CN105131779A - Ultraviolet curing organic silicon release agent and preparation method thereof - Google Patents
Ultraviolet curing organic silicon release agent and preparation method thereof Download PDFInfo
- Publication number
- CN105131779A CN105131779A CN201510580876.2A CN201510580876A CN105131779A CN 105131779 A CN105131779 A CN 105131779A CN 201510580876 A CN201510580876 A CN 201510580876A CN 105131779 A CN105131779 A CN 105131779A
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- CN
- China
- Prior art keywords
- organic silicon
- ultraviolet curing
- curing organic
- parting agent
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 52
- 239000010703 silicon Substances 0.000 title claims abstract description 52
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 45
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003921 oil Substances 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 13
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 3
- 238000001723 curing Methods 0.000 claims description 32
- -1 Amido silicon Chemical compound 0.000 claims description 25
- 229920002545 silicone oil Polymers 0.000 claims description 23
- 235000006708 antioxidants Nutrition 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinyl group Chemical group C1(O)=CC(O)=CC=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 239000003502 gasoline Substances 0.000 claims description 6
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 claims description 6
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 4
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 claims description 4
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000003848 UV Light-Curing Methods 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 claims description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 2
- XRCRJFOGPCJKPF-UHFFFAOYSA-N 2-butylbenzene-1,4-diol Chemical compound CCCCC1=CC(O)=CC=C1O XRCRJFOGPCJKPF-UHFFFAOYSA-N 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
- 125000000524 functional group Chemical group 0.000 claims description 2
- 230000000977 initiatory effect Effects 0.000 claims description 2
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 2
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 2
- 150000003254 radicals Chemical class 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 15
- 238000000576 coating method Methods 0.000 abstract description 15
- 239000002184 metal Substances 0.000 abstract description 8
- 229910052751 metal Inorganic materials 0.000 abstract description 8
- 239000011521 glass Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- OBFQBDOLCADBTP-UHFFFAOYSA-N aminosilicon Chemical compound [Si]N OBFQBDOLCADBTP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003085 diluting agent Substances 0.000 abstract 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 abstract 2
- 239000000919 ceramic Substances 0.000 abstract 1
- 238000011109 contamination Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000005303 weighing Methods 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 238000007711 solidification Methods 0.000 description 6
- 230000008023 solidification Effects 0.000 description 6
- 239000003973 paint Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 230000007547 defect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 230000001680 brushing effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000000181 anti-adherent effect Effects 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000007603 infrared drying Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Silicon Polymers (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims (12)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510580876.2A CN105131779B (en) | 2015-09-14 | 2015-09-14 | A kind of ultraviolet curing organic silicon mould release and preparation method thereof |
Applications Claiming Priority (1)
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CN201510580876.2A CN105131779B (en) | 2015-09-14 | 2015-09-14 | A kind of ultraviolet curing organic silicon mould release and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN105131779A true CN105131779A (en) | 2015-12-09 |
CN105131779B CN105131779B (en) | 2018-06-29 |
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CN201510580876.2A Active CN105131779B (en) | 2015-09-14 | 2015-09-14 | A kind of ultraviolet curing organic silicon mould release and preparation method thereof |
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CN (1) | CN105131779B (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105462489A (en) * | 2016-01-20 | 2016-04-06 | 上海应用技术学院 | Strippable blue gel and preparation process thereof |
CN105602443A (en) * | 2016-01-20 | 2016-05-25 | 上海应用技术学院 | Peelable blue gel and preparation method |
CN105719562A (en) * | 2016-01-28 | 2016-06-29 | 安徽盛鼎电器科技有限公司 | Label material free of release paper and making technology of label material |
CN105906831A (en) * | 2016-05-09 | 2016-08-31 | 吉翔宝(太仓)离型材料科技发展有限公司 | Ultraviolet-cured anti-scraping release film |
CN105949487A (en) * | 2016-05-09 | 2016-09-21 | 吉翔宝(太仓)离型材料科技发展有限公司 | Ultraviolet curable antistatic release film and preparation method thereof |
CN106381084A (en) * | 2016-10-17 | 2017-02-08 | 哈尔滨工业大学无锡新材料研究院 | Non-transfer organic silicon modified acrylate parting agent and preparation method thereof |
CN107570393A (en) * | 2017-07-19 | 2018-01-12 | 深圳市佰瑞兴实业有限公司 | A kind of coating process of reticulate pattern PET silicone release films |
CN110886127A (en) * | 2019-12-05 | 2020-03-17 | 江苏双冠新材料科技有限公司 | Preparation method of antibacterial antistatic release paper |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1880396A (en) * | 2005-06-13 | 2006-12-20 | 联合工艺公司 | Erosion resistant anti-icing coatings |
CN104213465A (en) * | 2014-07-31 | 2014-12-17 | 东莞宏石功能材料科技有限公司 | UV paper varnish having separating effect and being ultra-smooth after ultraviolet light curing and preparation method thereof |
CN104479506A (en) * | 2014-06-11 | 2015-04-01 | 深圳职业技术学院 | Stain-resistant UV hybrid curable coating composition and preparation method thereof |
-
2015
- 2015-09-14 CN CN201510580876.2A patent/CN105131779B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1880396A (en) * | 2005-06-13 | 2006-12-20 | 联合工艺公司 | Erosion resistant anti-icing coatings |
CN104479506A (en) * | 2014-06-11 | 2015-04-01 | 深圳职业技术学院 | Stain-resistant UV hybrid curable coating composition and preparation method thereof |
CN104213465A (en) * | 2014-07-31 | 2014-12-17 | 东莞宏石功能材料科技有限公司 | UV paper varnish having separating effect and being ultra-smooth after ultraviolet light curing and preparation method thereof |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105462489A (en) * | 2016-01-20 | 2016-04-06 | 上海应用技术学院 | Strippable blue gel and preparation process thereof |
CN105602443A (en) * | 2016-01-20 | 2016-05-25 | 上海应用技术学院 | Peelable blue gel and preparation method |
CN105602443B (en) * | 2016-01-20 | 2017-10-27 | 上海应用技术学院 | Peelable blue glue and preparation method |
CN105719562A (en) * | 2016-01-28 | 2016-06-29 | 安徽盛鼎电器科技有限公司 | Label material free of release paper and making technology of label material |
CN105906831A (en) * | 2016-05-09 | 2016-08-31 | 吉翔宝(太仓)离型材料科技发展有限公司 | Ultraviolet-cured anti-scraping release film |
CN105949487A (en) * | 2016-05-09 | 2016-09-21 | 吉翔宝(太仓)离型材料科技发展有限公司 | Ultraviolet curable antistatic release film and preparation method thereof |
CN106381084A (en) * | 2016-10-17 | 2017-02-08 | 哈尔滨工业大学无锡新材料研究院 | Non-transfer organic silicon modified acrylate parting agent and preparation method thereof |
CN106381084B (en) * | 2016-10-17 | 2019-08-27 | 哈尔滨工业大学无锡新材料研究院 | It is a kind of without transfer organosilicon-modified acrylate mould release and preparation method thereof |
CN107570393A (en) * | 2017-07-19 | 2018-01-12 | 深圳市佰瑞兴实业有限公司 | A kind of coating process of reticulate pattern PET silicone release films |
CN110886127A (en) * | 2019-12-05 | 2020-03-17 | 江苏双冠新材料科技有限公司 | Preparation method of antibacterial antistatic release paper |
Also Published As
Publication number | Publication date |
---|---|
CN105131779B (en) | 2018-06-29 |
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Effective date of registration: 20191114 Address after: 226600 No.16, Lianfa Road, Binhai New District, Haian City, Nantong City, Jiangsu Province Patentee after: Jiangsu Shuangguan New Material Technology Co.,Ltd. Address before: 200235 Xuhui District, Caobao Road, No. 120, Patentee before: Shanghai Institute of Technology |
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CP03 | Change of name, title or address | ||
CP03 | Change of name, title or address |
Address after: 226000 No. 16 Lianfa Road, Laobagang Binhai New Area, Haian City, Nantong City, Jiangsu Province Patentee after: Jiangsu Shuangguan New Materials Technology Co.,Ltd. Country or region after: China Address before: 226600 No.16 Lianfa Road, Binhai New Area, Hai'an City, Nantong City, Jiangsu Province Patentee before: Jiangsu Shuangguan New Material Technology Co.,Ltd. Country or region before: China |