CN104559698B - A kind of color inhibition UV transparent primings for electrostatic spraying - Google Patents
A kind of color inhibition UV transparent primings for electrostatic spraying Download PDFInfo
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- CN104559698B CN104559698B CN201410755595.1A CN201410755595A CN104559698B CN 104559698 B CN104559698 B CN 104559698B CN 201410755595 A CN201410755595 A CN 201410755595A CN 104559698 B CN104559698 B CN 104559698B
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- acrylate
- defoamer
- dispersant
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- filler
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
Abstract
The invention discloses a kind of color inhibition UV transparent primings for electrostatic spraying, it is made up of amino modified polyester acrylate, pure acrylate, monomer, filler, light trigger, defoamer, dispersant, anti-settling agent, silica, solvent, each component and its percentage by weight are as follows：Amino modified polyester acrylate 25 ~ 32%, pure acrylate 3 ~ 8%, monomer 25 ~ 40%, filler 5 ~ 12%, light trigger 3 ~ 5%, defoamer 0.1 ~ 0.5%, dispersant 0.2 ~ 0.8%, anti-settling agent 0.1 ~ 0.5%, silica 0.5 ~ 2%, solvent 20 ~ 25%, wherein the amino modified polyester acrylate is rich prosperous 7096 amino mixed polyester；The pure acrylate is Changxing 6071；The solvent is one or two in ethyl acetate, butyl acetate.Priming paint is done using the UV transparent primings, overall japanning efficiency can be greatly enhanced, meet the coating specification of all kinds of irregular shape base materials, reduce the loss of coating to greatest extent simultaneously, save and apply ETL estimated time of loading and artificial, raising coating efficiency, be that enterprise creates bigger profit value.
Description
Technical field
The present invention relates to chemistry painting industry field, a kind of more particularly to color inhibition UV clear bottoms for electrostatic spraying
Paint.
Background technology
UV paints are photocureable coating, and it is to apply more extensive furniture lacquer at present, and main feature has：By intensive ultraviolet
Photocuring is processed, color stability, for a long time Chang Xin.So be widely used at aspects such as cabinet family property timbers, cabinet family property in recent years
Timber etc. combines base material using irregular shape, can improve aesthetic property of its outward appearance etc..But general UV paints are not advised this
Construction is then difficult on the base material of shape, traditional way is by after mechanical grinding treatment, then spraying PU priming paint transition.So make
Increase into operation, man-hour lengthens, and is painted using PU, a large amount of organic solvent pollution air of release, overall efficiency and benefit are not
It is high.
The content of the invention
In order to solve above-mentioned the deficiencies in the prior art, can be sprayed on not using electrostatic spraying mode the invention provides one kind
Color inhibition UV transparent primings on regular shape base material, priming paint is made using the color inhibition UV transparent primings for being used for electrostatic spraying,
Overall japanning efficiency can be greatly enhanced, the coating specification of all kinds of irregular shape base materials be met, while subtracting to greatest extent
The loss of few coating, saves and applies ETL estimated time of loading with manually, improves coating efficiency, is that enterprise creates bigger profit value.
The technical problems to be solved by the invention are achieved by the following technical programs：
A kind of color inhibition UV transparent primings for electrostatic spraying, by amino modified polyester acrylate, pure acrylate,
Monomer, filler, light trigger, defoamer, dispersant, anti-settling agent, silica, solvent composition, each component and its weight hundred
Divide ratio as follows：
Amino modified polyester acrylate 25 ~ 32%
Pure acrylate 3 ~ 8%
Monomer 25 ~ 40%
Filler 5 ~ 12%
Light trigger 3 ~ 5%
Defoamer 0.1 ~ 0.5%
Dispersant 0.2 ~ 0.8%
Anti-settling agent 0.1 ~ 0.5%
Silica 0.5 ~ 2%
Solvent 20 ~ 25%；
Wherein, the amino modified polyester acrylate is rich prosperous 7096 amino mixed polyester；The pure acrylate is
Changxing 6071；The solvent is one or two in ethyl acetate, butyl acetate.
Preferably, a kind of color inhibition UV transparent primings each component and its percentage by weight for electrostatic spraying is as follows：
Amino modified polyester acrylate 27 ~ 30%
Pure acrylate 4 ~ 8%
Monomer 30 ~ 40%
Filler 5 ~ 10%
Light trigger 3 ~ 5%
Defoamer 0.1 ~ 0.5%
Dispersant 0.3 ~ 0.8%
Anti-settling agent 0.1 ~ 0.5%
Silica 0.5 ~ 2%
Solvent 20 ~ 23%.
Preferably, a kind of color inhibition UV transparent primings each component and its percentage by weight for electrostatic spraying is as follows：
Amino modified polyester acrylate 28%
Pure acrylate 6%
Monomer 25%
Filler 10%
Light trigger 5%
Defoamer 0.5%
Dispersant 0.5%
Anti-settling agent 0.5%
Silica 1 .5%
Solvent 23%.
Preferably, a kind of color inhibition UV transparent primings each component and its percentage by weight for electrostatic spraying is as follows：
Amino modified polyester acrylate 29%
Pure acrylate 5%
Monomer 28%
Filler 8%
Light trigger 5%
Defoamer 0.2%
Dispersant 0.5%
Anti-settling agent 0.3%
Silica 2%
Solvent 22%.
In the above-mentioned color inhibition UV transparent primings for electrostatic spraying, the amino modified polyester acrylate is preferably used
Rich prosperous 7096 amino mixed polyester, hardness is high, and transparency has well paint film rigidity higher, while having excellent yellowing resistance
Energy；The pure acrylate is an ester oligomer containing solvent-type acrylic preferably with Changxing 6071,6071, with preferably soft
Toughness, xanthochromia is good, has good adhesive force to plastic rubber substrate, metal and aluminium paint, is applicable the light such as the spraying of UV plastic cement, plating
In oil；The pure acrylate has low-down shrinkage simultaneously, greatly reduces the shrinkage stress of system, improves paint film attached
Put forth effort；Relatively low viscosity plays reduction paint viscosity, workability is reached requirement.
The monomer is tri (propylene glycol) diacrylate（TPGDA）, trimethylolpropane trimethacrylate
（TMPTA）, 1,6 hexanediyl esters（HDDA）, hydroxyethyl methacrylate（HEMA）In one or more；Play drop
Low viscosity, improves the effect of adhesive force.
The filler is one or more of talcum powder, calcium carbonate, transparent powder, zinc stearate.
The light trigger is 1- hydroxyls-cyclohexyl-phenyl ketone（184）, 2- hydroxy-2-methyl -1- phenyl -1- acetone
（1173）In one or more.
The defoamer is efficient acrylic acid defoamer（Such as Tego920）；The dispersant is efficient acrylic acid
Dispersant（Such as BYK2009, EFKA4010）.
The anti-settling agent is one or more in efficient organobentonite, Tissuemat E, aerosil.
The present invention has the advantages that：The painting method commonly used according to those skilled in the art makes above-mentioned material
Into photocureable priming coat, applied with electrostatic spraying mode and be attached on irregular shape base material, it is not necessary to the direct rapid curing of levelling, can pole
Big improve production efficiency.Its yellowing resistance is tested after solidification, the present market demand can be met completely.As common wealth furniture factory adopts
Painting construction with PU can produce 2000m daily2Plate；And 4000m can reach using the UV priming paint2Plate, without levelling line and treating
Dry place, can reduce the loss during coating application and can save the investment of production storehouse.
Specific embodiment
The color inhibition UV transparent primings for electrostatic spraying of the invention are described in detail with reference to embodiment.
Embodiment 1
A kind of color inhibition UV transparent primings for electrostatic spraying, each component and its percentage by weight are as follows：
Amino modified polyester acrylate 25%
Pure acrylate 4%
Monomer 30%
Filler 12%
Light trigger 3%
Defoamer 0.1%
Dispersant 0.2%
Anti-settling agent 0.2%
Silica 0.5%
Solvent 25%；
Wherein, the amino modified polyester acrylate is rich prosperous 7096 amino mixed polyester；The pure acrylate is
Changxing 6071；The monomer is tri (propylene glycol) diacrylate；The filler is talcum powder；The light trigger is 1-
Hydroxyl-cyclohexyl-phenyl ketone；The defoamer is acrylic acid defoamer；The dispersant is acrylic acid dispersant；It is used anti-
Heavy agent is organobentonite；The solvent is ethyl acetate.The painting method commonly used according to those skilled in the art is by above-mentioned material
Material is fabricated to photocureable priming coat, is applied with electrostatic spraying mode and is attached on irregular shape base material, and carries out performance test, as a result sees
Table 1.
Embodiment 2
A kind of color inhibition UV transparent primings for electrostatic spraying, each component and its percentage by weight are as follows：
Amino modified polyester acrylate 26%
Pure acrylate 4%
Monomer 33%
Filler 8%
Light trigger 3%
Defoamer 0.1%
Dispersant 0.4%
Anti-settling agent 0.5%
Silica 1 %
Solvent 24%；
Wherein, the amino modified polyester acrylate is rich prosperous 7096 amino mixed polyester；The pure acrylate is
Changxing 6071；The monomer is trimethylolpropane trimethacrylate；The filler is calcium carbonate；The light trigger is 2-
Hydroxy-2-methyl -1- phenyl -1- acetone；The defoamer is acrylic acid defoamer；The dispersant is acrylic acid dispersant；
Anti-settling agent used is Tissuemat E；The solvent is butyl acetate.The painting method commonly used according to those skilled in the art will be upper
State material and be fabricated to photocureable priming coat, applied with electrostatic spraying mode and be attached on irregular shape base material, and carry out performance test, tie
Fruit is shown in Table 1.
Embodiment 3
A kind of color inhibition UV transparent primings for electrostatic spraying, each component and its percentage by weight are as follows：
Amino modified polyester acrylate 27%
Pure acrylate 4%
Monomer 40%
Filler 5%
Light trigger 3%
Defoamer 0.1%
Dispersant 0.3%
Anti-settling agent 0.1%
Silica 0.5%
Solvent 20%；
Wherein, the amino modified polyester acrylate is rich prosperous 7096 amino mixed polyester；The pure acrylate is
Changxing 6071；The monomer is 1,6 hexanediyl esters；The filler is transparent powder；The light trigger is 1- hydroxyls
Base-cyclohexyl-phenyl ketone；The defoamer is acrylic acid defoamer；The dispersant is acrylic acid dispersant；It is used anti-settling
Agent is aerosil；The solvent is ethyl acetate.The painting method commonly used according to those skilled in the art is by above-mentioned material
Material is fabricated to photocureable priming coat, is applied with electrostatic spraying mode and is attached on irregular shape base material, and carries out performance test, as a result sees
Table 1.
Embodiment 4
A kind of color inhibition UV transparent primings for electrostatic spraying, each component and its percentage by weight are as follows：
Amino modified polyester acrylate 28%
Pure acrylate 6%
Monomer 25%
Filler 10%
Light trigger 5%
Defoamer 0.5%
Dispersant 0.5%
Anti-settling agent 0.5%
Silica 1 .5%
Solvent 23%；
Wherein, the amino modified polyester acrylate is rich prosperous 7096 amino mixed polyester；The pure acrylate is
Changxing 6071；The monomer is tri (propylene glycol) diacrylate 15% mixed with trimethylolpropane trimethacrylate 10%
Close；The filler is the mixing of talcum powder 5% and calcium carbonate 5%；The light trigger is 1- hydroxyls-cyclohexyl-phenyl ketone
2% with the mixing of 2- hydroxy-2-methyl -1- phenyl -1- acetone 3%；The defoamer is acrylic acid defoamer；The dispersant is
Acrylic acid dispersant；Anti-settling agent used is aerosil；The solvent is ethyl acetate 13% mixed with butyl acetate 10%
Close.Above-mentioned material is fabricated to photocureable priming coat by the painting method commonly used according to those skilled in the art, uses electrostatic spraying mode
Painting is attached on irregular shape base material, and carries out performance test, the results are shown in Table 1.
Embodiment 5
A kind of color inhibition UV transparent primings for electrostatic spraying, each component and its percentage by weight are as follows：
Amino modified polyester acrylate 29%
Pure acrylate 5%
Monomer 28%
Filler 8%
Light trigger 5%
Defoamer 0.2%
Dispersant 0.5%
Anti-settling agent 0.3%
Silica 2%
Solvent 22%；
Wherein, the amino modified polyester acrylate is rich prosperous 7096 amino mixed polyester；The pure acrylate is
Changxing 6071；The monomer is hydroxyethyl methacrylate；The filler is zinc stearate；The light trigger is 2- hydroxyls
Base -2- methyl isophthalic acids-phenyl -1- acetone；The defoamer is acrylic acid defoamer；The dispersant is acrylic acid dispersant；Institute
It is aerosil with anti-settling agent；The solvent is ethyl acetate.The painting method commonly used according to those skilled in the art will
Above-mentioned material is fabricated to photocureable priming coat, is applied with electrostatic spraying mode and is attached on irregular shape base material, and carries out performance test,
The results are shown in Table 1.
Embodiment 6
A kind of color inhibition UV transparent primings for electrostatic spraying, each component and its percentage by weight are as follows：
Amino modified polyester acrylate 30%
Pure acrylate 8%
Monomer 30%
Filler 5%
Light trigger 4%
Defoamer 0.2%
Dispersant 0.8%
Anti-settling agent 0.5%
Silica 1 .5%
Solvent 20%；
Wherein, the amino modified polyester acrylate is rich prosperous 7096 amino mixed polyester；The pure acrylate is
Changxing 6071；During the monomer is hydroxyethyl methacrylate；The filler is transparent powder；The light trigger is 2- hydroxyls
Base -2- methyl isophthalic acids-phenyl -1- acetone；The defoamer is acrylic acid defoamer；The dispersant is acrylic acid dispersant；Institute
It is aerosil with anti-settling agent；The solvent is butyl acetate.The painting method commonly used according to those skilled in the art will
Above-mentioned material is fabricated to photocureable priming coat, is applied with electrostatic spraying mode and is attached on irregular shape base material, and carries out performance test,
The results are shown in Table 1.
Embodiment 7
A kind of color inhibition UV transparent primings for electrostatic spraying, each component and its percentage by weight are as follows：
Amino modified polyester acrylate 32%
Pure acrylate 3%
Monomer 32%
Filler 7%
Initiator 3%
Defoamer 0.5%
Dispersant 0.8%
Anti-settling agent 0.5%
Silica 1 .2%
Solvent 20%；
Wherein, the amino modified polyester acrylate is rich prosperous 7096 amino mixed polyester；The pure acrylate is
Changxing 6071；The monomer is 1,6 hexanediyl esters；The filler is zinc stearate；The light trigger is 1-
Hydroxyl-cyclohexyl-phenyl ketone；The defoamer is acrylic acid defoamer；The dispersant is acrylic acid dispersant；It is used anti-
Heavy agent is organobentonite；The solvent is butyl acetate.The painting method commonly used according to those skilled in the art is by above-mentioned material
Material is fabricated to photocureable priming coat, is applied with electrostatic spraying mode and is attached on irregular shape base material, and carries out performance test, as a result sees
Table 1.
Comparative example 1
Epoxy acrylate（Changxing 6210G） 20%
Urethane acrylate（The wood 6318 of Jiangsu three） 14%
Monomer（HDDA） 28%
Filler（Talcum powder） 10%
Light trigger（2- hydroxy-2-methyl -1- phenyl -1- acetone） 5%
Defoamer（Tego920） 0.5%
Dispersant（BYK2009）0.5%
Silica 2%
Solvent（Toluene）20%.
The formulation product yellowing resistance of prior art is poor, and rigidity does not cause by force paint film resistance to scraping poor, price, while using
, used as retarder thinner, toxicity is big, and VOC volatile quantities are big for toluene, and influence workmen's is healthy, while polluting environment.
Performance test
Result of performance test is to the color inhibition UV transparent primings for electrostatic spraying prepared by each embodiment and comparative example
Performance test and evaluation are carried out, as a result as shown in table 1：
The definition of each test event and assessment method：
1st, outward appearance：Range estimation, it is good for judging whether surfacing, mirror effect, the problems such as without particle, orange peel.
2nd, adhesive force：Tested by GB/T9286-1998,0-5 grades of evaluation result point, wherein 0 is best, 5 is worst.
3rd, hardness：Detected by GB/T6739-1996 methods.Using pencil hardness rank method, i.e. 6B, 5B, 4B, 3B,
2B, B, H, B, H, 2H, 3H, 4H, 5H, 6H, 7H, 8H, 9H are represented from soft to hard.
4th, VOC content：Tested by GB18582-2008 standard methods.
5th, heat resistance：Tested by GB/T 1740-79 (89), △ is normal.
6th, resistance to 5% NaOH：Test plate (panel) is dipped in 25 DEG C of 5% NaOH solution, Visual appearance after 48 hours.
7th, resistance to 5% H2SO4：Test plate (panel) is dipped in 25 DEG C of 5% H2SO4In solution, Visual appearance after 48 hours.
From Experimental comparison results as can be seen that the present invention is by using the excellent amino mixed polyester and pure third of yellowing resistance
Olefin(e) acid resin greatly improves the yellowing resistance of product come implementation of arranging in pairs or groups, while by substituted for larger organic molten of toxicity
Agent toluene, uses ethyl acetate（Butyl acetate）, electrostatic spraying system is applicable not only to, and the body of the workmen for ensureing is good for
Kang Wenti, reaches electrostatic spraying requirement in the industry, and the quality and performance of product are improve while reducing production product.
Embodiment described above only expresses embodiments of the present invention, and its description is more specific and detailed, but can not
Therefore the limitation to the scope of the claims of the present invention is interpreted as, as long as the skill obtained in the form of equivalent or equivalent transformation
Art scheme, all should fall within the scope and spirit of the invention.
Claims (1)
1. a kind of color inhibition UV transparent primings for electrostatic spraying, by amino modified polyester acrylate, pure acrylate, list
Body, filler, light trigger, defoamer, dispersant, anti-settling agent, silica, solvent composition, each component and its weight percent
Than as follows：
Amino modified polyester acrylate 25 ~ 32%,
Pure acrylate 3 ~ 8%,
Monomer 25 ~ 40%,
Filler 5 ~ 12%,
Light trigger 3 ~ 5%,
Defoamer 0.1 ~ 0.5%,
Dispersant 0.2 ~ 0.8%,
Anti-settling agent 0.1 ~ 0.5%,
Silica 0.5 ~ 2%,
Solvent 20 ~ 25%；
Wherein, the amino modified polyester acrylate is rich prosperous 7096 amino mixed polyester；
The pure acrylate is Changxing 6071；
The solvent is one or two in ethyl acetate, butyl acetate；
The monomer is tri (propylene glycol) diacrylate, trimethylolpropane trimethacrylate, 1,6 hexanediyls
One or more in ester, hydroxyethyl methacrylate；
The filler is one or more of talcum powder, calcium carbonate, transparent powder, zinc stearate；
The light trigger is the one kind in 1- hydroxyls-cyclohexyl-phenyl ketone, 2- hydroxy-2-methyl -1- phenyl -1- acetone
Or two kinds；
The defoamer is acrylic acid defoamer；
The dispersant is acrylic acid dispersant；
The anti-settling agent is one or more in organobentonite, Tissuemat E, aerosil.
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| CN201410755595.1A CN104559698B (en) | 2014-12-11 | 2014-12-11 | A kind of color inhibition UV transparent primings for electrostatic spraying |
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|---|---|---|---|
| CN201410755595.1A CN104559698B (en) | 2014-12-11 | 2014-12-11 | A kind of color inhibition UV transparent primings for electrostatic spraying |
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| CN104559698A CN104559698A (en) | 2015-04-29 |
| CN104559698B true CN104559698B (en) | 2017-06-06 |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105482681A (en) * | 2016-01-19 | 2016-04-13 | 卓达新材料科技集团有限公司 | UV (ultraviolet) building coating and preparation method thereof |
| CN105670463B (en) * | 2016-04-11 | 2017-12-01 | 广东深展实业有限公司 | A kind of ultraviolet-curing vacuum coating metal primer of electrostatically sprayable |
| CN106634459A (en) * | 2016-11-22 | 2017-05-10 | 天长市金陵电子有限责任公司 | UV-curing electrostatic spraying paint |
| CN107011748B (en) * | 2017-04-24 | 2019-11-05 | 深圳铭锋达精密技术有限公司 | Glass inorganic agent and its application for glass plastic rubber member surface spray treatment |
| CN109437589A (en) * | 2018-11-12 | 2019-03-08 | 浙江中港玻璃有限公司 | A kind of production technology of glass |
| CN112210263A (en) * | 2020-09-18 | 2021-01-12 | 东来涂料技术（上海）股份有限公司 | UV-cured coating with water-drop-shaped effect and preparation method thereof |
| CN114539837B (en) * | 2022-04-12 | 2022-12-02 | 浙江宇豪新材料股份有限公司 | Sun-proof paint for dyed wood and coating method thereof |
| CN115960504B (en) * | 2022-11-30 | 2024-03-26 | 河南立邦长润发科技材料有限公司 | UV adhesive force primer for triamine paper and preparation method thereof |
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| CN101591484A (en) * | 2009-06-23 | 2009-12-02 | 浜二（宜昌）涂料有限公司 | A kind of photocureable coating for pianos |
| CN103013324A (en) * | 2012-12-21 | 2013-04-03 | 湖南松井新材料有限公司 | Self-repairing type ultraviolet light polymerization varnish |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005031271A1 (en) * | 2005-07-05 | 2007-01-18 | Degussa Ag | Process for the preparation of radiation-curable formulations with increased corrosion protection on metal substrates and such formulations |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101591484A (en) * | 2009-06-23 | 2009-12-02 | 浜二（宜昌）涂料有限公司 | A kind of photocureable coating for pianos |
| CN103013324A (en) * | 2012-12-21 | 2013-04-03 | 湖南松井新材料有限公司 | Self-repairing type ultraviolet light polymerization varnish |
| CN104073040A (en) * | 2014-07-15 | 2014-10-01 | 苏州市明大高分子科技材料有限公司 | UV-cured white curtaining paint and preparation method thereof |
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