CN103497668A - Ultraviolet curing stain-resistant and wear-resistant negative ion wood lacquer and preparation method thereof - Google Patents
Ultraviolet curing stain-resistant and wear-resistant negative ion wood lacquer and preparation method thereof Download PDFInfo
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Abstract
The invention discloses an ultraviolet curing stain-resistant and wear-resistant negative ion wood lacquer and a preparation method thereof. The ultraviolet curing stain-resistant and wear-resistant negative ion wood lacquer comprises bisphenol A epoxy acrylate, aliphatic urethane acrylate, TEPA (pentaerythritol triacrylate), TPGDA (Tripropylene Glycol Diacrylate), inorganic natural powder, a wetting agent and auxiliary agents, and is prepared through a grinding and mixing process. The wood lacquer has three-in-one superior performance of a novel instant curing filming coating, an environment-friendly, high-efficiency and energy-saving novel ultraviolet coating and a coating film, has a superior stain-resistant clean function and releases negative ions to purify air; the film comprises a three-dimensional netlike structure and has a superior wear-resistant scratch-resistant function; the problems of high probability of scratch, poor stain resistance and influence on the health of people due to included harmful substances existing in the conventional coating film are effectively solved.
Description
Technical field
The present invention relates to the technical field that wood lacquer is produced, particularly relate to a kind of ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer and preparation method thereof.
Background technology
At present, the paint that furniture industry is generally used is the type paints such as traditional solvent-borne type PU, PE, NC, and by the method for spraying application, not only efficiency is low, cost is high, contaminate environment, and has a strong impact on workmen's health; In addition, solvent based coating contains some have an opportunity volatile matter and TDI tolylene diisocyanates, and when people use the product that applies the paint film film forming, this series products can discharge harmful material, affects the healthy of user; Finally, the hardness of conventional solvent type coating paint film is in the 2H left and right, cause the wearing no resistance of product, rate of wear (g/100r)≤0.15, anti-zoned overstrain not strong, the paint film resistance to soiling is poor, once it is just extremely difficult clean clean to speckle with the oiliness color, apply the paint film product and very easily cause in daily life surface impaired, cause people's direct economy impaired.
Summary of the invention
In order to overcome above-mentioned the deficiencies in the prior art, the invention provides a kind of ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer and preparation method thereof, this wood lacquer is realized anti-soil, wear-resisting function and is had the characteristic of negative ion, the operating efficiency that can solve wood lacquer is low, cost is high, pollution is large, the anti-zoned overstrain of product is not strong, the problem that the paint film resistance to soiling is poor avoids the product that applies the paint film film forming to volatilize objectionable impurities and affect the healthy of people simultaneously.
The technical solution adopted in the present invention is: the invention provides a kind of ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer, it is characterized in that, the raw material of this wood lacquer comprises following composition and weight part.
| Sequence number | Material name | The component ratio |
| 1 | Aliphatic polyurethane vinylformic acid | 250g |
| 2 | Tripropylene glycol class diacrylate | 200g |
| 3 | Bisphenol-A epoxy vinylformic acid | 145g |
| 4 | Pentaerythritol triacrylate | 100g |
| 5 | Negative ion powder | 100g |
| 6 | Nano-aluminum hydroxide | 100g |
| 7 | 1-hydroxyl alkane is the base benzophenone | 50g |
| 8 | Flatting silica | 30g |
| 9 | The anti-soil auxiliary agent | 5g |
| 10 | The wax powder | 5g |
| 11 | Reactive amines | 5g |
| 12 | Dispersion agent | 3g |
| 13 | Anti-settling agent | 3g |
| 14 | Defoamer | 2g |
| 15 | Flow agent | 2g |
As preferably, polyurethane acroleic acid adopts DR-95 aliphatic polyurethane acrylic resin, has excellent anti-soil effect, containing 15%HDDA hexanediyl ester reactive monomer, containing 2 functional groups.
As preferably, bisphenol-A epoxy vinylformic acid adopts chemical 621A-80 epoxy acrylic resin, containing 15%TPGDA tripropylene glycol class diacrylate reactive monomer, 2 functional groups.
As preferably, tripropylene glycol diacrylate and pentaerythritol triacrylate adopt active 2 functional groups of chemical reaction type and 3 functional group's reactive monomers.
As preferably, ion powder negative ion powder utilizes nature to produce the principle of negative ion, and by natural materials, by the nanotechnology elaborate, nanometer anion powder keeps energetic and human residential environment's improvement is had to great help human body.
As preferably, nano-aluminum hydroxide can not only be fire-retardant as fire retardant, and can prevent from being fuming, do not produce dropping, do not produce toxic gas.
As preferably, 1-hydroxyl alkane base benzophenone adopts chemistry 184,1-hydroxyl alkane base benzophenone cracking type free radical photo-initiation.λ max is at 246nm, 280nm, 330nm.
As preferably, flatting silica adopts surface through the organic process precipitated silica.
As preferably, this wood lacquer needs following additional additives.
(1) the anti-soil auxiliary agent adopts chemical TEGO Protect 5001, for the manufacture of the polypropylene of coating type anti-graffiti coating, and acid esters upgrading silicone resin.
(2) to adopt the polytetrafluoroethylmodified modified wax of chemical 9610F, fineness be 3um, active part 100%, fluorine content 10% to the wax powder.
(3) reactive amines adopts chemical RAP115 reactive amine aided initiating, with the good consistency of acryloxy, low smell can participate in again the crosslinked λ max310nm ultraviolet region of can not moving that stronger absorption is arranged.
(4) dispersion agent adopts EFKA4010, and its composition is the modified polyurethane macromolecule dispersing agent, prevents that coating from condensing.
(5) anti-settling agent adopts CAB-O-SIL M-5, the non-processing type of a kind of medium surface-area aerosil, significantly the viscosity of enhance liquid system, prevent that coating from dividing heavy shallow lake to lump.
(6) defoamer adopts chemical BYK141 defoamer, chemical constitution to have the good bubble effect that presses down for breaking bubble polymkeric substance and siloxane solution.
(7) flow agent adopts chemical TEGO450, Chemical Composition polyether siloxane copolymer 100% active substance content, improves the film coated surface scratch resistance and smooth feel is provided.
As preferably, a kind of preparation production method of ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer is characterized in that this preparation method comprises the following steps.
(1) first light trigger 1-hydroxyl alkane base benzophenone 50g and tripropylene glycol diacrylate 200g pentaerythritol triacrylate 100g are dropped in advance in the experiment cup and stir, control speed for 1000r/min, stir after 10 minutes and splash into successively the higher TEGO Protect 5001 of anti-soil auxiliary agent enlightening, 5g, EFKA4010 dispersion agent 3g, BYK141 defoamer 2g, the high 450 flow agent 2g reactive amines 5g of enlightening splash in cup, after adding, disperse in advance to stir in 5 minutes.Add successively prepolymer bisphenol-A epoxy vinylformic acid 145g, aliphatic urethane acrylate 250g, added the fast 1200r/min of rear control to disperse to stir 10 minutes again.
(2) disperse slowly to add successively following powder, powder to add fashionable will slowly adding in cup successively.Add nanometer anion powder 100g, add aluminium hydroxide 100g to add flatting silica 30g, add wax powder 5g to add anti-settling agent 3g.After above powder slowly adds in cup successively, the fast 1500r/min of control disperses 45 minutes.Detecting paint liquid fineness is 25um, and paint fluid viscosity rotary viscosity is 800 ± 100mpas/25 ℃.
Compared with prior art, the invention has the beneficial effects as follows under the irradiation that the ultraviolet photo-curing coating in the present invention is 260-450nm at ultraviolet wavelength and impel decomposition of initiator, produce free radical, cause the resin reaction, the instantaneous solidification film forming.Compare ultraviolet photo-curing coating with conventional solvent type coating not containing the directly constructing operation application of organic solvent flashing.The application mode: roller coat, showering, spraying, can mechanical application circulation painting operation, greatly improve enterprises production efficiency, reduce organic volatile to the pollution of atmosphere simultaneously and affect the health of human body.
The present invention utilize natural nano negative ion powder introduce paint film after ultraviolet coating, film curing film forming so anion releasing purify air to, human body kept energetic and human residential environment's improvement is had to great help.Introduce fluorine-containing wax powder and anti-soil auxiliary agent and reduce skin friction coefficient, splendid anti-fruit juice, coffee, oiliness look liquid, water-based, permanent pen effect and surface cleaning effect are arranged after ultraviolet coating paint film film forming.Introduce wear-resisting effect that nano-aluminum hydroxide can improve coating surface greatly, aluminium hydroxide powder containing Al2O3 > 98.35%, Fe2O3 0.01～0.04% surface abrasion resistance that can improve ultraviolet paint film wipes effect.
Embodiment
Below the present invention is further described: a kind of ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer and preparation method thereof, it is characterized in that, the raw material of this ultraviolet photo-curing wood lacquer comprises following composition and weight part.
| The starting material title | Deal is than example 1 | Deal is than example 2 | Deal is than example 3 | Deal is than example 4 |
| Bisphenol-A epoxy vinylformic acid | 145g | 145g | 195g | 245g |
| Aliphatic polyurethane vinylformic acid | 250g | 250 | 200g | 150g |
| 1-hydroxyl alkane is the base benzophenone | 50g | 50g | 50g | 50g |
| Tripropylene glycol class diacrylate | 200g | 244g | 306g | 354g |
| Pentaerythritol triacrylate | 100g | 100g | 100g | 100g |
| The anti-soil auxiliary agent | 5g | 1g | 2g | 3g |
| Dispersion agent | 3g | 3g | 3g | 3g |
| Defoamer | 2g | 2g | 2g | 2g |
| Flow agent | 2g | 2g | 2g | 2g |
| Reactive amines | 5g | 5g | 5g | 5g |
| Anti-settling agent | 3g | 3g | 3g | 3g |
| Negative ion powder | 100g | 80 | 50g | 25g |
| Nano-aluminum hydroxide | 100g | 80g | 50g | 25g |
| Flatting silica | 30g | 30g | 30g | 30g |
| The wax powder | 5g | 1g | 2g | 3g |
By this experimental implementation production technique, first light trigger 1-hydroxyl alkane base benzophenone 50g and tripropylene glycol diacrylate 200g pentaerythritol triacrylate 100g are dropped in advance in the experiment cup and stir, control speed for 1000r/min, stir after 10 minutes and splash into successively the higher TEGO Protect 5001 of anti-soil auxiliary agent enlightening, 5g, EFKA4010 dispersion agent 3g, BYK141 defoamer 2g, the high 450 flow agent 2g reactive amines 5g of enlightening splash in cup, after adding, disperse in advance to stir in 5 minutes.Add successively prepolymer bisphenol-A epoxy vinylformic acid 145g, aliphatic urethane acrylate 250g, added the fast 1200r/min of rear control to disperse to stir 10 minutes again., above scattered following powder, the powder of slowly adding successively add fashionable will slowly adding in cup successively.Add nanometer anion powder 100g, add aluminium hydroxide 100g to add flatting silica 30g, add wax powder 5g to add anti-settling agent 3g.After above powder slowly adds in cup successively, the fast 1500r/min of control disperses 45 minutes, obtains a kind of ultraviolet photo-curing anti-soil, wear-resisting, negative ion wood lacquer.
Use this ultraviolet curing coating can utilize roller coat, spraying, these three kinds of coating process operation constructions of showering, the Specific construction mode is as follows:
The wide 40cm thickness of the long 30cm x of oak material specification 1.5cm, coating process are accompanied by lower form:
| Sequence number | Ultraviolet ray coating lacquer kind | Glue spread | The photocuring energy | Sanding |
| 1 | UV compound type transparent putty priming paint | 25±2g/m2 | ≥120mj/cm2 | The sanding of 240# sand paper |
| 2 | The UV transparent priming | 15±2g/m2 | ≥60mj/cm2 | Exempt from sanding |
| 3 | The UV transparent priming | 15±2g/m2 | ≥120mj/cm2 | The 240# sanding |
| 4 | The UV transparent priming | 15±2g/m2 | ≥60mj/cm2 | Exempt from sanding |
| 5 | The UV transparent priming | 15±2g/m2 | ≥120mj/cm2 | The 240# sanding |
| 6 | Ultraviolet curing anti-soil, wear-resistant anion wood lacquer finish paint | 10±2g/m2 | ≥60mj/cm2 | Exempt from sanding |
| 7 | Ultraviolet curing anti-soil, wear-resistant anion wood lacquer finish paint | 10±2g/m2 | ≥460mj/cm2 | Complete solidifying |
One UV compound type transparent putty of above oak material technique application, 4 road UV transparent priming 2 road ultraviolet photo-curing anti-soils, wear-resisting, negative ion wood lacquer finish paint, same coating process have been done respectively 4 application example laboratory contrasts.
After film-forming, application sheet material is done following performance test.
(1) sticking power test: with drawing the pattern of lattice device at 100 1mmx1mm of coating surface of coated substrate, the scotch tape even die attach that the model of producing with Minnesota Mining and Manufacturing Company is 600 is attached on grid, then with the fastest speed, vertically uncover and observe the cut edge and whether have or not pull-away, be 5B as the depainting amount between 0-5%, be 4B between 5-10%, be 3B between 10-20, be 2B between 20-30, be B between 30-50, be 0B more than 50%.
(2) hardness test: with reference to GB GB/T6739-1996 (hardness of film pencil assay method)
With 3H Mitsubishi pencil, pencil sharper is held to pencil and made it with 400# waterproof abrasive paper, become an angle of 90 degrees to exposing cylindrical lead for retractable pencil 3mm length left and right (attention can not damage pen core), do not stop to draw circle with friction pen core end face on sand paper, be contained in that on special-purpose pencil hardness tester device, (load be applied on nib is 1KG until obtain the lead for retractable pencil that the end face flat edges is sharp keen (edge must not breakage and breach), the angle of pencil and level is 45 °) promote pencil to front slide 5mm length, draw altogether 5 (different positionss) again with eraser by plumbous trace wiped clean, see if there is the broken trace of paint film, seamless breaking as qualified.
(3) RCA wearability test: wear resistance is the degree that paint film is wear-resisting, wear resistance is actually the embodiment of hardness of film, sticking power and force of cohesion combined effect, adopt the emery wheel abrasion instrument to measure the wear resistance of filming, the higher explanation wear resistance of abradability is poorer, refers to GB/T15036.2
Fixed temperature and humidity test: product is placed under the constant-temperature constant-humidity environment of 70 ± 2 ℃ of temperature, humidity 93 ± 2 and deposits 48h, place 2h observation outward appearance after test and test paint film adhesion under normal temperature environment.
(5) criterion: product surface is qualified without variable color, crackle, bubble, peeling paint phenomenon.
(6) impact strength test: impact strength mean to film the cracking resistance that can stand when external impacts or resist with base material between the ability of separating, the impact strength of filming adopts impact tester to measure, and refers to the GB1732-79(shock-resistant assay method of filming and exists).
(7) chemical resistance: chemical resistance refer to film the ability, the measuring method that stand chemical corrosion medium (acid, alkali, salt solution) will film invade in the regulation medium while reaching standard code after, take out that observing films and whether have or not peel off, the images such as bubble, variable color, loss of gloss (refer to GB T3810.13-2006).
(8) pollution resistance test: generally soy sauce, fruit juice, coffee liquid are poured on coating surface and wipe gently, whether wipe totally with wet cloth, wipe the explanation pollution resistance fully fine.Test scrub resistance quality, with the oil pen coating surface draw strokes, then with cotton, clean see whether restore to the original state, recovering seamless description effect, excellent (pollution resistance is tested and is referred to: GB/T1761-1979 paint film pollution resistance assay method).
(9) negative ion measurement pattern: anion test adopts the test of negative aeroion tester, be (to be generally that speed by per second 400cm3 enters inlet mouth for sampled air, by venting port, discharged again) measured, connect the ground wire of the ground connection of instrument; Select to determine POLARITY+or-, determine and just measuring or negative ion; Upright instrument, knob is at OFF, and the switch of button is placed on STANDBY, then knob to 19.99; Heat engine 1 minute, press the button RE-ZERO, and keep 3-5 second;-0.01 to 0.01 the time, just stable when the numeral shown; If unstable, need rezeroing; During measurement, the switch of button is placed on MEASURE just to start to measure; According to the size of the numerical value shown, knob can be followed the tracks of and be threaded on different range abilities; If show numeral 1 in measuring process, should be adjusted to a large range ability gear; Show stable after reading again, with the numeral of reading be multiplied by 1000 be exactly this measured zone just or the content of negative ion number (ion individual/cm3).
(11) weathering resistance test: the weathering resistance test is whether paint film under field conditions (factors) or under simulating natural condition, coating weatherability, observation paint film have the degree such as loss of gloss, variable color, efflorescence, crackle, bubble, (refer to: GB/T1865-1997 is tested with reference to GB).
Appendix: the examination criteria of a kind of anti-soil wear-resistant anion wood lacquer of ultraviolet photo-curing after according to the making sheet of company standard regulation:
| rate of wear (g/100r) | premium grads≤0.08 | acceptable end product≤0.10 | acceptable end product≤0.12 | salable product≤0.15 |
| the paint film water tolerance | 72h is non-foaming, wrinkle resistant, do not come off | 72h is non-foaming, wrinkle resistant, do not come off | 72h is non-foaming, wrinkle resistant, do not come off | 72h is non-foaming, wrinkle resistant, do not come off |
| acidproof (25%H2SO4) films | 48h is non-foaming, wrinkle resistant, do not come off | 48h is non-foaming, wrinkle resistant, do not come off | 48h is non-foaming, wrinkle resistant, do not come off | 48h is non-foaming, wrinkle resistant, do not come off |
| the pollution resistance test | soy sauce, oil pen wipe scouring seamless, easy to clean. | soy sauce, oil pen have wiped trace | soy sauce, oil pen have wiped trace | soy sauce, oil pen wipe slightly trace |
| the weathering resistance test | 72 hours without loss of gloss, variable color, efflorescence, crackle, bubble | 72 hours without loss of gloss, variable color, efflorescence, crackle, bubble | 72 hours without loss of gloss, variable color, efflorescence, crackle, bubble | 72 hours without loss of gloss, variable color, efflorescence, crackle, bubble |
Claims (10)
1. a ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer, is characterized in that, the raw material of this wood lacquer comprises following composition and weight part:
。
2. according to the ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer described in claim 1, it is characterized in that, described polyurethane acroleic acid adopts DR-95 aliphatic polyurethane acrylic resin, has excellent anti-soil effect, containing 15%HDDA hexanediyl ester reactive monomer, containing 2 functional groups.
3. according to the ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer described in claim 1, it is characterized in that, described bisphenol-A epoxy vinylformic acid adopts chemical 621A-80 epoxy acrylic resin, containing 15%TPGDA tripropylene glycol class diacrylate reactive monomer, 2 functional groups.
4. according to the ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer described in claim 1, it is characterized in that, described tripropylene glycol diacrylate and pentaerythritol triacrylate adopt active 2 functional groups of chemical reaction type and 3 functional group's reactive monomers.
5. according to the ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer described in claim 1, it is characterized in that, described ion powder negative ion powder utilizes nature to produce the principle of negative ion, by natural materials, by the nanotechnology elaborate, nanometer anion powder keeps energetic and human residential environment's improvement is had to great help human body.
6. according to the ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer described in claim 1, it is characterized in that, described nano-aluminum hydroxide can not only be fire-retardant as fire retardant, and can prevent from being fuming, do not produce dropping, do not produce toxic gas.
7. according to the ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer described in claim 1, it is characterized in that, described 1-hydroxyl alkane base benzophenone adopts chemistry 184,1-hydroxyl alkane base benzophenone cracking type free radical photo-initiation, and λ max is at 246nm, 280nm, 330nm.
8. according to the ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer described in claim 1, it is characterized in that, described flatting silica adopts surface through the organic process precipitated silica.
9. according to the ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer described in claim 1, it is characterized in that, this wood lacquer needs following additional additives:
(1) the anti-soil auxiliary agent adopts chemical TEGO Protect 5001, for the manufacture of the polypropylene of coating type anti-graffiti coating, and acid esters upgrading silicone resin;
(2) to adopt the polytetrafluoroethylmodified modified wax of chemical 9610F, fineness be 3um, active part 100%, fluorine content 10% to the wax powder;
(3) reactive amines adopts chemical RAP115 reactive amine aided initiating, with the good consistency of acryloxy, low smell can participate in again the crosslinked λ max310nm ultraviolet region of can not moving that stronger absorption is arranged;
(4) dispersion agent adopts EFKA4010, and its composition is the modified polyurethane macromolecule dispersing agent, prevents that coating from condensing;
(5) anti-settling agent adopts CAB-O-SIL M-5, the non-processing type of a kind of medium surface-area aerosil, significantly the viscosity of enhance liquid system, prevent that coating from dividing heavy shallow lake to lump;
(6) defoamer adopts chemical BYK141 defoamer, chemical constitution to have the good bubble effect that presses down for breaking bubble polymkeric substance and siloxane solution;
(7) flow agent adopts chemical TEGO450, Chemical Composition polyether siloxane copolymer 100% active substance content, improves the film coated surface scratch resistance and smooth feel is provided.
10. the preparation production method of a ultraviolet photo-curing anti-soil wear-resistant anion wood lacquer, is characterized in that, this preparation method comprises the following steps:
(1) first light trigger 1-hydroxyl alkane base benzophenone 50g and tripropylene glycol diacrylate 200g pentaerythritol triacrylate 100g are dropped in advance in the experiment cup and stir, control speed for 1000r/min, stir after 10 minutes and splash into successively the higher TEGO Protect 5001 of anti-soil auxiliary agent enlightening, 5g, EFKA4010 dispersion agent 3g, BYK141 defoamer 2g, the high 450 flow agent 2g reactive amines 5g of enlightening splash in cup, after adding, disperse in advance to stir in 5 minutes; Add successively prepolymer bisphenol-A epoxy vinylformic acid 145g, aliphatic urethane acrylate 250g, added the fast 1200r/min of rear control to disperse to stir 10 minutes again;
(2) disperseing slowly to add successively following powder, powder to add fashionablely will slowly add in cup successively, add nanometer anion powder 100g, add aluminium hydroxide 100g to add flatting silica 30g, add wax powder 5g to add anti-settling agent 3g, after above powder slowly adds in cup successively, the fast 1500r/min of control disperses 45 minutes, detecting paint liquid fineness is 25um, and paint fluid viscosity rotary viscosity is 800 ± 100mpas/25 ℃.
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