently easily, and leave no trace
Function.
Embodiment two:
Each constituent mass ratio is:
Aromatic urethane 6 functional group's acrylated oligomer: 30 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 10 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 6 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 40 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA) 5 parts；
Pentaerythritol triacrylate monomer (PET3A): 8 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 3 parts；
Response type tertiary amine aided initiating: 4 parts
Polyether-modified polydimethylsiloxane levelling agent: 0.5 part.
Embodiment three:
Each constituent mass ratio is:
Aromatic urethane 6 functional group's acrylated oligomer: 33 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 8 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 5 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 36 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA): 6 parts；
Pentaerythritol triacrylate monomer (PET3A): 9 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 2.5 parts；
Response type tertiary amine aided initiating: 5 parts
Polyether-modified polydimethylsiloxane levelling agent: 0.6 part.
Above-described embodiment is the description of the invention, is not limitation of the invention, any simple to the present invention
Scheme after conversion belongs to protection scope of the present invention.
Claims (6)
1. a no-solvent type ultraviolet photo-curing anti-soil paint easy to clean, it is characterised in that: include following components
And each constituent mass ratio is:
Aromatic urethane 6 functional group's acrylated oligomer: 25～35 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 8～12 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 5～7 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 35～45 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA) 4～6 parts；
Pentaerythritol triacrylate monomer (PET3A): 7～9 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 2.5～3.5 parts；
Response type tertiary amine aided initiating: 3～5 parts；
Polyether-modified polydimethylsiloxane levelling agent: 0.4～0.6 part.
A kind of no-solvent type ultraviolet photo-curing anti-soil paint easy to clean the most according to claim 1, it is special
Levy and be: each constituent mass ratio is:
Aromatic urethane 6 functional group's acrylated oligomer: 30 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 10 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 6 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 40 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA) 5 parts；
Pentaerythritol triacrylate monomer (PET3A): 8 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 3 parts；
Response type tertiary amine aided initiating: 4 parts
Polyether-modified polydimethylsiloxane levelling agent: 0.5 part.
A kind of no-solvent type ultraviolet photo-curing anti-soil paint easy to clean the most according to claim 1, it is special
Levy and be: each constituent mass ratio is:
Aromatic urethane 6 functional group's acrylated oligomer: 33 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 8 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 5 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 36 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA): 6 parts；
Pentaerythritol triacrylate monomer (PET3A): 9 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 2.5 parts；
Response type tertiary amine aided initiating: 5 parts
Polyether-modified polydimethylsiloxane levelling agent: 0.6 part.
A kind of no-solvent type ultraviolet photo-curing anti-soil paint easy to clean the most according to claim 1, it is special
Levy and be: each constituent mass ratio is:
Aromatic urethane 6 functional group's acrylated oligomer: 27 parts；
Aliphatic polyurethane 3 functional group's acrylated oligomer: 12 parts；
Bisphenol-A epoxy 2 functional group's acrylated oligomer: 7 parts；
Tripropylene glycol diacrylate monomer (TPGDA): 43 parts；
1,6-hexylene glycol two acrylic ester monomer (HDDA): 4 parts；
Pentaerythritol triacrylate monomer (PET3A): 7 parts；
2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 3.5 parts；
Response type tertiary amine aided initiating: 3 parts
Polyether-modified polydimethylsiloxane levelling agent: 0.4 part.
The preparation of a kind of no-solvent type ultraviolet photo-curing anti-soil paint easy to clean the most according to claim 1
Method, it is characterised in that: in turn include the following steps:
1) press formula proportion and add tripropylene glycol diacrylate monomer (TPGDA), and open stirring dispersion machine
Setting speed is 300 revs/min, slowly stirs；
2) in the ratio addition 1 in formula, 6-hexylene glycol two acrylic ester monomer (HDDA), it is kept stirring for dispersion
Machine setting speed is 300 revs/min, slowly stirs；
3) add pentaerythritol triacrylate monomer (PET3A) in the ratio in formula, be kept stirring for dispersion
Machine setting speed is 300 revs/min, slowly stirs；
4) add diphenyl ketone photo initiator (BP) in the ratio in formula, improve stirring dispersion machine rotating speed and set
Be set to 600 revs/min, middling speed agitation dissolve diphenyl ketone photo initiator (BP) till being completely dissolved,
The diphenyl ketone photo initiator stirring dispersion machine speed setting that slows down after being completely dissolved is 300 revs/min；
5) aliphatic polyurethane 6 functional group's acrylated oligomer is added in the ratio in formula；And be kept stirring for
Dispersing speed is set as 300 revs/min；
6) aliphatic polyurethane 6 functional group's acrylated oligomer is added in the ratio in formula；And be kept stirring for
Dispersing speed is set as 300 revs/min；
7) aliphatic polyurethane 3 functional group's acrylated oligomer is added in the ratio in formula；And be kept stirring for
Dispersing speed is set as 300 revs/min；
8) bisphenol-A epoxy 2 functional group's acrylated oligomer is added in the ratio in formula；And it is kept stirring for dispersion
Machine speed setting is 300 revs/min；
9) response type tertiary amine aided initiating is added in the ratio in formula；And be kept stirring for dispersing speed and set
It is set to 300 revs/min；
10) polyether-modified polydimethylsiloxane levelling agent is added in the ratio in formula；And be kept stirring for point
Dissipating machine speed setting is 300 revs/min；
11) 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173) is added in the ratio in formula；
Improving stirring dispersion machine speed setting is 1000 revs/min, stir 20 minutes to uniform, temperature is less than
50℃；
13) filter and package with grenadine and obtain that no-solvent type ultraviolet photo-curing anti-soil is easy to clean paints product.
The purposes of a kind of no-solvent type ultraviolet photo-curing anti-soil paint easy to clean the most according to claim 1,
It is characterized in that: for indoor PVC pad pasting body of wall flat board, coating weight control is at 20～25 grams/every square metre.
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Application publication date: 20160907 |