CN108300274B - Water-based ultraviolet-curing anti-fingerprint coating and preparation method thereof - Google Patents
Water-based ultraviolet-curing anti-fingerprint coating and preparation method thereof Download PDFInfo
- Publication number
- CN108300274B CN108300274B CN201710767455.XA CN201710767455A CN108300274B CN 108300274 B CN108300274 B CN 108300274B CN 201710767455 A CN201710767455 A CN 201710767455A CN 108300274 B CN108300274 B CN 108300274B
- Authority
- CN
- China
- Prior art keywords
- coating
- fingerprint
- curing
- water
- ultraviolet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a water-based ultraviolet-curing fingerprint-resistant coating and a preparation method thereof, belonging to the technical field of coating processing. The coating comprises the following components in percentage by mass: 12-22% of an anti-fouling resin; 12-44% of water-based ultraviolet curing oligomer; 5-20% of an ultraviolet curing monomer; 1-5% of a photoinitiator; 0.05-0.2% of a leveling agent; 0.05-0.2% of wetting agent; 0-10% of a film-forming assistant; 20-69% of deionized water. The fluorine-containing or silicon-containing anti-fouling resin and the aqueous ultraviolet oligomer are used as main bodies, and the aqueous Ultraviolet (UV) curing anti-fingerprint coating prepared by a certain preparation process adopts water as a dispersion medium, has the characteristics of low smell, nonflammability, low VOC content, water washing and the like, inherits the advantages of short UV coating curing time, high production efficiency, low energy consumption and the like, and meets the requirements of green environmental protection laws and regulations; the coating obtained from the coating has the advantages of excellent fingerprint resistance effect, strong durability and the like.
Description
Technical Field
The invention relates to the technical field of coating processing, in particular to a water-based ultraviolet-curing fingerprint-resistant coating and a preparation method thereof.
Background
In recent 20 years, 3C (Computer, Communication, and consumer electronics) electronic products have been rapidly developed in China, and their usage is increasing from luxury goods to consumer goods for daily use, and further to consumer goods for daily use, and competition in the industry is also increasing. In consideration of cost and performance, the 3C product mostly uses plastic substrates for the housing, and the corresponding coating effect is also receiving wide attention, and the beautiful appearance, comfortable hand feeling and durable performance are more and more favored by consumers. Among them, electronic products such as mobile phones and tablet computers are completely changed into touch operation, the surfaces of the body and the screen of the electronic products are contacted with fingers for a long time, fingerprints and sweat are easy to adhere to the surfaces of the electronic products, the surface coatings are slowly eroded to reduce the performance of the electronic products while the appearance of the electronic products is influenced, and therefore the fingerprint resisting effect of the surfaces slowly meets the requirements of consumers.
At present, in the coating industry, Ultraviolet (UV) curing coatings are widely applied due to the advantages of short curing time, high production efficiency, low energy consumption and the like, and the annual output of the UV curing coatings is increased year by year both domestically and internationally. Particularly for the heat-sensitive plastic substrate, the UV curing coating can be rapidly cured into a film only by UV illumination for 1-5min, the operation is simple and convenient, the energy consumption is low, and the problem of substrate thermal deformation is not needed to be worried about. Patent CN 103073934B discloses an ultraviolet-curing fingerprint-resistant coating for PMMA substrate, which adopts the combined action of fluorine-modified acrylate resin and silicon-modified acrylate resin to obtain the fingerprint-resistant effect of the coating. Patent CN 103571314B uses a fluorine modified hyperbranched oligomer, together with high functionality UV resin and UV monomer, to provide high hardness anti-fingerprint coating for PET substrate. Patent CN 101891991B uses fluorocarbon resin as main body and uses nanoparticles to further construct an ultra-low surface energy surface, thereby providing a high hardness anti-fingerprint coating for steel plate.
However, the anti-fingerprint coating still needs a large amount of solvent to obtain better coating workability and appearance, has potential huge influence on the environment and constructors, and has gradually increased laws and regulations along with the gradual enhancement of environmental awareness of people, so that the development of the real energy-saving and environment-friendly coating is not slow. The water-based Ultraviolet (UV) curing coating combines the advantages of the traditional UV curing technology and the water-based coating technology, adopts water as a dispersion medium, has the characteristics of low smell, nonflammability, low VOC content, water washing and the like, inherits the advantages of short curing time, high production efficiency, low energy consumption and the like of the UV coating, and meets the requirements of green environmental protection laws and regulations. Therefore, how to improve the water-based ultraviolet curing coating to make the coating have the anti-fingerprint effect is a problem to be solved by the technical personnel in the field.
Disclosure of Invention
The invention aims to provide an energy-saving environment-friendly coating with an excellent anti-fingerprint effect, so as to solve the problem that the existing anti-fingerprint coating has huge influence on the environment and constructors due to the existence of a large amount of organic solvents.
In order to achieve the purpose, the invention adopts the following technical scheme:
the water-based ultraviolet-curing fingerprint-resistant coating comprises the following components in percentage by mass:
preferably, the anti-fouling resin is at least one of organic silicon light-cured resin, organic fluorine light-cured resin, fluorocarbon resin, fluorine-silicon resin and nano modified resin.
Preferably, the aqueous ultraviolet light curing oligomer is at least one of aqueous polyurethane acrylate, aqueous polyester acrylate, aqueous acrylic acid modified acrylate, aqueous epoxy acrylate and aqueous polycarbonate acrylate.
In view of comprehensive properties, the aqueous ultraviolet-curable oligomer is more preferably at least one of aqueous urethane acrylate and aqueous polycarbonate acrylate.
Preferably, the ultraviolet-curable monomer is at least one of trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, propoxylated trimethylolpropane triacrylate, glycerol triacrylate, tripropylene glycol diacrylate, hexanediol diacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, neopentyl glycol diacrylate, propoxylated neopentyl glycol diacrylate, and 1, 3-butanediol diacrylate.
Preferably, the photoinitiator is at least one of a water-soluble cleavage type radical photoinitiator and a water-soluble hydrogen abstraction type radical photoinitiator.
Preferably, the leveling agent is an organic silicon leveling agent or a fluorine-containing leveling agent.
Preferably, the wetting agent is a silicone wetting agent or a polyacrylate wetting agent.
Preferably, the film-forming assistant is at least one of ethanol, ethylene glycol, propylene glycol, butylene glycol, diethylene glycol ethyl ether, diethylene glycol butyl ether, diacetone alcohol, propylene glycol methyl ether, propylene glycol ethyl ether and propylene glycol butyl ether.
Preferably, the water-based ultraviolet-curable fingerprint-resistant coating comprises the following components in percentage by mass:
preferably, the anti-fouling resin is at least one of organic silicon light-cured resin with the brand number of UA-888 (Zhongshanjie Dainiuchi chemical Co., Ltd.) or B-818/B-828/B-868 (Guangdong Boxing science and technology New Material science and technology Co., Ltd.), nano-modified resin of UA-1020 (Zhongshanjie Dainiuchi chemical Co., Ltd.), and organic fluorine light-cured resin of B-864 (Guangdong Boxing science and technology New Material science and technology Co., Ltd.);
the aqueous ultraviolet light curing oligomer is aqueous urethane acrylate UCECOATTM7210、UCECOATTM7200. At least one of a waterborne epoxy acrylate RS 7604 (Jiaxing Ruishi) and a waterborne polyester acrylate RS 7614 (Jiaxing Ruishi);
the ultraviolet light curing monomer is trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, propoxylated trimethylolpropane triacrylate, glycerol triacrylate, tripropylene glycol diacrylate or hexanediol diacrylate;
the photoinitiator is 2-hydroxy-2-methyl-1-phenyl-1-acetone;
the leveling agent is BYK162 or BYK 333;
the wetting agent is BYK346 or TEGO 270;
the film-forming assistant is propylene glycol methyl ether or diacetone alcohol.
The invention also provides a method for preparing the water-based ultraviolet-curing fingerprint-resistant coating, which comprises the following steps:
(1) mixing the anti-fouling resin, the ultraviolet curing monomer, the photoinitiator and the film forming additive, and stirring for 5-10 min at 500-1000 r/min until the mixture is uniformly mixed to obtain a primary mixture;
(2) under the stirring condition, adding the aqueous ultraviolet curing oligomer into the primary mixture, stirring for 10-15 min at 500-1000 r/min until the mixture is uniformly mixed, adding deionized water, a wetting agent and a flatting agent, dispersing for 0.5-1 h at 1000-3000 r/min, filtering and discharging to obtain the aqueous ultraviolet curing anti-fingerprint coating.
The invention also provides a construction method of the water-based ultraviolet-curing fingerprint-resistant coating, which comprises the following steps: and coating the coating on a substrate, and curing by ultraviolet light to obtain the anti-fingerprint coating. The ultraviolet curing conditions are as follows: the light intensity is 20mW/cm2The time is 1 min.
Compared with the prior art, the invention has the following beneficial effects:
the invention takes fluorine-containing or silicon-containing anti-fouling resin and water-based ultraviolet oligomer as main bodies, prepares the water-based Ultraviolet (UV) curing anti-fingerprint coating through a certain preparation process, combines the advantages of the traditional UV curing technology and the water-based coating technology, adopts water as a dispersion medium, has the characteristics of low smell, nonflammability, low VOC content, water washability and the like, inherits the advantages of short UV coating curing time, high production efficiency, low energy consumption and the like, and meets the requirements of green environmental protection laws and regulations.
The coating obtained by the coating has the advantages of excellent fingerprint resistance effect, strong durability and the like.
Detailed Description
The present invention will be further described with reference to the following examples.
Examples 1 to 5
The coating formulation was carried out according to the coating formulation of table 1, the specific preparation procedure was as follows:
(1) mixing the anti-fouling resin, the ultraviolet curing monomer, the photoinitiator and the film forming additive, and stirring for 5-10 min at 500-1000 r/min until the mixture is uniformly mixed to obtain a primary mixture;
(2) under the stirring condition, adding the aqueous ultraviolet curing oligomer into the primary mixture, stirring for 10-15 min at 500-1000 r/min until the mixture is uniformly mixed, adding deionized water, a wetting agent and a flatting agent, dispersing for 0.5-1 h at 1000-3000 r/min, filtering and discharging to obtain the aqueous ultraviolet curing anti-fingerprint coating.
TABLE 1
Comparative examples 1 to 3
Coating formulations were prepared according to the coating formulations of Table 2, following the same procedure as in examples 1-5.
TABLE 2
Application example
The coatings prepared in the above examples and comparative examples were sprayed, flow-coated or roll-coated on a plastic substrate with a light intensity of 20mW/cm2The UV lamp was cured for 1min to obtain an anti-fingerprint coating, the properties of which are shown in Table 3.
The performance test method comprises the following steps:
1. adhesion force
Cut into hundred squares and tested 3 times with 3M 600 tape.
2. Hardness of pencil
The test was carried out with a Mitsubishi pencil at 750 g.
3. Fingerprint resistance
(1) Coating a layer of vaseline on the cured coating, placing the coating in an environment with the relative humidity of 90% and the temperature of 50 ℃, wiping the coating with dust-free cloth after 24 hours, taking the coating without the vaseline as a standard sample, testing the delta E value of the coating after the experiment, and judging that the delta E is OK if the delta E is less than 3;
(2) writing on the coating with an oil pen, wiping with a dust-free cloth, recording the number of times the print of the oil pen can be wiped clean, and determining OK if the number of times is more than 50.
TABLE 3
Claims (7)
1. The water-based ultraviolet-curing fingerprint-resistant coating is characterized by comprising the following components in percentage by mass:
the anti-fouling resin is one of organic silicon light-cured resin with the trade mark of UA-860, UA-888, B-818, B-828 or B-868, nano modified resin with the trade mark of UA-1020 and organic fluorine light-cured resin with the trade mark of B-864;
the waterborne ultraviolet curing oligomer is UCECOAT with the mark numberTM7210 or UCECOATTM7200, RS 7604, RS 7614, or a mixture thereof;
the preparation method of the water-based ultraviolet curing anti-fingerprint coating comprises the following steps:
(1) mixing the anti-fouling resin, the ultraviolet curing monomer, the photoinitiator and the film forming additive, and stirring for 5-10 min at 500-1000 r/min until the mixture is uniformly mixed to obtain a primary mixture;
(2) under the stirring condition, adding the aqueous ultraviolet curing oligomer into the primary mixture, stirring for 10-15 min at 500-1000 r/min until the mixture is uniformly mixed, adding deionized water, a wetting agent and a flatting agent, dispersing for 0.5-1 h at 1000-3000 r/min, and filtering to obtain the aqueous ultraviolet curing anti-fingerprint coating.
2. The aqueous UV-curable fingerprint resistant coating of claim 1, wherein the UV-curable monomer is at least one of trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, propoxylated trimethylolpropane triacrylate, glycerol triacrylate, tripropylene glycol diacrylate, hexanediol diacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, neopentyl glycol diacrylate, propoxylated neopentyl glycol diacrylate, 1, 3-butanediol diacrylate.
3. The aqueous ultraviolet-curable fingerprint resistant coating of claim 1 wherein the photoinitiator is at least one of a water-soluble cleavage type radical photoinitiator and a water-soluble hydrogen abstraction type radical photoinitiator.
4. The aqueous ultraviolet-curable fingerprint resistant coating according to claim 1, wherein the leveling agent is an organic silicon leveling agent or a fluorine-containing leveling agent.
5. The aqueous ultraviolet-curable fingerprint-resistant coating as claimed in claim 1, wherein the wetting agent is a silicone wetting agent or a polyacrylate wetting agent.
6. The aqueous ultraviolet-curable fingerprint resistant coating according to claim 1, wherein the film forming aid is at least one of ethanol, ethylene glycol, propylene glycol, butylene glycol, diethylene glycol ethyl ether, diethylene glycol butyl ether, diacetone alcohol, propylene glycol methyl ether, propylene glycol ethyl ether, and propylene glycol butyl ether.
7. The aqueous ultraviolet-curing fingerprint-resistant coating as claimed in any one of claims 1 to 6, which comprises the following components in percentage by mass:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710767455.XA CN108300274B (en) | 2017-08-31 | 2017-08-31 | Water-based ultraviolet-curing anti-fingerprint coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710767455.XA CN108300274B (en) | 2017-08-31 | 2017-08-31 | Water-based ultraviolet-curing anti-fingerprint coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108300274A CN108300274A (en) | 2018-07-20 |
| CN108300274B true CN108300274B (en) | 2020-08-25 |
Family
ID=62869632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710767455.XA Active CN108300274B (en) | 2017-08-31 | 2017-08-31 | Water-based ultraviolet-curing anti-fingerprint coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108300274B (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641455B (en) * | 2017-09-27 | 2019-12-24 | 芜湖春风新材料有限公司 | Anti-fingerprint UV coating for automotive interior parts, and preparation method and application thereof |
| CN109294417A (en) * | 2018-09-28 | 2019-02-01 | 韶关市合众化工有限公司 | A kind of modified hydrophobic UV insulated paint of high rigidity of waterborne organic silicon |
| CN110003852A (en) * | 2019-04-18 | 2019-07-12 | 中山市安可玻璃防爆膜有限公司 | UV (ultraviolet) adhesive glue and preparation method thereof |
| CN110105877A (en) * | 2019-05-29 | 2019-08-09 | 无锡卡秀堡辉涂料有限公司 | Colored coating of a kind of easy clean ultraviolet light solidification of aqueous anti-fingerprint and preparation method thereof |
| BR112022000916A2 (en) * | 2019-08-01 | 2022-03-08 | Akzo Nobel Coatings Int Bv | Aqueous dispersion of a carboxyl-functional unsaturated polyester containing a perfluoropolyether block, water-based UV-curing coating composition, method of coating a substrate and coated substrate |
| WO2021074113A1 (en) * | 2019-10-15 | 2021-04-22 | Akzo Nobel Coatings International B.V. | Waterborne, uv curable coating composition for easy-clean coatings |
| CN111363400B (en) * | 2020-04-29 | 2022-09-02 | 卡秀万辉(无锡)高新材料有限公司 | Aqueous one-coating baking-free silver ultraviolet curing coating and preparation method thereof |
| CN112662307A (en) * | 2020-12-25 | 2021-04-16 | 惠州市韵点新材料科技股份有限公司 | UV-cured water-based vacuum sputtering coating |
| CN112625482A (en) * | 2020-12-25 | 2021-04-09 | 惠州市韵点新材料科技股份有限公司 | High-ductility UV (ultraviolet) curing water-based paint |
| CN112795302A (en) * | 2021-01-14 | 2021-05-14 | 昆山三越油墨有限公司 | Water-based ultraviolet-curing antibacterial and anti-fouling material for touch surface and preparation method thereof |
| CN113045929A (en) * | 2021-03-20 | 2021-06-29 | 中山市中益油墨涂料有限公司 | Anti-fouling UV-LED offset printing ink and preparation method thereof |
| CN113817403B (en) * | 2021-08-16 | 2023-05-05 | 上海金力泰化工股份有限公司 | Water-based stain-resistant additive UV (ultraviolet) coating and preparation method and application thereof |
| CN114891435A (en) * | 2022-06-30 | 2022-08-12 | 湖南松井新材料股份有限公司 | Preparation method of water-based UV-cured wear-resistant anti-fouling matte coating and coating film |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250340A (en) * | 2008-04-03 | 2008-08-27 | 惠州市长润发涂料有限公司 | Ultraviolet light curing fingerprint resistant paint |
| CN101570653A (en) * | 2008-04-29 | 2009-11-04 | 汉达精密电子(昆山)有限公司 | Fingerprint resisting ultraviolet curing paint and operating method thereof |
| CN105038575A (en) * | 2015-09-21 | 2015-11-11 | 张家港康得新光电材料有限公司 | Water-based anti-dazzle UV coating, hard coated film and preparation method of hard coated film |
| CN105647257A (en) * | 2016-03-23 | 2016-06-08 | 珠海市佳伟力环保科技有限公司 | Water-based radiation-cured coating and use thereof |
-
2017
- 2017-08-31 CN CN201710767455.XA patent/CN108300274B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250340A (en) * | 2008-04-03 | 2008-08-27 | 惠州市长润发涂料有限公司 | Ultraviolet light curing fingerprint resistant paint |
| CN101570653A (en) * | 2008-04-29 | 2009-11-04 | 汉达精密电子(昆山)有限公司 | Fingerprint resisting ultraviolet curing paint and operating method thereof |
| CN105038575A (en) * | 2015-09-21 | 2015-11-11 | 张家港康得新光电材料有限公司 | Water-based anti-dazzle UV coating, hard coated film and preparation method of hard coated film |
| CN105647257A (en) * | 2016-03-23 | 2016-06-08 | 珠海市佳伟力环保科技有限公司 | Water-based radiation-cured coating and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108300274A (en) | 2018-07-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108300274B (en) | Water-based ultraviolet-curing anti-fingerprint coating and preparation method thereof | |
| CN102206462B (en) | Metal UV (Ultraviolet) coating | |
| CN1255487C (en) | Ultraviolet cured paint | |
| CN103073934B (en) | Ultraviolet curing anti-fingerprint coating for acrylic and composite material base material thereof | |
| CN103571314B (en) | The anti-fingerprint coating composition of ultraviolet light polymerization high rigidity for PET base material | |
| CN103540255B (en) | There is the ultraviolet light curing fingerprint resistant coating composition of impressionability energy | |
| CN103031034A (en) | White finish coat photocurable UV (ultraviolet) paint and preparation method thereof | |
| CN103555193A (en) | Ultraviolet light cured elastic polyurethane acrylate flat lacquer and preparation method thereof | |
| CN103614085A (en) | Shock resisting protective film with high light transmittance as well as preparation method thereof | |
| CN104194613A (en) | Recoatable UV-curing colored one-step-coating aluminum powder paint and preparation method thereof | |
| CN112778880A (en) | Light-cured matte stain-resistant floor coating composition and preparation method thereof | |
| CN110591512A (en) | Ultraviolet-curing vacuum coating wrinkle primer and preparation method thereof | |
| CN107619622A (en) | A kind of glass water resistance UV gloss oil and preparation method thereof | |
| CN113072858A (en) | Environment-friendly water-based graphene heavy-duty anticorrosive paint and preparation method thereof | |
| CN112980318A (en) | Composite board high-wear-resistance fingerprint-resistant matte UV (ultraviolet) hardening liquid and preparation method thereof | |
| CN113462232A (en) | Water-proof antifouling photocureable coating and preparation method and application thereof | |
| CN104152010A (en) | Ultraviolet-curable pollution-resistant coating | |
| CN111548715A (en) | Preparation method and application of high-light-transmission anti-yellowing plastic coating | |
| CN101148562A (en) | Environmental protection acrylic polyurethane bicomponent surface lacquer enamel | |
| CN108219644B (en) | Photocuring and hardening water transfer film and preparation method thereof | |
| CN105482683A (en) | Anti-fouling UV cured resin coating for LCD screen | |
| CN107501574B (en) | UV-cured water-based composite emulsion and preparation method and application thereof | |
| CN109161258B (en) | Metal substrate water-based graphene modified long-acting anticorrosive paint and preparation method thereof | |
| CN105585898B (en) | A kind of UV coating dumb light ink and preparation method thereof | |
| CN112724818B (en) | AG glass effect-imitated UV coating and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220909 Address after: Xinzhai Industrial Zone, Xiaoyue Town, Shangyu District, Shaoxing City, Zhejiang Province, 312300 Patentee after: ZHEJIANG UVCHEM SPECIAL COATINGS Co.,Ltd. Address before: 312369 Hangzhou Shangyu economic and Technological Development Zone, Shaoxing, Zhejiang Patentee before: ZHEJIANG YOUTAI NEW MATERIAL TECHNOLOGY CO.,LTD. |