CN104497814A - Aldehyde-ketone resin modified unsaturated polyester primer and preparation method thereof - Google Patents
Aldehyde-ketone resin modified unsaturated polyester primer and preparation method thereof Download PDFInfo
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- CN104497814A CN104497814A CN201410766538.3A CN201410766538A CN104497814A CN 104497814 A CN104497814 A CN 104497814A CN 201410766538 A CN201410766538 A CN 201410766538A CN 104497814 A CN104497814 A CN 104497814A
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- unsaturated polyester
- ketone resin
- aldehyde ketone
- resin modified
- paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention relates to an aldehyde-ketone resin modified unsaturated polyester primer and a preparation method thereof. The aldehyde-ketone resin modified unsaturated polyester primer is prepared by mixing a main paint, an initiator and an accelerator at a weight ratio of 100:(1.0-1.5):(1.2-1.7), wherein the main pain is prepared from the following components in parts by weight: unsaturated polyester resin, a dispersing agent, hydroquinone, a defoaming agent, a leveling agent, a toner, heavy calcium carbonate, talc powder, fumed silica, zinc stearate, aldehyde-ketone resin solution and styrene, the accelerator is cobalt naphthenate, and the initiator is methyl ethyl ketone peroxide. The aldehyde-ketone resin modified unsaturated polyester primer prepared by adopting the preparation method can be directly sprayed on the substrate of a fiberboard without the necessity of polishing the substrate, and the aldehyde-ketone resin modified unsaturated polyester primer presents excellent adhesion and fullness after being sprayed on the substrate of the fiberboard.
Description
Technical field
The present invention relates to a kind of furniture coating, particularly a kind of aldehyde ketone resin modified unsaturated polyester priming paint and preparation method thereof.
Background technology
At present, on Coating Market, unsaturated polyester priming paint must first carry out the construction of PU seal coat when fiberboard ground is constructed, and does solid work rear polishing and could spray UPE unsaturated polyester priming paint; The working procedure of this kind of spraying method is complicated, and time and cost increase, and sticking power and fullness ratio bad, greatly reduce operating efficiency.If existing unsaturated polyester priming paint does not do PU seal coat and grinding process, direct spraying, there will be the defect problem that film adhesive is poor, easily fall paint, do not have fullness ratio.
Summary of the invention
The object of the invention is to overcome weak point of the prior art, a kind of aldehyde ketone resin modified unsaturated polyester priming paint and preparation method thereof is provided, aldehyde ketone resin modified unsaturated polyester primer applications prepared by the present invention does not need ground of polishing when fiberboard ground, can direct spraying, and after spraying, there is excellent sticking power and fullness ratio.
The present invention is achieved in that a kind of aldehyde ketone resin modified unsaturated polyester priming paint, mixed by the weight ratio of 100:1.0-1.5:1.2-1.7 by main paint, initiator, promotor, wherein main paint, initiator, promotor respectively by following component and ratio of weight and number formulated:
Wherein the component of main paint and ratio of weight and number as follows:
Promotor is cobalt naphthenate;
Initiator is methylethyl ketone peroxide.
Further prioritization scheme is: described unsaturated polyester resin is the chain macromolecule compound with ester bond ester bond and unsaturated double-bond of the unsaturated dibasic alcohol polycondensation of unsaturated dibasic acid dibasic alcohol or monounsaturated dicarboxylic acid, and described unsaturated polyester resin is admittedly containing being 75%-80%.Described unsaturated polyester resin is Changxing production of resins.
Further prioritization scheme is: the DN-PWS type dispersion agent that described dispersion agent adopts Song Wei company to produce.
Further prioritization scheme is: Resorcinol is stopper, and the massfraction adopting N-BUTYL ACETATE dissolved dilution to become is the Resorcinol liquid of 10%, and it adopts Dezhou Xin Quan company to produce.
Further prioritization scheme is: the OX880 type acrylate defoamer that described defoamer adopts Asahi Kasei Corporation to produce.
Further prioritization scheme is: the EFKA3777 type esters of acrylic acid flow agent that described flow agent adopts EFKA company to produce and German Bi Ke company produce the silicone based flow agent of BYK333 type.Silicone based flow agent is preferably the machine silicon class flow agent liquid of 10% with the massfraction that N-BUTYL ACETATE is diluted to.
Further prioritization scheme is: described toner adopts Clariant Corporation to produce.
Further prioritization scheme is: described water-ground limestone is the production of agriculture-countryside-farmer company.
Further prioritization scheme is: described talcum powder is that Lan Die company produces.
Further prioritization scheme is: described aerosil is that Cabot Co., Ltd produces, in white powder, and can unrestricted flow.
Further prioritization scheme is: described Zinic stearas is that hundred Li He companies produce.
Further prioritization scheme is: the massfraction of described aldehyde ketone resin liquid employing N-BUTYL ACETATE melt into is the aldehyde ketone resin liquid of 50%.
Further prioritization scheme is: described vinylbenzene is monomer.
A preparation method for aldehyde ketone resin modified unsaturated polyester priming paint, comprises following step:
(1), main paint is prepared according to following preparation method:
A, unsaturated polyester resin, dispersion agent, defoamer, esters of acrylic acid flow agent, Resorcinol are added in container and disperse to stir under the speed of 600-800 rev/min;
B, in order rutile titanium white powder, talcum powder, water-ground limestone, aerosil, Zinic stearas are added in said vesse under the speed of 600-800 rev/min, then disperse to stir under the speed of 1000-1200 rev/min;
C, under the speed of 600-800 rev/min, in order silicone based flow agent, aldehyde ketone resin liquid, vinylbenzene to be added in said vesse dispersion under the speed of 600-800 rev/min to stir preparation winner paint;
(2), by the main paint of above-mentioned preparation be divided into two equal portions, then promotor added in the main paint of a copy of it and mix, initiator is added in another part of main paint and mix, after being mixed by above-mentioned two parts of main paints during use, be sprayed at fiberboard ground.
Aldehyde ketone resin modified unsaturated polyester priming paint tool prepared by the present invention has the following advantages: the aldehyde ketone resin modified unsaturated polyester primer applications adopting component of the present invention and proportioning to combine preparation does not need ground of polishing when fiberboard ground, can direct spraying, and after spraying, there is excellent sticking power and fullness ratio, decrease working procedure simultaneously, save time and cost, add working efficiency.Described adhesion promoter can promote the sticking power of unsaturated polyester varnish and fiberboard ground.
The unsaturated polyester primer applications used in the market must obtain at the bottom of first with PU when fiberboard ground preciously carries out sealing process to ground, just can carry out the construction of unsaturated polyester priming paint after dry polishing, otherwise surperficial paint film is uneven does not even have paint film.The present invention reduces processing step, saved resource, improve efficiency.
The present invention realizes the fullness ratio of aldehyde ketone resin modified unsaturated polyester priming paint excellence and sticking power like this: by adding aldehyde ketone resin component in unsaturated polyester varnish, aldehyde ketone resin when unsaturated polyester varnish is constructed on fiberboard ground in paint film, wooden eye sealing, can not absorb the paint film of unsaturated polyester and go in wooden eye and reach excellent fullness ratio and sticking power.
Aldehyde ketone resin modified unsaturated polyester priming paint of the present invention also has the following advantages:
(1), the normal temperature solidified film forming of aldehyde ketone resin modified unsaturated polyester priming paint of the present invention.
(2), aldehyde ketone resin modified unsaturated polyester priming paint of the present invention can at the wood furniture surface direct spraying by corresponding construction technology process.
(3), aldehyde ketone resin modified unsaturated polyester priming paint of the present invention has excellent sticking power; solve that the white unsaturated polyester priming paint of not polishing for poly cyanamid ground does not grind, the phenomenon of poor adhesive force; be used in wood furniture and do coating protection on the surface, there is good sticking power and excellent mechanical property.
(4), aldehyde ketone resin modified unsaturated polyester priming paint of the present invention is simple to operate, and application property is good.
(5), the film performance of aldehyde ketone resin modified unsaturated polyester priming paint of the present invention is excellent.
Embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail.
(1) embodiment is as follows:
A kind of aldehyde ketone resin modified unsaturated polyester priming paint, is mixed by the weight ratio of 100:1.0-1.5:1.2-1.7 by main paint, initiator, promotor, wherein main paint, initiator, promotor respectively by following component and ratio of weight and number formulated:
Wherein the component of main paint and ratio of weight and number as follows:
Promotor is cobalt naphthenate;
Initiator is methylethyl ketone peroxide.
A preparation method for aldehyde ketone resin modified unsaturated polyester priming paint, comprises following step:
(1), main paint is prepared according to following preparation method:
A, unsaturated polyester resin, dispersion agent, defoamer, esters of acrylic acid flow agent, Resorcinol are added in container and disperse to stir under the speed of 600-800 rev/min;
B, in order rutile titanium white powder, talcum powder, water-ground limestone, aerosil, Zinic stearas are added in said vesse under the speed of 600-800 rev/min, then disperse to stir under the speed of 1000-1200 rev/min;
C, under the speed of 600-800 rev/min, in order silicone based flow agent, aldehyde ketone resin liquid, vinylbenzene to be added in said vesse dispersion under the speed of 600-800 rev/min to stir preparation winner paint;
(2), by the main paint of above-mentioned preparation be divided into two equal portions, then promotor added in the main paint of a copy of it and mix, initiator is added in another part of main paint and mix, after being mixed by above-mentioned two parts of main paints during use, be sprayed at fiberboard ground.
Above-mentioned unsaturated polyester resin adopts Changxing production of resins admittedly containing the unsaturated polyester resin for 75%-80%.The DN-PWS type dispersion agent that described dispersion agent adopts Song Wei company to produce.The massfraction that Resorcinol adopts Dezhou Xin Quan company to produce is the Resorcinol liquid of 10%.The OX880 type acrylate defoamer that described defoamer adopts Asahi Kasei Corporation to produce.The EFKA3777 type esters of acrylic acid flow agent that described flow agent adopts EFKA company to produce and German Bi Ke company produce the silicone based flow agent of BYK333 type.Described toner adopts Clariant Corporation to produce.Described water-ground limestone is the production of agriculture-countryside-farmer company.Described talcum powder is that Lan Die company produces.Described aerosil is that Cabot Co., Ltd produces, in white powder, and can unrestricted flow.Described Zinic stearas is that hundred Li He companies produce.The massfraction of described aldehyde ketone resin liquid employing N-BUTYL ACETATE melt into is the aldehyde ketone resin liquid of 50%.Described vinylbenzene is monomer.Described often kind of component also can adopt other type product similar.
(2) embodiment is as follows:
Embodiment 1: a kind of aldehyde ketone resin modified unsaturated polyester priming paint, is mixed by the weight ratio of 100:1.0:1.2 by main paint, initiator, promotor, wherein main paint, initiator, promotor respectively by following component and ratio of weight and number formulated:
Wherein the component of main paint and ratio of weight and number as follows:
Promotor is cobalt naphthenate;
Initiator is methylethyl ketone peroxide.
A preparation method for aldehyde ketone resin modified unsaturated polyester priming paint, comprises following step:
(1), main paint is prepared according to following preparation method:
A, unsaturated polyester resin 37.0 parts, dispersion agent 0.3 part, acrylate defoamer 0.1 part, esters of acrylic acid flow agent 0.2 part, Resorcinol 0.03 part are added in container and disperse to stir under the speed of 600 revs/min;
B, in order 7.0 parts, rutile titanium white powder, talcum powder 15.0 parts, water-ground limestone 30.0 parts, aerosil 0.2 part, Zinic stearas 3.0 parts are added in said vesse under the speed of 600 revs/min, then disperse to stir under the speed of 1000 revs/min;
C, under the speed of 600 revs/min, in order silicone based flow agent 0.2 part, aldehyde ketone resin liquid 5.0 parts, vinylbenzene 2.0 parts to be added in said vesse dispersion under the speed of 600 revs/min to stir preparation winner paint;
(2), by the main paint of above-mentioned preparation be divided into two equal portions, then promotor added in the main paint of a copy of it and mix, initiator is added in another part of main paint and mix, after being mixed by above-mentioned two parts of main paints during use, be sprayed at fiberboard ground.
Above-mentioned unsaturated polyester resin adopts Changxing production of resins admittedly containing the unsaturated polyester resin for 75%-80%.The DN-PWS type dispersion agent that described dispersion agent adopts Song Wei company to produce.The massfraction that Resorcinol adopts Dezhou Xin Quan company to produce is the Resorcinol liquid of 10%.The OX880 type acrylate defoamer that described defoamer adopts Asahi Kasei Corporation to produce.The EFKA3777 type esters of acrylic acid flow agent that described flow agent adopts EFKA company to produce and German Bi Ke company produce the silicone based flow agent of BYK333 type.Described toner adopts Clariant Corporation to produce.Described water-ground limestone is the production of agriculture-countryside-farmer company.Described talcum powder is that Lan Die company produces.Described aerosil is that Cabot Co., Ltd produces, in white powder, and can unrestricted flow.Described Zinic stearas is that hundred Li He companies produce.The massfraction of described aldehyde ketone resin liquid employing N-BUTYL ACETATE melt into is the aldehyde ketone resin liquid of 50%.Described vinylbenzene is monomer.
Embodiment 2: a kind of aldehyde ketone resin modified unsaturated polyester priming paint, is mixed by the weight ratio of 100:1.3:1.5 by main paint, initiator, promotor, wherein main paint, initiator, promotor respectively by following component and ratio of weight and number formulated:
Wherein the component of main paint and ratio of weight and number as follows:
Promotor is cobalt naphthenate;
Initiator is methylethyl ketone peroxide.
A preparation method for aldehyde ketone resin modified unsaturated polyester priming paint, comprises following step:
(1), main paint is prepared according to following preparation method:
A, unsaturated polyester resin 40.0 parts, dispersion agent 0.2 part, acrylate defoamer 0.2 part, esters of acrylic acid flow agent 0.3 part, Resorcinol 0.04 part are added in container and disperse to stir under the speed of 800 revs/min;
B, in order 10.0 parts, rutile titanium white powder, talcum powder 12.0 parts, water-ground limestone 20.0 parts, aerosil 0.3 part, Zinic stearas 4.0 parts are added in said vesse under the speed of 800 revs/min, then disperse to stir under the speed of 1200 revs/min;
C, under the speed of 800 revs/min, in order silicone based flow agent 0.3 part, aldehyde ketone resin liquid 10.0 parts, vinylbenzene 3.0 parts to be added in said vesse dispersion under the speed of 800 revs/min to stir preparation winner paint;
(2), by the main paint of above-mentioned preparation be divided into two equal portions, then promotor added in the main paint of a copy of it and mix, initiator is added in another part of main paint and mix, after being mixed by above-mentioned two parts of main paints during use, be sprayed at fiberboard ground.
Above-mentioned unsaturated polyester resin adopts Changxing production of resins admittedly containing the unsaturated polyester resin for 75%-80%.The DN-PWS type dispersion agent that described dispersion agent adopts Song Wei company to produce.The massfraction that Resorcinol adopts Dezhou Xin Quan company to produce is the Resorcinol liquid of 10%.The OX880 type acrylate defoamer that described defoamer adopts Asahi Kasei Corporation to produce.The EFKA3777 type esters of acrylic acid flow agent that described flow agent adopts EFKA company to produce and German Bi Ke company produce the silicone based flow agent of BYK333 type.Described toner adopts Clariant Corporation to produce.Described water-ground limestone is the production of agriculture-countryside-farmer company.Described talcum powder is that Lan Die company produces.Described aerosil is that Cabot Co., Ltd produces, in white powder, and can unrestricted flow.Described Zinic stearas is that hundred Li He companies produce.The massfraction of described aldehyde ketone resin liquid employing N-BUTYL ACETATE melt into is the aldehyde ketone resin liquid of 50%.Described vinylbenzene is monomer.
Embodiment 3: a kind of aldehyde ketone resin modified unsaturated polyester priming paint, is mixed by the weight ratio of 100:1.5:1.7 by main paint, initiator, promotor, wherein main paint, initiator, promotor respectively by following component and ratio of weight and number formulated:
Wherein the component of main paint and ratio of weight and number as follows:
Promotor is cobalt naphthenate;
Initiator is methylethyl ketone peroxide.
A preparation method for aldehyde ketone resin modified unsaturated polyester priming paint, comprises following step:
(1), main paint is prepared according to following preparation method:
A, unsaturated polyester resin 45.0 parts, dispersion agent 0.1 part, acrylate defoamer 0.3 part, esters of acrylic acid flow agent 0.3 part, Resorcinol 0.05 part are added in container and disperse to stir under the speed of 700 revs/min;
B, in order 12.0 parts, rutile titanium white powder, talcum powder 8.0 parts, water-ground limestone 10.0 parts, aerosil 0.4 part, Zinic stearas 5.0 parts are added in said vesse under the speed of 700 revs/min, then disperse to stir under the speed of 1200 revs/min;
C, under the speed of 700 revs/min, in order silicone based flow agent 0.4 part, aldehyde ketone resin liquid 15.0 parts, vinylbenzene 4.0 parts to be added in said vesse dispersion under the speed of 700 revs/min to stir preparation winner paint;
(2), by the main paint of above-mentioned preparation be divided into two equal portions, then promotor added in the main paint of a copy of it and mix, initiator is added in another part of main paint and mix, after being mixed by above-mentioned two parts of main paints during use, be sprayed at fiberboard ground.
Above-mentioned unsaturated polyester resin adopts Changxing production of resins admittedly containing the unsaturated polyester resin for 75%-80%.The DN-PWS type dispersion agent that described dispersion agent adopts Song Wei company to produce.The massfraction that Resorcinol adopts Dezhou Xin Quan company to produce is the Resorcinol liquid of 10%.The OX880 type acrylate defoamer that described defoamer adopts Asahi Kasei Corporation to produce.The EFKA3777 type esters of acrylic acid flow agent that described flow agent adopts EFKA company to produce and German Bi Ke company produce the silicone based flow agent of BYK333 type.Described toner adopts Clariant Corporation to produce.Described water-ground limestone is the production of agriculture-countryside-farmer company.Described talcum powder is that Lan Die company produces.Described aerosil is that Cabot Co., Ltd produces, in white powder, and can unrestricted flow.Described Zinic stearas is that hundred Li He companies produce.The massfraction of described aldehyde ketone resin liquid employing N-BUTYL ACETATE melt into is the aldehyde ketone resin liquid of 50%.Described vinylbenzene is monomer.
Through the test to the present embodiment, every technical performance index of aldehyde ketone resin modified unsaturated polyester priming paint of the present invention and experimental data are as follows respectively shown in table (remarks: 1 grade is best, 10 grades are the poorest):
| Project | Sticking power | Film thickness | Paint film effect | Fullness ratio |
| Commercially available prod | 4 grades | 35μm | Uneven, skinny and wizened | 9 grades |
| Embodiment 1 | 2 grades | 60μm | Flat smooth | 3 grades |
| Embodiment 2 | 2 grades | 65μm | Flat smooth | 2 grades |
| Embodiment 3 | 2 grades | 70μm | Flat smooth | 1 grade |
Test result from the above embodiments: aldehyde ketone resin modified unsaturated polyester primer applications prepared by the present invention does not need ground of polishing when fiberboard ground, can direct spraying, and after spraying, there is excellent sticking power and fullness ratio.
Above-mentioned embodiment is just explained in detail technical scheme of the present invention, and the present invention has more than and is only confined to above-described embodiment, and every any improvement according to the principle of the invention or replacement, all should within protection scope of the present invention.
Claims (7)
1. an aldehyde ketone resin modified unsaturated polyester priming paint, it is characterized in that, mixed by the weight ratio of 100:1.0-1.5:1.2-1.7 by main paint, initiator, promotor, wherein main paint, initiator, promotor respectively by following component and ratio of weight and number formulated:
Wherein the component of main paint and ratio of weight and number as follows:
Promotor is cobalt naphthenate;
Initiator is methylethyl ketone peroxide.
2. aldehyde ketone resin modified unsaturated polyester priming paint according to claim 1, it is characterized in that: described unsaturated polyester resin is the chain macromolecule compound with ester bond ester bond and unsaturated double-bond of the unsaturated dibasic alcohol polycondensation of unsaturated dibasic acid dibasic alcohol or monounsaturated dicarboxylic acid, described unsaturated polyester resin is admittedly containing being 75%-80%.
3. aldehyde ketone resin modified unsaturated polyester priming paint according to claim 1, is characterized in that: described aldehyde ketone resin liquid be with the massfraction of N-BUTYL ACETATE melt into be 50% aldehyde ketone resin liquid.
4. aldehyde ketone resin modified unsaturated polyester priming paint according to claim 1, is characterized in that: described Resorcinol be with N-BUTYL ACETATE dissolved dilution become massfraction be 10% Resorcinol liquid.
5. aldehyde ketone resin modified unsaturated polyester priming paint according to claim 1, is characterized in that: described defoamer is acrylate defoamer.
6. aldehyde ketone resin modified unsaturated polyester priming paint according to claim 1, is characterized in that: described silicone based flow agent be with the massfraction that N-BUTYL ACETATE is diluted to be 10% silicone based flow agent liquid.
7. a preparation method for the aldehyde ketone resin modified unsaturated polyester priming paint according to any one of claim 1-6, is characterized in that: comprise following step:
(1), main paint is prepared according to following preparation method:
A, unsaturated polyester resin, dispersion agent, defoamer, esters of acrylic acid flow agent, Resorcinol are added in container and disperse to stir under the speed of 600-800 rev/min;
B, in order rutile titanium white powder, talcum powder, water-ground limestone, aerosil, Zinic stearas are added in said vesse under the speed of 600-800 rev/min, then disperse to stir under the speed of 1000-1200 rev/min;
C, under the speed of 600-800 rev/min, in order silicone based flow agent, aldehyde ketone resin liquid, vinylbenzene to be added in said vesse dispersion under the speed of 600-800 rev/min to stir preparation winner paint;
(2), by the main paint of above-mentioned preparation be divided into two equal portions, then promotor added in the main paint of a copy of it and mix, initiator is added in another part of main paint and mix, during use, above-mentioned two parts of main paints are mixed rear spraying.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410766538.3A CN104497814A (en) | 2014-12-11 | 2014-12-11 | Aldehyde-ketone resin modified unsaturated polyester primer and preparation method thereof |
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| CN201410766538.3A CN104497814A (en) | 2014-12-11 | 2014-12-11 | Aldehyde-ketone resin modified unsaturated polyester primer and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105086785A (en) * | 2015-08-26 | 2015-11-25 | 成都展辰涂料有限公司 | Unsaturated polyester transparent primer for construction in high-humidity environment |
| CN107163205A (en) * | 2017-05-12 | 2017-09-15 | 常州大学 | A kind of unsaturated polyester (UP) performed polymer of ketone group containing and its production and use |
| CN107502046A (en) * | 2017-10-23 | 2017-12-22 | 惠州市华泓新材料股份有限公司 | A kind of environment-friendly type UV offset inks and preparation method thereof |
| WO2019155287A1 (en) * | 2018-02-08 | 2019-08-15 | Guangdong Huarun Paints Co., Ltd. | Ketone-aldehyde modified resin and the preparation process thereof |
| CN114634750A (en) * | 2022-03-22 | 2022-06-17 | 福建汇益家居用品有限公司 | Spray paint for artware and preparation method |
| CN114854299A (en) * | 2022-05-27 | 2022-08-05 | 广东深展实业有限公司 | Vacuum coating 2K primer for unsaturated polyester workpiece and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086785A (en) * | 2015-08-26 | 2015-11-25 | 成都展辰涂料有限公司 | Unsaturated polyester transparent primer for construction in high-humidity environment |
| CN107163205A (en) * | 2017-05-12 | 2017-09-15 | 常州大学 | A kind of unsaturated polyester (UP) performed polymer of ketone group containing and its production and use |
| CN107163205B (en) * | 2017-05-12 | 2019-03-22 | 常州大学 | A kind of unsaturated polyester (UP) performed polymer of ketone group containing and its preparation method and application |
| CN107502046A (en) * | 2017-10-23 | 2017-12-22 | 惠州市华泓新材料股份有限公司 | A kind of environment-friendly type UV offset inks and preparation method thereof |
| CN107502046B (en) * | 2017-10-23 | 2020-08-04 | 惠州市华泓新材料股份有限公司 | Environment-friendly UV offset printing ink and preparation method thereof |
| WO2019155287A1 (en) * | 2018-02-08 | 2019-08-15 | Guangdong Huarun Paints Co., Ltd. | Ketone-aldehyde modified resin and the preparation process thereof |
| US11692059B2 (en) | 2018-02-08 | 2023-07-04 | Guangdong Huarun Paints Co., Ltd. | Ketone-aldehyde modified resin and the preparation process thereof |
| CN114634750A (en) * | 2022-03-22 | 2022-06-17 | 福建汇益家居用品有限公司 | Spray paint for artware and preparation method |
| CN114854299A (en) * | 2022-05-27 | 2022-08-05 | 广东深展实业有限公司 | Vacuum coating 2K primer for unsaturated polyester workpiece and preparation method thereof |
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Application publication date: 20150408 |