CN104559741B - UV (ultraviolet) finishing varnish for laser roller coating - Google Patents

UV (ultraviolet) finishing varnish for laser roller coating Download PDF

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Publication number
CN104559741B
CN104559741B CN201410749717.6A CN201410749717A CN104559741B CN 104559741 B CN104559741 B CN 104559741B CN 201410749717 A CN201410749717 A CN 201410749717A CN 104559741 B CN104559741 B CN 104559741B
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Prior art keywords
radium
monomer
acrylate
weight
auxiliary agent
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CN201410749717.6A
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CN104559741A (en
Inventor
陈明
练世斌
戴超
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Guangdong Libang Changrunfa Science And Technology Material Co ltd
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TIANJIN CHANGRUNFA CHEMICAL Co Ltd
Huizhou Changrunfa Coating Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a UV (ultraviolet) finishing varnish for laser roller coating, which comprises the following raw materials in percentage by weight: 30-40% of polyurethane acrylate, 20-30% of epoxy acrylate, 30-36% of monomer, 1-7% of photoinitiator and 1-3% of assistant. The materials above can be made into the UV finishing varnish according to the common paint preparation method for technical personnel of the field. The UV finishing varnish can be coated on a substrate by laser rollers, wherein the coating weight is 30-50 g/m<2>, and the leveling time at 50 DEG C is 1-2 minutes; the UV finishing varnish can be directly cured, thereby greatly enhancing the production efficiency; and the film forming coating weight is low, thereby greatly lowering the cost. The cured UV finishing varnish can obtain excellent mirror effect, has high glossiness and high fullness, can achieve the surface effect of the PU (polyurethane) varnish, is environment-friendly, and can reduce the discharge of the organic solvent.

Description

A kind of UV glossy varnishes for radium-shine roller coat
Technical field
The present invention relates to painting field, more particularly to a kind of UV glossy varnishes for radium-shine roller coat.
Background technology
UV paints are photocureable coating, and it is to apply more extensive furniture lacquer, main feature to have at present:Through intensive ultraviolet Photocuring process, color stability, for a long time Chang Xin, environment friendly and pollution-free.UV paints mainly apply in plate fitment, and gloss varnish is in UV It is the difficult paint for doing of comparison in coating, the more difficult control in terms of construction, using spraying application waste than larger, efficiency Not high, thicker using showering film, cost is higher.In order to solve this problem, UV paints employ radium-shine in recent years(Laser) Roller application this method, it is poor to solve conventional roll overpainting richness, the bad problem of surface levelling, constructional difficulties, cost The problems such as with terms of efficiency, so as to excellent mirror effect can be reached at short notice, make roller coat UV paints reach spraying PU paints Surface effect, be the optimum selection of high-grade plate fitment.Coating can be saved, product quality and production effect can be greatly improved Rate.
But, prior art does not reach expected effect using the glossy varnish that radium-shine roller coat is made, with spraying PU paints Surface effect difference it is very remote, client is difficult to receive.Mainly deficiency is:1. there is the slivering print of weight in paint film, and levelling is undesirable, The mirror effect of PU sprayings is not reached;2. paint film is uneven, causes gloss of film uneven;3. coating weight of constructing does not increase, all In 20~30g/m2, do not reach paint film richness, brightness is not high;4. paint cost control is high, it is difficult to promote etc..These problems Prior art could not also be well solved, and be because that this is glossy varnish, belong to high finish coat varnish, it is necessary to have high light Pool, splendid mirror effect, surface have some flaws more apparent, and the dull surface paint and priming paint of similar technology is to oil on the market Paint surface effect requires, than relatively low, the more difficult discovery of surface blemish, to be easier control, so together on paint and production operation Class technology dull surface paint and priming paint have obtained good popularization, but light top coat top coat is not also promoted well.
The content of the invention
The invention solves the problems that in place of the deficiencies in the prior art, providing one kind according to the weak point of prior art problem is used for The UV glossy varnishes of radium-shine roller coat, do UV glossy varnishes with the method, can reach height in the case where film is relatively thin Richness, high levelling degree, with excellent mirror effect, not only improves overall coating efficiency and cost, and to environment friend It is good, the discharge of organic solvent can be reduced.
For solving above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of UV glossy varnishes for radium-shine roller coat, by weight, including the following raw material:Urethane acrylate 30 ~ 40%, epoxy acrylate 20 ~ 30%, monomer 30 ~ 36%, light trigger 1 ~ 7%, auxiliary agent 1 ~ 3%.
Further, above-mentioned for radium-shine(Laser)In the UV glossy varnishes of roller application, polyurethane third used Olefin(e) acid ester has extraordinary pliability, and contractility can effectively reduce the shrinkage stress of system, the raising to adhesive force than relatively low Have good assosting effect, with low optical index, to brightness in terms of have well raising, urethane acrylate can be One or more of aliphatic modified urethane acrylate, aromatic modified urethane acrylate;Epoxy acrylate is received Contracting can effectively reduce the shrinkage stress of system than relatively low, and optical index is low, to brightness in terms of have well raising.So, The present inventor's urethane acrylate commercially available to multiclass and epoxy acrylate carry out after experiment gropes, selecting following several cities The 6170 of the urethane acrylate sold, such as Changxing, the 2491 etc. of Baeyer.Following several commercially available epoxy acrylates are selected, The 6105-80 of three wood, the 622A-80 in Changxing, section Ningde 3215 etc., because these Polyurethane acrylate and epoxy acrylate Be it is commercially available, what those skilled in the art commonly used, the concrete composition of each of which commodity is all fixed, so only needing to select In this several commercially available Polyurethane acrylate and epoxy acrylate it is each any one, purchase return to add according to formula consumption It is added in the UV glossy varnish formula for radium-shine roller coat.Monomer used is tripropylene glycol dipropyl Olefin(e) acid ester(TPGDA), trimethylolpropane trimethacrylate(TMPTA), 1,6 hexanediyl esters(HDDA), ethyoxyl Change one or more in trimethylolpropane trimethacrylate (EO-TMPTA), play reduction viscosity, increase hardness and anti-scratch Property, improve the effect of adhesive force.Light trigger used is 1- hydroxyls-cyclohexyl-phenyl ketone(184), 2- hydroxy-2-methyls- 1- phenyl -1- acetone(1173), 2,4,6 (trimethylbenzoyl) diphenyl phosphine oxide(TPO)In one or more.It is used Auxiliary agent be efficient acrylic acid defoamer, such as:BYK-055 etc.;Efficient acrylic acid levelling agent, such as:BYK-358N etc..
Compared with prior art, UV glossy varnish of the present invention for radium-shine roller coat, by weight, including following original Material:Urethane acrylate 30 ~ 40%, epoxy acrylate 20 ~ 30%, monomer 30 ~ 36%, light trigger 1 ~ 7%, auxiliary agent 1 ~ 3%. Above-mentioned material is fabricated to into UV glossy varnishes according to the painting method that those skilled in the art commonly use, with radium-shine roller coat roller in base On material, coating weight is in 30 ~ 50g/m2, 50 DEG C of 1 ~ 2min of levelling, directly solidification can greatly improve production efficiency, film forming coating Measure low, great reduces cost.Splendid mirror effect can be obtained after solidification, and high glaze, high richness can reach PU lights The surface effect of paint.
Specific embodiment
Following examples are the preferred formula of UV glossy varnishes for radium-shine roller coat, and these formula are indefiniteness reality Mode is applied, which is that, for illustrating the present invention, those skilled in the art completely can be with thinking of the invention and sorting The formula that proportioning is filtered out is protection scope of the present invention.
Embodiment 1
A kind of UV glossy varnishes for radium-shine roller coat, by weight, are made up of following material:
Urethane acrylate(The 6170 of Changxing):40%,
Epoxy acrylate(The 6105-80 of three wood):20%,
Monomer(TPGDA):36%,
Light trigger:1%,
Auxiliary agent: 3%.
Above-mentioned material is fabricated to into UV glossy varnishes according to the painting method that those skilled in the art commonly use, with radium-shine (Laser), on base material, coating weight is in 30 ~ 50g/m for roller coat roller2, 50 DEG C of 1 ~ 2min of levelling, directly solidification.
Embodiment 2
A kind of UV glossy varnishes for radium-shine roller coat, by weight, are made up of following material:
Urethane acrylate(The 2491 of Baeyer):38%,
Epoxy acrylate(The 622A-80 in Changxing):22%,
Monomer(TMPTA):35%,
Light trigger:4%,
Auxiliary agent: 1%.
Above-mentioned material is fabricated to into UV glossy varnishes according to the painting method that those skilled in the art commonly use, with radium-shine (Laser), on base material, coating weight is in 30 ~ 50g/m for roller coat roller2, 50 DEG C of 1 ~ 2min of levelling, directly solidification.
Embodiment 3
A kind of UV glossy varnishes for radium-shine roller coat, by weight, are made up of following material:
Urethane acrylate(The 6170 of Changxing):36%,
Epoxy acrylate(Section Ningde 3215):24%,
Monomer(HDDA):34%,
Light trigger:5%,
Auxiliary agent: 1%.
Above-mentioned material is fabricated to into UV glossy varnishes according to the painting method that those skilled in the art commonly use, with radium-shine (Laser), on base material, coating weight is in 30 ~ 50g/m for roller coat roller2, 50 DEG C of 1 ~ 2min of levelling, directly solidification.
Embodiment 4
A kind of UV glossy varnishes for radium-shine roller coat, by weight, are made up of following material:
Urethane acrylate(The 2491 of Baeyer):34%,
Epoxy acrylate(The 6105-80 of three wood):26%,
Monomer(EO-TMPTA):35%,
Light trigger:3%,
Auxiliary agent: 2%.
Above-mentioned material is fabricated to into UV glossy varnishes according to the painting method that those skilled in the art commonly use, with radium-shine (Laser), on base material, coating weight is in 30 ~ 50g/m for roller coat roller2, 50 DEG C of 1 ~ 2min of levelling, directly solidification.
Embodiment 5
A kind of UV glossy varnishes for radium-shine roller coat, by weight, are made up of following material:
Urethane acrylate(The 6170 of Changxing):32%,
Epoxy acrylate(The 622A-80 in Changxing):28%,
Monomer(The mixing of TPGDA, TMPTA):30%,
Light trigger:7%,
Auxiliary agent: 3%.
Above-mentioned material is fabricated to into UV glossy varnishes according to the painting method that those skilled in the art commonly use, with radium-shine (Laser), on base material, coating weight is in 30 ~ 50g/m for roller coat roller2, 50 DEG C of 1 ~ 2min of levelling, directly solidification.
Embodiment 6
A kind of UV glossy varnishes for radium-shine roller coat, by weight, are made up of following material:
Urethane acrylate(The 2491 of Baeyer):30%,
Epoxy acrylate(Section Ningde 3215):30%,
Monomer(The mixing of HDDA, EO-TMPTA):35%,
Light trigger:4%,
Auxiliary agent: 1%.
Above-mentioned material is fabricated to into UV glossy varnishes according to the painting method that those skilled in the art commonly use, with radium-shine (Laser), on base material, coating weight is in 30 ~ 50g/m for roller coat roller2, 50 DEG C of 1 ~ 2min of levelling, directly solidification.
The effect of currently available technology is undesirable, does not reach good effect, essentially consists in the selection and proportioning of material Without using, for example:
Comparative example 1:
Epoxy acrylate(The 156 of double bond chemical industry):30%,
Polyester acrylate(The SM6605 of three wood):20%,
Monomer(TPGDA):45%,
Light trigger:3%,
Auxiliary agent:2%.
Above-mentioned material is fabricated to into UV glossy varnishes according to the painting method that those skilled in the art commonly use, with radium-shine (Laser), on base material, coating weight is in 30 ~ 50g/m for roller coat roller2, 50 DEG C of 1 ~ 2min of levelling, directly solidification.
Comparative example 2:
Polyester acrylate(The SM6605 of three wood):20%,
Amino acrylates(The 6119 of three wood):35%,
Monomer(TPGDA):40%,
Light trigger:4%,
Auxiliary agent: 1%.
Above-mentioned material is fabricated to into UV glossy varnishes according to the painting method that those skilled in the art commonly use, with radium-shine (Laser), on base material, coating weight is in 30 ~ 50g/m for roller coat roller2, 50 DEG C of 1 ~ 2min of levelling, directly solidification.
Comparative example 3:
Urethane acrylate(The 2491 of Baeyer):20%,
Epoxy acrylate(Section Ningde 3215):40%,
Monomer(The mixing of HDDA, EO-TMPTA):35%,
Light trigger:4%,
Auxiliary agent: 1%.
Above-mentioned material is fabricated to into UV glossy varnishes according to the painting method that those skilled in the art commonly use, with radium-shine (Laser), on base material, coating weight is in 30 ~ 50g/m for roller coat roller2, 50 DEG C of 1 ~ 2min of levelling, directly solidification.
Embodiment and comparative example traditional performance testing result, shown in following data:
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Comparative example 1 Comparative example 2 Comparative example 3
Outward appearance(Range estimation) It is water-white transparent It is water-white transparent It is water-white transparent It is water-white transparent It is water-white transparent It is water-white transparent It is water-white transparent It is water-white transparent It is water-white transparent
Film effect(Range estimation) Mirror effect Mirror effect Mirror effect Mirror effect Mirror effect Mirror effect Brightness is low Richness is poor There is slivering to print
Coating weight(Gravimetric method g/m2 30~50 30~50 30~50 30~50 30~50 30~50 20~25 20~25 20~25
Viscosity(mpa.s) 800~900 800~900 800~900 800~900 800~900 800~900 800~900 500~600 800~900
Pencil hardness 2H 2H 2H 2H 2H 2H H 3H 2H
60 glossiness 100° 100° 100° 100° 100° 100° 90° 90° 90°
Adhesive force(Cross-cut methods) ≤ 1 grade ≤ 1 grade ≤ 1 grade ≤ 1 grade ≤ 1 grade ≤ 1 grade 2 grades 2 grades 2 grades
Embodiment described above only expresses embodiments of the present invention, and its description is more concrete and detailed, but can not Therefore the restriction to the scope of the claims of the present invention is interpreted as, as long as obtained in the form of equivalent or equivalent transformation Technical scheme, all should fall within the scope and spirit of the invention.

Claims (5)

1. a kind of UV glossy varnishes for radium-shine roller coat, it is characterised in that by weight, including the following raw material:Poly- ammonia Ester acrylate 30 ~ 40%, epoxy acrylate 20 ~ 30%, monomer 30 ~ 36%, light trigger 1 ~ 7%, auxiliary agent 1 ~ 3%;
The urethane acrylate be aliphatic modified urethane acrylate, the one of aromatic modified urethane acrylate Plant or several;
The monomer is tri (propylene glycol) diacrylate, trimethylolpropane trimethacrylate, two propylene of 1,6- hexanediol One or more in acid esters, ethoxylated trimethylolpropane triacrylate;
Described light trigger be 1- hydroxy-cyclohexyl-phenyl ketones, 2- hydroxy-2-methyl -1- phenyl -1- acetone,( 2, 4,6- trimethylbenzoyls) one or more in diphenyl phosphine oxide;
Described auxiliary agent is acrylic acid levelling agent or acrylic acid defoamer.
2. UV glossy varnishes for radium-shine roller coat according to claim 1, it is characterised in that by weight, by Following material composition:Urethane acrylate 32 ~ 36%, epoxy acrylate 24 ~ 28%, monomer 30 ~ 35%, light trigger 3 ~ 7%, Auxiliary agent 1 ~ 3%.
3. UV glossy varnishes for radium-shine roller coat according to claim 1, it is characterised in that by weight, by Following material composition:Urethane acrylate 36%, epoxy acrylate 24%, monomer 34%, light trigger 5%, auxiliary agent 1%.
4. UV glossy varnishes for radium-shine roller coat according to claim 1, it is characterised in that by weight, by Following material composition:Urethane acrylate 34%, epoxy acrylate 26%, monomer 35%, light trigger 3%, auxiliary agent 2%.
5. UV glossy varnishes for radium-shine roller coat according to claim 1, it is characterised in that by weight, by Following material composition:Urethane acrylate 32%, epoxy acrylate 28%, monomer 30%, light trigger 7%, auxiliary agent 3%.
CN201410749717.6A 2014-12-10 2014-12-10 UV (ultraviolet) finishing varnish for laser roller coating Active CN104559741B (en)

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CN106700751A (en) * 2015-11-15 2017-05-24 惠州市长润发涂料有限公司 High-weatherability spraying glossy UV finishing varnish on calcium silicate board
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CN106634457A (en) * 2016-11-15 2017-05-10 惠州市长润发涂料有限公司 UV (ultraviolet) glossy finish paint capable of being used for spray coating and laser roller coating
CN107602892A (en) * 2017-08-25 2018-01-19 苏州广尔纳新材料科技股份有限公司 Printable printing anti scraping thin film of one kind and preparation method thereof
CN108148493A (en) * 2017-12-19 2018-06-12 东莞市优科印刷材料有限公司 The tasteless ultraviolet curing coating composition directly applied
CN108192416A (en) * 2018-03-13 2018-06-22 浙江美浓材料科技有限公司 A kind of silk-screen fission ink and preparation method thereof
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CN101570658A (en) * 2009-06-11 2009-11-04 李磊 Laser printing UV curing ink, preparation method and printing method
CN103627300A (en) * 2013-11-12 2014-03-12 惠州市长润发涂料有限公司 Ultraviolet (UV) laser roller coating woodware matt finish
CN103627301B (en) * 2013-11-12 2017-03-29 惠州市长润发涂料有限公司 A kind of photograph UV solidifies Lacquer finish coating
CN103980803A (en) * 2014-06-04 2014-08-13 广东美涂士建材股份有限公司 UV woodware laser roller-coating white finish coat and preparation method thereof

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Address after: 516221 No. 30 Xiayong Petrochemical Avenue, Daya Bay, Huizhou City, Guangdong Province

Co-patentee after: TIANJIN CHANGRUNFA CHEMICAL Co.,Ltd.

Patentee after: Guangdong Libang Changrunfa Science and Technology Material Co.,Ltd.

Address before: 516221 Xintang Industrial Zone, Qiuchang Town, Huiyang District, Huizhou City, Guangdong Province

Co-patentee before: TIANJIN CHANGRUNFA CHEMICAL Co.,Ltd.

Patentee before: HUIZHOU CHANGRUNFA COATING Co.,Ltd.

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Effective date of registration: 20221215

Address after: 516221 No. 30 Xiayong Petrochemical Avenue, Daya Bay, Huizhou City, Guangdong Province

Patentee after: Guangdong Libang Changrunfa Science and Technology Material Co.,Ltd.

Address before: 516221 No. 30 Xiayong Petrochemical Avenue, Daya Bay, Huizhou City, Guangdong Province

Patentee before: Guangdong Libang Changrunfa Science and Technology Material Co.,Ltd.

Patentee before: TIANJIN CHANGRUNFA CHEMICAL Co.,Ltd.