CN106519919A - UV (ultraviolet) primer composition attached to melamine board and preparation method of UV primer composition - Google Patents
UV (ultraviolet) primer composition attached to melamine board and preparation method of UV primer composition Download PDFInfo
- Publication number
- CN106519919A CN106519919A CN201610937328.5A CN201610937328A CN106519919A CN 106519919 A CN106519919 A CN 106519919A CN 201610937328 A CN201610937328 A CN 201610937328A CN 106519919 A CN106519919 A CN 106519919A
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- base compositions
- paint base
- melamine plate
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
An embodiment of the invention discloses UV (ultraviolet) primer composition attached to a melamine board and a preparation method of the UV primer composition. The composition is prepared from components by mass as follows: 20-30 parts of an epoxy acrylate oligomer, 16-30 parts of urethane acrylate oligomer, 4-5 parts of aldehyde ketone resin, 2-3 parts of acrylic resin, 10-17 parts of a diluent, 10-13 parts of 1,6-hexanediol diacrylate, 0.2-0.5 parts of a dispersant, 0.1-0.2 parts of an antifoaming agent, 4-5 parts of a photoinitiator, 0.3 parts of an anti-setting agent, 0.3-0.5 parts of a leveling agent and 10-40 parts of filler. According to the UV primer composition attached to the melamine board and the preparation method of the UV primer composition, the melamine board which is not subjected to surface treatment is directly coated with the prepared primer, the coating manner is quick and convenient, the primer can be directly subjected to UV curing after coating without standing, and short time is consumed.
Description
Technical field
The present invention relates to paint field, more particularly to a kind of UV paint base compositions for being attached to melamine plate and its preparation
Method.
Background technology
With the development of society, coating is widely used in industry-by-industry field.Wherein, ultraviolet-cured paint is wherein
It is a kind of., compared with other paint kind of site operation, generally, the solid content of UV paints is high, very for ultraviolet-cured paint (abbreviation UV is painted, as follows)
Admittedly contain as 100 parts, typically using roller application, efficiency of construction is high, and man-hour is short, production production capacity is high, and substantially VOC free row
Put.Certain status is occupied in furniture industry gradually in recent years, particularly in plate fitment, floor and timber industry.
But day by day extensively applying now with melamine sheet material, UV paints the adhesion problem on melamine sheet material
Also and then occur, this application difficult problem in terms of also becoming current UV paints.In order to solve problem above, existing woodenware factory
The daily life of a family is solved using following several method：Attachment bottom is done using PU paints, then again in UV lacquer for coating above；Using the mode of sanding
Increase the surface roughness of melamine, so that UV paints can adhere to.But, adhesion primer is done using PU paints, can be fine
Solve the problems, such as adhesive force, but for comparing UV paints, man-hour is longer, and it is also contemplated that solvent is released if the UV of application above
Put problem；The method for increasing the degree of roughness on melamine sheet material surface in the way of sanding, after the completion of construction, later stage attachment
Power can be deteriorated even depainting.
The content of the invention
In view of this, the invention provides a kind of be attached to UV paint base compositions of melamine plate and preparation method thereof,
The poor problem of adhesive force can be combined with effectively solving UV paint with melamine plate, while reducing duration, be improved efficiency.
On the one hand, the invention provides a kind of UV paint base compositions for being attached to melamine plate, said composition is by quality
Component includes：
Preferably, the composition is included by mass component：
Preferably, the composition is included by mass component：
Preferably, the diluent is the mixed of one or two in hydroxyethyl methacrylate and isobornyl acrylate
Close.
Preferably, the light trigger is 1- hydroxycyclohexyl phenyl ketones and 2- hydroxy-2-methyl -1- phenyl -1- third
One or two mixing in ketone.
Preferably, the anti-settling agent is aerosil.
Preferably, the levelling agent is acrylic compounds moistening flatting agent.
Preferably, the filler is one or two the mixing in transparent powder and talcum powder.
Preferably, the acrylic resin is low tg thermoplastic acrylic resins.
On the other hand, present invention also offers the preparation method of said composition, method includes：
Thermoplastic acrylic resin is added in 1,6- hexanediyl esters, rotating speed is 3000-4000 rev/min,
Thermoplastic acrylic resin is made to be completely dispersed and dissolve, it is standby；
Aldehyde ketone resin is added in 1,6- hexanediyl esters, rotating speed is 3000-4000 rev/min, makes aldehyde ketone tree
Fat is completely dispersed and dissolves, standby；
Modified epoxy acrylic ester oligomer and modified polyurethane acrylic resin oligomer, portion of diluent, light are drawn
Send out in agent, dispersant and defoamer addition dispersion cylinder, stirred 5-10 minutes with 1500-3000 rev/min of dispersion of rotating speed, then plus
Enter anti-settling agent, filler, rotating speed is 3000-4000 rev/min, disperses 20-30 minutes, makes fineness≤50um；
The aldehyde ketone resin for having dissolved and the thermoplastic acrylic resin for having dissolved are added in dispersion cylinder, rotating speed is 1500-
3000 revs/min, disperse 10-20 minutes；
Remaining diluent and acrylic compounds moistening flatting agent are added, rotating speed is that 1500-3000 rev/min of dispersion stirring is equal
Even 10-15 minutes, 100 mesh filter, packaging.
The present invention is attached to UV paint base compositions of melamine plate and preparation method thereof, is directly coated on without at surface
On the melamine sheet material of reason, application mode is efficient and convenient, need not place and wait to do and directly Jing UV machines can solidify, take after application
It is short.And two degree of applications of UV solid coatings can be directly carried out in partial desiccation state after solidifying, adhesive force is excellent, during with using
Between growth, be not in the problem of depainting.Wherein, the program that is incorporated as of aldehyde ketone resin and thermoplastic acrylic resin is carried
Higher adhesion performance is supplied so that the UV priming paint has excellent attachment on without surface-treated melamine sheet material
Power, after hardening, presentation is a kind of state of semi-solid preparation to the UV priming paint, and sanding of need not polishing just can directly carry out UV reality colors and apply
The follow-up application of material etc., it is efficient and convenient, realize variation of the melamine sheet material on color.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is a part of embodiment of the invention, rather than the embodiment of whole.Based on the enforcement in the present invention
Example, the every other embodiment obtained under the premise of creative work is not made by those of ordinary skill in the art are belonged to
The scope of protection of the invention.
It should be appreciated that when using in this specification and in the appended claims, term " including " and "comprising" are indicated
The presence of described feature, entirety, step, operation, element and/or component, but it is not precluded from one or more of the other feature, whole
The presence or addition of body, step, operation, element, component and/or its set.
It will be further appreciated that, the term "and/or" used in description of the invention and appended claims is
Refer to any combinations of one or more and be possible to combination being associated in the item listed, and including these combinations.
Embodiment 1
By weight, the composition component of the priming paint of the present embodiment is as follows：
| Modified epoxy acrylic ester oligomer | 30 parts |
| Modified urethane acrylate oligomer | 28 parts |
| Hydroxyethyl methacrylate | 5 parts |
| Isobornyl acrylate | 6 parts |
| Dispersant | 0.3 part |
| Defoamer | 0.1 part |
| 1- hydroxycyclohexyl phenyl ketones | 4 parts |
| Aerosil | 0.3 part |
| Transparent powder | 5 parts |
| Talcum powder | 5 parts |
| 40% aldehyde ketone resin solution | 10 parts |
| 30% thermoplastic acrylic resin solution | 6 parts |
| Acrylic compounds moistening flatting agent | 0.3 part |
Embodiment 2
By weight, the composition component of the priming paint of the present embodiment is as follows：
| Modified epoxy acrylic ester oligomer | 22 parts |
| Modified urethane acrylate oligomer | 22 parts |
| Hydroxyethyl methacrylate | 6 parts |
| Isobornyl acrylate | 9.7 part |
| Dispersant | 0.5 part |
| Defoamer | 0.2 part |
| 2- hydroxy-2-methyl -1- phenyl -1- acetone | 4 parts |
| Aerosil | 0.3 part |
| Transparent powder | 10 parts |
| Talcum powder | 5 parts |
| 40% aldehyde ketone resin solution | 12 parts |
| 30% thermoplastic acrylic resin solution | 8 parts |
| Acrylic compounds moistening flatting agent | 0.3 part |
Embodiment 3
By weight, the composition component of the priming paint of the present embodiment is as follows：
Embodiment 4
By weight, the composition component of the priming paint of the present embodiment is as follows：
Embodiment 5
By weight, the composition component of the priming paint of the present embodiment is as follows：
| Modified epoxy acrylic ester oligomer | 30 parts |
| Modified urethane acrylate oligomer | 30 parts |
| Hydroxyethyl methacrylate | 5.3 part |
| Isobornyl acrylate | 5 parts |
| Dispersant | 0.2 part |
| Defoamer | 0.2 part |
| 2- hydroxy-2-methyl -1- phenyl -1- acetone | 4 parts |
| 40% aldehyde ketone resin solution | 12 parts |
| 30% thermoplastic acrylic resin solution | 8 parts |
| Acrylic compounds moistening flatting agent | 0.3 part |
Embodiment 6
By weight, the composition component of the priming paint of the present embodiment is as follows：
Embodiment 7
By weight, the composition component of the priming paint of the present embodiment is as follows：
Embodiment 8
By weight, the composition component of the priming paint of the present embodiment is as follows：
Embodiment 9
By weight, the composition component of the priming paint of the present embodiment is as follows：
| Modified epoxy acrylic ester oligomer | 24 parts |
| Modified urethane acrylate oligomer | 20 parts |
| Hydroxyethyl methacrylate | 5 parts |
| Isobornyl acrylate | 7 parts |
| Dispersant | 0.4 part |
| Defoamer | 0.15 part |
| 2- hydroxy-2-methyl -1- phenyl -1- acetone | 2 parts |
| 1- hydroxycyclohexyl phenyl ketones | 2.5 part |
| Aerosil | 0.3 part |
| Transparent powder | 10 parts |
| Talcum powder | 12 parts |
| Aldehyde ketone resin | 4.5 part |
| Low tg thermoplastic acrylic resins | 2.5 part |
| Acrylic compounds moistening flatting agent | 0.4 part |
| 1,6 hexanediol diacrylate | 12 parts |
Wherein, 40% aldehyde ketone resin solution, 30% thermoplastic acrylic resin solution is all with 1,6- hexylene glycols, two propylene
Acid esters is used as solvent.Modified epoxy acrylic ester oligomer and 2 functional group modification urethane acrylate oligomers, are ultraviolet
Light-cured resin, after solidification, pliability is good, and adhesive force is good, and cured film shrinks little；Aldehyde ketone resin wetability is good, strong adhesive force；
Thermoplastic acrylic resin belongs to the thermoplastic acrylic resin of low Tg；Hydroxyethyl methacrylate and propylene are different
Norbornene ester is a kind of simple function group UV activated monomers, and reactive diluent can be hydroxyethyl methacrylate and isobomyl acrylate
One or two mixing in ester.
Modified epoxy acrylic ester oligomer curing rate is fast, and paint film is flexible, good to the adhesive force of various base materials.2 senses
Group's modified urethane acrylate oligomer curing rate is slow, but paint film is soft, good to the tack of various base materials, and is beneficial to layer
Between adhere to, the adjustable paint film suppleness of collocation modified epoxy acrylic ester oligomer and film curing speed make the attached of system
Put forth effort outstanding；The introducing of aldehyde ketone resin and thermoplastic acrylic resin, the main wetability using aldehyde ketone resin are good, adhesive force
Strong advantage, same thermoplastic acrylic resin also strengthen attachment of the system to melamine plate to a certain extent, solve
Problem of the UV coating in melamine plate poor adhesive force；Hydroxyethyl methacrylate diluting power is strong, soft after solidification, shrinks
It is little, and contain OH bases, the good attachment to ground；Propylene isobornyl thiocyanoacetate diluting power is strong, and curing rate is fast, shrinks little, attachment
Power is good；Aerosil is mainly used in the anti-settling of system, and transparent powder is 2500 purposes, and talcum powder is 1250 purposes, the present invention
Used in can be one or two mixing in transparent powder and talcum powder, dispersion at a high speed reaches fineness less than 50um,
Skeleton function is played in system, and talcum powder weatherability is preferable；Light trigger use 1- hydroxycyclohexyl phenyl ketones or 2- hydroxyls-
One or two mixing of 2- methyl isophthalic acids-phenyl -1- acetone, for system initiated polymerization under ultraviolet light.
Preparation method is：1. the low tg thermoplastic acrylic resins in component A are added in HDDA, at a high speed (3000～
4000 revs/min) it is dispersed to thermoplastic acrylic resin and is completely dissolved, it is standby；2. the aldehyde ketone resin in component A is added to into HDDA
In, (3000～4000 revs/min) are dispersed to aldehyde ketone resin and are completely dissolved at a high speed, standby；3. by the modified epoxy propylene in component A
Acid esters oligomer and acrylic resin modified, partial monosomy, light trigger, dispersant and defoamer add middling speed in dispersion cylinder
(1500～3000 revs/min) dispersions stir 5～10 minutes, add aerosil powder, and talcum powder and transparent powder are high
(3000～4000 revs/min) of speed is disperseed 20～30 minutes, checks fineness≤50um；4. the aldehyde ketone resin that 1. step dissolved and
2. during the middle low tg thermoplastic acrylic resins for having dissolved add dispersion cylinder, (1500～3000 revs/min) dispersions 10～20 of middling speed
Minute；5. remaining monomer in component and acrylic compounds moistening flatting agent are added, (1500～3000 revs/min) dispersions of middling speed are stirred
Mix uniform 10～15 minutes, 100 mesh are filtered and packaged.
During use by component A direct application (roller coating) on melamine sheet material, through it is ultraviolet light curing just can carry out after
Continuous construction.The construction times of general UV adhesion primers are 1 time, and construction weight is 8～15g/m2, depending on Specific construction situation
It is fixed.
Step in present invention method can carry out order adjustment according to actual needs, merge and delete.
It is more than that to provided by the present invention, beneficial effects of the present invention are：UV priming paint is directly coated on without at surface
On the melamine sheet material of reason, application mode is efficient and convenient, need not place and wait to do and directly Jing UV machines can solidify, take after application
It is short.And two degree of applications of UV solid coatings can be directly carried out in partial desiccation state after solidifying, adhesive force is excellent, during with using
Between growth, be not in the problem of depainting.Wherein, the program that is incorporated as of aldehyde ketone resin and thermoplastic acrylic resin is carried
Higher adhesion performance is supplied so that the UV priming paint has excellent attachment on without surface-treated melamine sheet material
Power.After hardening, presentation is a kind of state of semi-solid preparation to the UV priming paint, and sanding of need not polishing just can directly carry out UV reality colors and apply
The follow-up application of material etc., it is efficient and convenient, realize variation of the melamine sheet material on color.
It is described in detail herein, applies specific case and the principle and embodiment of the present invention are explained
State, above example is only intended to help and understands the method for the present invention and its core concept；Simultaneously for the general skill of this area
Art personnel, according to the thought of the present invention, will change in specific embodiments and applications, in sum, this
Description should not be construed as limiting the invention.
Those skilled in the art can be understood that, for convenience and simplicity of description, the system of foregoing description
With the specific work process of unit, the corresponding process in preceding method embodiment is may be referred to, be will not be described here.
Claims (10)
1. a kind of UV paint base compositions for being attached to melamine plate, it is characterised in that the composition is included by mass component：
。
2. the UV paint base compositions of melamine plate are attached to as claimed in claim 1, it is characterised in that the composition is pressed
Mass component includes：
。
3. the UV paint base compositions of melamine plate are attached to as claimed in claim 1, it is characterised in that the composition is pressed
Mass component includes：
。
4. the UV paint base compositions of melamine plate are attached to as claimed in claim 1, it is characterised in that：The diluent is
One or two mixing in hydroxyethyl methacrylate and isobornyl acrylate.
5. the UV paint base compositions of melamine plate are attached to as claimed in claim 1, it is characterised in that：The light trigger
For one or two the mixing in 1- hydroxycyclohexyl phenyl ketones and 2- hydroxy-2-methyl -1- phenyl -1- acetone.
6. the UV paint base compositions of melamine plate are attached to as claimed in claim 1, it is characterised in that：The anti-settling agent is
Aerosil.
7. the UV paint base compositions of melamine plate are attached to as claimed in claim 1, it is characterised in that：The levelling agent is
Acrylic compounds moistening flatting agent.
8. the UV paint base compositions of melamine plate are attached to as claimed in claim 1, it is characterised in that：The filler is
One or two mixing in transparent powder and talcum powder.
9. the UV paint base compositions of melamine plate are attached to as claimed in claim 1, it is characterised in that：The acrylic acid tree
Fat is low tg thermoplastic acrylic resins.
10. a kind of preparation method of the UV paint base compositions for being attached to melamine plate, it is characterised in that comprise the following steps：
Thermoplastic acrylic resin is added in 1,6- hexanediyl esters, rotating speed is 3000-4000 rev/min, makes heat
Plastic propene's acid resin is completely dispersed and dissolves, standby；
Aldehyde ketone resin is added in 1,6- hexanediyl esters, rotating speed is 3000-4000 rev/min, makes aldehyde ketone resin complete
Disperse entirely and dissolve, it is standby；
By modified epoxy acrylic ester oligomer and modified polyurethane acrylic resin oligomer, portion of diluent, light trigger,
During dispersant and defoamer add dispersion cylinder, stirred 5-10 minutes with 1500-3000 rev/min of dispersion of rotating speed, added anti-
Heavy agent, filler, rotating speed are 3000-4000 rev/min, disperse 20-30 minutes, make fineness≤50um；
The aldehyde ketone resin for having dissolved and the thermoplastic acrylic resin for having dissolved are added in dispersion cylinder, rotating speed is 1500-3000
Rev/min, disperse 10-20 minutes；
Remaining diluent and acrylic compounds moistening flatting agent are added, rotating speed stirs for 1500-3000 rev/min of dispersion
10-15 minutes, 100 mesh filter, packaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610937328.5A CN106519919A (en) | 2016-10-25 | 2016-10-25 | UV (ultraviolet) primer composition attached to melamine board and preparation method of UV primer composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610937328.5A CN106519919A (en) | 2016-10-25 | 2016-10-25 | UV (ultraviolet) primer composition attached to melamine board and preparation method of UV primer composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106519919A true CN106519919A (en) | 2017-03-22 |
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| CN201610937328.5A Pending CN106519919A (en) | 2016-10-25 | 2016-10-25 | UV (ultraviolet) primer composition attached to melamine board and preparation method of UV primer composition |
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Cited By (7)
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| CN109082208A (en) * | 2018-08-17 | 2018-12-25 | 张家港市五湖新材料技术开发有限公司 | A kind of ultraviolet curing type priming paint for furniture |
| CN109161306A (en) * | 2018-08-13 | 2019-01-08 | 广东新灏元科技有限公司 | A kind of runway fluorescence coating compositions and preparation method thereof |
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| WO2019185302A1 (en) | 2018-03-27 | 2019-10-03 | Mercene Labs Ab | Coating and primer |
| CN113717616A (en) * | 2021-10-19 | 2021-11-30 | 成都君子兰涂料有限公司 | Polishing-free UV (ultraviolet) adhesion primer for pasting melamine paper on medium density fiberboard and preparation method thereof |
| CN115836106A (en) * | 2020-07-07 | 2023-03-21 | 弗瑞兹艾格有限及两合公司 | Lacquerable and lacquered material with a structured surface |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383856A (en) * | 2017-08-16 | 2017-11-24 | 河北惠驰装饰材料有限公司 | A kind of modified resin and its preparation method and application |
| WO2019047994A1 (en) * | 2017-09-10 | 2019-03-14 | Mankiewicz Gebr. & Co. (Gmbh & Co. Kg) | Recyclable coatings and use thereof for printing reusable plastics |
| JP2020533451A (en) * | 2017-09-10 | 2020-11-19 | マンキーヴィッチ ゲブリューダー ウント コンパニー （ゲーエムベーハー ウント コンパニー カーゲー）Ｍａｎｋｉｅｗｉｃｚ Ｇｅｂｒ． ＆ Ｃｏ． ＧｍｂＨ＆ Ｃｏ． ＫＧ | Its use for printing on reusable coatings and reusable plastics |
| US11702549B2 (en) | 2017-09-10 | 2023-07-18 | Mankiewicz Gebr. & Co. (Gmbh & Co. Kg) | Recyclable coatings and use thereof for printing reusable plastics |
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Application publication date: 20170322 |