CN104213465A - UV paper varnish having separating effect and being ultra-smooth after ultraviolet light curing and preparation method thereof - Google Patents
UV paper varnish having separating effect and being ultra-smooth after ultraviolet light curing and preparation method thereof Download PDFInfo
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- CN104213465A CN104213465A CN201410371587.7A CN201410371587A CN104213465A CN 104213465 A CN104213465 A CN 104213465A CN 201410371587 A CN201410371587 A CN 201410371587A CN 104213465 A CN104213465 A CN 104213465A
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Abstract
The invention relates to the technical field of varnish and especially relates to a UV paper varnish having a separating effect and being ultra-smooth after ultraviolet light curing and a preparation method thereof. The UV paper varnish is composed of 15-30 parts of epoxy acrylic resin, 25-40 parts of modified acrylic resin, 40-50 parts of an acrylic monomer, 10-15 parts of a photoinitiator, 2-6 parts of an ultra-smooth peeling additive and 1-4 parts of an additive. The preparation method includes following steps: (a). filling a stirring pot with the acrylic monomer, a matting agent, the ultra-smooth peeling additive and the additive for performing pre-dispersion with mixing and stirring uniformly; (b). adding the epoxy acrylic resin, the modified acrylic resin, the acrylic monomer and the photoinitiator into the stirring pot with mixing and stirring uniformly to prepare an oily material; and (c) successively filtering the oily material. The UV paper varnish has a quite excellent ultra-smooth effect, is high in glossiness, is excellent in adhesive force and is high in wear resistance.
Description
Technical field
The present invention relates to gloss oil technical field, UV paper gloss oil having release effect, superslide refreshing after particularly relating to a kind of UV ultraviolet light polymerization and preparation method thereof.
Background technology
Release liners, also known as barrier paper, separate paper, is that one both can prevent pressure sensitive adhesive adhesion, can protects again the not contaminated separate paper of pressure sensitive adhesive, be widely used in the fields such as electronic product, automobile foam, packaging industry, advertisement, printing.Have a lot of release liners in the market, its preparation method majority is all obtain by the release emulsion of coated heat curing type on paper product or from dry mould release, and rate of drying is slow, has a strong impact on production efficiency.In addition, although also occurred that some with the addition of the UV paper gloss oil of the auxiliary agent that can improve slipping on the market, this analog assistant has reduced capillary poor performance, and smooth degree is low, does not have peeling effect, is attached to film coated surface with adhesive tape, does not have release effect when pulling at.Therefore, the above problems demand solves.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, and UV paper gloss oil having release effect, superslide refreshing after providing a kind of UV ultraviolet light polymerization and preparation method thereof, low, the surperficial superslide of this UV paper light oil surface tension is refreshing, release excellent.
The present invention is achieved through the following technical solutions.
Have the UV paper gloss oil that release effect, superslide are refreshing after UV ultraviolet light polymerization, it is made up of the component of following weight portion:
Epoxy acrylic resin 15-30 part
Modified acrylic resin 25-40 part
Acrylic monomer 40-50 part
Light trigger 10-15 part
Superslide is refreshing peels off auxiliary agent 2-6 part
Auxiliary agent 1-4 part.
Preferably, have the UV paper gloss oil that release effect, superslide are refreshing after a kind of UV ultraviolet light polymerization, it is made up of the component of following weight portion:
Epoxy acrylic resin 20-25 part
Modified acrylic resin 30-35 part
Acrylic monomer 42-48 part
Light trigger 12-14 part
Superslide is refreshing peels off auxiliary agent 3-5 part
Auxiliary agent 2-3 part.
More preferred, have the UV paper gloss oil that release effect, superslide are refreshing after a kind of UV ultraviolet light polymerization, it is made up of the component of following weight portion:
Epoxy acrylic resin 22 parts
Modified acrylic resin 32 parts
Acrylic monomer 45 parts
Light trigger 13 parts
Superslide is refreshing peels off auxiliary agent 4 parts
Auxiliary agent 2.5 parts.
Wherein, described superslide is felt well and peeled off auxiliary agent is silicone oil and the antiseized slip aid mixture in the ratio mixing composition of 1-2:3-5, the antiseized slip aid of antiseized slip aid to be the model of Di Gao company be TEGO Rad 2700.The chemical composition of the antiseized slip aid of TEGO Rad 2700 is response type silicone acrylates, it has extraordinary slipping, anti-stick company/peeling effect and good deaeration, make the refreshing auxiliary agent of peeling off of superslide strongly can reduce UV light oil surface tension, surperficial superslide is felt well, stick on film after hardening with adhesive tape, can remove easily, make the UV gloss oil obtained have good release effect.
Wherein, the bisphenol-A epoxy acrylic resin of epoxy acrylic resin to be the model of Dongguan Hongshi Function Materials Co., Ltd. be OG4705K3, it is as main body film forming matter, substantially increases ABRASION RESISTANCE and the glossiness of the film body that UV paper gloss oil that superslide feels well is formed after ultraviolet light polymerization; Acrylic resin modified is modified polyurethane acrylic resin, and it is as film forming matter, substantially increases adhesive force and the pliability of the film body that UV paper gloss oil that superslide feels well is formed after ultraviolet light polymerization.
Wherein, described acrylic monomer is 1, any one in 6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane triacrylate, or be 1, the mixture of any two kinds of ratios in the 1-3:2-4 mixing composition in 6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane triacrylate, or be 1,6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane triacrylate three in 3-5:2-4:1-3 ratio mixing composition mixture.The adjustable system viscosity of acrylic monomer, improves laser curing velocity.
Wherein, described light trigger is the mixture of any one or a few and tertiary amine aided initiating in benzophenone, 2-hydroxy-2-methyl-1-phenylacetone, 1-hydroxy cyclohexyl phenylketone or 2,4,6-trimethylbenzoy-dipheny phosphine oxide.The ultraviolet of light trigger Absorbable rod high-voltage mercury lamp radiation forms free radical or CATION, there is polymerization and cross-linking reaction in initiation acrylic monomer and acrylic resin, the high molecular polymer of tridimensional network is solidify to form in the very short time, this polymer becomes to be coated with membranaceous with the organic matting agent polymer inside gloss oil, is attached to paper surface, the refreshing UV paper gloss oil of this superslide be coated on paper has well impermeable, glossiness is high, richness is good, and adhesive force is fine, practical.
Benzophenone belongs to hydrogen-capture-type light initiator, after hydrogen-capture-type light initiator molecule absorption luminous energy, jump to excited triplet state through exciting and altering between being, with the tertiary amine aided initiating generation bimolecular effect as hydrogen donor, produce living radical through electro transfer, and then cause oligomer or reactive diluent cross-linked polymeric.Tertiary amine aided initiating compatibility is good, and active high, xanthochromia is low, and smell is low, and excitant is little, and efficiency is high, and can not move.
Wherein, described auxiliary agent is levelling agent and defoamer, and defoamer is the silicone defoaming agent of Bi Ke company or Di Gao company, and levelling agent is the organosilicon levelling agent of Di Gao company.
Have release effect after above-mentioned UV ultraviolet light polymerization, the preparation method of UV paper gloss oil that superslide is felt well, it comprises following preparation process:
A, acrylic monomer is divided into two parts, a part of acrylic monomer, delustering agent are added by weight carry out in agitated kettle pre-dispersed, mixing and stirring;
B, again continuation add epoxy acrylic resin, modified acrylic resin, another part acrylic monomer, light trigger and auxiliary agent by weight, mixing and stirring in agitated kettle, obtained oil plant;
C, oil plant 320 object filter bags to be filtered, the UV paper gloss oil namely having release effect, superslide refreshing after obtained UV ultraviolet light polymerization.
Wherein, in step a, the rotating speed of stirring is 700-900r/min, and the time of stirring is 25-35min; In step b, the rotating speed of stirring is 900-1100r/min, and the time of stirring is 80-100min.
Beneficial effect of the present invention is: have release effect after UV ultraviolet light polymerization of the present invention, the UV paper gloss oil that superslide is felt well is a kind of roller coat printing UV oil polish, high molecular polymer is formed mainly through absorbing the reaction of ultraviolet light generation polymerization crosslinking, and by adding, the superslide can participating in UV cross-linking reaction is refreshing peels off auxiliary agent, the mixture of to be silicone oil and the model of Di Gao company can participating in UV cross-linking reaction the be antiseized slip aid of TEGO Rad 2700 that this superslide is felt well and peeled off auxiliary agent, reduction UV light oil surface tension that can be strong, surperficial superslide is felt well, stick on film after hardening with adhesive tape, can remove easily, the UV gloss oil obtained is made to have good release effect, and feel well and peel off auxiliary agent by adding distinctive modified urethane acrylate and superslide and arrange in pairs or groups, reach good release effect and higher adhesive force further, there is good superslide may just as well, glossiness is high, richness is good, explosion-proof is good, adhesive force is good, the advantages such as high-wearing feature, in addition, owing to using the speed of printing machine coating UV paper gloss oil fast, therefore UV paper gloss oil of the present invention replaces the release emulsion of the heat cure adopted on the market, can increase substantially production efficiency, use manpower and material resources sparingly, also save production cost simultaneously.
Preparation method of the present invention is simple, and production efficiency is high, is suitable for large-scale production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
embodiment 1.
Have release effect after the UV ultraviolet light polymerization of the present embodiment, the preparation method of UV paper gloss oil that superslide is felt well, it comprises following preparation process:
A, by 30 part 1,6 hexanediyl esters, 2 parts of silicone oil, 4 parts of antiseized slip aid of TEGO Rad 2700 add carry out in agitated kettle pre-dispersed, mixing and stirring, the rotating speed of stirring is 700r/min, and the time of stirring is 35min;
B, again continuation add 15 parts of bisphenol-A epoxy acrylic resins, 25 parts of modified polyurethane acrylic resins, 20 parts of tripropylene glycol diacrylates, 3 parts of benzophenone, 4 parts of tertiary amine aided initiatings, 4 parts of 2-hydroxy-2-methyl-1-phenylacetones, 4 parts of 1-hydroxy cyclohexyl phenylketones, 2 parts of organosilicon levelling agents, 2 parts of silicone defoaming agents in agitated kettle, mixing and stirring, the rotating speed stirred is 1100r/min, the time of stirring is 80min, obtained oil plant;
C, oil plant 320 object filter bags to be filtered, the UV paper gloss oil namely having release effect, superslide refreshing after obtained UV ultraviolet light polymerization.
embodiment 2.
Have release effect after the UV ultraviolet light polymerization of the present embodiment, the preparation method of UV paper gloss oil that superslide is felt well, it comprises following preparation process:
A, by 16 part 1,6 hexanediyl esters, 2 parts of silicone oil, 3 parts of antiseized slip aid of TEGO Rad 2700 add carry out in agitated kettle pre-dispersed, mixing and stirring, the rotating speed of stirring is 750r/min, and the time of stirring is 32min;
B, again continue to add in agitated kettle 20 parts of bisphenol-A epoxy acrylic resins, 30 parts of modified polyurethane acrylic resins, 32 parts of tripropylene glycol diacrylates, 2 parts of benzophenone, 5 parts of tertiary amine aided initiatings, 3 parts of 2-hydroxy-2-methyl-1-phenylacetones, 4 part 2,4,6-trimethylbenzoy-dipheny phosphine oxide, 1 part of organosilicon levelling agent, 2 parts of silicone defoaming agents, mixing and stirring, the rotating speed stirred is 1050r/min, the time of stirring is 85min, obtained oil plant;
C, oil plant 320 object filter bags to be filtered, the UV paper gloss oil namely having release effect, superslide refreshing after obtained UV ultraviolet light polymerization.
embodiment 3.
Have release effect after the UV ultraviolet light polymerization of the present embodiment, the preparation method of UV paper gloss oil that superslide is felt well, it comprises following preparation process:
A, by 18 part 1,6 hexanediyl esters, 1 part of silicone oil, 3 parts of antiseized slip aid of TEGO Rad 2700 add carry out in agitated kettle pre-dispersed, mixing and stirring, the rotating speed of stirring is 800r/min, and the time of stirring is 30min;
B, again continue to add in agitated kettle 22 parts of bisphenol-A epoxy acrylic resins, 32 parts of modified polyurethane acrylic resins, 27 parts of tripropylene glycol diacrylates, 3 parts of benzophenone, 3 parts of tertiary amine aided initiatings, 3 parts of 1-hydroxy cyclohexyl phenylketones, 4 part 2,4,6-trimethylbenzoy-dipheny phosphine oxide, 1.5 parts of organosilicon levelling agents, 1 part of silicone defoaming agent, mixing and stirring, the rotating speed stirred is 1000r/min, the time of stirring is 90min, obtained oil plant;
C, oil plant 320 object filter bags to be filtered, the UV paper gloss oil namely having release effect, superslide refreshing after obtained UV ultraviolet light polymerization.
embodiment 4.
Have release effect after the UV ultraviolet light polymerization of the present embodiment, the preparation method of UV paper gloss oil that superslide is felt well, it comprises following preparation process:
A, by 21 part 1,6 hexanediyl esters, 14 parts of tripropylene glycol diacrylates, 0.5 part of silicone oil, 2.5 parts of antiseized slip aid of TEGO Rad 2700 add carry out in agitated kettle pre-dispersed, mixing and stirring, the rotating speed of stirring is 850r/min, and the time of stirring is 28min;
B, again continue to add in agitated kettle 25 parts of bisphenol-A epoxy acrylic resins, 35 parts of modified polyurethane acrylic resins, 7 parts of trimethylolpropane triacrylates, 2 parts of benzophenone, 3 parts of 2-hydroxy-2-methyl-1-phenylacetones, 2 parts of 1-hydroxy cyclohexyl phenylketones, 5 part 2,4,6-trimethylbenzoy-dipheny phosphine oxide, 1 part of organosilicon levelling agent, 1 part of silicone defoaming agent, mixing and stirring, the rotating speed stirred is 950r/min, the time of stirring is 95min, obtained oil plant;
C, oil plant 320 object filter bags to be filtered, the UV paper gloss oil namely having release effect, superslide refreshing after obtained UV ultraviolet light polymerization.
embodiment 5.
Have release effect after the UV ultraviolet light polymerization of the present embodiment, the preparation method of UV paper gloss oil that superslide is felt well, it comprises following preparation process:
A, by 20 part 1,6 hexanediyl esters, 10 parts of trimethylolpropane triacrylates, 0.5 part of silicone oil, 1.5 parts of antiseized slip aid of TEGO Rad 2700 add carry out in agitated kettle pre-dispersed, mixing and stirring, the rotating speed of stirring is 900r/min, and the time of stirring is 25min;
B, again continue to add in agitated kettle 30 parts of bisphenol-A epoxy acrylic resins, 40 parts of modified polyurethane acrylic resins, 10 parts of tripropylene glycol diacrylates, 2 part 2,4,6-trimethylbenzoy-dipheny phosphine oxide, 3 parts of tertiary amine aided initiatings, 2 parts of 2-hydroxy-2-methyl-1-phenylacetones, 3 parts of 1-hydroxy cyclohexyl phenylketones, 0.5 part of organosilicon levelling agent, 0.5 part of silicone defoaming agent, mixing and stirring, the rotating speed stirred is 900r/min, the time of stirring is 100min, obtained oil plant;
C, oil plant 320 object filter bags to be filtered, the UV paper gloss oil namely having release effect, superslide refreshing after obtained UV ultraviolet light polymerization.
There is release effect after the UV ultraviolet light polymerization that embodiments of the invention 1 ~ embodiment 5 is obtained, the performance detection data of UV paper gloss oil that superslide is felt well is in table 1.
Table 1
。
As can be seen from Table 1, the UV paper gloss oil having release effect, superslide refreshing after the UV ultraviolet light polymerization that embodiments of the invention 1 ~ embodiment 5 is obtained, the advantages such as its ABRASION RESISTANCE is good, adhesive force good, glossiness is high, curing rate is fast, product quality is good, serviceability is good, and marketing degree is high.
Finally should be noted that; above embodiment is only in order to illustrate technical scheme of the present invention; but not limiting the scope of the invention; although done to explain to the present invention with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify to technical scheme of the present invention or equivalent replacement, and not depart from essence and the scope of technical solution of the present invention.
Claims (10)
1. there is the UV paper gloss oil that release effect, superslide are refreshing after UV ultraviolet light polymerization, it is characterized in that: it is made up of the component of following weight portion:
Epoxy acrylic resin 15-30 part
Modified acrylic resin 25-40 part
Acrylic monomer 40-50 part
Light trigger 10-15 part
Superslide is refreshing peels off auxiliary agent 2-6 part
Auxiliary agent 1-4 part.
2. there is the UV paper gloss oil that release effect, superslide are refreshing after a kind of UV ultraviolet light polymerization according to claim 1, it is characterized in that: it is made up of the component of following weight portion:
Epoxy acrylic resin 20-25 part
Modified acrylic resin 30-35 part
Acrylic monomer 42-48 part
Light trigger 12-14 part
Superslide is refreshing peels off auxiliary agent 3-5 part
Auxiliary agent 2-3 part.
3. there is the UV paper gloss oil that release effect, superslide are refreshing after a kind of UV ultraviolet light polymerization according to claim 1, it is characterized in that: it is made up of the component of following weight portion:
Epoxy acrylic resin 22 parts
Modified acrylic resin 32 parts
Acrylic monomer 45 parts
Light trigger 13 parts
Superslide is refreshing peels off auxiliary agent 4 parts
Auxiliary agent 2.5 parts.
4. after a kind of UV ultraviolet light polymerization according to claim 1, there is the UV paper gloss oil that release effect, superslide are refreshing, it is characterized in that: described superslide is felt well and peeled off auxiliary agent is silicone oil and the antiseized slip aid mixture in the ratio mixing composition of 1-2:3-5, the antiseized slip aid of antiseized slip aid to be the model of Di Gao company be TEGO Rad 2700.
5. there is the UV paper gloss oil that release effect, superslide are refreshing after a kind of UV ultraviolet light polymerization according to claim 1, it is characterized in that: the bisphenol-A epoxy acrylic resin of epoxy acrylic resin to be the model of Dongguan Hongshi Function Materials Co., Ltd. be OG4705K3; Modified acrylic resin is modified polyurethane acrylic resin.
6. there is release effect after a kind of UV ultraviolet light polymerization according to claim 1, the UV paper gloss oil that superslide is refreshing, it is characterized in that: described acrylic monomer is 1, 6 hexanediyl esters, tripropylene glycol diacrylate, any one in trimethylolpropane triacrylate, or be 1, 6 hexanediyl esters, tripropylene glycol diacrylate, the mixture of any two kinds of ratios in the 1-3:2-4 mixing composition in trimethylolpropane triacrylate, or be 1, 6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane triacrylate three is in the mixture of the ratio mixing composition of 3-5:2-4:1-3.
7. after a kind of UV ultraviolet light polymerization according to claim 1, there is the UV paper gloss oil that release effect, superslide are refreshing; it is characterized in that: described light trigger is benzophenone, 2-hydroxy-2-methyl-1-phenylacetone, 1-hydroxy cyclohexyl phenylketone or 2; the mixture of any one or a few and tertiary amine aided initiating in 4,6-trimethylbenzoy-dipheny phosphine oxide.
8. after a kind of UV ultraviolet light polymerization according to claim 1, there is the UV paper gloss oil that release effect, superslide are refreshing, it is characterized in that: described auxiliary agent is levelling agent and defoamer, defoamer is the silicone defoaming agent of Bi Ke company or Di Gao company, and levelling agent is the organosilicon levelling agent of Di Gao company.
9. after a kind of UV ultraviolet light polymerization described in claim 1-8 any one, have release effect, the preparation method of UV paper gloss oil that superslide is felt well, it is characterized in that: it comprises following preparation process:
A, acrylic monomer is divided into two parts, by refreshingly to a part of acrylic monomer, superslide peeling off auxiliary agent, auxiliary agent add by weight carry out in agitated kettle pre-dispersed, mixing and stirring;
B, again continuation add epoxy acrylic resin, modified acrylic resin, another part acrylic monomer and light trigger by weight, mixing and stirring in agitated kettle, obtained oil plant;
C, oil plant filter bag to be filtered, the UV paper gloss oil namely having release effect, superslide refreshing after obtained UV ultraviolet light polymerization.
10. have release effect after a kind of UV ultraviolet light polymerization according to claim 9, the preparation method of UV paper gloss oil that superslide is felt well, it is characterized in that: in step a, the rotating speed of stirring is 700-900r/min, and the time of stirring is 25-35min; In step b, the rotating speed of stirring is 900-1100r/min, and the time of stirring is 80-100min.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877568A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet curable high-strippability anti-adhesive agent used in electronic field |
| CN105131779A (en) * | 2015-09-14 | 2015-12-09 | 上海应用技术学院 | Ultraviolet curing organic silicon release agent and preparation method thereof |
| CN110305510A (en) * | 2019-06-13 | 2019-10-08 | 广州骏捷环保科技有限公司 | A kind of method for stamping of UV gloss oil and its 3D imprinting apparatus |
| CN110330868A (en) * | 2019-07-11 | 2019-10-15 | 中体彩印务技术有限公司 | A kind of UV isolation oil and preparation method thereof suitable for instant lottery printing |
| CN110525075A (en) * | 2019-09-20 | 2019-12-03 | 湖北中烟工业有限责任公司 | A kind of process of cigarette 3D raster print product |
| CN110757973A (en) * | 2019-11-11 | 2020-02-07 | 保定永丽印务有限公司 | Kraft paper suitable for low-temperature printing and black card flat screen printing process |
| CN112552758A (en) * | 2020-12-11 | 2021-03-26 | 广东昊辉新材料有限公司 | UV-cured high-surface-tension gloss oil, and preparation method and application thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575827A (en) * | 2009-03-30 | 2009-11-11 | 上海东升新材料有限公司 | Aqueous calendering oil for glazing of calendaring technology of paper printing products |
| CN102492358A (en) * | 2011-11-14 | 2012-06-13 | 厦门市豪尔新材料有限公司 | Thermo-setting transfer mould release agent and method for preparing and using same |
| CN102964969A (en) * | 2012-11-14 | 2013-03-13 | 京东方科技集团股份有限公司 | Ultraviolet curing light oil and preparation method and curing method thereof as well as touch screen |
| CN103013295A (en) * | 2012-12-05 | 2013-04-03 | 北京化工大学常州先进材料研究院 | UV (ultraviolet) paper varnish and preparation method thereof |
| US20140171546A1 (en) * | 2012-10-31 | 2014-06-19 | Uschi M. Graham | Non-Yellowing easy-to-clean antimicrobial plastic |
-
2014
- 2014-07-31 CN CN201410371587.7A patent/CN104213465B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575827A (en) * | 2009-03-30 | 2009-11-11 | 上海东升新材料有限公司 | Aqueous calendering oil for glazing of calendaring technology of paper printing products |
| CN102492358A (en) * | 2011-11-14 | 2012-06-13 | 厦门市豪尔新材料有限公司 | Thermo-setting transfer mould release agent and method for preparing and using same |
| US20140171546A1 (en) * | 2012-10-31 | 2014-06-19 | Uschi M. Graham | Non-Yellowing easy-to-clean antimicrobial plastic |
| CN102964969A (en) * | 2012-11-14 | 2013-03-13 | 京东方科技集团股份有限公司 | Ultraviolet curing light oil and preparation method and curing method thereof as well as touch screen |
| CN103013295A (en) * | 2012-12-05 | 2013-04-03 | 北京化工大学常州先进材料研究院 | UV (ultraviolet) paper varnish and preparation method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877568A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet curable high-strippability anti-adhesive agent used in electronic field |
| CN105131779A (en) * | 2015-09-14 | 2015-12-09 | 上海应用技术学院 | Ultraviolet curing organic silicon release agent and preparation method thereof |
| CN110305510A (en) * | 2019-06-13 | 2019-10-08 | 广州骏捷环保科技有限公司 | A kind of method for stamping of UV gloss oil and its 3D imprinting apparatus |
| CN110330868A (en) * | 2019-07-11 | 2019-10-15 | 中体彩印务技术有限公司 | A kind of UV isolation oil and preparation method thereof suitable for instant lottery printing |
| CN110330868B (en) * | 2019-07-11 | 2021-03-16 | 中体彩印务技术有限公司 | UV (ultraviolet) insulating oil suitable for printing instant lottery and preparation method thereof |
| CN110525075A (en) * | 2019-09-20 | 2019-12-03 | 湖北中烟工业有限责任公司 | A kind of process of cigarette 3D raster print product |
| CN110757973A (en) * | 2019-11-11 | 2020-02-07 | 保定永丽印务有限公司 | Kraft paper suitable for low-temperature printing and black card flat screen printing process |
| CN112552758A (en) * | 2020-12-11 | 2021-03-26 | 广东昊辉新材料有限公司 | UV-cured high-surface-tension gloss oil, and preparation method and application thereof |
| CN115139674A (en) * | 2021-11-17 | 2022-10-04 | 山东泰宝防伪制品有限公司 | Bulging replacing process |
| CN115139674B (en) * | 2021-11-17 | 2024-02-23 | 山东泰宝防伪制品有限公司 | Raised substitution process |
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