CN105153777A - Solvent-free type ultraviolet (UV) photocuring water drop paint and preparation and use method thereof - Google Patents
Solvent-free type ultraviolet (UV) photocuring water drop paint and preparation and use method thereof Download PDFInfo
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- CN105153777A CN105153777A CN201510695567.XA CN201510695567A CN105153777A CN 105153777 A CN105153777 A CN 105153777A CN 201510695567 A CN201510695567 A CN 201510695567A CN 105153777 A CN105153777 A CN 105153777A
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Abstract
The invention discloses solvent-free type ultraviolet (UV) photocuring water drop paint and a preparation and use method thereof. The solvent-free type ultraviolet (UV) photocuring water drop paint is prepared from, by mass, 5-7 parts of aliphatic polyurethane 6 functional group crylic acid oligomer, 17-19 parts of aliphatic polyurethane 2 functional group crylic acid oligomer, 53.5-56.5 parts of bisphenol A epoxy 2 functional group crylic acid oligomer, 5-7 parts of tripropylene glycol diacrylate (TPGDA) monomers, 7-9 parts of 1,6-high definition discrete architecture (HDDA) monomers, 10-12 parts of pentaerythritol triacrylate (PET3A) monomers, 3-5 parts of 2-hydroxy-2-methyl-1-phenyl-1-acetone light initiator (1173), 2-3 parts of benzophenone photoinitiator (BP), 7-9 parts of reaction type tertiary amine promoter and 0.45-0.55 part of polyether modified polydimethylsiloxane flatting agent. According to the solvent-free type ultraviolet (UV) photocuring water drop paint and the preparation and use method thereof, energy saving and environment friendliness can be achieved, operation is easy and convenient, a water drop shape is naturally formed, curing and drying are fast, the visual effect is good, and the paint is suitable for indoor PVC coated wall slab decoration of building houses.
Description
[technical field]
The present invention relates to the technical field of chemistry painting industry, the technical field of particularly a kind of no-solvent type ultraviolet (UV) photocuring globule paint and preparation thereof, using method.
[background technology]
Civilian coating is widely used in the internal and external ornament of master builder room.Traditional coating is the smooth protective membrane forming one deck densification on coated substrate, can not have the artistic effect of the strong natural globule of stereoscopic sensation by self-assembling formation.
For meeting the vision requirement that people promote day by day to coatings decoration, arisen at the historic moment various artistry coating in market, these coating are when forming the artistry effect playing oneself, all need artificial singularity operation, as used special instrument or specific pattern mold etc., have and volatilize air-polluting VOC material in drying process, have and need long-time heating bake drying, not only consuming time but also take a lot of work.
[summary of the invention]
Object of the present invention solves the problems of the prior art exactly, propose that a kind of energy-conserving and environment-protective, simple to operation, self-assembling formation globule shape, rapid solidification are dry, no-solvent type ultraviolet (UV) the photocuring globule paint of good visual effect and preparation thereof, using method, be particularly suited for the use of PVC pad pasting body of wall flat board decoration in the room in master builder room, parlor by simple roller coat coating method.
For achieving the above object, the present invention proposes a kind of no-solvent type ultraviolet (UV) photocuring globule paint, comprise following component and the quality proportioning of each component is: aliphatic polyurethane 6 functional group acrylated oligomer: 5 ~ 7 parts, aliphatic polyurethane 2 functional group acrylated oligomer: 17 ~ 19 parts, bisphenol-A epoxy 2 functional group acrylated oligomer: 53.5 ~ 56.5 parts, tripropylene glycol diacrylate monomer (TPGDA): 5 ~ 7 parts, 1, 6-hexylene glycol two acrylic ester monomer (HDDA): 7 ~ 9, pentaerythritol triacrylate monomer (PET3A): 10 ~ 12 parts, 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 3 ~ 5 parts, diphenyl ketone photo initiator (BP): 2 ~ 3 parts, response type tertiary amine aided initiating: 7 ~ 9 parts, polyether-modified polydimethylsiloxane flow agent: 0.45 ~ 0.55 part.
As preferably, the quality proportioning of described each component is: aliphatic polyurethane 6 functional group acrylated oligomer: 6 parts, aliphatic polyurethane 2 functional group acrylated oligomer: 18 parts, bisphenol-A epoxy 2 functional group acrylated oligomer: 54.5 parts, tripropylene glycol diacrylate monomer (TPGDA): 6 parts, 1, 6-hexylene glycol two acrylic ester monomer (HDDA): 8, pentaerythritol triacrylate monomer (PET3A): 11 parts, 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 4 parts, diphenyl ketone photo initiator (BP): 2.5 parts, response type tertiary amine aided initiating: 8 parts, polyether-modified polydimethylsiloxane flow agent: 0.5 part.
For achieving the above object, the present invention proposes a kind of preparation method of no-solvent type ultraviolet (UV) photocuring globule paint, comprise the following steps:
A) add tripropylene glycol diacrylate monomer (TPGDA) in stirring dispersion machine in the ratio in formula, and to open stirring dispersion machine setting speed be 300 revs/min;
B) adding 1,6-hexylene glycol two acrylic ester monomer (HDDA) in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine setting speed to be 300 revs/min, stir 4 ~ 5 minutes;
C) adding pentaerythritol triacrylate monomer (PET3A) in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine setting speed to be 300 revs/min, stir 4 ~ 5 minutes;
D) diphenyl ketone photo initiator (BP) is being added in stirring dispersion machine in the ratio in formula, improving stirring dispersion machine speed setting is 600 revs/min, stir and dissolve diphenyl ketone photo initiator (BP) till dissolving completely, and the stirring dispersion machine speed setting that slows down is 300 revs/min;
E) adding aliphatic polyurethane 6 functional group acrylated oligomer in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 4 ~ 5 minutes;
F) adding aliphatic polyurethane 2 functional group acrylated oligomer in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
G) adding bisphenol-A epoxy 2 functional group acrylated oligomer in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
H) adding response type tertiary amine aided initiating in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
I) adding polyether-modified polydimethylsiloxane flow agent in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
J) 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173) is being added in stirring dispersion machine in the ratio in formula, improving stirring dispersion machine speed setting is 900 ~ 1000 revs/min, control temperature is no more than 45 ~ 50 DEG C, be stirred to evenly, obtained a kind of no-solvent type ultraviolet (UV) photocuring globule paint;
K) a kind of no-solvent type ultraviolet (UV) photocuring globule paint grenadine obtained in j) step is filtered and packs.
As preferably, in described j) step, stirring dispersion machine speed setting is 1000 revs/min, and control temperature is no more than 50 DEG C.
For achieving the above object, the present invention proposes a kind of using method of no-solvent type ultraviolet (UV) photocuring globule paint, comprise the following steps:
A) be coated on base material by no-solvent type ultraviolet (UV) photocuring globule paint by coating machine, glue spread is 20 ~ 25 grams/every square metre;
B) base material of coated described no-solvent type ultraviolet (UV) photocuring globule paint was through levelling line 3 ~ 5 minutes, formed the globule figure line of nature shape;
C) base material of the Natural Water pearl of formation no-solvent type ultraviolet (UV) photocuring globule paint enters the photo solidification machine with two medium pressure mercury lamps, and carry out photocuring complete drying, photocuring energy ensures 250 ~ 350mJ/cm
2, obtain the Natural Water pearl visual effect of described no-solvent type ultraviolet (UV) photocuring globule paint.
As preferably, in described a) step, base material is PVC pad pasting ash wall body plate, and coating machine is single roll coater, and glue spread is 23 grams/every square metre.
As preferably, in described b) step by the base material that scribbles no-solvent type ultraviolet (UV) photocuring globule paint through levelling line 4 minutes.
As preferably, described photocuring energy ensures 300mJ/cm
2.
Beneficial effect of the present invention: the present invention can dry, the good visual effect of energy-conserving and environment-protective, simple to operation, self-assembling formation globule shape, rapid solidification, is particularly suited for the use of PVC pad pasting body of wall flat board decoration in the room in master builder room, parlor by simple roller coat coating method.
[embodiment]
Embodiment 1
A kind of no-solvent type ultraviolet (UV) of the present invention photocuring globule paint, comprise following component and the quality proportioning of each component is: aliphatic polyurethane 6 functional group acrylated oligomer: 5 parts, aliphatic polyurethane 2 functional group acrylated oligomer: 17 parts, bisphenol-A epoxy 2 functional group acrylated oligomer: 53.5 parts, tripropylene glycol diacrylate monomer (TPGDA): 5 parts, 1, 6-hexylene glycol two acrylic ester monomer (HDDA): 7, pentaerythritol triacrylate monomer (PET3A): 10 parts, 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 3 parts, diphenyl ketone photo initiator (BP): 2 parts, response type tertiary amine aided initiating: 7 parts, polyether-modified polydimethylsiloxane flow agent: 0.45 part.
Embodiment 2
A kind of no-solvent type ultraviolet (UV) of the present invention photocuring globule paint, comprise following component and the quality proportioning of each component is: aliphatic polyurethane 6 functional group acrylated oligomer: 6 parts, aliphatic polyurethane 2 functional group acrylated oligomer: 18 parts, bisphenol-A epoxy 2 functional group acrylated oligomer: 54.5 parts, tripropylene glycol diacrylate monomer (TPGDA): 6 parts, 1, 6-hexylene glycol two acrylic ester monomer (HDDA): 8, pentaerythritol triacrylate monomer (PET3A): 11 parts, 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 4 parts, diphenyl ketone photo initiator (BP): 2.5 parts, response type tertiary amine aided initiating: 8 parts, polyether-modified polydimethylsiloxane flow agent: 0.5 part.
Embodiment 3
A kind of no-solvent type ultraviolet (UV) of the present invention photocuring globule paint, comprise following component and the quality proportioning of each component is: aliphatic polyurethane 6 functional group acrylated oligomer: 7 parts, aliphatic polyurethane 2 functional group acrylated oligomer: 19 parts, bisphenol-A epoxy 2 functional group acrylated oligomer: 56.5 parts, tripropylene glycol diacrylate monomer (TPGDA): 7 parts, 1, 6-hexylene glycol two acrylic ester monomer (HDDA): 9, pentaerythritol triacrylate monomer (PET3A): 12 parts, 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 5 parts, diphenyl ketone photo initiator (BP): 3 parts, response type tertiary amine aided initiating: 9 parts, polyether-modified polydimethylsiloxane flow agent: 0.55 part.
The preparation method of a kind of no-solvent type ultraviolet (UV) of the present invention photocuring globule paint, comprises the following steps:
A) add tripropylene glycol diacrylate monomer (TPGDA) in stirring dispersion machine in the ratio in formula, and to open stirring dispersion machine setting speed be 300 revs/min;
B) adding 1,6-hexylene glycol two acrylic ester monomer (HDDA) in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine setting speed to be 300 revs/min, stir 4 ~ 5 minutes;
C) adding pentaerythritol triacrylate monomer (PET3A) in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine setting speed to be 300 revs/min, stir 4 ~ 5 minutes;
D) diphenyl ketone photo initiator (BP) is being added in stirring dispersion machine in the ratio in formula, improving stirring dispersion machine speed setting is 600 revs/min, stir and dissolve diphenyl ketone photo initiator (BP) till dissolving completely, and the stirring dispersion machine speed setting that slows down is 300 revs/min;
E) adding aliphatic polyurethane 6 functional group acrylated oligomer in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 4 ~ 5 minutes;
F) adding aliphatic polyurethane 2 functional group acrylated oligomer in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
G) adding bisphenol-A epoxy 2 functional group acrylated oligomer in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
H) adding response type tertiary amine aided initiating in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
I) adding polyether-modified polydimethylsiloxane flow agent in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
J) 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173) is being added in stirring dispersion machine in the ratio in formula, improving stirring dispersion machine speed setting is 1000 revs/min, control temperature is no more than 50 DEG C, be stirred to evenly, obtained a kind of no-solvent type ultraviolet (UV) photocuring globule paint;
K) a kind of no-solvent type ultraviolet (UV) photocuring globule paint grenadine obtained in j) step is filtered and packs.
The using method of a kind of no-solvent type ultraviolet (UV) of the present invention photocuring globule paint, comprises the following steps:
A) be coated in PVC pad pasting ash wall body plate by no-solvent type ultraviolet (UV) photocuring globule paint by coating machine, glue spread is 23 grams/every square metre;
B) base material of coated described no-solvent type ultraviolet (UV) photocuring globule paint was through levelling line 4 minutes, formed the globule figure line of nature shape;
C) base material of the Natural Water pearl of formation no-solvent type ultraviolet (UV) photocuring globule paint enters the photo solidification machine with two medium pressure mercury lamps, and carry out photocuring complete drying, photocuring energy ensures 300mJ/cm
2, obtain the Natural Water pearl visual effect of described no-solvent type ultraviolet (UV) photocuring globule paint.
The present invention can dry, the good visual effect of energy-conserving and environment-protective, simple to operation, self-assembling formation globule shape, rapid solidification, is particularly suited for the use of PVC pad pasting body of wall flat board decoration in the room in master builder room, parlor by simple roller coat coating method.
Above-described embodiment is to explanation of the present invention, is not limitation of the invention, anyly all belongs to protection scope of the present invention to the scheme after simple transformation of the present invention.
Claims (8)
1. a no-solvent type ultraviolet (UV) photocuring globule paint, it is characterized in that: comprise following component and the quality proportioning of each component is: aliphatic polyurethane 6 functional group acrylated oligomer: 5 ~ 7 parts, aliphatic polyurethane 2 functional group acrylated oligomer: 17 ~ 19 parts, bisphenol-A epoxy 2 functional group acrylated oligomer: 53.5 ~ 56.5 parts, tripropylene glycol diacrylate monomer (TPGDA): 5 ~ 7 parts, 1, 6-hexylene glycol two acrylic ester monomer (HDDA): 7 ~ 9, pentaerythritol triacrylate monomer (PET3A): 10 ~ 12 parts, 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 3 ~ 5 parts, diphenyl ketone photo initiator (BP): 2 ~ 3 parts, response type tertiary amine aided initiating: 7 ~ 9 parts, polyether-modified polydimethylsiloxane flow agent: 0.45 ~ 0.55 part.
2. a kind of no-solvent type ultraviolet (UV) photocuring globule paint as claimed in claim 1, it is characterized in that: the quality proportioning of described each component is: aliphatic polyurethane 6 functional group acrylated oligomer: 6 parts, aliphatic polyurethane 2 functional group acrylated oligomer: 18 parts, bisphenol-A epoxy 2 functional group acrylated oligomer: 54.5 parts, tripropylene glycol diacrylate monomer (TPGDA): 6 parts, 1, 6-hexylene glycol two acrylic ester monomer (HDDA): 8, pentaerythritol triacrylate monomer (PET3A): 11 parts, 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173): 4 parts, diphenyl ketone photo initiator (BP): 2.5 parts, response type tertiary amine aided initiating: 8 parts, polyether-modified polydimethylsiloxane flow agent: 0.5 part.
3. a preparation method for no-solvent type ultraviolet (UV) photocuring globule paint, is characterized in that: comprise the following steps:
A) add tripropylene glycol diacrylate monomer (TPGDA) in stirring dispersion machine in the ratio in formula, and to open stirring dispersion machine setting speed be 300 revs/min;
B) adding 1,6-hexylene glycol two acrylic ester monomer (HDDA) in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine setting speed to be 300 revs/min, stir 4 ~ 5 minutes;
C) adding pentaerythritol triacrylate monomer (PET3A) in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine setting speed to be 300 revs/min, stir 4 ~ 5 minutes;
D) diphenyl ketone photo initiator (BP) is being added in stirring dispersion machine in the ratio in formula, improving stirring dispersion machine speed setting is 600 revs/min, stir and dissolve diphenyl ketone photo initiator (BP) till dissolving completely, and the stirring dispersion machine speed setting that slows down is 300 revs/min;
E) adding aliphatic polyurethane 6 functional group acrylated oligomer in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 4 ~ 5 minutes;
F) adding aliphatic polyurethane 2 functional group acrylated oligomer in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
G) adding bisphenol-A epoxy 2 functional group acrylated oligomer in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
H) adding response type tertiary amine aided initiating in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
I) adding polyether-modified polydimethylsiloxane flow agent in stirring dispersion machine in the ratio in formula, keeping stirring dispersion machine speed setting to be 300 revs/min, stir 8 ~ 10 minutes;
J) 2-hydroxy-2-methyl-1-phenyl-1-acetone light trigger (1173) is being added in stirring dispersion machine in the ratio in formula, improving stirring dispersion machine speed setting is 900 ~ 1000 revs/min, control temperature is no more than 45 ~ 50 DEG C, be stirred to evenly, obtained a kind of no-solvent type ultraviolet (UV) photocuring globule paint;
K) a kind of no-solvent type ultraviolet (UV) photocuring globule paint grenadine obtained in j) step is filtered and packs.
4. the preparation method of a kind of no-solvent type ultraviolet (UV) photocuring globule paint as claimed in claim 3, it is special
Levy and be: in described j) step, stirring dispersion machine speed setting is 1000 revs/min, and control temperature does not surpass
Cross 50 DEG C.
5. a using method for no-solvent type ultraviolet (UV) photocuring globule paint, is characterized in that: comprise following step
Rapid:
A) be coated on base material by no-solvent type ultraviolet (UV) photocuring globule paint by coating machine, glue spread is 20 ~ 25 grams/every square metre;
B) base material of coated described no-solvent type ultraviolet (UV) photocuring globule paint was through levelling line 3 ~ 5 minutes, formed the globule figure line of nature shape;
C) base material of the Natural Water pearl of formation no-solvent type ultraviolet (UV) photocuring globule paint enters the photo solidification machine with two medium pressure mercury lamps, and carry out photocuring complete drying, photocuring energy ensures 250 ~ 350mJ/cm
2, obtain the Natural Water pearl visual effect of described no-solvent type ultraviolet (UV) photocuring globule paint.
6. the using method of a kind of no-solvent type ultraviolet (UV) photocuring globule paint as claimed in claim 5, is characterized in that: in described a) step, base material is PVC pad pasting ash wall body plate, and coating machine is single roll coater, and glue spread is 23 grams/every square metre.
7. the using method of a kind of no-solvent type ultraviolet (UV) photocuring globule paint as claimed in claim 5, is characterized in that: in described b) step by the base material that scribbles no-solvent type ultraviolet (UV) photocuring globule paint through levelling line 4 minutes.
8. the using method of a kind of no-solvent type ultraviolet (UV) photocuring globule paint according to any one of claim 5 to 7, is characterized in that: described photocuring energy ensures 300mJ/cm
2.
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CN201510695567.XA CN105153777B (en) | 2015-10-23 | 2015-10-23 | A kind of no-solvent type ultraviolet (UV) photocuring globule paint and its preparation, application method |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105925170A (en) * | 2016-06-29 | 2016-09-07 | 海盐三田科技有限公司 | Solvent-free ultraviolet photocuring anti-flouring easily cleaned paint as well as preparation method and application thereof |
CN107384154A (en) * | 2017-07-27 | 2017-11-24 | 滁州金桥德克新材料有限公司 | A kind of solvent-free UV water droplet effects coating and preparation method thereof |
CN107716250A (en) * | 2017-09-28 | 2018-02-23 | 惠州学院 | A kind of three-dimensional globule spraying method |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1959530A (en) * | 2006-11-24 | 2007-05-09 | 中国乐凯胶片集团公司 | Ultraviolet light solidified coating in use for post processing of imaging material |
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2015
- 2015-10-23 CN CN201510695567.XA patent/CN105153777B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1959530A (en) * | 2006-11-24 | 2007-05-09 | 中国乐凯胶片集团公司 | Ultraviolet light solidified coating in use for post processing of imaging material |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105925170A (en) * | 2016-06-29 | 2016-09-07 | 海盐三田科技有限公司 | Solvent-free ultraviolet photocuring anti-flouring easily cleaned paint as well as preparation method and application thereof |
CN107384154A (en) * | 2017-07-27 | 2017-11-24 | 滁州金桥德克新材料有限公司 | A kind of solvent-free UV water droplet effects coating and preparation method thereof |
CN107716250A (en) * | 2017-09-28 | 2018-02-23 | 惠州学院 | A kind of three-dimensional globule spraying method |
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