CN102964981B - A kind of water-based UV metal decorating gloss oil and preparation method thereof - Google Patents
A kind of water-based UV metal decorating gloss oil and preparation method thereof Download PDFInfo
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- CN102964981B CN102964981B CN201210481526.7A CN201210481526A CN102964981B CN 102964981 B CN102964981 B CN 102964981B CN 201210481526 A CN201210481526 A CN 201210481526A CN 102964981 B CN102964981 B CN 102964981B
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Abstract
The present invention relates to gloss oil technical field, particularly relate to a kind of water-based UV metal decorating gloss oil and preparation method thereof, water-based UV metal decorating gloss oil of the present invention, is made up of the raw material of following weight part: 30 ~ 40 parts of water-based ultraviolet (UV) curable resins, 8 ~ 18 parts of UV curing acrylic emulsions, 12 ~ 18 parts of polyethyleneglycol diacrylates, 8 ~ 15 parts of ethoxyquin Viscoat 295s, 0.5 ~ 1 part of silicone antifoam agent, 1 ~ 5 part of organosilicon flow agent, 5 ~ 15 parts of alcohol analog assistants, 4 ~ 8 parts of light triggers, 2 ~ 6 parts of adhesion promoters, 4 ~ 10 parts of water.The present invention only adopts two kinds of water-based UV monomers can optimize the performance of gloss oil, simplifies the kind of UV monomer, and the usage quantity of UV monomer reduces, after glazing, residual smell is lower, and these two kinds of water-based UV monomers are low irritant UV monomer, little, safer concerning polluting Printing ink producing person and user.
Description
Technical field
The present invention relates to gloss oil technical field, particularly relate to a kind of water-based UV metal decorating gloss oil and preparation method thereof.
Background technology
Uv radiation curing technology is a kind of brand-new green technology developed since the seventies in the world, the ultraviolet-curing paint utilizing this technology to produce is referred to as UV coating, UV coating has not containing VOC, environmental pollution is little, curing speed is fast, save the energy, cured product performance good, be suitable for the advantages such as high-speed automated production.UV coating, due to the technology of uniqueness and application advantage, is applied to electronic product, machinofacture, the industry-by-industries such as anti-corrosion of metal and field rapidly widely.In recent years, along with the raising of environmental protection cry in world wide, the Water-borne modification research of UV coating also obtain significant progress, it has given full play to the comprehensive effectiveness that UV curing mode and water-based dilute two kinds of technology, has more the advantage of construction, economy, safety, application aspect than traditional solvent-borne type UV coating.
Application number is the Chinese invention patent of 201010530069.7, disclose a kind of high light wearable mobile phone UV coating oil, it adopts low-viscosity polyester acrylate, aliphatic urethane acrylate is matrix resin, be equipped with reactive thinner ethoxyquin tetramethylol methane tetraacrylate, Viscoat 295, tri (propylene glycol) diacrylate, 1, 6-hexanediyl ester and Isooctyl acrylate monomer, thinner alcohol and vinyl acetic monomer, light trigger benzophenone and 1-hydroxycyclohexylphenylketone, reactive amine aided initiating, defoamer, flow agent and slip(ping)agent etc. are uniformly mixed to form.In order to improve the performance of gloss oil, this UV coating oil adds the UV monomer of four kinds, but the quantity of adding UV monomer too much easily makes its residual smell large, when after the glazing using it for printed matter, the smell that pungency is strong can be remained, very large to the harm of operator, and certain pollution is caused to air, do not meet the requirement of environmental protection.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, and provide a kind of residual smell low, pollute little water-based UV metal decorating gloss oil and preparation method thereof.
The present invention is achieved through the following technical solutions.
A kind of water-based UV metal decorating gloss oil, is made up of the raw material of following weight part:
Water-based ultraviolet (UV) curable resin 30 ~ 40 parts
UV curing acrylic emulsion 8 ~ 18 parts
Polyethyleneglycol diacrylate 12 ~ 18 parts
Ethoxyquin Viscoat 295 8 ~ 15 parts
Silicone antifoam agent 0.5 ~ 1 part
Organosilicon flow agent 1 ~ 5 part
Alcohol analog assistant 5 ~ 15 parts
Light trigger 4 ~ 8 parts
Adhesion promoter 2 ~ 6 parts
4 ~ 10 parts, water.
Preferably, a kind of water-based UV metal decorating gloss oil, is made up of the raw material of following weight part:
Water-based ultraviolet (UV) curable resin 30 ~ 35 parts
UV curing acrylic emulsion 10 ~ 16 parts
Polyethyleneglycol diacrylate 13 ~ 17 parts
Ethoxyquin Viscoat 295 10 ~ 13 parts
Silicone antifoam agent 0.5 ~ 0.8 part
Organosilicon flow agent 2 ~ 4 parts
Alcohol analog assistant 8 ~ 12 parts
Light trigger 5 ~ 7 parts
Adhesion promoter 3 ~ 5 parts
5 ~ 8 parts, water.
More preferred, a kind of water-based UV metal decorating gloss oil, is made up of the raw material of following weight part:
Water-based ultraviolet (UV) curable resin 35 ~ 40 parts
UV curing acrylic emulsion 13 ~ 15 parts
Polyethyleneglycol diacrylate 15 ~ 16 parts
Ethoxyquin Viscoat 295 11 ~ 12 parts
Silicone antifoam agent 0.5 ~ 0.6 part
Organosilicon flow agent 2 ~ 3 parts
Alcohol analog assistant 10 ~ 11 parts
Light trigger 5 ~ 6 parts
Adhesion promoter 3 ~ 4 parts
6 ~ 7 parts, water.
Wherein, described water-based ultraviolet (UV) curable resin is aliphatic urethane acrylate, and aliphatic urethane acrylate is the CN9245 of Sartomer, appearance transparent, and solid content is 100%, viscosity (cps.25 DEG C) 20000, and functionality is 3, and second-order transition temperature is 26 DEG C.CN9245 is the aliphatic urethane acrylate of dilutable water, is convenient to the cleaning of equipment and container, and its quick solidifying, hardness is high, has outstanding wear resistance and sticking power.
Wherein, described UV curing acrylic emulsion is the CRAUMUL 2718 of Cray Willie, solid content is 45%, viscosity (mPa.s) < 1000, pH is 7.5-8.5, minimum film-forming temperature < 0 DEG C, and particle diameter is 80nm, there is fabulous chemical resistance, fabulous hardness and grinability.
Wherein, described polyethyleneglycol diacrylate is polyoxyethylene glycol (400) diacrylate, is the SR344 of Sartomer, appearance transparent, and solid content is 100%, viscosity (cps.25 DEG C) 57, and functionality is 2, and second-order transition temperature is 3 DEG C.SR344 is low functionality monomer, and second-order transition temperature is lower, greatly can reduce the cross-linking density of cured film, improves the snappiness of layer of ink, and is water-soluble UV monomer, low skin irritation, safety and environmental protection, quick solidifying.
Wherein, described ethoxyquin Viscoat 295 is (20) ethoxyquin Viscoat 295, is the SR415 of Sartomer, appearance transparent, solid content is 100%, viscosity (cps.25 DEG C) 225, functionality is 3, and second-order transition temperature is 38 DEG C.SR415 is water-soluble UV monomer, for the modification product of Viscoat 295 (TMPTA), not only there is identical performance and the purposes widely of TMPTA, have more the advantage of low viscosity, high curing rate, improve the snappiness of cured film, strengthen sticking power, reduce the pungency to skin, safety and environmental protection.
Wherein, described silicone antifoam agent is modified polyorganosiloxane interpolymer solution, and modified polyorganosiloxane interpolymer solution is the BYK-020 of German Bi Ke chemistry, prevents foam from generating when gloss oil is produced and apply.
Wherein, described organosilicon flow agent is the BYK-333 of Bi Ke chemistry.BYK-333 outward appearance is the micro-turbid liquid of clarification, and content is 99%, density 1.04kg/m
3, BYK-333 has good intermiscibility, can improve non-stick property in aqueous systems, prevents floating color separation in most of solvent systems, also can improve the smoothness on layer of ink surface, improves the wetting effect of ground, increases the gloss of layer of ink.
Wherein, described alcohol analog assistant is dehydrated alcohol, colourless transparent liquid, content (CH
3cH
2oH)/%>=99.8, density (200C)/(g/mL) 0.789-0.791, luminosity is good, caking ability is high, heat-resisting sun-proof humidity.
Wherein, described adhesion promoter is organic fluorine modified polyacrylate, and organic fluorine modified polyacrylate is the leveling3555 of Si Luoke, the faint yellow as clear as crystal liquid of outward appearance, effective content 100%, proportion is 0.97, and viscosity (25 DEG C/cps) is 25.Leveling3555 greatly can reduce the surface tension of system, increases the wettability of base material and sticking power, quick levelling, prevents the advantage of shrinkage cavity, does not promote surperficial smoothness, does not affect plating property, have no effect to recoatability and ply adhesion.
Wherein, described light trigger is 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone, and 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone is the IRGACURE 907 of Beijing English power.The molecular weight of IRGACURE 907 is 251.3446, and density is 1.19g/cm
3, fusing point is 74-76 DEG C, and boiling point is 410.5 ° of C, flash-point is 202.1 ° of C, IRGACURE 907 is a kind of ultraviolet initiators efficiently, and its distinctive high-selenium corn characteristic makes it be particularly suitable for UV curable coating, can make the long-term not yellowing of UV curable coating and extend the storage time.
Wherein, a kind of preparation method of water-based UV metal decorating gloss oil, comprises following methods step:
A, water-based ultraviolet (UV) curable resin, UV curing acrylic emulsion, polyethyleneglycol diacrylate, ethoxyquin Viscoat 295 to be added in pill tank by weight and stir, churning time is 25 ~ 35min;
B, the material mixed in step a is added light trigger by weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 25 ~ 35min;
C, the material stirring that mixes in the silicone antifoam agent of above-mentioned weight part, organosilicon flow agent, alcohol analog assistant, adhesion promoter, water and step b is even, churning time is 25 ~ 35min, obtained water-based UV metal decorating gloss oil.
Detect all technical of obtained water-based UV metal decorating gloss oil, the method of inspection of obtained water-based UV metal decorating gloss oil is: adopt Digital Viscometer to measure viscosity, YQM-1B ink viscosity instrument is adopted to measure stickiness, adopt pH tester pH value determination, adopt a dyne surface tension, adopt 65 ° of standard gloss testers to measure glossiness, adopt hundred lattice methods (3m adhesive tape) to measure sticking power.
Beneficial effect of the present invention is: ethoxyquin Viscoat 295 of the present invention is the modification product of Viscoat 295 (TMPTA), not only there is identical performance and the purposes widely of TMPTA, have more low viscosity, the advantage of high curing rate, therefore the present invention only need adopt polyethyleneglycol diacrylate and ethoxyquin Viscoat 295 two kinds of water-based UV monomers can optimize the performance of gloss oil, simplify the kind of UV monomer, the usage quantity of UV monomer reduces, after glazing, residual smell is lower, and above-mentioned two kinds of water-based UV monomers are low irritant UV monomer, little concerning polluting Printing ink producing person and user, safer.
Preparation method of the present invention is simple, strong operability, is easy to realize, and production cost is low, is conducive to popularity application.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
embodiment 1.
A kind of water-based UV metal decorating gloss oil, is made up of the raw material of following weight part: 35 parts of aliphatic urethane acrylates, 13 parts of UV curing acrylic emulsions, 15.5 parts of polyoxyethylene glycol (400) diacrylates, 11 parts of (20) ethoxyquin Viscoat 295s, 0.5 part of modified polyorganosiloxane interpolymer solution, 2 parts of organosilicon flow agents, 10 parts of dehydrated alcohols, 5 parts of 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone, 3 parts of organic fluorine modified polyacrylates, 5 parts of water.
The preparation method of a kind of water-based UV metal decorating gloss oil of the present embodiment, comprise following methods step: a, aliphatic urethane acrylate, UV curing acrylic emulsion, polyoxyethylene glycol (400) diacrylate, (20) ethoxyquin Viscoat 295 to be added in pill tank by weight and stir, churning time is 30min; B, the material mixed in step a is added 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone by weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 30min; C, the material stirring that mixes in the modified polyorganosiloxane interpolymer solution of above-mentioned weight part, organosilicon flow agent, dehydrated alcohol, organic fluorine modified polyacrylate, water and step b is even, churning time is 30min, obtained water-based UV metal decorating gloss oil.
Detect all technical of obtained water-based UV metal decorating gloss oil, properties test index is as shown in table 1.
embodiment 2.
A kind of water-based UV metal decorating gloss oil, is made up of the raw material of following weight part: 32 parts of aliphatic urethane acrylates, 15 parts of UV curing acrylic emulsions, 18 parts of polyoxyethylene glycol (400) diacrylates, 8 parts of (20) ethoxyquin Viscoat 295s, 0.6 part of modified polyorganosiloxane interpolymer solution, 3 parts of organosilicon flow agents, 8 parts of dehydrated alcohols, 5 parts of 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone, 2 parts of organic fluorine modified polyacrylates, 6 parts of water.
The preparation method of a kind of water-based UV metal decorating gloss oil of the present embodiment, comprise following methods step: a, aliphatic urethane acrylate, UV curing acrylic emulsion, polyoxyethylene glycol (400) diacrylate, (20) ethoxyquin Viscoat 295 to be added in pill tank by weight and stir, churning time is 30min; B, the material mixed in step a is added 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone by weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 35min; C, the material stirring that mixes in the modified polyorganosiloxane interpolymer solution of above-mentioned weight part, organosilicon flow agent, dehydrated alcohol, organic fluorine modified polyacrylate, water and step b is even, churning time is 32min, obtained water-based UV metal decorating gloss oil.
Detect all technical of obtained water-based UV metal decorating gloss oil, properties test index is as shown in table 1.
embodiment 3.
A kind of water-based UV metal decorating gloss oil, is made up of the raw material of following weight part: 36 parts of aliphatic urethane acrylates, 12 parts of UV curing acrylic emulsions, 16 parts of polyoxyethylene glycol (400) diacrylates, 10 parts of (20) ethoxyquin Viscoat 295s, 0.7 part of modified polyorganosiloxane interpolymer solution, 4 parts of organosilicon flow agents, 12 parts of dehydrated alcohols, 6 parts of 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone, 3 parts of organic fluorine modified polyacrylates, 7 parts of water.
The preparation method of a kind of water-based UV metal decorating gloss oil of the present embodiment, comprise following methods step: a, aliphatic urethane acrylate, UV curing acrylic emulsion, polyoxyethylene glycol (400) diacrylate, (20) ethoxyquin Viscoat 295 to be added in pill tank by weight and stir, churning time is 30min; B, the material mixed in step a is added 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone by weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 35min; C, the material stirring that mixes in the modified polyorganosiloxane interpolymer solution of above-mentioned weight part, organosilicon flow agent, dehydrated alcohol, organic fluorine modified polyacrylate, water and step b is even, churning time is 32min, obtained water-based UV metal decorating gloss oil.
Detect all technical of obtained water-based UV metal decorating gloss oil, properties test index is as shown in table 1.
embodiment 4.
A kind of water-based UV metal decorating gloss oil, is made up of the raw material of following weight part: 30 parts of aliphatic urethane acrylates, 8 parts of UV curing acrylic emulsions, 12 parts of polyoxyethylene glycol (400) diacrylates, 8 parts of (20) ethoxyquin Viscoat 295s, 0.5 part of modified polyorganosiloxane interpolymer solution, 1 part of organosilicon flow agent, 5 parts of dehydrated alcohols, 4 parts of 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone, 2 parts of organic fluorine modified polyacrylates, 4 parts of water.
The preparation method of a kind of water-based UV metal decorating gloss oil of the present embodiment, comprise following methods step: a, aliphatic urethane acrylate, UV curing acrylic emulsion, polyoxyethylene glycol (400) diacrylate, (20) ethoxyquin Viscoat 295 to be added in pill tank by weight and stir, churning time is 28min; B, the material mixed in step a is added 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone by weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 26min; C, the material stirring that mixes in the modified polyorganosiloxane interpolymer solution of above-mentioned weight part, organosilicon flow agent, dehydrated alcohol, organic fluorine modified polyacrylate, water and step b is even, churning time is 32min, obtained water-based UV metal decorating gloss oil.
Detect all technical of obtained water-based UV metal decorating gloss oil, properties test index is as shown in table 1.
embodiment 5.
A kind of water-based UV metal decorating gloss oil, is made up of the raw material of following weight part: 40 parts of aliphatic urethane acrylates, 18 parts of UV curing acrylic emulsions, 18 parts of polyoxyethylene glycol (400) diacrylates, 15 parts of (20) ethoxyquin Viscoat 295s, 1 part of modified polyorganosiloxane interpolymer solution, 5 parts of organosilicon flow agents, 15 parts of dehydrated alcohols, 8 parts of 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone, 6 parts of organic fluorine modified polyacrylates, 10 parts of water.
The preparation method of a kind of water-based UV metal decorating gloss oil of the present embodiment, comprise following methods step: a, aliphatic urethane acrylate, UV curing acrylic emulsion, polyoxyethylene glycol (400) diacrylate, (20) ethoxyquin Viscoat 295 to be added in pill tank by weight and stir, churning time is 35min; B, the material mixed in step a is added 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone by weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 25min; C, the material stirring that mixes in the modified polyorganosiloxane interpolymer solution of above-mentioned weight part, organosilicon flow agent, dehydrated alcohol, organic fluorine modified polyacrylate, water and step b is even, churning time is 30min, obtained water-based UV metal decorating gloss oil.
Detect all technical of obtained water-based UV metal decorating gloss oil, properties test index is as shown in table 1.
The properties test index of the water-based UV metal decorating gloss oil that embodiment 1 ~ embodiment 5 is made is as table 1.
Table 1
。
As can be seen from the properties test index of embodiment 1 ~ embodiment 5, the water-based UV metal decorating gloss oil that the present invention obtains has good glossiness, sticking power, and mechanical stability is excellent, stable.
The above embodiment, just better embodiment of the present invention, be not limit the scope of the present invention, therefore all equivalences done according to structure, feature and the principle described in the present patent application the scope of the claims change or modify, and all should comprise in patent claim of the present invention.
Claims (6)
1. a water-based UV metal decorating gloss oil, is characterized in that: be made up of the raw material of following weight part:
Water-based ultraviolet (UV) curable resin 30 ~ 40 parts
UV curing acrylic emulsion 8 ~ 18 parts
Polyethyleneglycol diacrylate 12 ~ 18 parts
Ethoxyquin Viscoat 295 8 ~ 15 parts
Silicone antifoam agent 0.5 ~ 1 part
Organosilicon flow agent 1 ~ 5 part
Alcohol analog assistant 5 ~ 15 parts
Light trigger 4 ~ 8 parts
Adhesion promoter 2 ~ 6 parts
4 ~ 10 parts, water;
Wherein, described adhesion promoter is organic fluorine modified polyacrylate, and organic fluorine modified polyacrylate is the leveling3555 of Si Luoke;
Wherein, described alcohol analog assistant is dehydrated alcohol;
Wherein, described light trigger is 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone, and 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone is the IRGACURE 907 of Beijing English power;
The preparation method of described water-based UV metal decorating gloss oil comprises following methods step:
A, water-based ultraviolet (UV) curable resin, UV curing acrylic emulsion, polyethyleneglycol diacrylate, ethoxyquin Viscoat 295 to be added in pill tank by weight and stir, churning time is 25 ~ 35min;
B, the material mixed in step a is added light trigger by weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 25 ~ 35min;
C, the material stirring that mixes in the silicone antifoam agent of above-mentioned weight part, organosilicon flow agent, alcohol analog assistant, adhesion promoter, water and step b is even, churning time is 25 ~ 35min, obtained water-based UV metal decorating gloss oil.
2. a kind of water-based UV metal decorating gloss oil according to claim 1, is characterized in that: be made up of the raw material of following weight part:
Water-based ultraviolet (UV) curable resin 30 ~ 35 parts
UV curing acrylic emulsion 10 ~ 16 parts
Polyethyleneglycol diacrylate 13 ~ 17 parts
Ethoxyquin Viscoat 295 10 ~ 13 parts
Silicone antifoam agent 0.5 ~ 0.8 part
Organosilicon flow agent 2 ~ 4 parts
Alcohol analog assistant 8 ~ 12 parts
Light trigger 5 ~ 7 parts
Adhesion promoter 3 ~ 5 parts
5 ~ 8 parts, water.
3. a kind of water-based UV metal decorating gloss oil according to claim 1, is characterized in that: be made up of the raw material of following weight part:
Water-based ultraviolet (UV) curable resin 35 ~ 40 parts
UV curing acrylic emulsion 13 ~ 15 parts
Polyethyleneglycol diacrylate 15 ~ 16 parts
Ethoxyquin Viscoat 295 11 ~ 12 parts
Silicone antifoam agent 0.5 ~ 0.6 part
Organosilicon flow agent 2 ~ 3 parts
Alcohol analog assistant 10 ~ 11 parts
Light trigger 5 ~ 6 parts
Adhesion promoter 3 ~ 4 parts
6 ~ 7 parts, water.
4. a kind of water-based UV metal decorating gloss oil according to claim 1, it is characterized in that: described water-based ultraviolet (UV) curable resin is aliphatic urethane acrylate, aliphatic urethane acrylate is the CN9245 of Sartomer.
5. a kind of water-based UV metal decorating gloss oil according to claim 1, it is characterized in that: described polyethyleneglycol diacrylate is the SR344 of Sartomer, described ethoxyquin Viscoat 295 is the SR415 of Sartomer.
6. a kind of water-based UV metal decorating gloss oil according to claim 1, is characterized in that: described silicone antifoam agent is modified polyorganosiloxane interpolymer solution, and modified polyorganosiloxane interpolymer solution is the BYK-020 of German Bi Ke chemistry.
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| CN104231685B (en) * | 2013-06-09 | 2017-02-08 | 展辰新材料集团股份有限公司 | Water-based UV paint used on organic glass, and preparation method thereof |
| CN104974648A (en) * | 2014-04-11 | 2015-10-14 | 昆山市万胜化工有限公司 | High-performance aqueous UV undercoat and preparation method thereof |
| EP2960306B1 (en) * | 2014-06-26 | 2020-12-23 | Agfa Nv | Aqueous radiation curable inkjet inks |
| CN104277631A (en) * | 2014-09-24 | 2015-01-14 | 安徽省中彩印务有限公司 | Non-toxic brightening oil for glazing technique |
| CN105385284B (en) * | 2015-12-30 | 2018-05-11 | 上海奇想青晨新材料科技股份有限公司 | A kind of aqueous UV base coat and preparation method thereof |
| CN111718647B (en) * | 2019-03-19 | 2022-04-15 | 立邦涂料（中国）有限公司 | Environment-friendly water-based UV coating and preparation method thereof |
| CN115746690B (en) * | 2022-12-06 | 2023-08-22 | 广东希贵光固化材料有限公司 | Water-based UV glass transparent gloss oil |
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| CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| CN102226049A (en) * | 2011-05-27 | 2011-10-26 | 东周化学工业（昆山）有限公司 | Printable ultraviolet light solidified waterproof printing ink for optical disk |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| CN102226049A (en) * | 2011-05-27 | 2011-10-26 | 东周化学工业（昆山）有限公司 | Printable ultraviolet light solidified waterproof printing ink for optical disk |
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