CN106398431A - High-adhesive-force UV paint special for glass, and preparation method of UV paint - Google Patents
High-adhesive-force UV paint special for glass, and preparation method of UV paint Download PDFInfo
- Publication number
- CN106398431A CN106398431A CN201610771382.7A CN201610771382A CN106398431A CN 106398431 A CN106398431 A CN 106398431A CN 201610771382 A CN201610771382 A CN 201610771382A CN 106398431 A CN106398431 A CN 106398431A
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- China
- Prior art keywords
- paint
- glass
- exclusively used
- parts
- high adhesion
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention relates to high-adhesive-force UV paint special for glass. The high-adhesive-force UV paint special for the glass is mainly prepared from the following components in parts by weight: 20 to 25 parts of UV attached type photosensitive resin, 20 to 25 parts of an acrylic oligomer, 10 to 15 parts of a polyurethane-acrylate oligomer, 10 to 20 parts of an active diluent, 1 to 3 parts of an adhesion promoter, 3 to 5 parts of a photoinitiator, 0.1 to 0.3 part of a defoaming agent, 0.5 to 1 part of an anti-settling agent and 15 to 20 parts of fillers. The adhesion UV paint for glass is environment-friendly and has extremely high adhesive force, high water resistance and excellent paint film property.
Description
Technical field
The invention belongs to paint field is and in particular to a kind of be exclusively used in high adhesion force UV paint of glass and preparation method thereof.
Background technology
Glass paint is broadly divided into two kinds in the market, waterborne glass coatings and conventional oil-based glass lacquer, water in intensity
Property paint be not so good as conventional oil-based paint, and traditional oil paint mostly is PU coating, NC coating, and volatile organic content is high, pollutes ring
Border, does not meet the theory of Green Development.The glass UV paint environmental protection of the present invention, paint film adhesion is good, excellent performance, solidification speed
Degree is fast, good leveling property, can adopt roller coat, the form of construction work of showering, and production efficiency is high.
Content of the invention
It is an object of the invention to provide a kind of be exclusively used in high adhesion force UV paint of glass and preparation method thereof, the UV of the present invention
The film forming matter of paint has the specific groups such as amino, ehter bond, hydrogen bond can be occurred to make with groups such as the siliconoxygen bond of glass surface, hydroxyls
With thus forming a kind of excellent glass UV paint of the fabulous paint film property of adhesive force.
The present invention is achieved by the following technical solutions：It is exclusively used in the high adhesion force UV paint of glass, mainly by with the following group
Divide and be formulated according to following weight portion：
UV attachment type photosensitive resin, acrylate oligomer, polyurethane acroleic acid oligomer and reactive diluent are as becoming
Film thing, they have the specific groups such as amino, ehter bond.
Further, described UV attachment type photosensitive resin is Changxing DR-E504, and described acrylic acid oligomer is Changxing
6071, described polyurethane acroleic acid oligomer is Changxing 611B-85.
Further, described reactive diluent is the third oxidation neopentylglycol diacrylate, tripropylene glycol two propylene
One of acid esters or hydroxyethyl methylacrylate or two or more arbitrary proportion mix.
Further, adhesion promoter is silane coupler.
Further, described light trigger is 2- hydroxy-2-methyl -1- phenylacetone or 1- hydroxy-cyciohexyl benzene first
One of ketone or two kinds mix according to arbitrary proportion.
Further, described defoamer is organic polymer.
Further, described anti-settling agent is aerosil.
Further, described filler is Pulvis Talci.
Be exclusively used in glass high adhesion force UV paint preparation method, by UV adhere to type photosensitive resin, acrylate oligomer,
Polyurethane acroleic acid oligomer, hydroxyethyl methylacrylate, adhesion promoter, light trigger and defoamer sequentially add reaction
In kettle, 800-1000r/min stirring 10-20 minute, to uniform, then reduce rotating speed and to 300-500r/min and adds anti-settling agent
And Pulvis Talci, finally stirred 15 minutes with 1500-1800r/min and be less than 40 microns with up to fineness.
Due to introducing the specific groups such as amino, ehter bond in film structure, can be with the siliconoxygen bond of glass surface, hydroxyl etc.
There is hydrogen bond action in group, improve ply adhesion, and selects suitable silane coupler, reaches the effect winning high adhesion force
Really.
Than prior art, the invention has the advantages that：The present invention is painted with attachment UV in glass, environmental protection,
Adhesive force is fabulous, water-tolerant, and paint film property is excellent.
Specific construction mode
With reference to specific embodiment, the present invention is expanded on further.
(1) specific embodiment
It is exclusively used in the high adhesion force UV paint of glass, be mainly formulated according to following weight portion by following components：
Described UV attachment type photosensitive resin is Changxing DR-E504, and described acrylic acid oligomer is Changxing 6071, described
Polyurethane acroleic acid oligomer be Changxing 611B-85.
Described reactive diluent is the third oxidation neopentylglycol diacrylate, tri (propylene glycol) diacrylate or first
One of base 2-(Acryloyloxy)ethanol or two or more arbitrary proportion mix, its preferably sharp field P02NPGDA, TPGDA,
HEMA.
Adhesion promoter is silane coupler, preferably silane coupling A 174, and other silane couplers can also.
Described light trigger is one of 2- hydroxy-2-methyl -1- phenylacetone or 1- hydroxy-cyciohexyl benzophenone
Or two kinds mix according to arbitrary proportion, the RUNTECURE 1104 of its preferably magnificent titanium.
Described defoamer is organic polymer, and its preferred enlightening is high by 920.
Described anti-settling agent is aerosil, its preferred Degussa R972 aerosil.Described filler is to slide
Stone powder.
(2) specific embodiment
Embodiment one
It is exclusively used in the high adhesion force UV paint of glass, be formulated according to following weight portion by following components：
UV adheres to 20 parts of type photosensitive resin
25 parts of acrylate oligomer
15 parts of polyurethane acroleic acid oligomer
15 parts of hydroxyethyl methylacrylate
1 part of adhesion promoter
5 parts of light trigger
0.2 part of defoamer
0.5 part of anti-settling agent
18.3 parts of Pulvis Talci.
Manufacturing process：UV is adhered to type photosensitive resin, acrylate oligomer, polyurethane acroleic acid oligomer, methyl-prop
Olefin(e) acid hydroxyl ethyl ester, adhesion promoter, light trigger and defoamer sequentially add in reactor, and 800r/min stirs 10 minutes extremely
Uniformly, then reduce rotating speed and to 300r/min and add anti-settling agent and Pulvis Talci, finally stirred more than 15 minutes with 1500r/min
It is less than 40 microns to fineness.
Embodiment two
It is exclusively used in the high adhesion force UV paint of glass, be formulated according to following weight portion by following components：
UV adheres to 22 parts of type photosensitive resin
25 parts of acrylate oligomer
15 parts of polyurethane acroleic acid oligomer
15 parts of hydroxyethyl methylacrylate
1 part of adhesion promoter
5 parts of light trigger
0.2 part of defoamer
0.5 part of anti-settling agent
16.3 parts of Pulvis Talci
Manufacturing process：UV is adhered to type photosensitive resin, acrylate oligomer, polyurethane acroleic acid oligomer, methyl-prop
Olefin(e) acid hydroxyl ethyl ester, adhesion promoter, light trigger and defoamer sequentially add in reactor, and 1000r/min stirs 20 minutes
To uniform, then reduce rotating speed and to 500r/min and add anti-settling agent and Pulvis Talci, finally with 1800r/min stir 15 minutes with
Up to fineness is less than 40 microns.
Embodiment three
It is exclusively used in the high adhesion force UV paint of glass, be formulated according to following weight portion by following components：
UV adheres to 25 parts of type photosensitive resin
20 parts of acrylate oligomer
15 parts of polyurethane acroleic acid oligomer
15 parts of hydroxyethyl methylacrylate
1 part of adhesion promoter
5 parts of light trigger
0.2 part of defoamer
0.5 part of anti-settling agent
18.3 parts of Pulvis Talci
Manufacturing process：UV is adhered to type photosensitive resin, acrylate oligomer, polyurethane acroleic acid oligomer, methyl-prop
Olefin(e) acid hydroxyl ethyl ester, adhesion promoter, light trigger and defoamer sequentially add in reactor, and 900r/min stirring 10-20 divides
Clock, to uniform, then reduced rotating speed and to 400r/min and adds anti-settling agent and Pulvis Talci, finally stirred 15 minutes with 1600r/min
It is less than 40 microns with up to fineness.
Example IV
It is exclusively used in the high adhesion force UV paint of glass, be formulated according to following weight portion by following components：
UV adheres to 25 parts of type photosensitive resin
25 parts of acrylate oligomer
10 parts of polyurethane acroleic acid oligomer
20 parts of hydroxyethyl methylacrylate
1 part of adhesion promoter
5 parts of light trigger
0.2 part of defoamer
0.5 part of anti-settling agent
18.3 parts of Pulvis Talci
Manufacturing process：UV is adhered to type photosensitive resin, acrylate oligomer, polyurethane acroleic acid oligomer, methyl-prop
Olefin(e) acid hydroxyl ethyl ester, adhesion promoter, light trigger and defoamer sequentially add in reactor, and 900r/min stirs 15 minutes extremely
Uniformly, then reduce rotating speed and to 400r/min and add anti-settling agent and Pulvis Talci, finally stirred more than 15 minutes with 1700r/min
It is less than 40 microns to fineness.
Embodiment five
It is exclusively used in the high adhesion force UV paint of glass, be formulated according to following weight portion by following components：
UV adheres to 20 parts of type photosensitive resin
25 parts of acrylate oligomer
15 parts of polyurethane acroleic acid oligomer
10 parts of hydroxyethyl methylacrylate
1 part of adhesion promoter
5 parts of light trigger
0.2 part of defoamer
0.5 part of anti-settling agent
18.3 parts of Pulvis Talci
Manufacturing process：UV is adhered to type photosensitive resin, acrylate oligomer, polyurethane acroleic acid oligomer, methyl-prop
Olefin(e) acid hydroxyl ethyl ester, adhesion promoter, light trigger and defoamer sequentially add in reactor, and 800-1000r/min stirs 10-
To uniform, then reduce rotating speed and to 300-500r/min and add anti-settling agent and Pulvis Talci, finally with 1500-1800r/ within 20 minutes
Min stirs 15 minutes and is less than 40 microns with up to fineness.
Construction method：The glass of embodiment 1-5 preparation is painted with UV, respectively the glass plate of roller coat surface cleaning, coating weight
For 10g/m2, excessively ultraviolet light curing process (180mj/cm2, 25m/min).Then roller coat UV sanding priming paint, coating weight is 20g/
m2, excessively ultraviolet light curing process (350mj/cm2, 25m/min), last roller coat UV finish paint, coating weight is 10g/m2, cross uviol lamp
Cured (400mj/cm2, 25m/min).
Through the test to embodiment 1-5, glass of the present invention UV paint opens every technical performance index and experimental data such as
Shown in following table,
Comparative example is to carry out, using commercially available UV paint, the data that above-mentioned construction obtains.
Following tables glass of the present invention experimental data of the UV every technical performance index of paint and each embodiment simply：
Anti- stripping：Paint film is easily stripped as 6 grades, and paint film cannot be peeled off as 0 grade.
Adhesive force test is with reference to GB/T9286-1998《Film adhesive testing standard》
Above-mentioned specific embodiment the present invention program has been carried out explained in detail, the present invention and than only shall be limited only to
In the specific embodiment of upper description, any improvement according to the principle of the invention or replacement, all should be in protection scope of the present invention
Interior.
Claims (8)
1. a kind of high adhesion force UV paint being exclusively used in glass it is characterised in that：Mainly joined according to following weight portion by following components
System forms：
2. the high adhesion force UV paint being exclusively used in glass according to claim 1 it is characterised in that：Described reactive diluent is
Third oxidation neopentylglycol diacrylate, one of tri (propylene glycol) diacrylate or hydroxyethyl methylacrylate or
Two or more arbitrary proportions mix.
3. the high adhesion force UV paint being exclusively used in glass according to claim 1 it is characterised in that：Described adhesive force promotes
Agent is silane coupler.
4. the high adhesion force UV paint being exclusively used in glass according to claim 1 it is characterised in that：Described light trigger is
One of 2- hydroxy-2-methyl -1- phenylacetone or 1- hydroxy-cyciohexyl benzophenone or two kinds are according to arbitrary proportion mixing
Become.
5. the high adhesion force UV paint being exclusively used in glass according to claim 1 it is characterised in that：Described defoamer is to have
Machine polymer.
6. the high adhesion force UV paint being exclusively used in glass according to claim 1 it is characterised in that：Described anti-settling agent is gas
Aerosil.
7. the high adhesion force UV paint being exclusively used in glass according to claim 1 it is characterised in that：Described filler is Talcum
Powder.
8. the preparation method of the high adhesion force UV paint being exclusively used in glass according to any one in claim 1-7, it is special
Levy and be：By UV adhere to type photosensitive resin, acrylate oligomer, polyurethane acroleic acid oligomer, hydroxyethyl methylacrylate,
Adhesion promoter, light trigger and defoamer sequentially add in reactor, and 800-1000r/min stirring 10-20 minute is to equal
Even, then reduce rotating speed and to 300-500r/min and add anti-settling agent and Pulvis Talci, finally stir 15 with 1500-1800r/min
Minute is less than 40 microns with up to fineness, obtains final product the described high adhesion force UV paint being exclusively used in glass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610771382.7A CN106398431A (en) | 2016-08-31 | 2016-08-31 | High-adhesive-force UV paint special for glass, and preparation method of UV paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610771382.7A CN106398431A (en) | 2016-08-31 | 2016-08-31 | High-adhesive-force UV paint special for glass, and preparation method of UV paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106398431A true CN106398431A (en) | 2017-02-15 |
Family
ID=58003308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610771382.7A Pending CN106398431A (en) | 2016-08-31 | 2016-08-31 | High-adhesive-force UV paint special for glass, and preparation method of UV paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106398431A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109016913A (en) * | 2018-07-13 | 2018-12-18 | 上海银玛标识股份有限公司 | A kind of seamless coating forming method of endowed processing of glass surface ink |
| CN110938340A (en) * | 2018-09-21 | 2020-03-31 | 独山县玉水鸿浩门业有限公司 | Door panel uv anti-cracking paint and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090162592A1 (en) * | 2007-12-18 | 2009-06-25 | Dow Global Technologies Inc. | Protective coating for window glass having enhanced adhesion to glass bonding adhesives |
| CN102492330A (en) * | 2011-12-02 | 2012-06-13 | 中山大学 | Ultraviolet (UV) photocurable inkjet ink for glass substrate and preparation method for UV photocurable inkjet ink |
| CN104530931A (en) * | 2014-12-12 | 2015-04-22 | 惠州市长润发涂料有限公司 | UV-curing primer for marble |
| CN104974309A (en) * | 2014-04-07 | 2015-10-14 | 尹学重 | Ultraviolet Curable Resin Composition |
-
2016
- 2016-08-31 CN CN201610771382.7A patent/CN106398431A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090162592A1 (en) * | 2007-12-18 | 2009-06-25 | Dow Global Technologies Inc. | Protective coating for window glass having enhanced adhesion to glass bonding adhesives |
| CN102492330A (en) * | 2011-12-02 | 2012-06-13 | 中山大学 | Ultraviolet (UV) photocurable inkjet ink for glass substrate and preparation method for UV photocurable inkjet ink |
| CN104974309A (en) * | 2014-04-07 | 2015-10-14 | 尹学重 | Ultraviolet Curable Resin Composition |
| CN104530931A (en) * | 2014-12-12 | 2015-04-22 | 惠州市长润发涂料有限公司 | UV-curing primer for marble |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109016913A (en) * | 2018-07-13 | 2018-12-18 | 上海银玛标识股份有限公司 | A kind of seamless coating forming method of endowed processing of glass surface ink |
| CN110938340A (en) * | 2018-09-21 | 2020-03-31 | 独山县玉水鸿浩门业有限公司 | Door panel uv anti-cracking paint and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170215 |
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| RJ01 | Rejection of invention patent application after publication |