CN105482690B - Peelable blue glue and its synthetic method - Google Patents
Peelable blue glue and its synthetic method Download PDFInfo
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- CN105482690B CN105482690B CN201610038613.3A CN201610038613A CN105482690B CN 105482690 B CN105482690 B CN 105482690B CN 201610038613 A CN201610038613 A CN 201610038613A CN 105482690 B CN105482690 B CN 105482690B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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Abstract
The invention discloses a kind of peelable blue glue and its synthetic method.The peelable blue glue of the present invention, in parts by weight, it is made up of 80 120 parts of UV solidified resins A, 80 120 parts of UV solidified resins B, 80 120 parts of UV solidified resins C, 0.05 0.1 parts of levelling agents, 1 10 parts of wetting agent, 0.2 1 parts of defoamer, 1 10 parts of mill bases, 37 parts of light trigger A and 37 parts of photoinitiator b.There are quick setting capabilities after the irradiation of 365nmUV LEDs, the good non-scale of adhesion comes off, peeled off easily, completely, does not flow residual stain after the peelable blue glue film of the present invention；It can be applied to the insulating, the be moistureproof of materials such as PET, ITO conducting film, ito glass, mobile phone glass, strengthened glass form, anti-pollution and scratch resistant protection.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of peelable blue glue and its synthetic method, this can
Peel off blue glue and irradiated especially suitable for 365nm UV-LED light sources and solidified.
Background technology
In recent years, the fast development of digital product has driven the fast development of touch-screen industry.High performance touch-screen system
Standby technique needs the ink with resistance erosion function or " peelable blue gel ", " surface protective glue " of metal surface processing protection.
When manufacturing printed board, some parts will often be covered using adhesive on plate, in order to avoid poured during scolding tin by tin, such as golden hand
Finger, interface card, the plate face of carbonaceous conductive button and larger area, these are required for optionally scolding tin and multiple continuously scolding tin,
Such as SMD hybrid precast, Reflow Soldering craft and automatic and other soldering tin techniques etc..Peelable blue gel is used for reference in PCB industry printed boards
Protected mode in technique, avoid touch-screen from sustaining damage in the mill using printing peelable glue, improve production efficiency and production
Product quality.Generally, peelable glue is a kind of one pack system touch-screen special isolation protection pliability ink, and color is sticky for blueness
Shape liquid, it is more prone to peel off by the peelable gel coating after high temperature resistant, toughness can also be strengthened, and can use hand after application
Or instrument easily peels off, without having residue in material surface or contaminated materials, it is not necessary to secondary cleaning, there is attachment
Power is good, cull, endurance (acid-base property) be not excellent, smooth bright easy-peel, it is easy to operate the advantages that.It is mainly used in touch-screen thoroughly
Bright ITO electro-conductive glass, ito thin film, the insulation plated film flow of PET film, it can be dried by being screen printed onto in PET film and glass
Be roasted into after film and play a part of preventing material contaminated in process of production or scratch, on the touchscreen, lower circuit bonding before,
It can be taken off with simple and easy method, and be once stripped clean.
Current peelable blue glue typically heats more than 100 DEG C to be solidified, and solidification temperature is high, and in general is peelable
Blue glue equally there is also time length, stripping process exist it is cumbersome, have the problems such as residual.
Based on background above, it is necessary to develop one kind can rapid curing, the good non-scale of adhesion come off, have peel off easily,
Completely, peelable blue glue of high temperature resistant of the good peeling effect such as residual stain and preparation method thereof is not flowed.
Based on background above, it is necessary to develop peelable blue glue of a kind of high temperature resistant and preparation method thereof.
The content of the invention
One of the object of the invention provides a kind of energy rapid curing, while has the peelable blue glue of high glaze, color changeable effect.
The two of the object of the invention provide a kind of above-mentioned synthetic method of peelable blue glue.
Technical scheme is specifically described as follows.
The present invention provides a kind of peelable blue glue, and in parts by weight, its raw material composition and content are as follows：
Wherein：Described UV solidified resins A chemical structural formula is as follows：
Wherein：M is the integer in the range of 1-30；N is the integer in the range of 1-30；
Described UV solidified resins B is hyperbranched UV solidified resins；
Described UV solidified resins C is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
Olefin(e) acid ester, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra acid
Ester, three (2- ethoxys) isocyanuric acid triacrylates, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris propylene
Acid esters, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, three
Cyclodecane Dimethanol Diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane trimethacrylate,
Hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester list
One or more in acrylate, epoxy silicone monomer, silicone acrylate and vinyl ethers monomer；
Described mill base is mill base indigo plant F4049.
In the present invention, in parts by weight, its raw material composition and content are as follows by described UV solidified resins A：
Described UV solidified resins A is prepared as follows：
Methyl and phenyl hydrogen-containing silicon oil and propoxylation trimethylolpropane trimethacrylate are proportionally added into reaction to hold
In device, polymerization inhibitor is added, is passed through protective gas, stirs and heats, is warming up to 60~80 DEG C, adds catalyst, stirs lower perseverance
3~5h of temperature, stop heating, treat that flask temperature drops to room temperature, produce UV solidified resins A.
In the present invention, described levelling agent be selected from the high Tego Glide 410 of enlightening, German BYK Bi Ke BYK-UV3510,
One or more in BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348；Described wetting agent is
One or both of the NP-100 of LG-DOW company or the levelling agents of German BYK 333；Described defoamer is selected from Germany
One kind or several in BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038
Kind.
In the present invention, described light trigger A is BASF Irgacure1173, Irgacure 184D, Irgacure
TPO, Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular
One or more in light trigger Esacure KIP 150；Described photoinitiator b is selected from BASF BASF light triggers
It is one or more of in Irgacure 2959, IRGACURE500 or IRGACURE819DW.
The present invention also provides a kind of synthetic method of peelable blue glue, comprises the following steps that：
According to formula, wetting agent, levelling agent, defoamer are added in control rotating speed 300-400r/min high speed dispersor
With mill base, rotating speed is down to 300r/min after disperseing 15-20min under 600-800r/min rotating speeds, add UV solidified resins A,
UV solidified resin B, UV solidified resin C and light trigger A, photoinitiator b, continue scattered 5-10min, be well mixed, that is, obtain
Peelable blue glue.
The useful achievement of the present invention is as follows：
A kind of peelable blue glue of the present invention, as a result of the UV solidified resins A and tool of multi-functional acrylate
The hyperbranched UV solidified resins for having dissaving structure make it have the rapid capability under 365nmUV-LED, lamp source irradiation.
The peelable blue glue of gained of the invention, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai rotate viscous
Degree meter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of condition of room temperature
Under detected, its viscosity is 23000~40000mPa.s.
The peelable blue glue of gained of the invention, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of fineness " carries out the fineness test of peelable blue glue, and measuring fineness is：≤μm.
Further, the load glass of peelable blue glue is precoated after the peelable blue glue film of present invention gained through UV nail polish light irradiation
The surface of piece, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as completely
The standard of solidification, when being fully cured with peelable blue glue the shortest time used characterize), after testing, quick-drying of the invention can
The hardening time for peeling off blue glue is 3-30s.
Further, a kind of peelable blue glue of the invention, the UV solidified resin A molecular structures as main film forming substance are
Organosilicon structures, there is very low surface energy, reduce the interaction between film and base material, be allowed to embody preferably from stripping
Property, be not required to add stripping auxiliary agent again, effectively overcome stripping after residual stain the problem of.Peel strength newly thinks carefully company using Shenzhen
CMT5104 electronic tension testers press GB/T2790-1995 standards " 180 ° of peeling strength test sides of adhesive at room temperature
Method " carries out 180 ° of peel test, draw speed 50mm/min；It is 0.21~0.25kN/m to measure peel strength；
Further, the chameleon pigment of the peelable blue glue addition of present invention gained brings thousand changes ten thousand to peelable blue glue
The color of change, addition have toughening effect UV solidified resin C, peelable blue glue is had certain toughness.
In summary, a kind of peelable blue glue of the invention, there is the rapid curing under the irradiation of 365nmUV-LED lamp sources
Ability, it has higher toughness, easily peelable after film.And its preparation method due to technique it is simple, it is easy to control, therefore have
Technology maturation, it is quick, efficient the features such as, and be suitable to industrialized production.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows：
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of peelable blue glue, in parts by weight, its raw material composition and content are as follows：
Wherein：In parts by weight, it is formed described UV solidified resins A and content is as follows：
Described UV solidified resins A is prepared as follows：By 20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of propoxylations
Trimethylolpropane trimethacrylate is added in 500ml three-necked flask, adds 0.005 part of hydroquinone of polymerization retarder,
Protective gas is passed through, stirs and heats, is warming up to 60 DEG C, adds 0.03 part of catalyst chloroplatinic acid/aqueous isopropanol, stirs lower perseverance
Warm 3h, stop heating, treat that flask temperature drops to room temperature, produce UV solidified resins A.
Described UV solidified resins B is hyperbranched UV solidified resins；
Described UV solidified resins C is isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, (2) third oxidations
Neopentylglycol diacrylate, (15) ethoxyquin trimethylolpropane trimethacrylate in mass ratio 1：1：1：The mixing of 1 composition
Thing；
Described levelling agent is the high Tego Glide 410 of enlightening；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is German BYK-035, BYK-037 in mass ratio 1：1 mixture；
Described UV mill bases are mill base indigo plant F4049
Described light trigger A is BASF Irgacure1173, Irgacure 184D, Irgacure TPO press quality
Than 1:1:The mixture of 1 composition；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 in mass ratio
1:The mixture of 1 composition；
In the present embodiment, a kind of synthetic method of peelable blue glue, specifically comprise the following steps：
According to formula, in control rotating speed 300r/min GFJ-0.4 types high speed dispersor, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent of middle addition, 0.05 part of levelling agent, 0.2 part of defoamer and 1 part of mill base, through disperseing under 600r/min rotating speeds
Rotating speed is down to 300r/min after 15min, adds 50 parts of UV solidified resins A, 50 parts of UV solidified resins B, 50 parts of UV solidified resins
C, 3 parts of light trigger A and 3 parts of photoinitiator bs, continue scattered 10min, be well mixed, that is, obtain peelable blue glue.
Peelable blue glue obtained by the present embodiment, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai are rotated
Viscosimeter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of bar of room temperature
Detected under part, its viscosity is 40000mPa.s.
Peelable blue glue obtained by the present embodiment, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, measures fineness as 4.5 μM.
The UV-LED light irradiations through 365nm precoat the load of peelable blue glue after peelable blue glue film obtained by the present embodiment
The surface of slide, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as complete
The standard of all solidstate, when being fully cured with peelable blue glue shortest time used characterize), after testing, quick-drying of the invention
The hardening time of peelable blue glue is 3s.
Further, a kind of peelable blue glue of the present embodiment, the UV solidified resin A molecular structures as main film forming substance
For organosilicon structures, there is very low surface energy, reduce the interaction between film and base material, be allowed to embody preferably from stripping
From property, peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 using Shenzhen
Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, draw speed 50mm/min；Measure stripping
Intensity is 0.25kN/m；
Higher curing rate after peelable blue glue film obtained by above the present embodiment, while there is color changeable effect.
Embodiment 2
A kind of peelable blue glue, in parts by weight, its raw material composition and content are as follows：
Wherein：In parts by weight, it is formed described UV solidified resins A and content is as follows：
Described UV solidified resins A is prepared as follows：By above-mentioned 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 part of third oxygen
Base trimethylolpropane trimethacrylate is added in 500ml three-necked flask, adds 0.01 part of polymerization inhibitor to hydroxyl
Methyl phenyl ethers anisole, protective gas is passed through, stirs and heat, be warming up to 80 DEG C, add 0.05 part of catalyst chloroplatinic acid/vinyl double seal head
Complex compound, lower constant temperature 5h is stirred, stops heating, treats that flask temperature drops to room temperature, produce UV solidified resins A.
Described UV solidified resins B is hyperbranched UV solidified resins；
Described UV solidified resins C is isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, (2) third oxidations
Neopentylglycol diacrylate, (15) ethoxyquin trimethylolpropane trimethacrylate in mass ratio 1：2：2：The mixing of 2 compositions
Thing；
Described levelling agent is German BYK-345, BYK-346 in mass ratio 1：The mixture of 1 composition；
Described wetting agent is German BYK 333；
Described defoamer is German BYK Bi Ke BYK-024, BYK-025 in mass ratio 1:The mixture of 1 composition；
Described UV mill bases are mill base indigo plant F4049
Described light trigger A is BASF Irgacure 184D, Irgacure TPO, Irgacure 369 press quality
Than 1:1：More than 1 kinds of mixture；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 in mass ratio
2:The mixture of 1 composition；
In the present embodiment, a kind of synthetic method of peelable blue glue, specifically comprise the following steps：
According to formula, in control rotating speed 400r/min GFJ-0.4 types high speed dispersor, (the new promise instrument and equipment in Shanghai is limited
Company) 10 parts of wetting agents of middle addition, 0.1 part of levelling agent, 1 part of defoamer and 10 parts of mill bases, through disperseing under 800r/min rotating speeds
Rotating speed is down to 300r/min after 20min, adds 80 parts of UV solidified resins A, 80 parts of UV solidified resins B, 80 parts of UV solidified resins
C, 5 parts of light trigger A and 5 parts of photoinitiator bs, continue scattered 10min, be well mixed, that is, obtain peelable blue glue.
Peelable blue glue obtained by the present embodiment, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai are rotated
Viscosimeter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of bar of room temperature
Detected under part, its viscosity is 23000mPa.s.
Peelable blue glue obtained by the present embodiment, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, measures fineness as 3.5 μm.
The UV-LED light irradiations through 365nm precoat the load of peelable blue glue after peelable blue glue film obtained by the present embodiment
The surface of slide, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as complete
The standard of all solidstate, when being fully cured with peelable blue glue shortest time used characterize), after testing, quick-drying of the invention
The hardening time of peelable blue glue is 30s.Color changeable effect is presented after solidification.
Further, a kind of peelable blue glue of the present embodiment, the UV solidified resin A molecular structures as main film forming substance
For organosilicon structures, there is very low surface energy, reduce the interaction between film and base material, be allowed to embody preferably from stripping
From property, peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 using Shenzhen
Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, draw speed 50mm/min；Measure stripping
Intensity is 0.21kN/m；
Higher curing rate after the peelable blue glue film of the gained of above example 2, while there is color changeable effect.
In summary, peelable blue glue of the invention improves it and consolidated using UV curing formulas, UV high speed curable
Change speed, only 3~30s；UV solidified resin A molecular structures as main film forming substance are organosilicon structures, are had very low
Surface energy, reduce the interaction between film and base material, be allowed to embody preferably from fissility, be not required to add stripping again and help
Agent, effectively overcome stripping after residual stain the problem of, peel strength is 0.21~0.25kN/m；Addition has toughening effect UV
Solidified resin C, make peelable blue glue that there is certain toughness, it is more easily peelable.Passed through after the peelable blue glue film of the high temperature resistant
There are quick setting capabilities, the good non-scale of adhesion comes off, peeled off easily, completely, do not flow residual after 365nmUV-LED light irradiations
Stain.
The content is only the basic explanation under present inventive concept, and is made according to technical scheme any etc.
Effect conversion, all should belong to protection scope of the present invention.
Claims (4)
1. a kind of peelable blue glue, it is characterised in that in parts by weight, its raw material composition and content are as follows：
Wherein：Described UV solidified resins A chemical structural formula is as follows：
Wherein：M is the integer in the range of 1-30；N is the integer in the range of 1-30；
Described UV solidified resins B is hyperbranched UV solidified resins；
Described UV solidified resins C is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran acrylic acid
Ester, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra-acrylate, three
(2- ethoxys) isocyanuric acid triacrylate, pentaerythritol triacrylate, third oxidation trimethylolpropane trimethacrylate,
Ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, the third oxidation new penta 2
Alcohol diacrylate, ethoxyquin trimethylolpropane trimethacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester,
Carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylic acid
One or more in ester and vinyl ethers monomer；
Described mill base is mill base indigo plant F4049.
2. peelable blue glue according to claim 1, it is characterised in that described UV solidified resins A is counted in parts by weight
Calculate, its raw material composition and content are as follows：
Described UV solidified resins A is prepared as follows：
Methyl and phenyl hydrogen-containing silicon oil and propoxylation trimethylolpropane trimethacrylate are proportionally added into reaction vessel,
Add polymerization inhibitor, be passed through protective gas, stir and heat, be warming up to 60~80 DEG C, add catalyst, stir lower constant temperature 3~
5h, stop heating, treat that flask temperature drops to room temperature, produce UV solidified resins A.
3. peelable blue glue according to claim 1, it is characterised in that described levelling agent is selected from the high Tego Glide of enlightening
410th, in German BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348
One or more；Described wetting agent is one or both of NP-100 or German BYK 333 of LG-DOW company；
Described defoamer is in German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-044 or BYK-038
One or more.
4. peelable blue glue according to claim 1, it is characterised in that described light trigger A is BASF
Irgacure1173、Irgacure 184D、Irgacure TPO、Irgacure 369、Irgacure 651、Irgacure
379th, the one or more in Irgacure 819, Irgacure 907 or macromolecular photoinitiator Esacure KIP 150；Institute
The photoinitiator b stated is in BASF BASF light triggers Irgacure 2959, IRGACURE500 or IRGACURE819DW
It is one or more of.
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| CN103627313A (en) * | 2013-11-29 | 2014-03-12 | 广州机械科学研究院有限公司 | Ultraviolet-cured stripping protective material and preparation method and application thereof |
| CN104745068A (en) * | 2013-12-30 | 2015-07-01 | 比亚迪股份有限公司 | Modified UV paint and preparation method thereof |
| CN105219252A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of UV solidifies strippable water-based paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10155184A1 (en) * | 2001-11-12 | 2003-05-22 | Bayer Ag | Emulsion polymers as a peelable varnish |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031053A (en) * | 2013-01-06 | 2013-04-10 | 北京海斯迪克新材料有限公司 | UV-cured peelable blue gel for temporary protection of touch screen and preparation method thereof |
| CN103627313A (en) * | 2013-11-29 | 2014-03-12 | 广州机械科学研究院有限公司 | Ultraviolet-cured stripping protective material and preparation method and application thereof |
| CN104745068A (en) * | 2013-12-30 | 2015-07-01 | 比亚迪股份有限公司 | Modified UV paint and preparation method thereof |
| CN105219252A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of UV solidifies strippable water-based paint and preparation method thereof |
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