CN105496817B - A kind of peelable nail polish glue and its synthesis technology - Google Patents
A kind of peelable nail polish glue and its synthesis technology Download PDFInfo
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- CN105496817B CN105496817B CN201610038537.6A CN201610038537A CN105496817B CN 105496817 B CN105496817 B CN 105496817B CN 201610038537 A CN201610038537 A CN 201610038537A CN 105496817 B CN105496817 B CN 105496817B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/893—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
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Abstract
The invention discloses a kind of peelable nail polish glue and its synthesis technologies.Peelable nail polish glue of the invention, in parts by weight, it is made of UV solidified resin C, 0.05-0.1 part levelling agent, 1-10 parts of wetting agent, 0.2-1 parts of defoaming agent, 1-10 parts of mill bases and 3-5 parts of A and 3-5 parts of photoinitiator of the photoinitiator b of UV solidified resin B, 50-80 part of 50-80 parts of UV solidified resin A, 50-80 part.There are after 365nmUV-LED light irradiation quick setting capabilities after peelable nail polish glue film of the invention, the technical fields such as the manicure of various people can be widely used.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of peelable nail polish glue and its synthesis technology, it should
Peelable nail polish glue is irradiated especially suitable for 365nm UV-LED light source to be solidified.
Background technique
Ms likes having deep love for derived from one kind to manicure.Nail polish glue using when with tool be applied to nail, by common UV light
Crosslink polymerization reaction after the light source treatment with irradiation of source, the nail polish adhesive curing object of generation is beautiful in colour, glittering and translucent full, change
It is infinite, it is the favorite of ladies.Compared with common UV light source curing mode, UV-LED light source is high with luminous efficiency, the service life is long,
Many advantages, such as reaction speed is fast, heat release is few, energy-saving and environmental protection has gradually substituted common UV light source.With enriching for city life
With the quickening of rhythm of life transformation, ladies have liked the nail of allegro transformation oneself.Peelable nail polish glue is easy to use,
Do not have to whole of cleaner energy when needing to remove to peel off, easily, is particularly suitable for child and uses.But current peelable nail polish glue
Generally aqueous, the transparent water that need to arrange in pairs or groups or sealing water use；It is not so good as oiliness nail polish glue in persistence, drying is slower, and can
Stripping nail polish glue is generally added to peelable component in the formula of nail polish glue, makes troubles to the production and use of nail polish glue.
Summary of the invention
For overcome the deficiencies in the prior art, one of the object of the invention provides a kind of energy rapid curing, while having bloom
Damp, color changeable effect peelable nail polish glue.The two of the object of the invention provide a kind of above-mentioned synthesis technology of peelable nail polish glue.
Technical solution of the present invention is specifically described as follows.
The present invention provides a kind of peelable nail polish glue, and in parts by weight, raw material composition and content are as follows:
Wherein: the chemical structure of the UV solidified resin A is as follows:
Wherein: m is the integer within the scope of 1-30；N is the integer within the scope of 1-30；
The UV solidified resin B is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran
Acrylate, pentaerythritol tetraacrylate, ethoxylated bisphenol A dimethylacrylate, two-trimethylolpropane tetras acid
Ester, three (2- ethoxy) isocyanuric acid triacrylates, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris propylene
Acid esters, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin pentaerythritol tetraacrylate, isobornyl acrylate, three
Cyclodecane Dimethanol Diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane trimethacrylate,
Hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester list
One or more of acrylate, epoxy silicone monomer, silicone acrylate and vinyl ethers monomer；
The UV solidified resin C is toughened resin.
In the present invention, the levelling agent be selected from Digao Tego Glide 410, Germany BYK Bi Ke BYK-UV3510,
One or more of BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348.
In the present invention, the wetting agent is in the NP-100 or Germany's 333 levelling agent of BYK of Dow company
It is one or two kinds of.
In the present invention, the UV mill base be selected from mill base indigo plant F4049, purple F612, red F3087, red F3095, orange F8010 or
One or more of yellow F512.
In the present invention, the defoaming agent be selected from Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037,
One or more of BYK-038, BYK-044 or BYK-038.
In the present invention, the photoinitiator A is selected from BASF Irgacure1173, Irgacure 184D, Irgacure
TPO, Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular
One or more of photoinitiator Esacure KIP 150；The photoinitiator b is BASF BASF photoinitiator
It is one or more of in Irgacure 2959, IRGACURE500 or IRGACURE819DW.
In the present invention, in parts by weight, raw material composition and content are as follows by the UV solidified resin A:
The UV solidified resin A is prepared as follows:
Methyl and phenyl hydrogen-containing silicon oil and propoxylation trimethylolpropane trimethacrylate are proportionally added into reaction to hold
In device, polymerization inhibitor is added, is passed through protective gas, stir and is heated, is warming up to 60~80 DEG C, catalyst is added, stirs lower perseverance
3~5h of temperature stops heating, drops to room temperature to temperature to get UV solidified resin A.
The present invention also provides a kind of synthesis technologies of peelable nail polish glue, the specific steps are as follows:
According to formula, wetting agent, levelling agent, defoaming agent are added in the high speed disperser of control revolving speed 300-400r/min
With mill base, revolving speed is down to 300r/min after dispersing 15-20min under 600-800r/min revolving speed, be added UV solidified resin A,
UV solidified resin B, UV solidified resin C and photoinitiator A, photoinitiator b continue to disperse 5-10min, be uniformly mixed to get arriving
Peelable nail polish glue.
Beneficial achievement of the invention is as follows:
A kind of peelable nail polish glue of the invention, due to use multi-functional acrylate UV solidified resin A and
Hyperbranched UV solidified resin B with dissaving structure makes it have the rapid capability under the irradiation of 365nmUV-LED lamp source.
Further, peelable nail polish glue is precoated through UV nail polish light irradiation after the resulting peelable nail polish glue film of the present invention
The surface of glass slide, according to the fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, with tack-free work
For the standard being fully cured, the shortest time used is characterized when being fully cured with peelable nail polish glue), through detecting, the present invention
The peelable nail polish glue of quick-drying curing time be 2-30s.
Further, a kind of peelable nail polish glue of the invention, the UV solidified resin A molecular structure as main film forming substance
The interaction between film and substrate is reduced with very low surface energy for organosilicon structures, is allowed to embody preferably peelable
From property, peel strength newly thinks carefully the CMT5104 electronic tension tester of company at room temperature by GB/T2790-1995 using Shenzhen
Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, tensile speed 50mm/min；Measure removing
Intensity is 0.21~0.25kN/m；
Further, the UV mill base of the resulting peelable nail polish glue addition of the present invention brings thousand changes ten thousand to peelable nail polish glue
The color of change, addition have toughening effect UV solidified resin C, peelable nail polish glue are made to have certain toughness.
In conclusion a kind of peelable nail polish glue of the invention, has quick solid under the irradiation of 365nmUV-LED lamp source
Change ability, the toughness with higher, easily peelable after film.And preparation method is due to simple process, it is easy to control, therefore have
There is the features such as technology maturation, quick, efficient, and is suitable for industrialized production.
Specific embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment and the information of manufacturer used in the present invention are as follows:
GFJ-0.4 type high speed disperser, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of peelable nail polish glue, in parts by weight, raw material composition and content are as follows:
Wherein: in parts by weight, composition and content are as follows by the UV solidified resin A:
The UV solidified resin A is prepared as follows: by 20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of propoxylations
Trimethylolpropane trimethacrylate is added in the three-necked flask of 500ml, adds 0.005 part of polymerization inhibitor para hydroxybenzene first
Ether is passed through protective gas, stirs and heats, and is warming up to 60 DEG C, and 0.03 part of catalyst chloroplatinic acid/aqueous isopropanol is added, stirring
Lower constant temperature 3h stops heating, drops to room temperature to flask temperature to get UV solidified resin A.
The UV solidified resin B is double pentaerythritol methacrylate, isobornyl acrylate, Tricyclodecane Dimethanol
The mixture of the acrylate monomers such as diacrylate, hyperbranched polyester acrylic ester 1:1:1:1 in mass ratio composition；
The levelling agent is Digao Tego Glide 410；
The wetting agent is the NP-100 of Dow company；
The defoaming agent is Germany BYK-035, BYK-037 mixture of 1:1 in mass ratio；
The UV mill base is mill base royal purple F612；
The photoinitiator A is that BASF Irgacure1173, Irgacure 184D, Irgacure TPO press quality
Than the mixture of 1:1:1 composition；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 1:1 composition；
In the present embodiment, a kind of synthesis technology of peelable nail polish glue, the specific steps are as follows:
According to formula, in the GFJ-0.4 type high speed disperser for controlling revolving speed 300r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent of middle addition, 0.05 part of levelling agent, 0.2 part of defoaming agent and 1 part of mill base, through dispersing under 600r/min revolving speed
Revolving speed is down to 300r/min after 15min, 50 parts of UV solidified resin A, 50 parts of UV solidified resin B, 50 parts of UV solidified resins are added
C, 3 parts of photoinitiator A and 3 parts of photoinitiator bs continue to disperse 10min, are uniformly mixed to get peelable nail polish glue is arrived.
UV-LED light irradiation after the resulting peelable nail polish glue film of the present embodiment through 365nm precoats peelable nail polish glue
Glass slide surface, according to the fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, with tack-free
As the standard being fully cured, the shortest time used is characterized when being fully cured with peelable nail polish glue), through detecting, this hair
The curing time of the peelable nail polish glue of bright quick-drying is 2s.Color changeable effect is presented after solidification.
Peel strength newly thinks carefully the CMT5104 electronic tension tester of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.25kN/m；
Higher curing rate after the above resulting peelable nail polish glue film of the present embodiment, it is easily peelable.
Embodiment 2
A kind of peelable nail polish glue, in parts by weight, raw material composition and content are as follows:
Wherein: in parts by weight, composition and content are as follows by the UV solidified resin A:
The UV solidified resin A is prepared as follows: by 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of propoxylations
Trimethylolpropane trimethacrylate is added in the three-necked flask of 500ml, adds 0.01 part of hydroquinone of polymerization retarder, is led to
Enter protective gas, stir and heat, be warming up to 80 DEG C, 0.05 part of catalyst chloroplatinic acid/vinyl double seal head solution is added, stirs
Lower constant temperature 5h stops heating, drops to room temperature to flask temperature to get UV solidified resin A.
The UV solidified resin B is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
The mixture of olefin(e) acid ester, isobornyl acrylate 2:1:1:1 in mass ratio composition；
The levelling agent is the mixture of Germany BYK-345, BYK-346 1:1 in mass ratio composition；
The wetting agent is Germany BYK 333；
The defoaming agent is the mixture of Germany BYK Bi Ke BYK-024, BYK-025 1:1 in mass ratio composition；
The UV mill base is mill base indigo plant F4049；
The photoinitiator A is BASF Irgacure 184D, Irgacure TPO, Irgacure 369 press quality
Mixture is planted than 1:1:1 more；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 2:1 composition；
In the present embodiment, a kind of synthesis technology of peelable nail polish glue specifically comprises the following steps:
According to formula, in the GFJ-0.4 type high speed disperser for controlling revolving speed 400r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 10 parts of wetting agents of middle addition, 0.1 part of levelling agent, 1 part of defoaming agent and 10 parts of mill bases, through dispersing under 800r/min revolving speed
Revolving speed is down to 300r/min after 20min, 80 parts of UV solidified resin A, 80 parts of UV solidified resin B, 80 parts of UV solidified resins are added
C, 5 parts of photoinitiator A and 5 parts of photoinitiator bs continue to disperse 10min, are uniformly mixed to get peelable nail polish glue is arrived.
UV-LED light irradiation after the resulting peelable nail polish glue film of the present embodiment through 365nm precoats peelable nail polish glue
Glass slide surface, according to the fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, with tack-free
As the standard being fully cured, the shortest time used is characterized when being fully cured with peelable nail polish glue), through detecting, this hair
The curing time of the peelable nail polish glue of bright quick-drying is 30s.
Peel strength newly thinks carefully the CMT5104 electronic tension tester of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.21kN/m；
It is originally higher curing rate after the resulting peelable nail polish glue film of embodiment above, it is easily peelable.
In conclusion peelable nail polish glue of the invention is using UV curing formula, the high speed curable of UV improves it
Curing rate, only 2~30s；The UV mill base of the resulting peelable nail polish glue addition of the present invention is brought to peelable nail polish glue
Ever-changing color, addition have toughening effect UV solidified resin C, peelable nail polish glue are made to have certain toughness.Make
Be organosilicon structures for the UV solidified resin A molecular structure of main film forming substance, with very low surface can, reduce film with
Interaction between substrate is allowed to embody preferable rippability, and peel strength is 0.21~0.25kN/m；Without residual after removing
It stays.
Above said content is only the basic explanation under present inventive concept, and is appointed made by technical solution according to the present invention
What equivalent transformation, is within the scope of protection of the invention.
Claims (8)
1. a kind of peelable nail polish glue, which is characterized in that in parts by weight, raw material composition and content are as follows:
Wherein: the chemical structure of the UV solidified resin A is as follows:
Wherein: m is the integer within the scope of 1-30；N is the integer within the scope of 1-30；
The UV solidified resin B is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran acrylic acid
Ester, pentaerythritol tetraacrylate, ethoxylated bisphenol A dimethylacrylate, two-trimethylolpropane tetra-acrylates, three
(2- ethoxy) isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane trimethacrylate,
Third oxidation trimethylolpropane trimethacrylate, ethoxyquin pentaerythritol tetraacrylate, isobornyl acrylate, tristane
Dimethanol Diacrylate, third oxidation neopentylglycol diacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester,
Carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylic acid
One or more of ester and vinyl ethers monomer；
The UV solidified resin C is toughened resin.
2. peelable nail polish glue as described in claim 1, which is characterized in that the levelling agent is selected from Digao Tego Glide
410, Germany BYK Bi Ke BYK-UV3510, in BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348
One or more.
3. peelable nail polish glue as described in claim 1, which is characterized in that the wetting agent is Dow company
One or both of NP-100 or Germany BYK 333.
4. peelable nail polish glue as described in claim 1, which is characterized in that the UV mill base is selected from mill base indigo plant F4049, purple
One or more of F612, red F3087, red F3095, orange F8010 or Huang F512.
5. peelable nail polish glue as described in claim 1, which is characterized in that the defoaming agent is selected from Germany BYK Bi Ke
One or more of BYK-024, BYK-025, BYK-035, BYK-037, BYK-038 or BYK-044.
6. peelable nail polish glue as described in claim 1, which is characterized in that the photoinitiator A is selected from BASF
Irgacure1173、Irgacure 184D、Irgacure TPO、Irgacure 369、Irgacure 651、Irgacure
379, one or more of Irgacure819, Irgacure 907 or macromolecular photoinitiator Esacure KIP 150；Institute
The photoinitiator b stated is one in BASF BASF photoinitiator Irgacure 2959, IRGACURE500 or IRGACURE819DW
Kind is several.
7. peelable nail polish glue as described in claim 1, which is characterized in that the UV solidified resin A is according to parts by weight
It calculates, raw material composition and content are as follows:
The UV solidified resin A is prepared as follows:
Methyl and phenyl hydrogen-containing silicon oil and propoxylation trimethylolpropane trimethacrylate are proportionally added into reaction vessel,
Add polymerization inhibitor, be passed through protective gas, stir and heat, be warming up to 60~80 DEG C, catalyst is added, stir lower constant temperature 3~
5h stops heating, drops to room temperature to temperature to get UV solidified resin A.
8. a kind of synthesis technology of peelable nail polish glue as described in claim 1, which is characterized in that specific step is as follows:
Wetting agent, levelling agent, defoaming agent and mill base are added in the high speed disperser of control revolving speed 300-400r/min, through 600-
Disperse after 15-20min revolving speed being down to 300r/min under 800r/min revolving speed, UV solidified resin A, UV solidified resin B, UV is added
Solidified resin C and photoinitiator A, photoinitiator b continue to disperse 5-10min, are uniformly mixed to get peelable nail polish glue is arrived.
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| CN201610038537.6A CN105496817B (en) | 2016-01-20 | 2016-01-20 | A kind of peelable nail polish glue and its synthesis technology |
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| CN201610038537.6A CN105496817B (en) | 2016-01-20 | 2016-01-20 | A kind of peelable nail polish glue and its synthesis technology |
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| US11213475B2 (en) | 2019-03-29 | 2022-01-04 | L'oréal | Multi-layer peelable nail polish |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
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| JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
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| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
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