CN104130675B - A kind of mute oil of scratch-resistant UV for mute film and preparation method thereof - Google Patents
A kind of mute oil of scratch-resistant UV for mute film and preparation method thereof Download PDFInfo
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- CN104130675B CN104130675B CN201410372189.7A CN201410372189A CN104130675B CN 104130675 B CN104130675 B CN 104130675B CN 201410372189 A CN201410372189 A CN 201410372189A CN 104130675 B CN104130675 B CN 104130675B
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Abstract
The present invention relates to mute oil tech field, particularly relating to a kind of mute oil of scratch-resistant UV for mute film and preparation method thereof, the mute oil of scratch-resistant UV for mute film of the present invention is made up of the epoxy acrylic resin of 5 15 parts, the modified acrylic resin of 20 35 parts, the acrylic monomer of 50 65 parts, the light trigger of 10 15 parts, the delustering agent of 5 15 parts, the auxiliary agent of 15 parts；The preparation method of the present invention is: a, acrylic monomer, delustering agent are added in agitated kettle carry out pre-dispersed, mixing and stirring；B, it is further continued in agitated kettle adding epoxy acrylic resin, modified acrylic resin, acrylic monomer, light trigger and auxiliary agent, mixing and stirring, prepares oil plant；C, carry out filtering by oil plant.The mute oil of scratch-resistant UV of the present invention is printed on mute film has preferably scratch-resistant performance, and feel degree fine and smooth, mute is low, visual effect is good, adhesive force is good, wearability is good.
Description
Technical field
The present invention relates to UV mute oil tech field, particularly relate to a kind of mute oil of scratch-resistant UV for mute film and preparation method thereof.
Background technology
Along with the development of society, nowadays people are more and more higher to the requirement of the appearance such as matte effect of paper product, and because the mute oil of UV is because of features such as its special matte effect, good, the soft handles of levelability, are widely used in all kinds of packaging producers.But; the mute oil of UV the most on the market; mostly add the flatting silica of inorganic silicon dioxide type; when this type of inorganic flatting silica particle diameter is the biggest, flatting efficiency is the best; when dried coating film, the molecule of aerosil can form slightly rough surface in film coated surface and reduce the reflection acquisition delustring outward appearance of light; this kind of inorganic flatting silica is simply filled in inside coating; do not participate in reaction; under external force; it is fairly easily scratched off; show scratch-resistant performance the best, additionally use adhesive force on mute film the best.Therefore, problems described above is urgently to be resolved hurrily.
Summary of the invention
Present invention aims to the deficiencies in the prior art, and provide a kind of mute oil of scratch-resistant UV for mute film and preparation method thereof, scratch-resistant is good, adhesive force is strong, mute degree is low, visual effect is good for this UV mute oil.
The present invention is achieved through the following technical solutions.
A kind of mute oil of scratch-resistant UV for mute film, it is made up of the component of following weight portion:
Epoxy acrylic resin
5-15 part
Modified acrylic resin
20-35 part
Acrylic monomer
50-65 part
Light trigger
10-15 part
Delustering agent
5-15 part
Auxiliary agent
1-5 part.
Preferably, a kind of mute oil of scratch-resistant UV for mute film, it is made up of the component of following weight portion:
Epoxy acrylic resin
8-12 part
Modified acrylic resin
25-30 part
Acrylic monomer
55-60 part
Light trigger
12-14 part
Delustering agent
8-12 part
Auxiliary agent
2-4 part.
Being more highly preferred to, a kind of mute oil of scratch-resistant UV for mute film, it is made up of the component of following weight portion:
Epoxy acrylic resin
10 parts
Modified acrylic resin
28 parts
Acrylic monomer
56 parts
Light trigger
13 parts
Delustering agent
10 parts
Auxiliary agent
3 parts.
Wherein, described delustering agent is the organic matting agent containing carbon-carbon double bond and active methylol.This organic matting agent is the organic polymer that model is M5 of Albemarle Corporation of the U.S., the M5 organic polymer of the refined treasured of the U.S. is a kind of fluffy powder of porous with high-specific surface area, low bulk density, it it is the granule being gathered into about 5-9um by the fundamental particle that mean diameter is 0.1-0.15um, make it have higher void content and the most uneven distribution of particles, thus it possesses the extinction effect of excellence, it has the further advantage that not thickening, the least on the viscosity of coating and mobility impact simultaneously, easily disperses；Water-based system it is also particularly well suited in addition to being suitable for solvent-based system；High (the refraction index D of transparency20=1.607) do not absorb ultraviolet, be particularly suitable for UV curing system；The soft suitable mesh of paint film, flexible, and have soft hand feel, it is suitable for the application of leatherware and internal decoration of car；To the adhesive force of paint film, pliability, scratch resistance, wear-resisting there is substantial help.The active methylol of 0.6% contained in the M5 organic polymer of the refined treasured of the U.S. can participate in crosslinking during coating resin film forming, promote that paint film shrinks to be gathered into the most concavo-convex surface and produce delustring, also strengthen hardness and the attrition resistance of paint film simultaneously, substantially increasing the scratch-resistant performance of the mute oil of UV, flatting efficiency is high.
Wherein, epoxy acrylic resin is the bisphenol-A epoxy acrylic resin that model is OG4705K3 of Dongguan Hongshi Function Materials Co., Ltd., it, as main body film forming matter, substantially increases wearability and the glossiness of the film body that the mute oil of scratch-resistant UV is formed after ultraviolet light polymerization；Acrylic resin modified for modified polyurethane acrylic resin, it, as film forming matter, substantially increases adhesive force and the pliability of the film body that the mute oil of scratch-resistant UV is formed after ultraviolet light polymerization.
Wherein, described acrylic monomer is 1, any one in 6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, or be 1, any two kinds in 6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate are mixed the mixture formed in the ratio of 1-3:2-4, or be that 1,6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate three are in the mixture of the ratio mixing composition of 2-4:1-3:1-2.Acrylic monomer scalable system viscosity, improves laser curing velocity.
Wherein, described light trigger is benzophenone, 2-hydroxy-2-methyl-1-phenylacetone, 1-hydroxy cyclohexyl phenylketone or 2, any one or a few mixture with tertiary amine aided initiating in 4,6-trimethylbenzoy-dipheny phosphine oxides.Light trigger can absorb the ultraviolet of high voltage mercury lamp radiation and forms free radical or cation, cause acrylic monomer and acrylic resin that polymerization and cross-linking reaction occur, the high molecular polymer of tridimensional network it is solidify to form in the shortest time, this polymer and the organic matting agent polymer inside gloss oil become to be coated with membranaceous, are attached to paper surface, the mute oil of this scratch-resistant UV be coated on paper have the most impermeable, glossiness is high, richness is good, and adhesive force is fine, practical.
Benzophenone belongs to hydrogen-capture-type light initiator, after hydrogen-capture-type light initiator molecule absorption luminous energy, alter between exciting and being and jump to excited triplet state, with the tertiary amine aided initiating generation bimolecular effect as hydrogen donor, produce living radical through electron transfer, and then cause oligomer or reactive diluent cross-linked polymeric.The tertiary amine aided initiating compatibility is good, and activity is high, and xanthochromia is low, and abnormal smells from the patient is low, and zest is little, and efficiency is high, and will not migrate.
Wherein, described auxiliary agent is levelling agent and defoamer, and defoamer is Bi Ke company or the organic silicon defoamer of Di Gao company, and levelling agent is the organosilicon levelling agent of Di Gao company.
The preparation method of the above-mentioned mute oil of scratch-resistant UV for mute film, it includes following preparation process:
A, acrylic monomer is divided into two parts, a part of acrylic monomer, delustering agent are added by weight agitated kettle is carried out pre-dispersed, mixing and stirring；
B, it is further continued in agitated kettle adding epoxy acrylic resin, modified acrylic resin, another part acrylic monomer, light trigger and auxiliary agent by weight, mixing and stirring, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, i.e. prepare the mute oil of scratch-resistant UV for mute film.
Wherein, in step a, the rotating speed of stirring is 700-900r/min, and the time of stirring is 25-35min；In step b, the rotating speed of stirring is 700-900r/min, and the time of stirring is 80-100min.
The invention have the benefit that the mute oil of scratch-resistant UV for mute film of the present invention is a kind of roller coat printing UV oil polish, mainly by absorbing ultraviolet light generation polymerization crosslinking reaction formation high molecular polymer, and by adding the organic matting agent that can participate in reaction, a little double bond and active methylol that this organic matting agent contains can participate in crosslinking during coating resin film forming, when ultraviolet light polymerization directly with acrylic resin together with monomer crosslinked, substantially increasing the scratch-resistant performance of the mute oil of UV, flatting efficiency is high；It addition, the present invention is by adding modified acrylic resin, substantially increase the adhesive force of the mute oil of UV.To sum up, the mute oil of scratch-resistant UV of the present invention is printed on mute film and has preferably scratch-resistant performance, the advantage such as feel degree fine and smooth, mute is low, visual effect is good, adhesive force is good, wearability is good.
The preparation method of the present invention is simple, and production efficiency is high, is suitable to large-scale production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment
1
。
The preparation method of the mute oil of scratch-resistant UV for mute film of the present embodiment, including following preparation process:
A, by 39 part 1,6 hexanediyl esters, 15 parts of organic matting agents add and carry out pre-dispersed in agitated kettles, and mixing and stirring, the rotating speed of stirring is 700r/min, and the time of stirring is 35min；
B, be further continued in agitated kettle add 5 parts of bisphenol-A epoxy acrylic resins, 35 parts of modified polyurethane acrylic resins, 26 parts of tripropylene glycol diacrylates, 3 parts of benzophenone, 4 parts of tertiary amine aided initiatings, 4 parts of 2-hydroxy-2-methyl-1-phenylacetones, 4 parts of 1-hydroxy cyclohexyl phenylketones, 2 parts of organosilicon levelling agents, 3 parts of organic silicon defoamers, mixing and stirring, the rotating speed of stirring is 900r/min, the time of stirring is 80min, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, i.e. prepare the mute oil of scratch-resistant UV for mute film.
Embodiment
2
。
The preparation method of the mute oil of scratch-resistant UV for mute film of the present embodiment, including following preparation process:
A, by 20 part 1,6 hexanediyl esters, 12 parts of organic matting agents add and carry out pre-dispersed in agitated kettles, and mixing and stirring, the rotating speed of stirring is 750r/min, and the time of stirring is 32min；
B, be further continued in agitated kettle adding 8 parts of bisphenol-A epoxy acrylic resins, 30 parts of modified polyurethane acrylic resins, 40 parts of tripropylene glycol diacrylates, 2 parts of benzophenone, 5 parts of tertiary amine aided initiatings, 3 parts of 2-hydroxy-2-methyl-1-phenylacetones, 4 part 2; 4; 6-trimethylbenzoy-dipheny phosphine oxide, 2 parts of organosilicon levelling agents, 2 parts of organic silicon defoamers; mixing and stirring; the rotating speed of stirring is 850r/min; the time of stirring is 85min, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, i.e. prepare the mute oil of scratch-resistant UV for mute film.
Embodiment
3
。
The preparation method of the mute oil of scratch-resistant UV for mute film of the present embodiment, including following preparation process:
A, by 24 part 1,6 hexanediyl esters, 10 parts of organic matting agents add and carry out pre-dispersed in agitated kettles, and mixing and stirring, the rotating speed of stirring is 800r/min, and the time of stirring is 30min；
B, be further continued in agitated kettle adding 10 parts of bisphenol-A epoxy acrylic resins, 28 parts of modified polyurethane acrylic resins, 32 parts of tripropylene glycol diacrylates, 3 parts of benzophenone, 3 parts of tertiary amine aided initiatings, 3 parts of 1-hydroxy cyclohexyl phenylketones, 4 part 2; 4; 6-trimethylbenzoy-dipheny phosphine oxide, 1 part of organosilicon levelling agent, 2 parts of organic silicon defoamers; mixing and stirring; the rotating speed of stirring is 800r/min; the time of stirring is 90min, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, i.e. prepare the mute oil of scratch-resistant UV for mute film.
Embodiment
4
。
The preparation method of the mute oil of scratch-resistant UV for mute film of the present embodiment, including following preparation process:
A, by 22 part 1,6 hexanediyl esters, 22 parts of tripropylene glycol diacrylates, 8 parts of organic matting agents add and carry out pre-dispersed in agitated kettles, and mixing and stirring, the rotating speed of stirring is 850r/min, and the time of stirring is 28min；
B, be further continued in agitated kettle adding 12 parts of bisphenol-A epoxy acrylic resins, 25 parts of modified polyurethane acrylic resins, 11 parts of trimethylolpropane trimethacrylates, 2 parts of benzophenone, 3 parts of 2-hydroxy-2-methyl-1-phenylacetones, 2 parts of 1-hydroxy cyclohexyl phenylketones, 5 part 2; 4; 6-trimethylbenzoy-dipheny phosphine oxide, 1 part of organosilicon levelling agent, 1 part of organic silicon defoamer; mixing and stirring; the rotating speed of stirring is 750r/min; the time of stirring is 95min, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, i.e. prepare the mute oil of scratch-resistant UV for mute film.
Embodiment
5
。
The preparation method of the mute oil of scratch-resistant UV for mute film of the present embodiment, including following preparation process:
A, by 30 part 1,6 hexanediyl esters, 10 parts of trimethylolpropane trimethacrylates, 5 parts of organic matting agents add and carry out pre-dispersed in agitated kettles, and mixing and stirring, the rotating speed of stirring is 900r/min, and the time of stirring is 25min；
B, be further continued in agitated kettle adding 15 parts of bisphenol-A epoxy acrylic resins, 20 parts of modified polyurethane acrylic resins, 10 parts of tripropylene glycol diacrylates, 2 part 2; 4; 6-trimethylbenzoy-dipheny phosphine oxide, 3 parts of tertiary amine aided initiatings, 2 parts of 2-hydroxy-2-methyl-1-phenylacetones, 3 parts of 1-hydroxy cyclohexyl phenylketones, 0.5 part of organosilicon levelling agent, 0.5 part of organic silicon defoamer; mixing and stirring; the rotating speed of stirring is 700r/min; the time of stirring is 100min, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, i.e. prepare the mute oil of scratch-resistant UV for mute film.
The performance detection data for the mute oil of scratch-resistant UV of mute film that embodiments of the invention 1 ~ embodiment 5 prepares is shown in Table 1.
Table 1
。
As it can be seen from table 1 the mute oil of scratch-resistant UV for mute film that embodiments of the invention 1 ~ embodiment 5 prepares, the advantages such as its wearability is good, adhesive force is strong, mute degree is low, sense of touch is fine and smooth, curing rate is fast, product quality is good, and serviceability is good, and marketing degree is high.
Finally should be noted that; above example is only in order to illustrate technical scheme; rather than limiting the scope of the invention; although having made to explain to the present invention with reference to preferred embodiment; it will be understood by those within the art that; technical scheme can be modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Claims (6)
1. the mute oil of scratch-resistant UV for mute film, it is characterised in that: it is made up of the component of following weight portion:
Epoxy acrylic resin
5-15 part
Modified acrylic resin
20-35 part
Acrylic monomer
50-65 part
Light trigger
10-15 part
Delustering agent
5-15 part
Auxiliary agent
1-5 part；
Described delustering agent is the organic matting agent containing carbon-carbon double bond and active methylol；
Epoxy acrylic resin is the bisphenol-A epoxy acrylic resin that model is OG4705K3 of Dongguan Hongshi Function Materials Co., Ltd.；Modified acrylic resin is modified polyurethane acrylic resin；
Described acrylic monomer is 1, any two kinds in 6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate are mixed the mixture formed in the ratio of 1-3:2-4, or be that 1,6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate three are in the mixture of the ratio mixing composition of 2-4:1-3:1-2；
Described auxiliary agent is levelling agent and defoamer, and defoamer is Bi Ke company or the organic silicon defoamer of Di Gao company, and levelling agent is the organosilicon levelling agent of Di Gao company.
A kind of mute oil of scratch-resistant UV for mute film the most according to claim 1, it is characterised in that: it is made up of the component of following weight portion:
Epoxy acrylic resin
8-12 part
Modified acrylic resin
25-30 part
Acrylic monomer
55-60 part
Light trigger
12-14 part
Delustering agent
8-12 part
Auxiliary agent
2-4 part.
A kind of mute oil of scratch-resistant UV for mute film the most according to claim 1, it is characterised in that: it is made up of the component of following weight portion:
Epoxy acrylic resin
10 parts
Modified acrylic resin
28 parts
Acrylic monomer
56 parts
Light trigger
13 parts
Delustering agent
10 parts
Auxiliary agent
3 parts.
A kind of mute oil of scratch-resistant UV for mute film the most according to claim 1; it is characterized in that: described light trigger is benzophenone, 2-hydroxy-2-methyl-1-phenylacetone, 1-hydroxy cyclohexyl phenylketone or 2; any one or a few mixture with tertiary amine aided initiating in 4,6-trimethylbenzoy-dipheny phosphine oxides.
5. the preparation method of a kind of mute oil of scratch-resistant UV for mute film described in claim 1-4 any one, it is characterised in that: it includes following preparation process:
A, acrylic monomer is divided into two parts, a part of acrylic monomer, delustering agent are added by weight agitated kettle is carried out pre-dispersed, mixing and stirring；
B, it is further continued in agitated kettle adding epoxy acrylic resin, modified acrylic resin, another part acrylic monomer, light trigger and auxiliary agent by weight, mixing and stirring, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, i.e. prepare the mute oil of scratch-resistant UV for mute film.
The preparation method of a kind of mute oil of scratch-resistant UV for mute film the most according to claim 5, it is characterised in that: in step a, the rotating speed of stirring is 700-900r/min, and the time of stirring is 25-35min；In step b, the rotating speed of stirring is 700-900r/min, and the time of stirring is 80-100min.
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| CN201410372189.7A CN104130675B (en) | 2014-07-31 | 2014-07-31 | A kind of mute oil of scratch-resistant UV for mute film and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104442061B (en) * | 2014-12-29 | 2017-05-10 | 东莞市卓艺印刷制品有限公司 | Transfer film with UV (ultraviolet) coating layer |
| CN105176429A (en) * | 2015-07-14 | 2015-12-23 | 潮安新纪源实业有限公司 | Anti-wear matt pre-coating film, preparation method and applications thereof |
| CN110757973A (en) * | 2019-11-11 | 2020-02-07 | 保定永丽印务有限公司 | Kraft paper suitable for low-temperature printing and black card flat screen printing process |
| CN110964250A (en) * | 2019-12-06 | 2020-04-07 | 东莞市美盈森环保科技有限公司 | Wear-resistant matte glue silk-screen UV color box powder falling prevention method |
| CN111205699A (en) * | 2020-02-28 | 2020-05-29 | 上海超彩油墨有限公司 | UV matte ink for gloss oil surface and preparation method thereof |
| CN111205686A (en) * | 2020-03-19 | 2020-05-29 | 上海扬盛印务有限公司 | Low-odor UV matte oil and printing process |
| CN114773932B (en) * | 2022-04-29 | 2022-12-16 | 北京金印联国际供应链管理有限公司 | Environment-friendly water-based matt varnish replacing film laminating process and preparation method thereof |
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| CN101638554A (en) * | 2009-05-06 | 2010-02-03 | 佛山市顺德区希贵光固化材料有限公司 | Ultraviolet curing coating |
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