CN105748317B - Quick-setting strippable property nail polish glue and preparation method thereof - Google Patents
Quick-setting strippable property nail polish glue and preparation method thereof Download PDFInfo
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- CN105748317B CN105748317B CN201610099216.7A CN201610099216A CN105748317B CN 105748317 B CN105748317 B CN 105748317B CN 201610099216 A CN201610099216 A CN 201610099216A CN 105748317 B CN105748317 B CN 105748317B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/544—Dendrimers, Hyperbranched polymers
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Abstract
The invention discloses a kind of quick-setting strippable property nail polish glue, in parts by weight, it is made of reactive diluent, 0.05-0.1 parts of levelling agents, 1-10 parts of wetting agent, 0.2-1 parts of defoaming agent, 1-10 parts of mill bases, 3-5 parts of A and 3-5 parts of photoinitiator of the photoinitiator b of UV solidified resin B, 50-80 part of 50-80 parts of UV solidified resin A, 50-80 part.The present invention also provides the preparation methods of above-mentioned strippable property nail polish glue, wetting agent, levelling agent, defoaming agent and mill base are added in high speed disperser, UV solidified resin A, UV solidified resin B, reactive diluent, photoinitiator A and photoinitiator b are added after dispersion, continue to disperse, it is uniformly mixed to get strippable property nail polish glue is arrived.To there are quick setting capabilities after 385nmUV-LED light irradiation after nail polish glue film of the invention, the technical fields such as the manicure of various people can be widely used.
Description
Technical field
The invention belongs to polymeric material fields, are related to a kind of nail polish glue, specifically a kind of quick-setting peelable
Property nail polish glue and preparation method thereof.
Background technique
Ms likes having deep love for derived from one kind to manicure.Nail polish glue using when with tool be applied to nail, by common UV light
Crosslink polymerization reaction after the light source treatment with irradiation of source, the nail polish adhesive curing object of generation is beautiful in colour, glittering and translucent full, change
It is infinite, it is the favorite of ladies.Compared with common UV light source curing mode, UV-LED light source is high with luminous efficiency, the service life is long,
Many advantages, such as reaction speed is fast, heat release is few, energy-saving and environmental protection has gradually substituted common UV light source.With enriching for city life
With the quickening of rhythm of life transformation, ladies have liked the nail of allegro transformation oneself.Peelable nail polish glue is easy to use,
Do not have to whole of cleaner energy when needing to remove to peel off, easily, is particularly suitable for child and uses.But current peelable nail polish glue one
As peelable component is added in the formula of nail polish glue, make troubles to the production and use of nail polish glue.
Based on background above, need to develop one kind can rapid curing, have from removing component and meanwhile have decorative effect,
The good strippable property nail polish glue and preparation method thereof of peeling effect.
Summary of the invention
For above-mentioned technical problem in the prior art, the present invention provides a kind of quick-setting strippable property nail polish glue and
Preparation method, described this quick-setting strippable property nail polish glue and preparation method thereof will solve nail polish in the prior art
Peelable component is added in glue formula, the technical issues of production and use to nail polish glue are made troubles.
The present invention provides a kind of quick-setting strippable property nail polish glue, and in parts by weight, raw material forms and contains
It measures as follows:
Wherein, the chemical structure of the UV solidified resin A is as follows:
Wherein: m is the integer within the scope of 1-30；N is the integer within the scope of 1-30；
The UV solidified resin A's the preparation method is as follows:
1) following each component is weighed in parts by weight:
2) above-mentioned resulting methyl and phenyl hydrogen-containing silicon oil and pentaerythritol tetraacrylate are added to a reaction vessel
In, polymerization inhibitor is added, protective gas is passed through, stirs and heats, is warming up to 60~80 DEG C, catalyst is added, stirs lower constant temperature 3
~5h stops heating, drops to room temperature to temperature to get UV solidified resin A；
The UV solidified resin B is hyperbranched UV solidified resin；
The reactive diluent is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
Olefin(e) acid ester, pentaerythritol tetraacrylate, ethoxylated bisphenol A dimethylacrylate, two-trimethylolpropane tetras acid
Ester, three (2- ethoxy) isocyanuric acid triacrylates, pentaerythritol tetraacrylate, ethoxyquin trimethylolpropane tris propylene
Acid esters, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin pentaerythritol tetraacrylate, isobornyl acrylate, three
Cyclodecane Dimethanol Diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane trimethacrylate,
Hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester list
In acrylate, epoxy silicone monomer, silicone acrylate or vinyl ethers monomer any one or it is two or more
Mixture；
The levelling agent is Digao Tego Glide 410, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-
344, any one in BYK-345, BYK-346, BYK-347 or BYK-348 or two or more mixtures；
The UV wetting agent is one of NP-100 or Germany's 333 levelling agent of BYK of Dow company or two
Kind mixture；
The defoaming agent is Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-
Any one in 044 or BYK-038 or two or more mixtures；
The photoinitiator A be BASF Irgacure1173, Irgacure 184D, Irgacure TPO,
Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular light
Any one in initiator Esacure KIP 150 or two or more mixtures；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 or
Any one in IRGACURE819DW or two or more mixtures；
Further, the mill base is a kind of temperature sensing color changing mill base of changeable colour.
Further, a kind of quick-setting strippable property nail polish glue of the invention, in parts by weight, raw material composition
And content is as follows:
Wherein the UV solidified resin A's the preparation method comprises the following steps:
Above-mentioned 20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of pentaerythritol tetraacrylates are added to a reaction vessel
In, 0.005 part of polymerization inhibitor is added, protective gas is passed through, stirs and heats, is warming up to 60 DEG C, catalyst, stirring is added
Lower constant temperature 3h stops heating, drops to room temperature to temperature to get UV solidified resin A；
The reactive diluent is tetrahydrofuran acrylate, pentaerythritol tetraacrylate and ethoxylated bisphenol A bis-
The mixture of methacrylate 1:1:1 in mass ratio composition；
The levelling agent is Digao Tego Glide 410；
The wetting agent is the NP-100 of Dow company；
The defoaming agent is Germany BYK-035, BYK-037 mixture of 1:1 in mass ratio；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is that BASF Irgacure1173, Irgacure 184D, Irgacure TPO press quality
Than the mixture of 1:1:1 composition；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 1:1 composition.
Further, a kind of quick-setting strippable property nail polish glue of the invention, in parts by weight, raw material composition
And content is as follows:
Wherein the UV solidified resin A's the preparation method is as follows:
Above-mentioned 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of pentaerythritol tetraacrylates are added to a reaction vessel
In, 0.01 part of polymerization inhibitor is added, protective gas is passed through, stirs and heats, is warming up to 80 DEG C, 0.05 part of catalyst is added,
Lower constant temperature 5h is stirred, stops heating, drops to room temperature to temperature to get UV solidified resin A；
The reactive diluent is tetrahydrofuran acrylate, pentaerythritol tetraacrylate and ethoxylated bisphenol A bis-
The mixture of methacrylate 2:1:1 in mass ratio composition；
The levelling agent is the mixture of Germany BYK-345, BYK-346 1:1 in mass ratio composition；
The wetting agent is Germany BYK 333；
The defoaming agent is the mixture of Germany BYK Bi Ke BYK-024, BYK-025 1:1 in mass ratio composition；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is BASF Irgacure 184D, Irgacure TPO, Irgacure 369 press quality
Mixture is planted than 1:1:1 more；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 2:1 composition.
The present invention also provides a kind of preparation methods of above-mentioned quick-setting strippable property nail polish glue, including walk as follows
It is rapid:
1) UV solidified resin A, UV solidified resin B is weighed according to parts by weight, reactive diluent, levelling agent, wetting agent, is disappeared
Infusion, mill base, photoinitiator A and photoinitiator b；
2) wetting agent, levelling agent, defoaming agent and mill base are added in the high speed disperser of control revolving speed 300-400r/min,
Revolving speed is down to 300r/min after dispersing 15-20min under 600-800r/min revolving speed, UV solidified resin A, UV solidification tree is added
Rouge B, UV solidified resin C and photoinitiator A, photoinitiator b continue to disperse 5-10min, are uniformly mixed to get strippable property first is arrived
Factice.
The reaction equation of above-mentioned UV solidified resin A is as follows:
The present invention is due to using making it have containing several functional group propenoic acid esters in UV solidified resin A molecular structure
Rapid capability at 385nmUV-LED, lamp source irradiation.It is shone after the resulting strippable property nail polish glue film of the present invention through UV nail polish lamp
The surface for penetrating the glass slide of precoating strippable property nail polish glue, according to fingers-touch method (the strippable property first for the cured a period of time that press...withes one's finger
The surface of factice, using tack-free as the standard being fully cured, the shortest time used when being fully cured with strippable property nail polish glue
To characterize), through detecting, the curing time of quick-drying strippable property nail polish glue of the invention is 1-7s.Conduct of the invention mainly forms a film
The UV solidified resin A molecular structure of substance is organosilicon structures, with very low surface energy, reduces the phase between film and substrate
Interaction is allowed to embody preferable rippability, and peel strength newly thinks carefully the CMT5104 electronics pull test of company using Shenzhen
Machine presses the peel test that GB/T2790-1995 standard " 180 ° of peeling strength test methods of adhesive " carry out 180 ° at room temperature,
Tensile speed 50mm/min；Measuring peel strength is 0.21~0.25kN/m；The chameleon pigment that the present invention adds is to strippable property
Nail polish glue brings ever-changing color, and addition has toughening effect UV solidified resin C, strippable property nail polish glue is made to have one
Fixed toughness.
The present invention is compared with prior art, and technological progress is significant.A kind of strippable property nail polish glue of the invention exists
Quick setting capabilities under the irradiation of 385nmUV-LED lamp source have the characteristics that covering with paint is convenient and efficient, color is bright changeable, simultaneously
There is good peelable effect with high glaze, without adding remover.Toughness with higher after its film is cured, preferably
Strippable property the features such as.And preparation method is due to simple process, it is easy to control, thus have technology maturation, quickly, the spies such as efficiently
The technical fields such as the manicure of various people can be widely used in point, be suitable for industrialized production.
Specific embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment and the information of manufacturer used in the present invention are as follows:
GFJ-0.4 type high speed disperser, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of strippable property nail polish glue, in parts by weight, raw material composition and content are as follows:
Wherein in parts by weight, composition and content are as follows by the UV solidified resin A:
The UV solidified resin A is prepared as follows:
Above-mentioned 20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of pentaerythritol tetraacrylates are added to three mouthfuls of burnings of 500ml
In bottle, 0.005 part of polymerization inhibitor is added, protective gas is passed through, stirs and heats, be warming up to 60 DEG C, catalyst, stirring is added
Lower constant temperature 3h stops heating, drops to room temperature to flask temperature to get UV solidified resin A.
The reactive diluent is tetrahydrofuran acrylate, pentaerythritol tetraacrylate, (2) ethoxylated bisphenol A
The mixture of dimethylacrylate, the composition of 1:1:1 in mass ratio；
The levelling agent is Digao Tego Glide 410；
The wetting agent is the NP-100 of Dow company；
The defoaming agent is Germany BYK-035, BYK-037 mixture of 1:1 in mass ratio；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is that BASF Irgacure1173, Irgacure 184D, Irgacure TPO press quality
Than
The mixture of 1:1:1 composition；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 1:1 composition；
A kind of preparation method of above-mentioned strippable property nail polish glue, specifically comprises the following steps:
(1), the preparation of strippable property nail polish glue
According to formula, in the GFJ-0.4 type high speed disperser for controlling revolving speed 300r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent of middle addition, 0.05 part of levelling agent, 0.2 part of defoaming agent and 1 part of mill base, through dispersing under 600r/min revolving speed
Revolving speed is down to 300r/min after 15min, be added 50 parts of UV solidified resin A, 50 parts of UV solidified resin B, 50 portions of reactive diluents,
3 parts of photoinitiator A and 3 parts of photoinitiator bs continue to disperse 10min, are uniformly mixed to get strippable property nail polish glue is arrived.
The UV-LED light irradiation through 385nm precoats strippable property nail polish glue after the resulting strippable property nail polish glue film of the present invention
The surface of glass slide, according to the fingers-touch method (surface of the strippable property nail polish glue for the cured a period of time that press...withes one's finger, with tack-free work
For the standard being fully cured, the shortest time used is characterized when being fully cured with strippable property nail polish glue), through detecting, the present invention
Quick-drying strippable property nail polish glue curing time be 1s.
Further, a kind of strippable property nail polish glue of the invention, the UV solidified resin A molecular structure as main film forming substance
The interaction between film and substrate is reduced with very low surface energy for organosilicon structures, is allowed to embody preferably peelable
From property, peel strength newly thinks carefully the CMT5104 electronic tension tester of company at room temperature by GB/T2790-1995 using Shenzhen
Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, tensile speed 50mm/min；Measure removing
Intensity is 0.25kN/m；Therefore, higher curing rate after the resulting strippable property nail polish glue film of the present invention, it is easily peelable.
Embodiment 2
A kind of strippable property nail polish glue, in parts by weight, raw material composition and content are as follows:
Wherein in parts by weight, composition and content are as follows by the UV solidified resin A:
The UV solidified resin A is prepared as follows:
Above-mentioned 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of pentaerythritol tetraacrylates are added to three mouthfuls of burnings of 500ml
In bottle, 0.01 part of polymerization inhibitor is added, protective gas is passed through, stirs and heats, is warming up to 80 DEG C, 0.05 part of catalysis is added
Agent stirs lower constant temperature 5h, stops heating, drop to room temperature to flask temperature to get UV solidified resin A.
The reactive diluent is tetrahydrofuran acrylate, pentaerythritol tetraacrylate, (2) ethoxylated bisphenol A
The mixture of dimethylacrylate, the composition of 2:1:1 in mass ratio；
The levelling agent is the mixture of Germany BYK-345, BYK-346 1:1 in mass ratio composition；
The wetting agent is Germany BYK 333；
The defoaming agent is the mixture of Germany BYK Bi Ke BYK-024, BYK-025 1:1 in mass ratio composition；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is BASF Irgacure 184D, Irgacure TPO, Irgacure 369, presses quality
Mixture is planted than 1:1:1 more；
The photoinitiator b is BASF BASF photoinitiator Irgacure 2959, IRGACURE500, in mass ratio
The mixture of 2:1 composition；
A kind of preparation method of above-mentioned strippable property nail polish glue, specifically comprises the following steps:
According to formula, in the GFJ-0.4 type high speed disperser for controlling revolving speed 400r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 10 parts of wetting agents of middle addition, 0.1 part of levelling agent, 1 part of defoaming agent and 10 parts of mill bases, through dispersing under 800r/min revolving speed
Revolving speed is down to 300r/min after 20min, be added 80 parts of UV solidified resin A, 80 parts of UV solidified resin B, 80 portions of reactive diluents,
5 parts of photoinitiator A and 5 parts of photoinitiator bs continue to disperse 10min, are uniformly mixed to get strippable property nail polish glue is arrived.
The UV-LED light irradiation through 385nm precoats strippable property nail polish glue after the resulting strippable property nail polish glue film of the present invention
The surface of glass slide, according to the fingers-touch method (surface of the strippable property nail polish glue for the cured a period of time that press...withes one's finger, with tack-free work
For the standard being fully cured, the shortest time used is characterized when being fully cured with strippable property nail polish glue), through detecting, the present invention
Quick-drying strippable property nail polish glue curing time be 7s.
Peel strength newly thinks carefully the CMT5104 electronic tension tester of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.21kN/m；Therefore, higher curing rate after the resulting strippable property nail polish glue film of the present invention, it is easy-peel
From.
In conclusion strippable property nail polish glue of the invention, using UV curing formula, the high speed curable of UV improves it
Curing rate, only 1~7s；Addition has toughening effect UV solidified resin C, and strippable property nail polish glue is made to have centainly tough
Property.UV solidified resin A molecular structure as main film forming substance is organosilicon structures, with very low surface energy, is reduced
Interaction between film and substrate is allowed to embody preferable rippability, and peel strength is 0.21~0.25kN/m.
The content is only the basic explanation under present inventive concept, and any etc. made by technical solution according to the present invention
Effect transformation, is within the scope of protection of the invention.
Claims (5)
1. a kind of quick-setting strippable property nail polish glue, it is characterised in that in parts by weight, raw material composition and content are such as
Under:
Wherein, the chemical structure of the UV solidified resin A is as follows:
Wherein: m is the integer within the scope of 1-30；N is the integer within the scope of 1-30；
The UV solidified resin A's the preparation method is as follows:
1) following each component is weighed in parts by weight:
2) above-mentioned resulting methyl and phenyl hydrogen-containing silicon oil and pentaerythritol tetraacrylate are added in a reaction vessel, then
Polymerization inhibitor is added, is passed through protective gas, stirs and heat, is warming up to 60~80 DEG C, catalyst is added, stirs lower 3~5h of constant temperature,
Stop heating, drops to room temperature to temperature to get UV solidified resin A；
The UV solidified resin B is hyperbranched UV solidified resin；
The reactive diluent is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran acrylic acid
Ester, pentaerythritol tetraacrylate, ethoxylated bisphenol A dimethylacrylate, two-trimethylolpropane tetra-acrylates, three
(2- ethoxy) isocyanuric acid triacrylate, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin pentaerythrite 4 third
Olefin(e) acid ester, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, the third oxidation neopentylglycol diacrylate, ethoxy
Change trimethylolpropane trimethacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, miaow
Oxazolyl mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylate or vinyl ethers
Any one in monomer or two or more mixtures；
The levelling agent be Digao Tego Glide 410, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344,
Any one in BYK-345, BYK-346, BYK-347 or BYK-348 or two or more mixtures；
The wetting agent is the mixing of one or both of NP-100 or Germany's 333 levelling agent of BYK of Dow company
Object；
The defoaming agent is Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-044 or BYK-
Any one in 038 or two or more mixtures；
The photoinitiator A is BASF Irgacure1173, Irgacure 184D, Irgacure TPO, Irgacure
369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular photoinitiator
Any one in Esacure KIP 150 or two or more mixtures；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 or
Any one in IRGACURE819 DW or two or more mixtures.
2. a kind of quick-setting strippable property nail polish glue as described in claim 1, it is characterised in that: the mill base is one kind
The temperature sensing color changing mill base of changeable colour.
3. a kind of quick-setting strippable property nail polish glue as described in claim 1, it is characterised in that in parts by weight,
Raw material composition and content are as follows:
Wherein, the UV solidified resin A's the preparation method comprises the following steps:
20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of pentaerythritol tetraacrylates are added in a reaction vessel, are added
0.005 part of polymerization inhibitor, is passed through protective gas, stirs and heats, and is warming up to 60 DEG C, and catalyst is added, and stirs lower constant temperature 3h, stops
It only heats, drops to room temperature to temperature to get UV solidified resin A；
The reactive diluent is tetrahydrofuran acrylate, pentaerythritol tetraacrylate and ethoxylated bisphenol A dimethyl
The mixture of acrylate 1:1:1 in mass ratio composition；
The levelling agent is Digao Tego Glide 410；
The wetting agent is the NP-100 of Dow company；
The defoaming agent is Germany BYK-035, BYK-037 mixture of 1:1 in mass ratio；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is BASF Irgacure1173, Irgacure 184D, Irgacure TPO in mass ratio 1:
The mixture of 1:1 composition；
The photoinitiator b is BASF BASF photoinitiator Irgacure 2959, IRGACURE500 1:1 group in mass ratio
At mixture.
4. a kind of quick-setting strippable property nail polish glue as described in claim 1, it is characterised in that in parts by weight,
Raw material composition and content are as follows:
Wherein the UV solidified resin A's the preparation method is as follows:
60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of pentaerythritol tetraacrylates are added in a reaction vessel, are added
0.01 part of polymerization inhibitor, is passed through protective gas, stirs and heats, and is warming up to 80 DEG C, and 0.05 part of catalyst is added, and stirs lower constant temperature
5h stops heating, drops to room temperature to temperature to get UV solidified resin A；
The reactive diluent is tetrahydrofuran acrylate, pentaerythritol tetraacrylate and ethoxylated bisphenol A dimethyl
The mixture of acrylate 2:1:1 in mass ratio composition；
The levelling agent is the mixture of Germany BYK-345, BYK-346 1:1 in mass ratio composition；
The wetting agent is Germany BYK 333；
The defoaming agent is the mixture of Germany BYK Bi Ke BYK-024, BYK-025 1:1 in mass ratio composition；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is BASF Irgacure 184D, Irgacure TPO, Irgacure 369 in mass ratio 1:
More kinds of mixtures of 1:1；
The photoinitiator b is BASF BASF photoinitiator Irgacure 2959, IRGACURE500 2:1 group in mass ratio
At mixture.
5. a kind of preparation method of quick-setting strippable property nail polish glue described in claim 1, it is characterised in that including as follows
Step:
1) UV solidified resin A, UV solidified resin B, reactive diluent, levelling agent, wetting agent, defoaming are weighed according to parts by weight
Agent, mill base, photoinitiator A and photoinitiator b；
2) wetting agent, levelling agent, defoaming agent and mill base, warp are added in the high speed disperser of control revolving speed 300-400r/min
Disperse after 15-20min revolving speed being down to 300r/min under 600-800r/min revolving speed, UV solidified resin A, UV solidified resin is added
B, reactive diluent and photoinitiator A, photoinitiator b continue to disperse 5-10min, are uniformly mixed to get strippable property nail polish is arrived
Glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610099216.7A CN105748317B (en) | 2016-02-23 | 2016-02-23 | Quick-setting strippable property nail polish glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610099216.7A CN105748317B (en) | 2016-02-23 | 2016-02-23 | Quick-setting strippable property nail polish glue and preparation method thereof |
Publications (2)
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| CN107281010A (en) * | 2017-06-23 | 2017-10-24 | 梁萍 | A kind of nail polish glue containing plants essential oil and preparation method thereof |
| CN112168742A (en) * | 2020-10-21 | 2021-01-05 | 广东蓝天优创美化妆品有限公司 | Nail polish gel meeting European Union personal use standard |
| CN113244128A (en) * | 2021-05-13 | 2021-08-13 | 广东蓝天优创美化妆品有限公司 | Odor-free and ultralow-VOC-emission nail polish gel and preparation method thereof |
| CN114903816A (en) * | 2022-06-06 | 2022-08-16 | 东莞市百拓实业有限公司 | Nail polish gel and preparation method thereof |
| CN115192477A (en) * | 2022-08-10 | 2022-10-18 | 上海春之葆生物科技有限公司 | UV (ultraviolet) moisture dual-curing nail polish gel and preparation method thereof |
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| JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
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