CN108641581A - A kind of environment-friendly water-based floor coatings - Google Patents
A kind of environment-friendly water-based floor coatings Download PDFInfo
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- CN108641581A CN108641581A CN201810507914.5A CN201810507914A CN108641581A CN 108641581 A CN108641581 A CN 108641581A CN 201810507914 A CN201810507914 A CN 201810507914A CN 108641581 A CN108641581 A CN 108641581A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Floor Finish (AREA)
Abstract
The present invention provides a kind of environment-friendly water-based floor coatings, are made of the raw material of following parts by weight：The water that acrylic emulsion that Corvic that fluorocarbon resin that pH value adjustment agent that Acrylic hydroxyl emulsion that water soluble acrylic acid epoxy modified resin that aliphatic polyisocyante that ester gum modified alkyd resin that parts by weight are 10-25, parts by weight are 10-20, parts by weight are 2-5, parts by weight are 10-20, parts by weight are 2-5, parts by weight are 2-5, parts by weight are 1-2, parts by weight are 2-5, parts by weight are 5-10.Coating of the present invention is using water as decentralized medium; without using any cosolvent; the VOC content of coating is extremely low; bulk petroleum resource is not only saved, the fire hazard in production, storage, transport and construction is eliminated, is conducive to environmental protection and construction personnel's health; and suitable environment is wide; it is easy for construction, it can directly construct in moist substrate surface, overcome weakness of the solvent type floor coatings to water sensitive.
Description
Technical field
The present invention relates to environmentally friendly science and technology field more particularly to a kind of environment-friendly water-based floor coatings.
Background technology
80% or more floor coatings of the country are solvent type, including polyurethane floor coatings and epoxy flooring coating at present.This
A little solvent type floor coatings all contain more organic solvent, not only cause to seriously endanger to environment and health, but also right
Petroleum resources are also greatly to waste.
Also contain a certain amount of free isocyanate monomer, in the construction process, meeting in solvent borne polyurethane floor coatings
Seriously affect the health and living environment of people.In addition, solvent type floor coatings can be by environment temperature and humidity, base
The influence and restriction of other problems existing for humidity and basal plane, especially its construction are very high to the aridity requirement of base material, but
It is difficult often to meet in practice of construction.Therefore, many is will appear in construction and is difficult to the disadvantage overcome, such as：Blister, be bubbled,
It falls off, adhere to phenomena such as bad, affect the protecting effect of floor coatings.Although also whether there is or not SOLVENT BASED EPOXY FLOOR COATINGS,
It is because wherein containing a certain amount of reactive diluent, such as common butyl glycidyl ethers, it has certain toxicity, to human body
Health is unfavorable.
As the increasingly stringent of environmental regulation requirement, people are to the common concern and attention of environmental protection and health and stone
Oil product price it is unprecedented soaring, the Water-borne modification of floor coatings has become inevitable development trend.Published aqueous floor coatings
Most of patent is related to water-base epoxy type floor coatings, such as Chinese patent CN101565584A, CN1702132A, CN1597812A
Deng although the organic solvent content in these floor coatings systems is far below existing solvent type floor coatings, its epoxy resin
Weatherability difference and apply the shortcomings of film quality is crisp easy to crack and can not still overcome, thus the open air having higher requirements to weatherability cannot be met
The requirement of the special terrace of sports.CN101362922A discloses a kind of water-based mono-component aliphatic polyurethane floor coatings,
Compared with water-base epoxy class floor coatings, there is preferable wearability and weatherability, but since base-material used is aqueous single group
Divide aliphatic polyurathane emulsion, film that can not provide good weatherability, and when preparing coating without chemical crosslinking,
It still needs to that a certain amount of cosolvent is added, which increases the volatile organic contents in coating, have an impact environment and human body.
Invention content
In order to solve the above technical problem, the present invention provides a kind of environment-friendly water-based floor coatings, by following parts by weight
Raw material forms：Aliphatic polyisocyante that ester gum modified alkyd resin that parts by weight are 10-25, parts by weight are 10-20, weight
The PH that Acrylic hydroxyl emulsion that the water soluble acrylic acid epoxy modified resin for part being 2-5, parts by weight are 10-20, parts by weight are 2-5
The acrylic acid that Corvic that fluorocarbon resin that value conditioning agent, parts by weight are 2-5, parts by weight are 1-2, parts by weight are 2-5
Lotion, the water that parts by weight are 5-10.
Further, the environment-friendly water-based floor coatings further include the reflective glass beads that parts by weight are 10-15.
Further, the reflective glass beads include big grain size reflective glass beads, middle grain size reflective glass beads and
Small particle reflective glass beads；Wherein
The parts by weight of the big grain size reflective glass beads are 10-25 parts, the weight of the middle grain size reflective glass beads
Part is 20-30 parts, and the parts by weight of the small particle reflective glass beads are 30-40 parts.
Further, the grain size of the big grain size reflective glass beads is 20-50 μm, the middle grain size reflective glass beads
Grain size be 1-20 μm, the grain sizes of the small particle reflective glass beads is 0.1-1 μm.
Further, the Corvic is graininess, and the average diameter of particle is 0.5-1 μm.
Further, the preparation method of the Corvic includes the following steps：
By the mixture microsuspension polymerization of vinyl chloride monomer, polymerization initiator, emulsifier and buffer in aqueous solvent,
To obtain a kind of Corvic latex；
The Corvic latex is spray-dried.
Further, the emulsifier includes alkenyl oligosaccharides glycosides, alcohol polyglyceryl ether and organic alcohol amine.
Further, the mass ratio of the vinyl chloride monomer, polymerization initiator, emulsifier and buffer is 1-2:3-5:3-
4:1。
Further, the environment-friendly water-based floor coatings further include：Parts by weight are the aluminium triphosphate of 1-5.
Further, the environment-friendly water-based floor coatings further include：Parts by weight are the diatomite of 2-4.
Coating of the present invention does not use any cosolvent, the VOC contents of coating are extremely low, not only save using water as decentralized medium
Bulk petroleum resource eliminates the fire hazard in production, storage, transport and construction, is conducive to environmental protection and construction
Personnel health, and suitable environment is wide, it is easy for construction, it can directly construct in moist substrate surface, overcome the painting of solvent type terrace
Expect the weakness to water sensitive.
According to hereafter to the detailed description of the specific embodiment of the invention, will become more apparent to one of ordinary skill in the art the present invention
Above-mentioned and other purposes, advantages and features.
Specific implementation mode
Embodiment 1：
An embodiment of the present invention provides a kind of environment-friendly water-based floor coatings, are made of the raw material of following parts by weight：Parts by weight
For 10 ester gum modified alkyd resin, parts by weight be 20 aliphatic polyisocyante, parts by weight be 5 water soluble acrylic acid epoxy
The fluorine carbon tree that pH value adjustment agent that Acrylic hydroxyl emulsion that modified resin, parts by weight are 20, parts by weight are 5, parts by weight are 2
The water that acrylic emulsion that Corvic that fat, parts by weight are 2, parts by weight are 5, parts by weight are 10；Wherein, the pH value
Conditioning agent includes polyether compound and thermoplastic polyester, and the polyether compound has cyclic hydrocarbon group.
Embodiment 2：
An embodiment of the present invention provides a kind of environment-friendly water-based floor coatings, are made of the raw material of following parts by weight：Parts by weight
For 25 ester gum modified alkyd resin, parts by weight be 10 aliphatic polyisocyante, parts by weight be 2 water soluble acrylic acid epoxy
The fluorine carbon tree that pH value adjustment agent that Acrylic hydroxyl emulsion that modified resin, parts by weight are 15, parts by weight are 2, parts by weight are 5
The water and parts by weight that acrylic emulsion that Corvic that fat, parts by weight are 1, parts by weight are 2, parts by weight are 5 are 10
Reflective glass beads；Wherein, the pH value adjustment agent includes polyether compound and thermoplastic polyester, the polyether compound
With cyclic hydrocarbon group.
The reflective glass beads include that big grain size reflective glass beads, middle grain size reflective glass beads and small particle are reflective
Glass microballoon；The parts by weight of the wherein described big grain size reflective glass beads are 25 parts, the weight of the middle grain size reflective glass beads
It is 20 parts to measure part, and the parts by weight of the small particle reflective glass beads are 40 parts.
The grain size of the big grain size reflective glass beads is 20-25 μm, and the grain size of the middle grain size reflective glass beads is
1-5 μm, the grain size of the small particle reflective glass beads is 0.1-0.3 μm.
Embodiment 3：
An embodiment of the present invention provides a kind of environment-friendly water-based floor coatings, are made of the raw material of following parts by weight：Parts by weight
For 20 ester gum modified alkyd resin, parts by weight be 15 aliphatic polyisocyante, parts by weight be 3 water soluble acrylic acid epoxy
The fluorine carbon tree that pH value adjustment agent that Acrylic hydroxyl emulsion that modified resin, parts by weight are 10, parts by weight are 3, parts by weight are 3
The water and parts by weight that acrylic emulsion that Corvic that fat, parts by weight are 1.5, parts by weight are 3, parts by weight are 8 are 15
Reflective glass beads；Wherein, the pH value adjustment agent includes polyether compound and thermoplastic polyester, the polyethers chemical combination
Object has cyclic hydrocarbon group.
The reflective glass beads include that big grain size reflective glass beads, middle grain size reflective glass beads and small particle are reflective
Glass microballoon；The parts by weight of the wherein described big grain size reflective glass beads are 10 parts, the weight of the middle grain size reflective glass beads
It is 30 parts to measure part, and the parts by weight of the small particle reflective glass beads are 30 parts.
The grain size of the big grain size reflective glass beads is 25-35 μm, and the grain size of the middle grain size reflective glass beads is
5-10 μm, the grain size of the small particle reflective glass beads is 0.3-0.6 μm.
The Corvic is graininess, and the average diameter of particle is 0.5 μm.
Embodiment 4：
An embodiment of the present invention provides a kind of environment-friendly water-based floor coatings, are made of the raw material of following parts by weight：Parts by weight
For 15 ester gum modified alkyd resin, parts by weight be 18 aliphatic polyisocyante, parts by weight be 4 water soluble acrylic acid epoxy
The fluorine carbon tree that pH value adjustment agent that Acrylic hydroxyl emulsion that modified resin, parts by weight are 17, parts by weight are 4, parts by weight are 4
The water and parts by weight that acrylic emulsion that Corvic that fat, parts by weight are 2, parts by weight are 4, parts by weight are 9 are 13
Reflective glass beads；Wherein, the pH value adjustment agent includes polyether compound and thermoplastic polyester, the polyether compound
With cyclic hydrocarbon group.
The reflective glass beads include that big grain size reflective glass beads, middle grain size reflective glass beads and small particle are reflective
Glass microballoon；The parts by weight of the wherein described big grain size reflective glass beads are 15 parts, the weight of the middle grain size reflective glass beads
It is 25 parts to measure part, and the parts by weight of the small particle reflective glass beads are 35 parts.
The grain size of the big grain size reflective glass beads is 35-40 μm, and the grain size of the middle grain size reflective glass beads is
10-15 μm, the grain size of the small particle reflective glass beads is 0.6-0.8 μm.
The Corvic is graininess, and the average diameter of particle is 1 μm.
The preparation method of the Corvic includes the following steps：By vinyl chloride monomer, polymerization initiator, emulsifier
With mixture microsuspension polymerization of the buffer in aqueous solvent, to obtain a kind of Corvic latex；To the polychlorostyrene
Vinyl latex is spray-dried.
The emulsifier includes alkenyl oligosaccharides glycosides, alcohol polyglyceryl ether and organic alcohol amine.The vinyl chloride monomer, polymerization are drawn
The mass ratio for sending out agent, emulsifier and buffer is 1:3:3:1.
Embodiment 5：
An embodiment of the present invention provides a kind of environment-friendly water-based floor coatings, are made of the raw material of following parts by weight：Parts by weight
For 18 ester gum modified alkyd resin, parts by weight be 12 aliphatic polyisocyante, parts by weight be 3.5 water soluble acrylic acid ring
PH value adjustment agent that Acrylic hydroxyl emulsion that oxygen modified resin, parts by weight are 19, parts by weight are 3.5, parts by weight are 2.5
The water and weight that acrylic emulsion that Corvic that fluorocarbon resin, parts by weight are 1, parts by weight are 2.5, parts by weight are 6
The reflective glass beads that part is 11；Wherein, the pH value adjustment agent includes polyether compound and thermoplastic polyester, described poly-
Ether compound has cyclic hydrocarbon group；
The reflective glass beads include that big grain size reflective glass beads, middle grain size reflective glass beads and small particle are reflective
Glass microballoon；The parts by weight of the wherein described big grain size reflective glass beads are 18 parts, the weight of the middle grain size reflective glass beads
It is 28 parts to measure part, and the parts by weight of the small particle reflective glass beads are 32 parts.
The grain size of the big grain size reflective glass beads is 40-50 μm, and the grain size of the middle grain size reflective glass beads is
15-20 μm, the grain size of the small particle reflective glass beads is 0.8-1 μm.
The Corvic is graininess, and the average diameter of particle is 0.6 μm.
The preparation method of the Corvic includes the following steps：By vinyl chloride monomer, polymerization initiator, emulsifier
With mixture microsuspension polymerization of the buffer in aqueous solvent, to obtain a kind of Corvic latex；To the polychlorostyrene
Vinyl latex is spray-dried.
The emulsifier includes alkenyl oligosaccharides glycosides, alcohol polyglyceryl ether and organic alcohol amine.The vinyl chloride monomer, polymerization are drawn
The mass ratio for sending out agent, emulsifier and buffer is 2:5:4:1.
The environment-friendly water-based floor coatings further include：The diatomite that the aluminium triphosphate and parts by weight that parts by weight are 5 are 2.
Embodiment 6：
An embodiment of the present invention provides a kind of environment-friendly water-based floor coatings, are made of the raw material of following parts by weight：Parts by weight
For 12 ester gum modified alkyd resin, parts by weight be 18 aliphatic polyisocyante, parts by weight be 5 water soluble acrylic acid epoxy
The fluorine carbon tree that pH value adjustment agent that Acrylic hydroxyl emulsion that modified resin, parts by weight are 20, parts by weight are 5, parts by weight are 2
The water and parts by weight that acrylic emulsion that Corvic that fat, parts by weight are 2, parts by weight are 3.5, parts by weight are 7 are 14
Reflective glass beads；Wherein, the pH value adjustment agent includes polyether compound and thermoplastic polyester, the polyethers chemical combination
Object has cyclic hydrocarbon group.
The reflective glass beads include that big grain size reflective glass beads, middle grain size reflective glass beads and small particle are reflective
Glass microballoon；The parts by weight of the wherein described big grain size reflective glass beads are 22 parts, the weight of the middle grain size reflective glass beads
It is 23 parts to measure part, and the parts by weight of the small particle reflective glass beads are 37 parts.
The grain size of the big grain size reflective glass beads is 45-50 μm, and the grain size of the middle grain size reflective glass beads is
10-18 μm, the grain size of the small particle reflective glass beads is 0.5-1 μm.
The Corvic is graininess, and the average diameter of particle is 0.8 μm.
The preparation method of the Corvic includes the following steps：By vinyl chloride monomer, polymerization initiator, emulsifier
With mixture microsuspension polymerization of the buffer in aqueous solvent, to obtain a kind of Corvic latex；To the polychlorostyrene
Vinyl latex is spray-dried.
The emulsifier includes alkenyl oligosaccharides glycosides, alcohol polyglyceryl ether and organic alcohol amine.The vinyl chloride monomer, polymerization are drawn
The mass ratio for sending out agent, emulsifier and buffer is 1.5:3.5:3.5:1.
The environment-friendly water-based floor coatings further include：The diatomite that the aluminium triphosphate and parts by weight that parts by weight are 1 are 4.
Coating of the present invention does not use any cosolvent, the VOC contents of coating are extremely low, not only save using water as decentralized medium
Bulk petroleum resource eliminates the fire hazard in production, storage, transport and construction, is conducive to environmental protection and construction
Personnel health, and suitable environment is wide, it is easy for construction, it can directly construct in moist substrate surface, overcome the painting of solvent type terrace
Expect the weakness to water sensitive.
So far, although those skilled in the art will appreciate that present invention has been shown and described in detail herein multiple shows
Example property embodiment still without departing from the spirit and scope of the present invention, still can according to the present disclosure directly
Determine or derive many other variations or modifications consistent with the principles of the invention.Therefore, the scope of the present invention is understood that and recognizes
It is set to and covers other all these variations or modifications.
Claims (10)
1. a kind of environment-friendly water-based floor coatings, which is characterized in that be made of the raw material of following parts by weight：Parts by weight are 10-25's
The water soluble acrylic acid epoxy that aliphatic polyisocyante that ester gum modified alkyd resin, parts by weight are 10-20, parts by weight are 2-5
PH value adjustment agent that Acrylic hydroxyl emulsion that modified resin, parts by weight are 10-20, parts by weight are 2-5, parts by weight are 2-5's
The water that acrylic emulsion that Corvic that fluorocarbon resin, parts by weight are 1-2, parts by weight are 2-5, parts by weight are 5-10.
2. environment-friendly water-based floor coatings according to claim 1, which is characterized in that the environment-friendly water-based floor coatings also wrap
Include the reflective glass beads that parts by weight are 10-15.
3. environment-friendly water-based floor coatings according to claim 2, which is characterized in that the reflective glass beads include big grain
Diameter reflective glass beads, middle grain size reflective glass beads and small particle reflective glass beads；Wherein
The parts by weight of the big grain size reflective glass beads are 10-25 parts, and the parts by weight of the middle grain size reflective glass beads are
20-30 parts, the parts by weight of the small particle reflective glass beads are 30-40 parts.
4. environment-friendly water-based floor coatings according to claim 3, which is characterized in that the big grain size reflective glass beads
Grain size is 20-50 μm, and the grain size of the middle grain size reflective glass beads is 1-20 μm, the grain of the small particle reflective glass beads
Diameter is 0.1-1 μm.
5. environment-friendly water-based floor coatings according to claim 1, which is characterized in that the Corvic is particle
The average diameter of shape, particle is 0.5-1 μm.
6. environment-friendly water-based floor coatings according to claim 1, which is characterized in that the preparation side of the Corvic
Method includes the following steps：
By the mixture microsuspension polymerization of vinyl chloride monomer, polymerization initiator, emulsifier and buffer in aqueous solvent, to obtain
Obtain a kind of Corvic latex；
The Corvic latex is spray-dried.
7. environment-friendly water-based floor coatings according to claim 6, which is characterized in that the emulsifier includes alkenyl oligosaccharides
Glycosides, alcohol polyglyceryl ether and organic alcohol amine.
8. environment-friendly water-based floor coatings according to claim 6, which is characterized in that the vinyl chloride monomer, polymerization cause
The mass ratio of agent, emulsifier and buffer is 1-2:3-5:3-4:1.
9. environment-friendly water-based floor coatings according to claim 1, which is characterized in that the environment-friendly water-based floor coatings also wrap
It includes：Parts by weight are the aluminium triphosphate of 1-5.
10. environment-friendly water-based floor coatings according to claim 1, which is characterized in that the environment-friendly water-based floor coatings are also
Including：Parts by weight are the diatomite of 2-4.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810507914.5A CN108641581A (en) | 2018-05-24 | 2018-05-24 | A kind of environment-friendly water-based floor coatings |
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| CN201810507914.5A CN108641581A (en) | 2018-05-24 | 2018-05-24 | A kind of environment-friendly water-based floor coatings |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109609010A (en) * | 2018-12-12 | 2019-04-12 | 厦门安必信新材料科技有限公司 | A kind of super abrasive aqueous polyurethane floor coatings and preparation method thereof |
| CN110804357A (en) * | 2019-11-18 | 2020-02-18 | 深圳陆城装饰设计工程有限公司 | Building exterior wall coating with good weather resistance and exterior wall coating construction process |
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| CN102634273A (en) * | 2012-05-11 | 2012-08-15 | 中国海洋石油总公司 | Environment-friendly water-based double-component polyurethane floor coating |
| CN104768982A (en) * | 2012-11-02 | 2015-07-08 | 韩化石油化学株式会社 | Polyvinyl chloride resin and method of preparing the same |
| CN105862543A (en) * | 2016-04-13 | 2016-08-17 | 安徽拓力工程材料科技有限公司 | Color reflective antiskid pavement and manufacturing method thereof |
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2018
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597806A (en) * | 2004-07-23 | 2005-03-23 | 庄晓明 | Reflective paint |
| CN102634273A (en) * | 2012-05-11 | 2012-08-15 | 中国海洋石油总公司 | Environment-friendly water-based double-component polyurethane floor coating |
| CN104768982A (en) * | 2012-11-02 | 2015-07-08 | 韩化石油化学株式会社 | Polyvinyl chloride resin and method of preparing the same |
| CN105862543A (en) * | 2016-04-13 | 2016-08-17 | 安徽拓力工程材料科技有限公司 | Color reflective antiskid pavement and manufacturing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109609010A (en) * | 2018-12-12 | 2019-04-12 | 厦门安必信新材料科技有限公司 | A kind of super abrasive aqueous polyurethane floor coatings and preparation method thereof |
| CN110804357A (en) * | 2019-11-18 | 2020-02-18 | 深圳陆城装饰设计工程有限公司 | Building exterior wall coating with good weather resistance and exterior wall coating construction process |
| CN110804357B (en) * | 2019-11-18 | 2021-07-02 | 深圳陆城装饰设计工程有限公司 | Building exterior wall coating with good weather resistance and exterior wall coating construction process |
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