CN105602443B - Peelable blue glue and preparation method - Google Patents
Peelable blue glue and preparation method Download PDFInfo
- Publication number
- CN105602443B CN105602443B CN201610038599.7A CN201610038599A CN105602443B CN 105602443 B CN105602443 B CN 105602443B CN 201610038599 A CN201610038599 A CN 201610038599A CN 105602443 B CN105602443 B CN 105602443B
- Authority
- CN
- China
- Prior art keywords
- byk
- blue glue
- peelable blue
- irgacure
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/005—Dendritic macromolecules
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
Abstract
The invention discloses the peelable blue glue of one kind and preparation method.The peelable blue glue of the present invention, calculate, be made up of 50 80 parts of UV solidified resins A, 50 80 parts of UV solidified resins B, 50 80 parts of UV solidified resins C, 0.05 0.1 parts of levelling agents, 1 10 parts of wetting agent, 0.2 1 parts of defoamer, 1 10 parts of mill bases and 35 parts of light trigger A and 35 parts of photoinitiator b by weight.There are quick setting capabilities, adhesion is good after being irradiated after the peelable blue glue film of the present invention through 365nmUV LEDs, non-scale is come off, peeled off easily, completely, and residual stain is not flowed；It can be applied to the insulating of the materials such as PET, ITO conducting film, ito glass, mobile phone glass, strengthened glass form, moistureproof, anti-pollution and scratch resistant protection.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of peelable blue glue and preparation method, this is peelable
The irradiation solidification of 365nm UV-LED light sources is particularly suitable for use in from blue glue.
Background technology
In recent years, the fast development of digital product has driven the fast development of touch-screen industry.High performance touch-screen system
Standby technique needs to lose the ink of function with resistance or metal surface is processed " peelable blue gel ", " surface protective glue " of protection.
When manufacturing printed board, some parts will often be covered using adhesive on plate, in order to avoid poured during scolding tin by tin, such as golden hand
Finger, interface card, the plate face of carbonaceous conductive button and larger area, these are required for optionally scolding tin and multiple continuously scolding tin,
Such as SMD hybrid precast, Reflow Soldering craft and automatic and other soldering tin techniques etc..Peelable blue gel is used for reference in PCB industry printed boards
Protected mode in technique, avoids touch-screen from sustaining damage in the mill using printing peelable glue, improves production efficiency and production
Product quality.Generally, peelable glue is a kind of one pack system touch-screen special isolation protection pliability ink, and color is sticky for blueness
Shape liquid, is more prone to peel off, toughness can also be strengthened, and hand can be used after application by the peelable gel coating after high temperature resistant
Or instrument is easily peeled off, without having residue in material surface or contaminated materials, it is not necessary to secondary cleaning, with attachment
Power is good, not cull, endurance (acid-base property) it is excellent, smooth light is easy-peel, the advantages of easy to operate.It is mainly used in touch-screen thoroughly
Bright ITO electro-conductive glass, ito thin film, the insulation plated film flow of PET film, can be dried by being screen printed onto on PET film and glass
Be roasted into after film and play a part of preventing material contaminated in process of production or scratch, on the touchscreen, lower circuit bonding before,
It can be taken off, and be once stripped clean with simple and easy method.
General heated more than 100 DEG C of current peelable blue glue is solidified, and solidification temperature is high, and typically peelable
Blue glue is same there is also the time is long, stripping process there are problems that it is cumbersome, have.
The content of the invention
, can fast curing-formed, adhesion it is an object of the invention to provide one kind in order to overcome the deficiencies in the prior art
Good peelable blue glue and preparation method.The preparation method of the invention is simple, and obtained peelable blue glue peeling effect is good.
Technical scheme is specifically described as follows.
The present invention provides a kind of peelable blue glue, calculates by weight, and its raw material composition and content are as follows：
Wherein：Described UV solidified resins A chemical structural formula is as follows：
Wherein：M is the integer in the range of 1-30；N is the integer in the range of 1-30；
Described UV solidified resins B is hyperbranched UV solidified resins；
Described UV solidified resins C is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran
Acrylate, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra acid
Ester, three (2- ethoxys) isocyanuric acid triacrylates, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris propylene
Acid esters, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, three
Cyclodecane Dimethanol Diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane trimethacrylate,
The acrylate monomers such as hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals list acrylic acid
One kind in ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylate and vinyl ethers monomer
Or it is several；
One kind or two in NP-100 or Germany's levelling agents of BYK 333 of the described wetting agent selected from LG-DOW company
Kind；
Described mill base is mill base indigo plant F4049；
Described light trigger A be selected from BASF Irgacure1173, Irgacure 184D, Irgacure TPO,
Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907, macromolecular are light-initiated
One or more mixtures in agent Esacure KIP 150；
Described photoinitiator b select BASF BASF light triggers Irgacure 2959, IRGACURE500,
One or more mixtures in IRGACURE819DW.
In the present invention, described UV solidified resins A is calculated by weight, and its raw material composition and content are as follows：
Described UV solidified resins A is prepared as follows：
Methyl and phenyl hydrogen-containing silicon oil and glycerol propoxylate triacrylate are proportionally added into reaction vessel, added
Polymerization inhibitor, is passed through protective gas, stirs and heats, and is warming up to 60~80 DEG C, adds catalyst, and the lower 3~5h of constant temperature of stirring stops
Heating, treats that temperature drops to room temperature, produces UV solidified resins A.
In the present invention, described levelling agent be selected from the high Tego Glide 410 of enlightening, Germany BYK Bi Ke BYK-UV3510,
One or more in BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348.
In the present invention, described defoamer be selected from Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037,
One or more in BYK-038, BYK-044 or BYK-038.
The present invention also provides a kind of preparation method of peelable blue glue, comprises the following steps that：
According to formula, wetting agent, levelling agent, froth breaking are added in control rotating speed 500-1200r/min high speed dispersor
Agent and mill base, 300r/min is down to after disperseing 15-20min under 600-800r/min rotating speeds by rotating speed, adds UV solidified resins
A, UV solidified resin B, UV solidified resin C and light trigger A, photoinitiator b, continue scattered 60-120min, are well mixed, i.e.,
Obtain peelable blue glue.
The useful achievement of the present invention is as follows：
A kind of peelable blue glue of the present invention, as a result of the UV solidified resins A and tool of multi-functional acrylate
The hyperbranched UV solidified resins for having dissaving structure are made it have in 365nmUV-LED, the rapid capability under lamp source irradiation.
A kind of peelable blue glue of the present invention, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai rotates viscous
Degree meter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of condition of room temperature
Lower to be detected, its viscosity is 25000~40000mPa.s.
Peelable blue glue obtained by the present invention, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of fineness " carries out the fineness test of peelable blue glue, measures fineness for 4.5 μM.
Further, the load glass of peelable blue glue is precoated after the peelable blue glue film obtained by the present invention through UV nail polish light irradiation
The surface of piece, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as completely
The standard of solidification, the shortest time used characterizes when being fully cured with peelable blue glue), after testing, quick-drying of the invention can
The hardening time for peeling off blue glue is 1-17s.
Further, a kind of peelable blue glue of the invention, be as the UV solidified resin A molecular structures of main film forming substance
Organosilicon structures, with very low surface energy, reduce the interaction between film and base material, are allowed to embody preferably from stripping
Property, it is not required to add stripping auxiliary agent again, the problem of effectively overcoming residual stain after stripping.Peel strength newly thinks carefully company using Shenzhen
CMT5104 electronic tension testers at room temperature press GB/T2790-1995 standards " 180 ° of peeling strength test sides of adhesive
Method " carries out 180 ° of peel test, draw speed 50mm/min；Peel strength is measured for 0.21~0.25kN/m；
Further, the chameleon pigment of the peelable blue glue addition obtained by the present invention brings thousand changes ten thousand to peelable blue glue
The color of change, addition have toughening effect UV solidified resin C, make peelable blue glue that there is certain toughness.
In summary, a kind of peelable blue glue of the invention, with the rapid curing under the irradiation of 365nmUV-LED lamp sources
Ability, it has higher toughness, gloss and metachrosis after film.And its preparation method due to technique it is simple, it is easy to control,
Therefore with technology maturation, it is quick, efficient the features such as, and suitable for industrialized production.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows：
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of peelable blue glue, is calculated by weight, and its raw material composition and content are as follows：
Wherein：Described UV solidified resins A is calculated by weight, and it is constituted and content is as follows：
Described UV solidified resins A is prepared as follows：20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 part of third oxidation are sweet
Oily triacrylate is added in 500ml three-necked flask, is added 0.005 polymerization inhibitor MEHQ, is passed through protection
Gas, stirs and heats, and is warming up to 60 DEG C, adds 0.03 part of catalyst chloroplatinic acid/aqueous isopropanol, and the lower constant temperature 3h of stirring stops
Only heat, treat that flask temperature drops to room temperature, produce UV solidified resins A.
Described UV solidified resins C is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
Olefin(e) acid ester, tetramethylol methane tetraacrylate in mass ratio 2：1：1：The mixture of 2 compositions；
Described levelling agent is the high Tego Glide 410 of enlightening；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is Germany BYK-035, BYK-037 in mass ratio 1：1 mixture；
Described UV mill bases are mill base indigo plant F4049；
Described light trigger A is BASF Irgacure1173, Irgacure 184D, Irgacure TPO, by quality
Than 1:1:The mixture of 1 composition；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 in mass ratio
1:The mixture of 1 composition；
In the present embodiment, a kind of preparation method of peelable blue glue specifically includes following steps：
According to formula, in control rotating speed 500r/min GFJ-0.4 types high speed dispersor, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent of middle addition, 0.05 part of levelling agent, 0.2 part of defoamer and 1 part of mill base, through disperseing under 600r/min rotating speeds
Rotating speed is down to 300r/min after 15min, 50 parts of UV solidified resins A, 50 parts of UV solidified resins B, 50 parts of UV solidified resins are added
C, 3 parts of light trigger A and 3 parts of photoinitiator bs, continue scattered 60min, are well mixed, that is, obtain peelable blue glue.
Peelable blue glue obtained by the present embodiment, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai is rotated
Viscosimeter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of bar of room temperature
Detected under part, its viscosity is 40000mPa.s.
Peelable blue glue obtained by the present embodiment, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, measures fineness for 4.5 μM.
The UV-LED light irradiations through 365nm precoat the load of peelable blue glue after peelable blue glue film obtained by the present embodiment
The surface of slide, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as complete
The standard of all solidstate, shortest time used characterizes when being fully cured with peelable blue glue), after testing, quick-drying of the invention
The hardening time of peelable blue glue is 1s.
Further, a kind of peelable blue glue of the present embodiment, is used as the UV solidified resin A molecular structures of main film forming substance
For organosilicon structures, with very low surface can, reduce the interaction between film and base material, be allowed to embody preferably peelable
From property, peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 using Shenzhen
Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, draw speed 50mm/min；Measure stripping
Intensity is 0.25kN/m；
Curing rate higher after the peelable blue glue film obtained by this present embodiment, easily peelable in summary.
Embodiment 2
A kind of peelable blue glue, is calculated by weight, and its raw material composition and content are as follows：
Wherein：Described UV solidified resins A is calculated by weight, and it is constituted and content is as follows：
Described UV solidified resins A is prepared as follows：By above-mentioned 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 part of third oxygen
Change glycerol tri-acrylate to be added in 500ml three-necked flask, add 0.01 part of polymerization inhibitor MEHQ, be passed through
Protective gas, stirs and heats, and is warming up to 80 DEG C, adds 0.05 part of catalyst chloroplatinic acid/vinyl double seal head complex compound, stirring
Lower constant temperature 5h, stops heating, treats that flask temperature drops to room temperature, produce UV solidified resins A.
Described UV solidified resins C is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
Olefin(e) acid ester, tetramethylol methane tetraacrylate in mass ratio 1：1：1：The mixture of 1 composition；
Described levelling agent is Germany BYK-345, BYK-346 in mass ratio 1：The mixture of 1 composition；
Described wetting agent is Germany BYK 333；
Described defoamer is Germany BYK Bi Ke BYK-024, BYK-025 in mass ratio 1:The mixture of 1 composition；
Described UV mill bases are mill base indigo plant F4049
Described light trigger A be BASF Irgacure 184D, Irgacure TPO, Irgacure 369, by quality
Than 1:1：More than 1 kinds of mixture；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 in mass ratio
2:The mixture of 1 composition；
In the present embodiment, a kind of preparation method of peelable blue glue specifically includes following steps：
According to formula, in control rotating speed 1200r/min GFJ-0.4 types high speed dispersor, (the new promise instrument and equipment in Shanghai has
Limit company) 10 parts of wetting agents of middle addition, 0.1 part of levelling agent, 1 part of defoamer and 10 parts of mill bases, through disperseing under 800r/min rotating speeds
Rotating speed is down to 300r/min after 20min, 80 parts of UV solidified resins A, 80 parts of UV solidified resins B, 80 parts of UV solidified resins are added
C, 5 parts of light trigger A and 5 parts of photoinitiator bs, continue scattered 120min, are well mixed, that is, obtain peelable blue glue.
Peelable blue glue obtained by the present embodiment, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai is rotated
Viscosimeter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of bar of room temperature
Detected under part, its viscosity is 25000mPa.s.
Peelable blue glue obtained by the present embodiment, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, measures fineness for 4.5 μM.
The UV-LED light irradiations through 365nm precoat the load of peelable blue glue after peelable blue glue film obtained by the present embodiment
The surface of slide, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as complete
The standard of all solidstate, shortest time used characterizes when being fully cured with peelable blue glue), after testing, quick-drying of the invention
The hardening time of peelable blue glue is 17s.Color changeable effect is presented after solidification.
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, draw speed 50mm/min；Measure
Peel strength is 0.21kN/m；
Higher curing rate, easily peelable after peelable blue glue film obtained by above the present embodiment.
In summary, peelable blue glue of the invention uses UV curing formulas, and UV high speed curable improves it and consolidated
Change speed, only 1~17s；That adds has toughening effect UV solidified resin C, peelable blue glue is had certain toughness.Make
Be organosilicon structures for the UV solidified resin A molecular structures of main film forming substance, with very low surface can, reduce film with
Interaction between base material, is allowed to embody preferably from fissility, is not required to add stripping auxiliary agent again, effectively overcomes after stripping
The problem of residual stain, peel strength is 0.21~0.25kN/m；Shone after the peelable blue glue film of the high temperature resistant through 365nmUV-LED lamps
There are quick setting capabilities, the good non-scale of adhesion is come off, peeled off easily, completely, and residual stain is not flowed after penetrating.
The content is only the basic explanation under present inventive concept, and according to technical scheme made it is any etc.
Effect conversion, all should belong to protection scope of the present invention.
Claims (5)
1. a kind of peelable blue glue, it is characterised in that calculate by weight, its raw material composition and content are as follows：
Wherein：Described UV solidified resins A chemical structural formula is as follows：
Wherein：M is the integer in the range of 1-30；N is the integer in the range of 1-30；
Described UV solidified resins B is hyperbranched UV solidified resins；
Described UV solidified resins C is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran propylene
Acid esters, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra-acrylate,
Three (2- ethoxys) isocyanuric acid triacrylates, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris acrylic acid
Ester, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, three rings
Decane Dimethanol Diacrylate, the third oxidation neopentylglycol diacrylate, hyperbranched polyester acrylic ester, alkoxypropan olefin(e) acid
Ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone propylene
One or more in acid esters and vinyl ethers monomer；
Described wetting agent is selected from one or both of NP-100 or Germany's levelling agents of BYK 333 of LG-DOW company；
Described mill base is mill base indigo plant F4049；
Described light trigger A is selected from BASF Irgacure1173, Irgacure 184D, Irgacure TPO, Irgacure
369th, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907, macromolecular photoinitiator Esacure
One or more mixtures in KIP 150；
Described photoinitiator b be selected from BASF BASF light triggers Irgacure 2959, IRGACURE500,
One or more mixtures in IRGACURE819DW.
2. peelable blue glue according to claim 1, it is characterised in that the viscosity at its 25 DEG C is 25000-
40000mPa.s, hardening time is 1-17s, and the peel strength under draw speed 50mm/min is 0.21~0.25kN/m.
3. peelable blue glue according to claim 1, it is characterised in that described UV solidified resins A is counted by weight
Calculate, its raw material composition and content are as follows：
Described UV solidified resins A is prepared as follows：
Methyl and phenyl hydrogen-containing silicon oil and glycerol propoxylate triacrylate are proportionally added into reaction vessel, inhibition is added
Agent, is passed through protective gas, stirs and heats, and is warming up to 60~80 DEG C, adds catalyst, and stirring 3~5h of lower constant temperature stops adding
Heat, treats that temperature drops to room temperature, produces UV solidified resins A.
4. peelable blue glue according to claim 1, it is characterised in that described levelling agent is selected from the high Tego Glide of enlightening
410th, in Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348
One or more.
5. peelable blue glue according to claim 1, it is characterised in that described defoamer is selected from Germany BYK Bi Ke
One or more in BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610038599.7A CN105602443B (en) | 2016-01-20 | 2016-01-20 | Peelable blue glue and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610038599.7A CN105602443B (en) | 2016-01-20 | 2016-01-20 | Peelable blue glue and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105602443A CN105602443A (en) | 2016-05-25 |
| CN105602443B true CN105602443B (en) | 2017-10-27 |
Family
ID=55982815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610038599.7A Expired - Fee Related CN105602443B (en) | 2016-01-20 | 2016-01-20 | Peelable blue glue and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105602443B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109438613B (en) * | 2018-10-23 | 2021-01-22 | 上海应用技术大学 | Damping resin emulsion and preparation method thereof |
| CN109438614B (en) * | 2018-10-23 | 2021-01-22 | 上海应用技术大学 | Water-based resin emulsion and preparation method thereof |
| CN111138607B (en) * | 2019-12-30 | 2021-11-19 | 西安交通大学 | Temperature-sensitive coacervate type hyperbranched polyethylene glycol and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031053A (en) * | 2013-01-06 | 2013-04-10 | 北京海斯迪克新材料有限公司 | UV-cured peelable blue gel for temporary protection of touch screen and preparation method thereof |
| CN103627313A (en) * | 2013-11-29 | 2014-03-12 | 广州机械科学研究院有限公司 | Ultraviolet-cured stripping protective material and preparation method and application thereof |
| CN105131779A (en) * | 2015-09-14 | 2015-12-09 | 上海应用技术学院 | Ultraviolet curing organic silicon release agent and preparation method thereof |
| CN105219252A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of UV solidifies strippable water-based paint and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5616672A (en) * | 1995-11-17 | 1997-04-01 | General Electric Company | Paper release compositions having improved release characteristics |
-
2016
- 2016-01-20 CN CN201610038599.7A patent/CN105602443B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031053A (en) * | 2013-01-06 | 2013-04-10 | 北京海斯迪克新材料有限公司 | UV-cured peelable blue gel for temporary protection of touch screen and preparation method thereof |
| CN103627313A (en) * | 2013-11-29 | 2014-03-12 | 广州机械科学研究院有限公司 | Ultraviolet-cured stripping protective material and preparation method and application thereof |
| CN105131779A (en) * | 2015-09-14 | 2015-12-09 | 上海应用技术学院 | Ultraviolet curing organic silicon release agent and preparation method thereof |
| CN105219252A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of UV solidifies strippable water-based paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105602443A (en) | 2016-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106010144B (en) | A kind of UV-LED solidification optical fiber coated with resins and its preparation method and application | |
| CN105125421B (en) | A kind of peelable nail polish glue of UV curable water-bornes and preparation method thereof | |
| CN105602443B (en) | Peelable blue glue and preparation method | |
| CN108359312A (en) | A kind of high temperature resistant type UV-LED inkjet printings welding resistance ink and its preparation method and application | |
| CN109517433B (en) | Recoatable high-coverage UV ink and preparation method and application thereof | |
| CN105748317B (en) | Quick-setting strippable property nail polish glue and preparation method thereof | |
| CN105482689B (en) | Peelable blue glue and preparation method thereof | |
| CN105006272A (en) | Ultraviolet conductive silver slurry, and preparation method and application thereof | |
| CN104327593A (en) | UV-curable strippable ink as well as production method and construction method of UV-curable strippable ink | |
| CN105686972B (en) | Strippable property nail polish glue and preparation method thereof | |
| CN105534741B (en) | A kind of peelable nail polish glue and its synthetic method | |
| CN105434189B (en) | A kind of peelable nail polish glue and preparation method thereof | |
| CN105482692B (en) | A kind of peelable blue glue and preparation method | |
| CN105440942B (en) | A kind of peelable blue glue and preparation method thereof | |
| CN105462489B (en) | Peelable blue glue and its preparation technology | |
| CN105596232B (en) | Peelable nail polish glue and preparation method thereof | |
| CN105560082B (en) | Improved strippable property nail polish glue and preparation method thereof | |
| CN105482691A (en) | Strippable blue gel and preparation process thereof | |
| CN105482690B (en) | Peelable blue glue and its synthetic method | |
| CN105733496B (en) | A kind of improved strippable property indigo plant glue and preparation method thereof | |
| CN105754051B (en) | A kind of strippable property indigo plant glue and preparation method thereof | |
| CN105602255B (en) | Noctilucence 3D printing light-sensitive emulsion and preparation method thereof | |
| CN105566916B (en) | A kind of quick-setting noctilucence 3D printing light-sensitive emulsion and preparation method thereof | |
| CN105001707B (en) | A kind of UV photocurings water-based ink and preparation method thereof | |
| CN105496817B (en) | A kind of peelable nail polish glue and its synthesis technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171027 Termination date: 20210120 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |