CN105602443A - Peelable blue gel and preparation method - Google Patents
Peelable blue gel and preparation method Download PDFInfo
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- CN105602443A CN105602443A CN201610038599.7A CN201610038599A CN105602443A CN 105602443 A CN105602443 A CN 105602443A CN 201610038599 A CN201610038599 A CN 201610038599A CN 105602443 A CN105602443 A CN 105602443A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/005—Dendritic macromolecules
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
Abstract
The invention discloses a peelable blue gel and a preparation method. The peelable blue gel comprises, by weight, 50-80 parts of UV cured resin A, 50-80 parts of UV cured resin B, 50-80 parts of UV cured resin C, 0.05-0.1 part of flatting agent, 1-10 parts of wetting agent, 0.2-1 part of defoamer, 1-10 parts of color paste special for UV nail polish, 3-5 parts of photoinitiator A and 3-5 parts of photoinitiator B. After being irradiated by a 365nm UV-LED light, the peelable blue gel can be cured rapidly, has good binding force without peeling off, is easy to peel completely without residue, and can be applied to insulation, damp proof, pollution prevention, scratch protection of materials such as PET and ITO conducting films, ITO glass, glass of cellphones and tempered glass windows.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of peelable blue glue and preparation method, this peelable indigo plantGlue is specially adapted to 365nmUV-LED light source and irradiates curing.
Background technology
In recent years, the fast development of digital product has driven the fast development of touch-screen industry. High performance touch-screen is prepared workSkill need to have the ink of resistance erosion function or " peelable blue glue ", " surface protective glue " of metal surface processing protection use. In systemWhile making printed board, on plate, some part often will adopt adhesive to hide, in order to avoid poured for example golden hand when scolding tin by tinFinger, interface card, carbonaceous conductive button and larger area plate face, these all need optionally scolding tin and multiple scolding tin continuously,As the hybrid precast of SMD, Reflow Soldering craft and automatic and other soldering tin techniques etc. Using for reference peelable blue glue prints in PCB industryProtected mode in mask-making technology, adopts printing peelable glue to avoid touch-screen to sustain damage in the mill, enhances productivityAnd product quality. Conventionally, peelable glue is that use pliability ink, color be blueness to the protection of a kind of one pack system touch-screen special isolationGlutinous thick liquid, be more prone to peel off through high temperature resistant peelable glue coating later, toughness also can be strengthened, can after being finishedTo peel off easily with hand or instrument, and do not have residue at material surface or contaminated materials, do not need secondary cleaning, toolHave that adhesive force is good, cull, endurance (Acidity of Aikalinity) are unexcellent, the easily stripping of level and smooth light, the advantage such as easy to operate. Main applicationThe insulation plated film flow process of transparent ITO electro-conductive glass, ito thin film, PET film in touch-screen, can be by serigraphyAt PET film and on glass, after baking film forming, play in process of production the effect that prevents that material is contaminated or scratch, touchingShield upper and lower circuit bonding before, available simple and easy method is taken off, and once peels off clean.
Current peelable blue glue generally heats and is cured more than 100 DEG C, and solidification temperature is high, and general peelable indigo plantGlue equally also life period is long, and that stripping process exists is loaded down with trivial details, have the problems such as residual.
Summary of the invention
In order to overcome the deficiencies in the prior art, the object of the present invention is to provide a kind of can be fast curing-formed, adhesion goodPeelable blue glue and preparation method. The preparation method of this invention is simple, and the peelable blue glue obtaining is peeled off effective.
Technical scheme of the present invention is specifically described as follows.
The invention provides a kind of peelable blue glue, calculate by weight, its raw material composition and content are as follows:
Wherein: the chemical structural formula of described UV cured resin A is as follows:
Wherein: m is the integer within the scope of 1-30; N is the integer within the scope of 1-30;
Described UV cured resin B is hyperbranched UV cured resin;
Described UV cured resin C is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, oxolaneAcrylate, tetramethylol methane tetraacrylate, ethoxyquin bisphenol a dimethacrylate, two-trimethylolpropane 4 thirdOlefin(e) acid ester, three (2-ethoxy) isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trihydroxy methyl thirdAlkane triacrylate, the third oxidation trimethylolpropane triacrylate, ethoxyquin tetramethylol methane tetraacrylate, acrylic acid are differentNorbornene ester, tristane dimethanol diacrylate, the third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropaneThe acrylate monomer such as triacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester,Imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylate and vinylOne or more in ethers monomer;
Described wetting agent is selected from one or both in NP-100 or the German BYK333 levelling agent of LG-DOW company;
Described mill base is the blue F4049 of mill base;
Described light trigger A be selected from BASF Irgacure1173, Irgacure184D, IrgacureTPO, Irgacure369,Irgacure651, Irgacure379, Irgacure819, Irgacure907, macromolecular photoinitiator EsacureKIP150In one or more mixtures;
Described photoinitiator b select BASF BASF light trigger Irgacure2959, IRGACURE500,One or more mixtures in IRGACURE819DW.
In the present invention, described UV cured resin A calculates by weight, and its raw material composition and content are as follows:
Described UV cured resin A is prepared as follows:
Methyl and phenyl hydrogen-containing silicon oil and glycerol propoxylate triacrylate are joined in reaction vessel in proportion, then add inhibitionAgent, passes into protective gas, stirs and heats, and is warming up to 60～80 DEG C, adds catalyst, stirs lower constant temperature 3～5h, stopsOnly heating, treats that temperature drops to room temperature, obtains UV cured resin A.
In the present invention, described levelling agent be selected from the high TegoGlide410 of enlightening, German BYK Bi Ke BYK-UV3510,One or more in BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348.
In the present invention, described defoamer be selected from German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037,One or more in BYK-038, BYK-044 or BYK-038.
The present invention also provides a kind of preparation method of peelable blue glue, and concrete steps are as follows:
According to formula, in the high speed dispersor of controlling rotating speed 500-1200r/min, add wetting agent, levelling agent, defoamerWith mill base, after disperseing 15-20min under 600-800r/min rotating speed, rotating speed is down to 300r/min, add UV cured resinA, UV cured resin B, UV cured resin C and light trigger A, photoinitiator b, continue to disperse 60-120min,Mix, obtain peelable blue glue.
Useful achievement of the present invention is as follows:
The peelable blue glue of one of the present invention, owing to having adopted multi-functional acrylate's UV cured resin A and having had superThe hyperbranched UV cured resin of branched structure makes it have at 365nmUV-LED, the quick ability under the irradiation of lamp source.
The peelable blue glue of one of the present invention, the NDJ-1 rotation viscometer that adopts Shanghai sharp bearing device Manufacturing Co., Ltd to provide,By GB/T2794-2013, " the mensuration list cylinder rotary viscosimeter method of adhesive viscosity " entered under the condition of 25 DEG C of room temperaturesRow detects, and its viscosity is 25000～40000mPa.s.
The peelable blue glue of gained of the present invention, by GB/T6753.1-2007 standard, " colored paint, varnish and printing-ink grindThe mensuration of fineness " carry out the fineness test of peelable blue glue, recording fineness is 4.5 μ M.
Further, after the peelable blue glue film of gained of the present invention through the slide of the peelable blue glue of UV nail polish light irradiation precoatingSurface, according to fingers-touch method, (surface of the peelable blue glue of the pressing solidly that press...with one's finger a period of time, using tack-free as completely solidThe standard of changing, while solidifying completely with peelable blue glue, the shortest time used characterizes), after testing, quick-drying of the present invention canBe 1-17s the hardening time of peeling off blue glue.
Further, the peelable blue glue of one of the present invention, as the UV cured resin A molecular structure of main film forming substance isOrganosilicon structure, has very low surface energy, has reduced the interaction between film and base material, makes it to embody better from strippingFrom property, do not need to add again and peel off auxiliary agent, effectively overcome the problem of peeling off rear residual stain. Peel strength adopts Shenzhen newly to think carefullyThe CMT5104 electronic tension tester of company is at room temperature pressed " the 180 ° of peel strength examinations of adhesive of GB/T2790-1995 standardProved recipe method " carry out the test of peeling off of 180 °, draw speed 50mm/min; Recording peel strength is 0.21～0.25kN/m;
Further, the chameleon pigment that the peelable blue glue of gained of the present invention adds has come Protean to peelable blue adhesive tapeColor, interpolation there is toughening effect UV cured resin C, make peelable blue glue there is certain toughness.
In sum, the peelable blue glue of one of the present invention, has the rapid curing energy under irradiating in 365nmUV-LED lamp sourcePower, it has higher toughness, gloss and metachrosis after film. And its preparation method is because technique is simple, easy to control,Therefore possess skills maturation, the feature such as quick, efficient, and be suitable for suitability for industrialized production.
Detailed description of the invention
Below by embodiment, the present invention is described in further detail, but do not limit the present invention.
In various embodiments of the present invention raw material used, except the special producer and specification showing, other raw materials are commercially available, specificationBe chemical pure.
The model of various device and the information of manufacturer that the present invention is used are as follows:
GFJ-0.4 type high speed dispersor, Shanghai Xin Nuo instrument and equipment Co., Ltd produces.
Embodiment 1
A kind of peelable blue glue, calculates by weight, and its raw material composition and content are as follows:
Wherein: described UV cured resin A calculates by weight, and its composition and content are as follows:
Described UV cured resin A is prepared as follows: by 20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of glycerol propoxylatesTriacrylate joins in the there-necked flask of 500ml, then adds 0.005 polymerization inhibitor MEHQ, passes into protection gasBody, stirs and heats, and is warming up to 60 DEG C, adds 0.03 part of catalyst chloroplatinic acid/aqueous isopropanol, stirs lower constant temperature 3h,Stop heating, treat that flask temperature drops to room temperature, obtain UV cured resin A.
Described UV cured resin C is double pentaerythritol methacrylate, diethylene glycol diacrylate, oxolane thirdOlefin(e) acid ester, tetramethylol methane tetraacrylate be the mixture of 2:1:1:2 composition in mass ratio;
Described levelling agent is the high TegoGlide410 of enlightening;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is German BYK-035, the BYK-037 mixture of 1:1 in mass ratio;
Described UV mill base is the blue F4049 of mill base;
Described light trigger A is BASF Irgacure1173, Irgacure184D, IrgacureTPO, 1:1:1 in mass ratioThe mixture of composition;
Described photoinitiator b be BASF BASF light trigger Irgacure2959, IRGACURE500 in mass ratioThe mixture of 1:1 composition;
In the present embodiment, a kind of preparation method of peelable blue glue, specifically comprises the steps:
According to formula, in GFJ-0.4 type high speed dispersor (the limited public affairs of the new promise instrument and equipment in Shanghai of controlling rotating speed 500r/minDepartment) in add 1 part of wetting agent, 0.05 part of levelling agent, 0.2 part of defoamer and 1 part of mill base, through lower point of 600r/min rotating speedAfter loose 15min, rotating speed is down to 300r/min, adds 50 parts of UV cured resin A, 50 parts of UV cured resin B, 50Part UV cured resin C, 3 parts of light trigger A and 3 parts of photoinitiator bs, continue to disperse 60min, mixes,Obtain peelable blue glue.
The peelable blue glue of the present embodiment gained, the NDJ-1 rotary viscosity that adopts Shanghai sharp bearing device Manufacturing Co., Ltd to provideMeter, by GB/T2794-2013, " the mensuration list cylinder rotary viscosimeter method of adhesive viscosity ", in the condition of 25 DEG C of room temperaturesUnder detect, its viscosity is 40000mPa.s.
The peelable blue glue of the present embodiment gained, by GB/T6753.1-2007 standard, " colored paint, varnish and printing-ink grindThe mensuration of grinding rate " carry out the fineness test of peelable blue glue, recording fineness is 4.5 μ M.
After the peelable blue glue film of the present embodiment gained through the peelable blue glue of the UV-LED of 365nm light irradiation precoating carry glassThe surface of sheet, according to fingers-touch method, (surface of the peelable blue glue of the pressing solidly that press...with one's finger a period of time, using tack-free as completeComplete curing standard, while solidifying completely with peelable blue glue, the shortest time used characterizes), after testing, of the present invention fastBe 1s the hardening time of dry peelable blue glue.
Further, the peelable blue glue of the one of the present embodiment, as the UV cured resin A molecular structure of main film forming substanceFor organosilicon structure, there is very low surface energy, reduce the interaction between film and base material, make it to embody and better canFissility, peel strength adopt CMT5104 electronic tension tester that Shenzhen newly thinks carefully company at room temperature byGB/T2790-1995 standard " 180 ° of peeling strength test methods of adhesive " is carried out the test of peeling off of 180 °, draw speed50mm/min; Recording peel strength is 0.25kN/m;
Higher curing rate after the peelable blue glue film of this present embodiment gained, easily peels off in sum.
Embodiment 2
A kind of peelable blue glue, calculates by weight, and its raw material composition and content are as follows:
Wherein: described UV cured resin A calculates by weight, and its composition and content are as follows:
Described UV cured resin A is prepared as follows: by above-mentioned 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 part of third oxidationGlycerol tri-acrylate joins in the there-necked flask of 500ml, then adds the polymerization inhibitor MEHQ of 0.01 part, passes into guarantorProtect gas, stir and heat, be warming up to 80 DEG C, add 0.05 part of catalyst chloroplatinic acid/vinyl double-seal head complex compound, stirLower constant temperature 5h, stops heating, treats that flask temperature drops to room temperature, obtains UV cured resin A.
Described UV cured resin C is double pentaerythritol methacrylate, diethylene glycol diacrylate, oxolane thirdOlefin(e) acid ester, tetramethylol methane tetraacrylate be the mixture of 1:1:1:1 composition in mass ratio;
Described levelling agent is German BYK-345, the BYK-346 mixture of 1:1 composition in mass ratio;
Described wetting agent is German BYK333;
Described defoamer is German BYK Bi Ke BYK-024, the BYK-025 mixture of 1:1 composition in mass ratio;
Described UV mill base is the blue F4049 of mill base
Described light trigger A is BASF Irgacure184D, IrgacureTPO, Irgacure369, in mass ratioMany kinds of mixtures of 1:1:1;
Described photoinitiator b be BASF BASF light trigger Irgacure2959, IRGACURE500 in mass ratioThe mixture of 2:1 composition;
In the present embodiment, a kind of preparation method of peelable blue glue, specifically comprises the steps:
According to formula, in GFJ-0.4 type high speed dispersor (the limited public affairs of the new promise instrument and equipment in Shanghai of controlling rotating speed 1200r/minDepartment) in add 10 parts of wetting agents, 0.1 part of levelling agent, 1 part of defoamer and 10 parts of mill bases, under 800r/min rotating speed, disperseAfter 20min, rotating speed is down to 300r/min, add 80 parts of UV cured resin A, 80 parts of UV cured resin B, 80 partsUV cured resin C, 5 parts of light trigger A and 5 parts of photoinitiator bs, continue to disperse 120min, mixes, and to obtain final productTo peelable blue glue.
The peelable blue glue of the present embodiment gained, the NDJ-1 rotary viscosity that adopts Shanghai sharp bearing device Manufacturing Co., Ltd to provideMeter, by GB/T2794-2013, " the mensuration list cylinder rotary viscosimeter method of adhesive viscosity ", in the condition of 25 DEG C of room temperaturesUnder detect, its viscosity is 25000mPa.s.
The peelable blue glue of the present embodiment gained, by GB/T6753.1-2007 standard, " colored paint, varnish and printing-ink grindThe mensuration of grinding rate " carry out the fineness test of peelable blue glue, recording fineness is 4.5 μ M.
After the peelable blue glue film of the present embodiment gained through the peelable blue glue of the UV-LED of 365nm light irradiation precoating carry glassThe surface of sheet, according to fingers-touch method, (surface of the peelable blue glue of the pressing solidly that press...with one's finger a period of time, using tack-free as completeComplete curing standard, while solidifying completely with peelable blue glue, the shortest time used characterizes), after testing, of the present invention fastBe 17s the hardening time of dry peelable blue glue. After solidifying, present color changeable effect.
The CMT5104 electronic tension tester that company is newly thought carefully in peel strength employing Shenzhen is at room temperature by GB/T2790-1995Standard " 180 ° of peeling strength test methods of adhesive " is carried out the test of peeling off of 180 °, draw speed 50mm/min; Record strippingBe 0.21kN/m from intensity;
Higher curing rate after the peelable blue glue film of above the present embodiment gained, easily peels off.
In sum, what peelable blue glue of the present invention adopted is UV curing formula, and the high speed of UV is solidified and promoted it and solidifySpeed, only has 1～17s; That adds has a toughening effect UV cured resin C, makes peelable blue glue have certain toughness.UV cured resin A molecular structure as main film forming substance is organosilicon structure, has very low surface energy, has reducedInteraction between film and base material, makes it to embody better from fissility, does not need to add again and peels off auxiliary agent, effectively overcomesPeel off the problem of rear residual stain, peel strength is 0.21～0.25kN/m; Warp after this is high temperature resistant peelable blue glue filmAfter 365nmUV-LED light irradiation, have rapid curing ability, the good non-scale of adhesion comes off, peels off easy, complete, does not flowResidual stain.
Described content is only the basic explanation of the present invention under conceiving, and any equivalence of doing according to technical scheme of the present invention becomesChange, all should belong to protection scope of the present invention.
Claims (6)
1. a peelable blue glue, is characterized in that calculating by weight, and its raw material composition and content are as follows:
Wherein: the chemical structural formula of described UV cured resin A is as follows:
Wherein: m is the integer within the scope of 1-30; N is the integer within the scope of 1-30;
Described UV cured resin B is hyperbranched UV cured resin;
Described UV cured resin C is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, oxolaneAcrylate, tetramethylol methane tetraacrylate, ethoxyquin bisphenol a dimethacrylate, two-trimethylolpropane 4 thirdOlefin(e) acid ester, three (2-ethoxy) isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trihydroxy methyl thirdAlkane triacrylate, the third oxidation trimethylolpropane triacrylate, ethoxyquin tetramethylol methane tetraacrylate, acrylic acid are differentNorbornene ester, tristane dimethanol diacrylate, the third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropaneTriacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals list acrylic acidIn ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylate and vinyl ethers monomer oneKind or several;
Described wetting agent is selected from a kind of in the NP-100 of LG-DOW company or German BYK333 levelling agent or twoKind;
Described mill base is the blue F4049 of mill base;
Described light trigger A be selected from BASF Irgacure1173, Irgacure184D, IrgacureTPO, Irgacure369,Irgacure651, Irgacure379, Irgacure819, Irgacure907, macromolecular photoinitiator EsacureKIP150In one or more mixtures;
Described photoinitiator b select BASF BASF light trigger Irgacure2959, IRGACURE500,One or more mixtures in IRGACURE819DW.
2. peelable blue glue according to claim 1, is characterized in that, the viscosity at its 25 DEG C is 25000-40000mPa.s,Be 1-17s hardening time, and the peel strength under draw speed 50mm/min is 0.21～0.25kN/m.
3. peelable blue glue according to claim 1, is characterized in that, described UV cured resin A counts by weightCalculate, its raw material composition and content are as follows:
Described UV cured resin A is prepared as follows:
Methyl and phenyl hydrogen-containing silicon oil and glycerol propoxylate triacrylate are joined in reaction vessel in proportion, then add inhibitionAgent, passes into protective gas, stirs and heats, and is warming up to 60～80 DEG C, adds catalyst, stirs lower constant temperature 3～5h, stopsOnly heating, treats that temperature drops to room temperature, obtains UV cured resin A.
4. peelable blue glue according to claim 1, is characterized in that, described levelling agent be selected from the high TegoGlide410 of enlightening,Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 orOne or more in BYK-348.
5. peelable blue glue according to claim 1, is characterized in that, described defoamer is selected from German BYK Bi KeA kind of in BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038 orSeveral.
6. a preparation method for peelable blue glue, is characterized in that, concrete steps are as follows:
According to formula, in the high speed dispersor of controlling rotating speed 500-1200r/min, add wetting agent, levelling agent, defoamerWith mill base, after disperseing 15-20min under 600-800r/min rotating speed, rotating speed is down to 300r/min, add UV cured resinA, UV cured resin B, UV cured resin C and light trigger A, photoinitiator b, continue to disperse 60-120min,Mix, obtain peelable blue glue.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109438613A (en) * | 2018-10-23 | 2019-03-08 | 上海应用技术大学 | A kind of damping resin emulsion and preparation method thereof |
| CN109438614A (en) * | 2018-10-23 | 2019-03-08 | 上海应用技术大学 | A kind of resin aqueous emulsion and preparation method thereof |
| CN111138607A (en) * | 2019-12-30 | 2020-05-12 | 西安交通大学 | Temperature-sensitive coacervate type hyperbranched polyethylene glycol and preparation method and application thereof |
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| CN103627313A (en) * | 2013-11-29 | 2014-03-12 | 广州机械科学研究院有限公司 | Ultraviolet-cured stripping protective material and preparation method and application thereof |
| CN105131779A (en) * | 2015-09-14 | 2015-12-09 | 上海应用技术学院 | Ultraviolet curing organic silicon release agent and preparation method thereof |
| CN105219252A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of UV solidifies strippable water-based paint and preparation method thereof |
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| CN109438613A (en) * | 2018-10-23 | 2019-03-08 | 上海应用技术大学 | A kind of damping resin emulsion and preparation method thereof |
| CN109438614A (en) * | 2018-10-23 | 2019-03-08 | 上海应用技术大学 | A kind of resin aqueous emulsion and preparation method thereof |
| CN111138607A (en) * | 2019-12-30 | 2020-05-12 | 西安交通大学 | Temperature-sensitive coacervate type hyperbranched polyethylene glycol and preparation method and application thereof |
| CN111138607B (en) * | 2019-12-30 | 2021-11-19 | 西安交通大学 | Temperature-sensitive coacervate type hyperbranched polyethylene glycol and preparation method and application thereof |
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