CN105482689B - Peelable blue glue and preparation method thereof - Google Patents
Peelable blue glue and preparation method thereof Download PDFInfo
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- CN105482689B CN105482689B CN201610038540.8A CN201610038540A CN105482689B CN 105482689 B CN105482689 B CN 105482689B CN 201610038540 A CN201610038540 A CN 201610038540A CN 105482689 B CN105482689 B CN 105482689B
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- blue glue
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses peelable blue glue of one kind and preparation method thereof.The peelable blue glue of the present invention, calculate, be made up of 60 150 parts of UV solidified resins A, 60 150 parts of UV solidified resins B, 0.05 0.1 parts of levelling agents, 1 10 parts of wetting agent, 0.2 1 parts of defoamer, 1 10 parts of UV mill bases, 35 parts of light trigger A and 35 parts of photoinitiator b by weight.After the peelable blue glue film of the present invention, there are quick setting capabilities after being irradiated through 365nmUV LEDs, adhesion is good, non-scale is come off, peeled off easily, completely, and residual stain is not flowed；It can be applied to the insulating of the materials such as PET, ITO conducting film, ito glass, mobile phone glass, strengthened glass form, moistureproof, anti-pollution and scratch resistant protection.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of peelable blue glue and preparation method thereof.
Background technology
In recent years, the fast development of digital product has driven the fast development of touch-screen industry.High performance touch-screen system
Standby technique needs to lose the ink of function with resistance or metal surface is processed " peelable blue gel ", " surface protective glue " of protection.
When manufacturing printed board, some parts will often be covered using adhesive on plate, in order to avoid poured during scolding tin by tin, such as golden hand
Finger, interface card, the plate face of carbonaceous conductive button and larger area, these are required for optionally scolding tin and multiple continuously scolding tin,
Such as SMD hybrid precast, Reflow Soldering craft and automatic and other soldering tin techniques etc..Peelable blue gel is used for reference in PCB industry printed boards
Protected mode in technique, avoids touch-screen from sustaining damage in the mill using printing peelable glue, improves production efficiency and production
Product quality.Generally, peelable glue is a kind of one pack system touch-screen special isolation protection pliability ink, and color is sticky for blueness
Shape liquid, is more prone to peel off, toughness can also be strengthened, and hand can be used after application by the peelable gel coating after high temperature resistant
Or instrument is easily peeled off, without having residue in material surface or contaminated materials, it is not necessary to secondary cleaning, with attachment
Power is good, not cull, endurance (acid-base property) it is excellent, smooth light is easy-peel, the advantages of easy to operate.It is mainly used in touch-screen thoroughly
Bright ITO electro-conductive glass, ito thin film, the insulation plated film flow of PET film, can be dried by being screen printed onto on PET film and glass
Be roasted into after film and play a part of preventing material contaminated in process of production or scratch, on the touchscreen, lower circuit bonding before,
It can be taken off, and be once stripped clean with simple and easy method.
General heated more than 100 DEG C of current peelable blue glue is solidified, and solidification temperature is high, and typically peelable
Blue glue is same there is also the time is long, stripping process there are problems that it is cumbersome, have.
Based on background above, it is necessary to develop one kind can rapid curing, the good non-scale of adhesion come off, with peel off easily,
Completely, peelable blue glue of high temperature resistant of the good peeling effect such as residual stain and preparation method thereof is not flowed.
The content of the invention
In order to overcome the deficiencies in the prior art, there is rapid curing, with noctilucence it is an object of the invention to provide one kind
Peelable blue glue of visual capabilities and preparation method thereof.The peelable blue glue high temperature resistant prepared, peeling effect is good.
Technical scheme is specifically described as follows
A kind of peelable blue glue, is calculated by weight, and its raw material composition and content are as follows：
Wherein：
Described UV solidified resins A structural formula is as follows：
Wherein：M is the integer in the range of 1-30；N is the integer in the range of 1-30；
Described UV solidified resins B is toughened resin；
Described UV mill bases are mill base indigo plant F4049；
Described light trigger A be selected from BASF Irgacure1173, Irgacure 184D, Irgacure TPO,
Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular light draw
Send out the one or more in agent Esacure KIP 150；
Described photoinitiator b be selected from BASF BASF light triggers Irgacure 2959, IRGACURE500 or
It is one or more of in IRGACURE819 DW.
In the present invention, described UV solidified resins A is calculated by weight, and its raw material composition and content are as follows：
Described UV solidified resins A is prepared as follows：
Methyl Hydrogen Polysiloxane Fluid and ethoxylated trimethylolpropane triacrylate are proportionally added into reaction vessel,
Polymerization inhibitor is added, protective gas is passed through, stirs and heats, 60~80 DEG C are warming up to, catalyst is added, the lower constant temperature 3 of stirring~
5h, stops heating, treats that temperature drops to room temperature, produce UV solidified resins A.
In the present invention, described UV solidified resins B is selected from epoxy acrylate, urethane acrylate, polyester acrylic
One or more in ester or polyether acrylate.
In the present invention, described levelling agent be selected from the high Tego Glide 410 of enlightening, Germany BYK Bi Ke BYK-UV3510,
One or more in BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348；Described wetting agent choosing
One or both of NP-100 or Germany's levelling agents of BYK 333 from LG-DOW company；The defoamer is selected from Germany
One kind or several in BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038
Kind.
The present invention also provides a kind of preparation method of peelable blue glue, comprises the following steps that：
According to formula, wetting agent, levelling agent, froth breaking are added in control rotating speed 300-1400r/min high speed dispersor
Agent and UV mill bases, 300r/min is down to after disperseing 15-20min under 600-800r/min rotating speeds by rotating speed, adds UV solidification trees
Fat A, UV solidified resin B and light trigger A, photoinitiator b, continue scattered 50-100min, are well mixed, that is, obtain peelable
Blue glue.
The useful achievement of the present invention is as follows：
The present invention a kind of peelable blue glue, due to the present invention a kind of peelable blue glue curing of coating after contain it is numerous can
The acrylate structural of crosslinking, rapid curing is can be achieved under 365nm UV-LED light sources irradiation.
Peelable blue glue obtained by the present invention, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai rotates viscous
Degree meter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of condition of room temperature
Lower to be detected, its viscosity is 30000-40000mPa.s.
Further, carried out by GB/T 6753.1-2007 standards " measure of colored paint, varnish and printing-ink fineness of grind "
The fineness test of peelable blue glue, measuring fineness is：≦5μm.
Further, peelable blue glue is precoated through 365nm UV-LED light irradiations after the peelable blue glue film obtained by the present invention
Slide surface, according to fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, with it is tack-free make
For the standard being fully cured, the shortest time used characterizes when being fully cured with peelable blue glue), it is after testing, of the invention
The hardening time of the peelable blue glue of quick-drying is 1-5s.
Further, peelable blue glue of the invention, is organic as the UV solidified resin A molecular structures of main film forming substance
Silicon structure, with very low surface energy, reduces the interaction between film and base material, is allowed to embody preferably from fissility,
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 standards using Shenzhen
" 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, draw speed 50mm/min；Measure peel strength
For 0.21~0.25kN/m；
Further, the peelable blue glue that prepared by the present invention adds UV mill bases, makes it have noctilucence characteristic.
In summary, a kind of peelable blue glue of the invention, has faster curing rate and with night after film
Illumination effect.The preparation method technique of the present invention is simple, easy to control, technology maturation, quick, efficiently, and suitable for industrialized production.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows：
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of peelable blue glue, is calculated by weight, and its raw material composition and content are as follows：
Wherein：Described UV solidified resins A is calculated by weight, and it is constituted and content is as follows：
Described UV solidified resins A is carried out as follows：
10 parts of Methyl Hydrogen Polysiloxane Fluids and 10 parts of ethoxylated trimethylolpropane triacrylates are added to the three of 500ml
In mouth flask, 0.01 part of hydroquinone of polymerization retarder is added, protective gas is passed through, stirs and heat, be warming up to 60 DEG C, addition
The complex compound of 0.03 part of chloroplatinic acid, the lower constant temperature 3h of stirring, stops heating, treats that flask temperature drops to room temperature, produce UV solidified resins
A。
Described UV solidified resins B is toughened resin, such as epoxy acrylate, urethane acrylate in mass ratio 1:1
The mixture of composition；
Described levelling agent is the high Tego Glide 410 of enlightening；
Described UV wetting agents are the NP-100 of LG-DOW company；
The yellowish green MG-1 that described UV mill bases provide for Dongguan City Chun Liang process materials Co., Ltd；
Described defoamer is Germany BYK-035, BYK-037 in mass ratio 1：1 mixture；
Described light trigger A is that BASF Irgacure1173, Irgacure 184D, Irgacure TPO press quality
Than 1:1:The mixture of 2 compositions；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 in mass ratio
1:The mixture of 1 composition；
In the present embodiment, a kind of preparation method of peelable blue glue specifically includes following steps：
According to formula, in control rotating speed 300r/min GFJ-0.4 types high speed dispersor, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent of middle addition, 0.05 part of levelling agent, 0.2 part of defoamer and 1 part of UV mill base, through disperseing under 600r/min rotating speeds
Rotating speed is down to 300r/min after 15min, 60 parts of UV solidified resins A, 60 parts of UV solidified resins B, 3 parts of light trigger A and 3 are added
Part photoinitiator b, continues scattered 50min, is well mixed, that is, obtains peelable blue glue.
Peelable blue glue obtained by the present embodiment, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai is rotated
Viscosimeter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of bar of room temperature
Detected under part, its viscosity is 30000mPa.s.
Peelable blue glue obtained by the present embodiment, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, and measuring fineness is：3.5μm.
The load of peelable blue glue is precoated after peelable blue glue film obtained by the present embodiment through 365nm UV-LED light irradiations
The surface of slide, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as complete
The standard of all solidstate, shortest time used characterizes when being fully cured with peelable blue glue), after testing, quick-drying of the invention
The hardening time of peelable blue glue is 1s.
Further, a kind of peelable blue glue of the present embodiment, is used as the UV solidified resin A molecular structures of main film forming substance
For organosilicon structures, with very low surface can, reduce the interaction between film and base material, be allowed to embody preferably peelable
From property, peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 using Shenzhen
Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, draw speed 50mm/min；Measure stripping
Intensity is 0.25kN/m；
Fast curing properties after peelable blue glue film obtained by above the present embodiment, peeling effect is good.
Embodiment 2
A kind of peelable blue glue, is calculated by weight, and its raw material composition and content are as follows：
Wherein：Described UV solidified resins A is calculated by weight, and it is constituted and content is as follows：
Described UV solidified resins A is carried out as follows：
20 parts of Methyl Hydrogen Polysiloxane Fluids and 20 parts of ethoxylated trimethylolpropane triacrylates are added to the three of 500ml
In mouth flask, 0.02 part of hydroquinone of polymerization retarder is added, protective gas is passed through, stirs and heat, be warming up to 80 DEG C, addition
The complex compound of 0.05 part of chloroplatinic acid, the lower constant temperature 5h of stirring, stops heating, treats that flask temperature drops to room temperature, produce UV solidified resins
A。
Described UV solidified resins B is toughened resin, such as epoxy acrylate, urethane acrylate in mass ratio 2:1
The mixture of composition；
Described levelling agent is Germany BYK-345, BYK-346 in mass ratio 1：The mixture of 1 composition；
Described UV wetting agents are Germany BYK 333；
The sky blue UV mill bases that huge light Materials Co., Ltd of described Foshan City provides；
Described defoamer is that German BYK Bi Ke BYK-024, BYK-025, BYK-035 are 1 in mass ratio：1：1 composition
Mixture；
Described light trigger A be BASF Irgacure 184D, Irgacure TPO, Irgacure 369,
Irgacure 819 in mass ratio 1:1:1:The mixture of 1 composition；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 in mass ratio
1:The mixture of 2 compositions；
A kind of preparation method of peelable blue glue, specifically includes following steps：
According to formula, in control rotating speed 1400r/min GFJ-0.4 types high speed dispersor, (the new promise instrument and equipment in Shanghai has
Limit company) in add 10 parts of wetting agents, 0.1 part of levelling agent, 1 part of defoamer and 10 parts of UV mill bases, through lower point of 800r/min rotating speeds
Rotating speed is down to 300r/min after scattered 20min, 150 parts of UV solidified resins A, 150 parts of UV solidified resins B, 5 parts of light triggers are added
A, 5 parts of photoinitiator bs, continue scattered 100min, are well mixed, that is, obtain peelable blue glue.
Peelable blue glue obtained by the present embodiment, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai is rotated
Viscosimeter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of bar of room temperature
Detected under part, its viscosity is 40000mPa.s.
Peelable blue glue obtained by the present embodiment, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, measures fineness for 4.5 μm.
The load of peelable blue glue is precoated after peelable blue glue film obtained by the present embodiment through 365nm UV-LED light irradiations
The surface of slide, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as complete
The standard of all solidstate, shortest time used characterizes when being fully cured with peelable blue glue), after testing, quick-drying of the invention
The hardening time of peelable blue glue is 5s.
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, draw speed 50mm/min；Measure
Peel strength is 0.21kN/m；
Fast curing properties after peelable blue glue film obtained by above the present embodiment, peeling effect is good.
In summary, peelable blue glue of the invention uses UV curing formulas, and UV high speed curable improves it and consolidated
Change speed, only 1-5s；Peelable blue glue has noctilucence characteristic.It is used as the UV solidified resin A molecular structures of main film forming substance
For organosilicon structures, with very low surface energy, the interaction between film and base material is reduced, is allowed to embody preferably from stripping
From property, peel strength is 0.21~0.25kN/m.Have after the peelable blue glue film of the high temperature resistant after 365nmUV-LED light irradiations
There are quick setting capabilities, the good non-scale of adhesion is come off, peeled off easily, completely, and residual stain is not flowed.
Above said content is only the basic explanation under present inventive concept, and according to appointing that technical scheme is made
What equivalent transformation, all should belong to protection scope of the present invention.
Claims (5)
1. a kind of peelable blue glue, it is characterised in that calculate by weight, its raw material composition and content are as follows：
Wherein：Described UV solidified resins A structural formula is as follows：
Wherein：M is the integer in the range of 1-30；N is the integer in the range of 1-30；
Described UV solidified resins B is toughened resin；
Described UV mill bases are mill base indigo plant F4049；
Described light trigger A is selected from BASF Irgacure1173, Irgacure 184D, Irgacure TPO, Irgacure
369th, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular photoinitiator
One or more in Esacure KIP 150；
Described photoinitiator b be selected from BASF BASF light triggers Irgacure 2959, IRGACURE500 or
It is one or more of in IRGACURE819DW.
2. peelable blue glue according to claim 1, it is characterised in that its viscosity under conditions of 25 DEG C of room temperature is
30000-40000mPa.s, fineness Wei≤5 μm, hardening time is 1-5s, and the stripping measured in draw speed 50mm/min is strong
Spend for 0.21~0.25kN/m.
3. peelable blue glue according to claim 1, it is characterised in that described UV solidified resins A is counted by weight
Calculate, its raw material composition and content are as follows：
Described UV solidified resins A is prepared as follows：
Methyl Hydrogen Polysiloxane Fluid and ethoxylated trimethylolpropane triacrylate are proportionally added into reaction vessel, then added
Enter polymerization inhibitor, be passed through protective gas, stir and heat, be warming up to 60~80 DEG C, add catalyst, the lower 3~5h of constant temperature of stirring stops
Only heat, treat that temperature drops to room temperature, produce UV solidified resins A.
4. peelable blue glue according to claim 1, it is characterised in that described UV solidified resins B is selected from propylene oxide
One or more in acid esters, urethane acrylate, polyester acrylate or polyether acrylate.
5. peelable blue glue according to claim 1, it is characterised in that described levelling agent is selected from the high Tego Glide of enlightening
410th, in Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348
One or more；One kind or two in NP-100 or Germany BYK 333 of the described wetting agent selected from LG-DOW company
Kind；The defoamer is selected from Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-044 or BYK-038
In one or more.
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| CN114729181A (en) * | 2019-12-20 | 2022-07-08 | Dic株式会社 | Aqueous urethane resin dispersion, synthetic leather, and method for producing synthetic leather |
| CN111139015A (en) * | 2019-12-31 | 2020-05-12 | 天津久日新材料股份有限公司 | Environment-friendly UV LED (ultraviolet light emitting diode) curing peelable blue glue and preparation method thereof |
| CN113667394B (en) * | 2021-08-16 | 2023-06-23 | 广东希贵光固化材料有限公司 | UV illumination demolding temporary protective coating and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031053A (en) * | 2013-01-06 | 2013-04-10 | 北京海斯迪克新材料有限公司 | UV-cured peelable blue gel for temporary protection of touch screen and preparation method thereof |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
| CN105176449A (en) * | 2015-07-24 | 2015-12-23 | 中山市伯伦克专用化学产品有限公司 | UV-curing peelable blue glue and preparation method therefor |
| CN105219252A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of UV solidifies strippable water-based paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000345109A (en) * | 1999-06-02 | 2000-12-12 | Mitsuo Oyanagi | Peelable coating material having excellent appearance and peeling properties |
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2016
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031053A (en) * | 2013-01-06 | 2013-04-10 | 北京海斯迪克新材料有限公司 | UV-cured peelable blue gel for temporary protection of touch screen and preparation method thereof |
| CN105176449A (en) * | 2015-07-24 | 2015-12-23 | 中山市伯伦克专用化学产品有限公司 | UV-curing peelable blue glue and preparation method therefor |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
| CN105219252A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of UV solidifies strippable water-based paint and preparation method thereof |
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