CN105482692B - A kind of peelable blue glue and preparation method - Google Patents
A kind of peelable blue glue and preparation method Download PDFInfo
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- CN105482692B CN105482692B CN201610038611.4A CN201610038611A CN105482692B CN 105482692 B CN105482692 B CN 105482692B CN 201610038611 A CN201610038611 A CN 201610038611A CN 105482692 B CN105482692 B CN 105482692B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D187/00—Coating compositions based on unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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Abstract
The invention discloses a kind of peelable blue glue and preparation method.The peelable blue glue of the present invention, in parts by weight, it is made up of 50 80 parts of UV solidified resins A, 50 80 parts of UV solidified resins B, 50 80 parts of UV solidified resins C, 0.05 0.1 parts of levelling agents, 1 10 parts of wetting agent, 0.2 1 parts of defoamer, 1 10 parts of mill bases and 35 parts of light trigger.There are quick setting capabilities after the irradiation of 365nmUV LEDs, the good non-scale of adhesion comes off, peeled off easily, completely, does not flow residual stain after the peelable blue glue film of the present invention；It can be applied to the insulating, the be moistureproof of materials such as PET, ITO conducting film, ito glass, mobile phone glass, strengthened glass form, anti-pollution and scratch resistant protection.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of peelable blue glue and preparation method, this can
Peel off blue glue and irradiated especially suitable for 365nm UV-LED light sources and solidified.
Background technology
In recent years, the fast development of digital product has driven the fast development of touch-screen industry.High performance touch-screen system
Standby technique needs the ink with resistance erosion function or " peelable blue gel ", " surface protective glue " of metal surface processing protection.
When manufacturing printed board, some parts will often be covered using adhesive on plate, in order to avoid poured during scolding tin by tin, such as golden hand
Finger, interface card, the plate face of carbonaceous conductive button and larger area, these are required for optionally scolding tin and multiple continuously scolding tin,
Such as SMD hybrid precast, Reflow Soldering craft and automatic and other soldering tin techniques etc..Peelable blue gel is used for reference in PCB industry printed boards
Protected mode in technique, avoid touch-screen from sustaining damage in the mill using printing peelable glue, improve production efficiency and production
Product quality.Generally, peelable glue is a kind of one pack system touch-screen special isolation protection pliability ink, and color is sticky for blueness
Shape liquid, it is more prone to peel off by the peelable gel coating after high temperature resistant, toughness can also be strengthened, and can use hand after application
Or instrument easily peels off, without having residue in material surface or contaminated materials, it is not necessary to secondary cleaning, there is attachment
Power is good, cull, endurance (acid-base property) be not excellent, smooth bright easy-peel, it is easy to operate the advantages that.It is mainly used in touch-screen thoroughly
Bright ITO electro-conductive glass, ito thin film, the insulation plated film flow of PET film, it can be dried by being screen printed onto in PET film and glass
Be roasted into after film and play a part of preventing material contaminated in process of production or scratch, on the touchscreen, lower circuit bonding before,
It can be taken off with simple and easy method, and be once stripped clean.
Current peelable blue glue typically heats more than 100 DEG C to be solidified, and solidification temperature is high, and in general is peelable
Blue glue equally there is also time length, stripping process exist it is cumbersome, have the problems such as residual.
The content of the invention
One of the object of the invention provide one kind can rapid curing, the good non-scale of adhesion come off, have peel off it is easy, complete
It is whole, the peelable blue glue of high temperature resistant of the good peeling effect such as residual stain is not flowed.
The two of the object of the invention provide a kind of above-mentioned preparation method of peelable blue glue.
Technical scheme is specifically described as follows.
A kind of peelable blue glue, in parts by weight, its raw material composition and content are as follows：
Wherein：Described UV solidified resins A chemical constitution is as follows：
Wherein：M is the integer in the range of 1-30；N is the integer in the range of 1-30；PU is aliphatic, aromatic series or alicyclic ring
Adoption urethane；
Described UV solidified resins B is hyperbranched UV solidified resins；
Described UV solidified resins C is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
Olefin(e) acid ester, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra acid
Ester, three (2- ethoxys) isocyanuric acid triacrylates, pentaerythritol triacrylate, the third oxidation trimethylolpropane tris propylene
Acid esters, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, the third oxidation
Neopentylglycol diacrylate, ethoxyquin trimethylolpropane trimethacrylate, hyperbranched polyester acrylic ester, alkoxy propylene
Acid esters, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone third
One or more in olefin(e) acid ester and vinyl ethers monomer；
Described UV mill bases are mill base indigo plant F4049；
Described light trigger A be BASF Irgacure1173, Irgacure 184D, Irgacure TPO,
Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular light
One or more in initiator Esacure KIP 150；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 or
It is one or more of in IRGACURE819DW.
In the present invention, in parts by weight, its raw material composition and content are as follows by described UV solidified resins A：
Described UV solidified resins A is prepared as follows：
The polyurethane that phenyl hydrogen-containing silicon oil and triacrylate block is proportionally added into reaction vessel, adds resistance
Poly- agent, is passed through protective gas, stirs and heats, and is warming up to 60~80 DEG C, adds catalyst, stirs 3~5h of lower constant temperature, stops adding
Heat, treat that temperature drops to room temperature, produce UV solidified resins A.
In the present invention, described levelling agent be selected from the high Tego Glide 410 of enlightening, German BYK Bi Ke BYK-UV3510,
One or more in BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348；Described UV wettings
Agent is one or both of NP-100 or German BYK 333 of LG-DOW company；Described defoamer is selected from German BYK
One or more in Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-044 or BYK-038.
The useful achievement of the present invention is as follows：
A kind of peelable blue glue of the present invention, as a result of the UV solidified resins A and tool of multi-functional acrylate
The hyperbranched UV solidified resins for having dissaving structure make it have the rapid capability under 365nmUV-LED, lamp source irradiation.
The peelable blue glue of gained of the invention, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai rotate viscous
Degree meter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of condition of room temperature
Under detected, its viscosity is 30000-40000mPa.s.
The peelable blue glue of the gained of the present invention, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, measures fineness as 4.5 μM.
Further, the load glass of peelable blue glue is precoated after the peelable blue glue film of present invention gained through UV nail polish light irradiation
The surface of piece, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as completely
The standard of solidification, when being fully cured with peelable blue glue the shortest time used characterize), after testing, quick-drying of the invention can
The hardening time for peeling off blue glue is 5-30s.
Further, addition has toughening effect UV solidified resin C, peelable blue glue is had certain toughness.
Further, a kind of peelable blue glue of the invention, the UV solidified resin A molecular structures as main film forming substance are
Organosilicon structures, there is very low surface energy, reduce the interaction between film and base material, be allowed to embody preferably from stripping
Property, be not required to add stripping auxiliary agent again, effectively overcome stripping after residual stain the problem of.Peel strength newly thinks carefully company using Shenzhen
CMT5104 electronic tension testers press GB/T2790-1995 standards " 180 ° of peeling strength test sides of adhesive at room temperature
Method " carries out 180 ° of peel test, draw speed 50mm/min；It is 0.21~0.25kN/m to measure peel strength；
In summary, a kind of peelable blue glue of the invention, there is the rapid curing under the irradiation of 365nmUV-LED lamp sources
Ability, it has higher toughness, easily peelable after film.Preparation method is easy to control because technique is simple, therefore has technology
The features such as ripe, quick, efficient, and it is suitable to industrialized production.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows：
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of peelable blue glue, in parts by weight, its raw material composition and content are as follows：
Wherein：In parts by weight, it is formed described UV solidified resins A and content is as follows：
Described UV solidified resins A is prepared as follows：20 parts of phenyl hydrogen-containing silicon oils and 10 triacrylates are blocked
Polyurethane be added in 500ml three-necked flask, add 0.005 part of hydroquinone of polymerization retarder, be passed through protective gas, stir
Mix and heat, be warming up to 60 DEG C, add 0.03 part of catalyst chloroplatinic acid/aqueous isopropanol, stir lower constant temperature 3h, stop heating,
Treat that flask temperature drops to room temperature, produce UV solidification Resin As.
Described UV solidified resins B is hyperbranched UV solidified resins；
Described UV solidified resins C is tetramethylol methane tetraacrylate, two-trimethylolpropane tetra-acrylate, three (2-
Ethoxy) isocyanuric acid triacrylate, pentaerythritol triacrylate in mass ratio 1：1：1：1：The mixture of 1 composition；
Described levelling agent is the high Tego Glide 410 of enlightening；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is German BYK-035, BYK-037 in mass ratio 1：1 mixture；
Described UV mill bases are mill base indigo plant F4049
Described light trigger A is BASF Irgacure1173, Irgacure 184D, Irgacure TPO press quality
Than 1:1:The mixture of 1 composition；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 in mass ratio
1:The mixture of 1 composition；
In the present embodiment, a kind of preparation method of peelable blue glue, specifically comprise the following steps：
According to formula, in control rotating speed 300r/min GFJ-0.4 types high speed dispersor, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent of middle addition, 0.05 part of levelling agent, 0.2 part of defoamer and 1 part of mill base, through disperseing under 600r/min rotating speeds
Rotating speed is down to 300r/min after 15min, adds 50 parts of UV solidified resins A, 50 parts of UV solidified resins B, 50 parts of UV solidified resins
C, 3 parts of light trigger A and 3 parts of photoinitiator bs, continue scattered 10min, be well mixed, that is, obtain peelable blue glue.
Peelable blue glue obtained by the present embodiment, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai are rotated
Viscosimeter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of bar of room temperature
Detected under part, its viscosity is 30000mPa.s.
Peelable blue glue obtained by the present embodiment, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, measures fineness as 4.5 μm.
The UV-LED light irradiations through 365nm precoat the load of peelable blue glue after peelable blue glue film obtained by the present embodiment
The surface of slide, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as complete
The standard of all solidstate, when being fully cured with peelable blue glue shortest time used characterize), after testing, quick-drying of the invention
The hardening time of peelable blue glue is 5s.
Further, a kind of peelable blue glue of the present embodiment, the UV solidified resin A molecular structures as main film forming substance
For organosilicon structures, there is very low surface energy, reduce the interaction between film and base material, be allowed to embody preferably peelable
From property, peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 using Shenzhen
Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, draw speed 50mm/min；Measure stripping
Intensity is 0.25kN/m；
Higher curing rate, peeling effect are good after peelable blue glue film obtained by above the present embodiment.
Embodiment 2
A kind of peelable blue glue, in parts by weight, its raw material composition and content are as follows：
Wherein：In parts by weight, it is formed described UV solidified resins A and content is as follows：
Described UV solidified resins A is prepared as follows：The poly- ammonia that phenyl hydrogen-containing silicon oil and triacrylate are blocked
Ester is added in 500ml three-necked flask according to a certain percentage, adds a certain amount of polymerization inhibitor, is passed through protective gas, stirring
And heat, 60~80 DEG C are warming up to, adds catalyst, lower 3~5h of constant temperature is stirred, stops heating, treat that flask temperature drops to room temperature,
Produce UV solidification Resin As.
Described UV solidified resins B is hyperbranched UV solidified resins；
Described UV solidified resins C is tetramethylol methane tetraacrylate, two-trimethylolpropane tetra-acrylate, three (2-
Ethoxy) isocyanuric acid triacrylate, pentaerythritol triacrylate in mass ratio 1：1：2：2：The mixture of 1 composition；
Described levelling agent is German BYK-345, BYK-346 in mass ratio 1：The mixture of 1 composition；
Described wetting agent is German BYK 333；
Described defoamer is German BYK Bi Ke BYK-024, BYK-025 in mass ratio 1:The mixture of 1 composition；
Described UV mill bases are mill base indigo plant F4049；
Described light trigger A is BASF Irgacure 184D, Irgacure TPO, Irgacure 369 press quality
Than 1:1：More than 1 kinds of mixture；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 in mass ratio
2:The mixture of 1 composition；
In the present embodiment, a kind of preparation method of peelable blue glue, specifically comprise the following steps：
According to formula, in control rotating speed 400r/min GFJ-0.4 types high speed dispersor, (the new promise instrument and equipment in Shanghai is limited
Company) 10 parts of wetting agents of middle addition, 0.1 part of levelling agent, 1 part of defoamer and 10 parts of mill bases, through disperseing under 800r/min rotating speeds
Rotating speed is down to 300r/min after 20min, adds 80 parts of UV solidified resins A, 80 parts of UV solidified resins B, 80 parts of UV solidified resins
C, 5 parts of light trigger A and 5 parts of photoinitiator bs, continue scattered 10min, be well mixed, that is, obtain peelable blue glue.
Peelable blue glue obtained by the present embodiment, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai are rotated
Viscosimeter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of bar of room temperature
Detected under part, its viscosity is 30000mPa.s.
Peelable blue glue obtained by the present embodiment, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, measures fineness as 4.5 μM.
The UV-LED light irradiations through 365nm precoat the load of peelable blue glue after peelable blue glue film obtained by the present embodiment
The surface of slide, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as complete
The standard of all solidstate, when being fully cured with peelable blue glue shortest time used characterize), after testing, quick-drying of the invention
The hardening time of peelable blue glue is 30s.Color changeable effect is presented after solidification.
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, draw speed 50mm/min；Measure
Peel strength is 0.21, kN/m；
Higher curing rate after peelable blue glue film obtained by above the present embodiment, while there is color changeable effect.
In summary, peelable blue glue of the invention improves it and consolidated using UV curing formulas, UV high speed curable
Change speed, only 5~30s；Addition has toughening effect UV solidified resin C, peelable blue glue is had certain toughness.Make
Be organosilicon structures for the UV solidified resin A molecular structures of main film forming substance, there is very low surface energy, reduce film with
Interaction between base material, it is allowed to embody preferably from fissility, is not required to add stripping auxiliary agent again, after effectively overcoming stripping
The problem of residual stain.Peel strength is 0.21~0.25kN/m；Shone after the peelable blue glue film of the high temperature resistant through 365nmUV-LED lamps
There are quick setting capabilities, the good non-scale of adhesion comes off, peeled off easily, completely, does not flow residual stain after penetrating.
The content is only the basic explanation under present inventive concept, and is made according to technical scheme any etc.
Effect conversion, all should belong to protection scope of the present invention.
Claims (4)
1. a kind of peelable blue glue, it is characterised in that in parts by weight, its raw material composition and content are as follows：
Wherein：Described UV solidified resins A chemical constitution is as follows：
Wherein：M is the integer in the range of 1-30；N is the integer in the range of 1-30；PU is aliphatic, aromatic series or alicyclic ring adoption
Urethane；
Described UV solidified resins B is hyperbranched UV solidified resins；
Described UV solidified resins C is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran acrylic acid
Ester, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra-acrylate, three
(2- ethoxys) isocyanuric acid triacrylate, pentaerythritol triacrylate, third oxidation trimethylolpropane trimethacrylate,
Ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, the third oxidation new penta 2
Alcohol diacrylate, ethoxyquin trimethylolpropane trimethacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester,
Carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylic acid
One or more in ester and vinyl ethers monomer；
Described UV mill bases are mill base indigo plant F4049；
Described light trigger A is BASF Irgacure1173, Irgacure 184D, Irgacure TPO, Irgacure
369th, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular photoinitiator
One or more in Esacure KIP 150；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 or
It is one or more of in IRGACURE819DW.
2. peelable blue glue according to claim 1, it is characterised in that the viscosity at its 25 DEG C is 30000-
40000mPa.s, hardening time 5-30s, the peel strength under draw speed 50mm/min are 0.21~0.25kN/m.
3. peelable blue glue according to claim 1, it is characterised in that described UV solidified resins A is counted in parts by weight
Calculate, its raw material composition and content are as follows：
Described UV solidified resins A is prepared as follows：
The polyurethane that phenyl hydrogen-containing silicon oil and triacrylate block is proportionally added into reaction vessel, adds inhibition
Agent, protective gas is passed through, stirs and heat, be warming up to 60~80 DEG C, add catalyst, stir 3~5h of lower constant temperature, stop adding
Heat, treat that temperature drops to room temperature, produce UV solidified resins A.
4. peelable blue glue according to claim 1, it is characterised in that described levelling agent is selected from the high Tego Glide of enlightening
410th, German BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348
In one or more；Described UV wetting agents for the NP-100 of LG-DOW company or one kind in German BYK 333 or
Two kinds；Described defoamer be selected from German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-044 or
One or more in BYK-038.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10155184A1 (en) * | 2001-11-12 | 2003-05-22 | Bayer Ag | Emulsion polymers as a peelable varnish |
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| CN103031053A (en) * | 2013-01-06 | 2013-04-10 | 北京海斯迪克新材料有限公司 | UV-cured peelable blue gel for temporary protection of touch screen and preparation method thereof |
| CN103627313A (en) * | 2013-11-29 | 2014-03-12 | 广州机械科学研究院有限公司 | Ultraviolet-cured stripping protective material and preparation method and application thereof |
| CN104745068A (en) * | 2013-12-30 | 2015-07-01 | 比亚迪股份有限公司 | Modified UV paint and preparation method thereof |
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| CN105482692A (en) | 2016-04-13 |
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