CN103540255B - There is the ultraviolet light curing fingerprint resistant coating composition of impressionability energy - Google Patents
There is the ultraviolet light curing fingerprint resistant coating composition of impressionability energy Download PDFInfo
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- CN103540255B CN103540255B CN201310451134.0A CN201310451134A CN103540255B CN 103540255 B CN103540255 B CN 103540255B CN 201310451134 A CN201310451134 A CN 201310451134A CN 103540255 B CN103540255 B CN 103540255B
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Abstract
The invention discloses a kind of ultraviolet light curing fingerprint resistant coating composition with impressionability energy.Said composition comprises each component of following parts by weight: acrylate resin 20 ~ 50 parts, monomer 25 ~ 65 parts, light trigger 4 ~ 6 parts, solvent 100 ~ 250 parts, flow agent 0.05 ~ 0.5 part, antifouling resin 1 ~ 5 part.Compared with prior art, the invention provides there is anti-fingerprint effect while possess again the coating composition of ink printing; By using the fluorin modified crylic acid resin that molecular weight is large, in coating forming procedure, migration amount is relatively little, contributes to ink printing, and double bond participates in solidification, and after solidification, fluorine resin transport property is little, and coating performance is stablized, and Long-Term Properties change is little.
Description
Technical field
The present invention relates to ultraviolet-curing paint field, be specifically related to a kind of ultraviolet light curing fingerprint resistant coating composition with impressionability energy.
Background technology
Ultraviolet-curing paint (UV coating) has the advantages such as efficient, energy-conservation, suitability is wide, ambient cure, has been widely applied to the fields such as electronics, communication, chemical industry, machinery, furniture, ink.For the difference of used base material, can simply UV coating be divided into: plastic basis material UV coating, metallic substance UV coating, timber UV coating, inorganic materials UV coating, paper UV coating etc.
Along with the fast development of electronics, communication industry, demand for plastic basis material UV coating is also increasing, and the great development of electronic product touchization makes to propose new requirement to the UV coating of plastic basis material, the anti-fingerprint effect of screen is also more and more required in daily life.Patents report for the preparation of anti-fingerprint coating is more, through finding the retrieval of existing document, CN103073934A discloses a kind of ultraviolet light curing fingerprint resistant coating for acrylic and composite material base thereof, its coating water contact angle prepared is general all more than 100 °, and oil pen easily wipes; CN101570653B discloses a kind of fingerprint resisting ultraviolet curing paint and working method thereof, the easy wiping of oil pen; CN102675941A discloses a kind of UV and solidifies super-hydrophobic fingerprint-resistant coating and preparation method thereof.But disclosed most of anti-fingerprint patent all pursues the easy wiping of water contact angle high as far as possible and oil pen now, and ignore the coating possessing ink printing while exploitation has anti-fingerprint effect.
Summary of the invention
The object of the invention is to the deficiency overcoming the existence of above-mentioned prior art, a kind of ultraviolet light curing fingerprint resistant coating composition with impressionability energy is provided.
The object of the invention is to be achieved through the following technical solutions:
The present invention relates to a kind of ultraviolet light curing fingerprint resistant coating composition with impressionability energy, comprise each component of following parts by weight:
Preferably, described acrylate resin is one or more in aliphatic urethane acrylate resin, aliphatic polyester acrylate resin, aliphatic polyurethane methacrylate resin, aliphatic polyester methacrylate resin.
Preferably, described monomer is one or more in 1,6 hexanediol diacrylate, tripropylene glycol diacrylate, polyethyleneglycol diacrylate, Viscoat 295, trimethylolpropane trimethacrylate, ethoxyquin Viscoat 295, the third oxidation Viscoat 295, pentaerythritol triacrylate, tetramethylol methane tetraacrylate, ethoxyquin tetramethylol methane tetraacrylate, the third oxidation tetramethylol methane tetraacrylate, dipentaerythritol acrylate.
Preferably, described light trigger is one or more in benzophenone, 1-hydroxy-cyclohexyl-phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1 acetone, 2,4,6-trimethylbenzoy-dipheny phosphine oxides, isopropyl thioxanthone.
Preferably, described solvent is one or more in vinyl acetic monomer, propyl acetate, N-BUTYL ACETATE, acetone, butanone, Virahol, propyl carbinol, ethanol, propylene glycol monomethyl ether, ethylene glycol ethyl ether, 1-Methoxy-2-propyl acetate.
Preferably, described flow agent is one or more in organic silicon modified by polyether, polyester resin change properties of organic silicon, polydimethylsiloxane, fluorin modified crylic acid ester, acrylate copolymer.
Preferably, described antifouling resin is fluorin modified crylic acid ester resin, and weight-average molecular weight is 5000 ~ 10000.
Further preferably, the weight-average molecular weight of described fluorin modified crylic acid ester resin is 5000 ~ 7000.
Compared with prior art, the beneficial effect that the present invention has is: use the fluorin modified crylic acid resin that molecular weight is large, in coating forming procedure, migration amount is relatively little, contribute to ink printing, double bond participates in solidification, after solidification, fluorine resin transport property is little, and coating performance is stablized, and Long-Term Properties change is little.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.Following examples will contribute to those skilled in the art and understand the present invention further, but not limit the present invention in any form.It should be pointed out that to those skilled in the art, without departing from the inventive concept of the premise, some distortion and improvement can also be made.These all belong to protection scope of the present invention.
embodiment 1
The present embodiment relates to a kind of ultraviolet light curing fingerprint resistant coating composition with impressionability energy, comprises the component shown in table 1 and parts by weight.During preparation, raw material stirring described in table is mixed.
This coating is through 900mJ/cm
2energy-curable after performance as follows: coating water contact angle is 79.5 °, fingerprint pressing wiping 60 noresidues, and Seiko HAC(is dense 710 black) 70 DEG C, ink solidification test attachment in 1 hour do not fall.
embodiment 2
The present embodiment relates to a kind of ultraviolet light curing fingerprint resistant coating composition with impressionability energy, comprises the component shown in table 1 and parts by weight.
This coating is through 900mJ/cm
2energy-curable after performance as follows: coating water contact angle is 83.2 °, fingerprint pressing wiping 70 noresidues, and Seiko HAC(120 is white) 70 DEG C, ink solidification test attachment in 1 hour do not fall.
embodiment 3
The present embodiment relates to a kind of ultraviolet light curing fingerprint resistant coating composition with impressionability energy, comprises the component shown in table 1 and parts by weight.
This coating is through 900mJ/cm
2energy-curable after performance as follows: coating water contact angle is 84.2 °, fingerprint pressing wiping 70 noresidues, and Seiko HAC(is dense 710 black) 70 DEG C, ink solidification test attachment in 1 hour do not fall.
embodiment 4
The present embodiment relates to a kind of ultraviolet light curing fingerprint resistant coating composition with impressionability energy, comprises the component shown in table 1 and parts by weight.
This coating is through 900mJ/cm
2energy-curable after performance as follows: coating water contact angle is 73.5 °, fingerprint pressing wiping 30 noresidues, and Seiko HAC(is dense 710 black) 70 DEG C, ink solidification test attachment in 1 hour do not fall.
embodiment 5
The present embodiment relates to a kind of ultraviolet light curing fingerprint resistant coating composition with impressionability energy, comprises the component shown in table 1 and parts by weight.
This coating is through 900mJ/cm
2energy-curable after performance as follows: coating water contact angle is 78 °, fingerprint pressing wiping 60 noresidues, and Seiko HAC(is dense 710 black) 70 DEG C, ink solidification test attachment in 1 hour do not fall.
embodiment 6
The present embodiment relates to a kind of ultraviolet light curing fingerprint resistant coating composition with impressionability energy, comprises the component shown in table 1 and parts by weight.
This coating is through 900mJ/cm
2energy-curable after performance as follows: coating water contact angle is 77.5 °, fingerprint pressing wiping 60 noresidues, and Seiko HAC(is dense 710 black) 70 DEG C, ink solidification test attachment in 1 hour do not fall.
comparative example 1
This comparative example comprises the component shown in table 1 and parts by weight.
This coating is through 900mJ/cm
2energy-curable after performance as follows: coating water contact angle is 105.5 °, fingerprint pressing wiping 80 noresidues, and Seiko HAC(is dense 710 black) 70 DEG C, ink solidification test attachment in 1 hour falls.
Each component and parts by weight thereof in table 1 embodiment and comparative example
Above specific embodiments of the invention are described.It is to be appreciated that the present invention is not limited to above-mentioned particular implementation, those skilled in the art can make various distortion or amendment within the scope of the claims, and this does not affect flesh and blood of the present invention.
Claims (5)
1. there is a ultraviolet light curing fingerprint resistant coating composition for impressionability energy, it is characterized in that, comprise each component of following parts by weight:
Described acrylate resin is one or more in aliphatic urethane acrylate resin, aliphatic polyester acrylate resin, aliphatic polyurethane methacrylate resin, aliphatic polyester methacrylate resin;
Described antifouling resin is fluorin modified crylic acid ester resin, and weight-average molecular weight is 5000 ~ 10000;
Described monomer is one or more in 1,6 hexanediol diacrylate, tripropylene glycol diacrylate, polyethyleneglycol diacrylate, Viscoat 295, trimethylolpropane trimethacrylate, ethoxyquin Viscoat 295, the third oxidation Viscoat 295, pentaerythritol triacrylate, tetramethylol methane tetraacrylate, ethoxyquin tetramethylol methane tetraacrylate, the third oxidation tetramethylol methane tetraacrylate, dipentaerythritol acrylate.
2. the ultraviolet light curing fingerprint resistant coating composition with impressionability energy according to claim 1; it is characterized in that; described light trigger is benzophenone, 1-hydroxy-cyclohexyl-phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1 acetone, 2; one or more in 4,6-trimethylbenzoy-dipheny phosphine oxide, isopropyl thioxanthone.
3. the ultraviolet light curing fingerprint resistant coating composition with impressionability energy according to claim 1, it is characterized in that, described solvent is one or more in vinyl acetic monomer, propyl acetate, N-BUTYL ACETATE, acetone, butanone, Virahol, propyl carbinol, ethanol, propylene glycol monomethyl ether, ethylene glycol ethyl ether, 1-Methoxy-2-propyl acetate.
4. the ultraviolet light curing fingerprint resistant coating composition with impressionability energy according to claim 1, it is characterized in that, described flow agent is one or more in organic silicon modified by polyether, polyester resin change properties of organic silicon, polydimethylsiloxane, fluorin modified crylic acid ester, acrylate copolymer.
5. the ultraviolet light curing fingerprint resistant coating composition with impressionability energy according to claim 1, it is characterized in that, the weight-average molecular weight of described fluorin modified crylic acid ester resin is 5000 ~ 7000.
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| CN103540255B true CN103540255B (en) | 2016-03-16 |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273585B (en) * | 2015-10-20 | 2017-11-21 | 宁波大榭开发区综研化学有限公司 | A kind of UV separates antifouling application composition, cured film and preparation method |
| CN105419619A (en) * | 2015-11-27 | 2016-03-23 | 常熟市晓轶金属配件厂 | Tension disc for textile machinery |
| CN105623477A (en) * | 2016-03-17 | 2016-06-01 | 柳州市凯佰化工有限公司 | Anti-fingerprint ultraviolet curing high-gloss varnish |
| CN106243990A (en) * | 2016-08-31 | 2016-12-21 | 侯颖 | A kind of ultraviolet light polymerization transfer coatings compositions |
| CN107641455B (en) * | 2017-09-27 | 2019-12-24 | 芜湖春风新材料有限公司 | Anti-fingerprint UV coating for automotive interior parts, and preparation method and application thereof |
| CN107974152A (en) * | 2017-11-15 | 2018-05-01 | 深圳雅联实业有限公司 | A kind of anti-pollution UV photocureable coating and preparation method thereof |
| CN108329827A (en) * | 2018-02-11 | 2018-07-27 | 东莞市威霸涂料有限公司 | A kind of coating easy to clean and preparation method |
| CN109880411A (en) * | 2018-12-21 | 2019-06-14 | 宁波激智科技股份有限公司 | A kind of hardened layer coating fluid and a kind of cured film |
| CN110183926B (en) * | 2019-05-09 | 2020-05-22 | 华南理工大学 | Anti-fouling organic-inorganic silicon hybrid coating and preparation method and application thereof |
| CN110511663B (en) * | 2019-09-06 | 2021-09-10 | 江苏皇冠新材料科技有限公司 | Printable hardened film formula suitable for oil-water dual-purpose ink and printing film |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250340A (en) * | 2008-04-03 | 2008-08-27 | 惠州市长润发涂料有限公司 | Ultraviolet light curing fingerprint resistant paint |
| CN102643600A (en) * | 2012-04-18 | 2012-08-22 | 上海维凯化学品有限公司 | Ultraviolet light curing coating composition |
| CN102807805A (en) * | 2011-05-31 | 2012-12-05 | 比亚迪股份有限公司 | Ultraviolet curing coating composition and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5803260B2 (en) * | 2011-05-17 | 2015-11-04 | 横浜ゴム株式会社 | Curable resin composition |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250340A (en) * | 2008-04-03 | 2008-08-27 | 惠州市长润发涂料有限公司 | Ultraviolet light curing fingerprint resistant paint |
| CN102807805A (en) * | 2011-05-31 | 2012-12-05 | 比亚迪股份有限公司 | Ultraviolet curing coating composition and preparation method thereof |
| CN102643600A (en) * | 2012-04-18 | 2012-08-22 | 上海维凯化学品有限公司 | Ultraviolet light curing coating composition |
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