CN202391056U - Ultraviolet curing painting decorative plate - Google Patents
Ultraviolet curing painting decorative plate Download PDFInfo
- Publication number
- CN202391056U CN202391056U CN2011204967241U CN201120496724U CN202391056U CN 202391056 U CN202391056 U CN 202391056U CN 2011204967241 U CN2011204967241 U CN 2011204967241U CN 201120496724 U CN201120496724 U CN 201120496724U CN 202391056 U CN202391056 U CN 202391056U
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- ultraviolet light
- light polymerization
- coating
- ultraviolet curing
- decorative panel
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Abstract
The utility model belongs to the field of a decorative plate in building materials and particularly relates to an ultraviolet curing painting decorative plate, which is produced by coating ultraviolet curing coatings on the surface of a decorative plate substrate. An ultraviolet curing close adhesive transparent primer coating is coated on the surface of the decorative plate substrate; an ultraviolet curing adhesive coating is coated on the surface of the ultraviolet curing close adhesive transparent primer coating; a pattern layer is painted on the surface of the ultraviolet curing adhesive coating; and an ultraviolet curing finish paint coating is coated on the surface of the pattern layer. The ultraviolet curing painting decorative plate provided by the utility model is rich in patterns and has the coatings with good adhesive force, strong stereoscopic impression, high hardness, scratch resistance, durable service and the like, thereby being widely applicable in the fields of inner and outer walls, ground, table facets and the like.
Description
Technical field
The utility model belongs to constructional materials decorative panel field, the ultraviolet light polymerization air brushing decorative panel of particularly producing through the application ultraviolet-curing paint on the surface of decorative panel matrix.
Background technology
At present, along with building increase luxurious day by day with various interior decorations day by day, country is also increasingly high with the environmental protection of material, requirement such as energy-conservation to building and architectural decoration, decoration; Therefore, present Imitation Rock Porcelain Tiles, half Imitation Rock Porcelain Tiles, ceramic brick etc. use day by day and reduce; The processing of Imitation Rock Porcelain Tiles, half Imitation Rock Porcelain Tiles, ceramic brick etc. need be passed through the sintering procedure of secondary, belongs to high pollution, the product of high energy consumption; And the ultraviolet light polymerization air brushing decorative panel that the surface at the decorative panel matrix that the utility model adopted produces through application ultraviolet-curing paint (being called for short UV coating) method compares with existing similar tile product; Can reduce the process of gloss firing; Simultaneously owing to only adopt identical even the substrate of low side more; Can the temperature and time of firing for the first time all be reduced accordingly, the content of potter's clay also effectively reduces; The defect ware that when making Imitation Rock Porcelain Tiles, half Imitation Rock Porcelain Tiles, ceramic brick, produces in addition etc. can adopt the utility model to upgrade once more, improves quality and surcharge; The utility model meets the strategic demand of the sustainable development of national environmental protection, the energy fully.Advantages such as the speed of production of the utility model is fast, and energy consumption is low, and equipment investment is low, and the place area occupied is little; The product of using the utility model production can be widely used in fields such as interior exterior wall, ground, table top.
Summary of the invention
The purpose of the utility model provides a kind of rich patterns, and third dimension is strong, the ornamental and strong ultraviolet light polymerization air brushing decorative panel of protectiveness.
The ultraviolet light polymerization air brushing decorative panel of the utility model is that the surfaces coated at the decorative panel matrix is equipped with the ultraviolet light polymerization sealing and adheres to primer coating clearly; Adhering to clearly in described ultraviolet light polymerization sealing, the surfaces coated of primer coating is equipped with the ultraviolet cured adhesive coating; Surperficial air brushing at described ultraviolet light polymerization gel coating has patterned layer, in the surfaces coated of described patterned layer the ultraviolet light polymerization topcoat is housed.
The surface of described ultraviolet light polymerization topcoat can further be posted and is used to protect object surfaces to avoid scuffing, abrasive polypropylene diaphragm or polyethylene protective film.
Described decorative panel matrix is selected from a kind of in porcelain plate, half porcelain plate, ceramic plate, type ceramic scutum etc.
The technology application that primer coating clearly can adopt roller coat, showering, spraying or brushing is adhered in the sealing of described ultraviolet light polymerization, and the thickness of coating is 5～100 μ m.
Described ultraviolet light polymerization gel coating can adopt the technology application of roller coat, showering, spraying or brushing, and the thickness of coating is 5～100 μ m.
Described patterned layer can be plotted in the picture of its storage the surface of described ultraviolet light polymerization gel coating through computer through the air brushing machine.
Described ultraviolet light polymerization topcoat can adopt the technology application of roller coat, showering, spraying or brushing, and the thickness of coating is 5～200 μ m, and gloss is that 10～100 degree (60 degree gloss meter) are adjustable.
The preparation method of the ultraviolet light polymerization air brushing decorative panel of the utility model is following:
(1). matrix surface is handled;
(2). priming paint is clearly adhered in the sealing of application ultraviolet light polymerization on the matrix of step (1); Thickness is 5～100 μ m;
(3). ultraviolet light polymerization;
(4). application ultraviolet cured adhesive on the matrix of step (3); Thickness is 5～100 μ m;
(5). the ultraviolet light semi-solid preparation;
(6). printing pattern on the matrix of step (5);
(7). application ultraviolet light polymerization finish paint on the matrix of step (6); Thickness is 5～200 μ m;
(8). ultraviolet light polymerization;
(9). check;
(10). pasting protective film;
(11). packing.
Described matrix surface is handled: matrix surface sand milling, dedusting.
The mode of described application can adopt the mode of roller coat, showering, spraying or brushing.
Described ultraviolet light polymerization: be coated with in the photo solidification machine that the decorative panel that installs gets into the ultraviolet tube (high-pressure sodium lamp) that 1～6 3～20kw is housed and carry out illumination, ultraviolet curable coating is solidified, the transmission speed of solidifying machine is 5～50 meters/minute.
Described ultraviolet light semi-solid preparation: be coated with in the photo solidification machine that the decorative panel that installs gets into the ultraviolet tube (high-pressure sodium lamp) that 1～6 3～20kw is housed and carry out illumination, ultraviolet curable coating is solidified, the transmission speed of solidifying machine is 5～50 meters/minute.
Described printing pattern: the similar ink-jet printer of the operating principle of air brushing machine, be this area common equipment, computer is plotted in through the air brushing machine picture of its storage the surface of described ultraviolet light polymerization gel coating with printing ink.
Described check: whether the ultraviolet light polymerization air brushing decorative panel that check is made is qualified.
The sealing of employed ultraviolet light polymerization adheres to clearly that priming paint, ultraviolet cured adhesive and ultraviolet light polymerization finish paint are common used material in this area in the utility model.By weight percentage: common described ultraviolet light polymerization sealing is adhered to priming paint clearly and is made up of 10～80% acrylic ester prepolymer, 10～60% acrylate monomer, 3～6% light trigger, 0～2% auxiliary agent and 5～30% filler.Described ultraviolet cured adhesive is made up of acrylic ester prepolymer 30～80%, acrylate monomer 10～60%, light trigger 1～5% and 0～5% of auxiliary agent.Described ultraviolet curing transparent finish paint is made up of 10～80% acrylic ester prepolymer, 10～60% acrylate monomer, 3～6% light trigger, 0～2% auxiliary agent and 0～50% filler.
Wherein said acrylic ester prepolymer is reactive fluorine-containing modified prepolymers and/or reactive acroleic acid modified prepolymers.
Wherein said reactive fluorine-containing modified prepolymers is selected from least a in the group that fluorine-containing epoxy acrylate, fluorine-containing epoxy methacrylates, fluorochemical urethane acrylic acid ester, fluorochemical urethane methacrylate, fluorine-containing polyester acrylate, fluorine-containing polyester methacrylate, fluorine-containing amino acrylates, fluorine-containing amino methyl acrylic acid ester, fluoro-acrylate copolymer form.
Wherein said reactive acroleic acid modified prepolymers is selected from least a in the group that epoxy acrylate, urethane acrylate, polyester acrylate, amino acrylates, acrylate copolymer form.
Wherein said acrylate monomer is fluorinated acrylate monomer and/or acrylate monomer.
Wherein said fluorinated acrylate monomer is selected from least a in the group that trifluoroethyl methacrylate, acrylic acid trifluoro ethyl ester, methacrylic acid hexafluoro butyl ester, acrylic acid hexafluoro butyl ester, methacrylic acid ten difluoro heptyl esters, dodecafluorhe-ptylacrylate form.
Wherein said acrylate monomer is selected from least a in the group that two (diethylene glycol) diacrylates of EMA, ethyl acrylate, butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer, hydroxyethyl methacrylate, hydroxy-ethyl acrylate, tri (propylene glycol) diacrylate (TPGDA), propylene glycol diacrylate (DPGDA), neopentylglycol diacrylate, the third oxidation neopentylglycol diacrylate (PO-NPGDA), phthalic acid, 1,6 hexanediyl ester, trimethylolpropane triacrylate (TMPTA), ethoxyquin trimethylolpropane triacrylate (EO-TMPTA), the third oxidation trimethylolpropane triacrylate, pentaerythritol triacrylate, dipentaerythritol acrylate etc. are formed.
Wherein said light trigger is selected from see at least a in the group that oxygen compound light trigger, benzoic ether light trigger formed of benzoin ether light trigger, benzil ketals light trigger, acetophenone light trigger, anthraquinone light trigger, thioxanthone photo initiator, benzophenone light trigger, acyl group.
Described benzoin ether light trigger is selected from least a in the group that benzoin methyl ether, benzoin ethylether, benzoin isopropyl ether formed.
Described benzil ketals light trigger is the benzil dimethyl ketal.
Described acetophenone light trigger is selected from acetophenone, 2; 2-dimethoxy-2-phenyl acetophenone, 2; 2-diethoxy-2-phenyl acetophenone, 1, at least a in 1-dichloroacetophenone, 1-hydroxy acetophenone, 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-(4-isopropyl phenyl)-2-hydroxy-2-methyl-1-acetone, 1-[4-(2-hydroxyl-oxethyl) phenyl]-2-hydroxy-2-methyl-1-acetone, 2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone, the 2-benzyl-2-dimethylamino-1-group that (4-morpholinyl phenyl)-the 1-butanone is formed.
Described anthraquinone light trigger is selected from least a in the group that 2-tert-butyl group anthraquinone, 1-chloroanthraquinone, 2-amyl anthraquinone formed.
Described thioxanthone photo initiator is selected from 2; 4-dimethyl thia anthrone, 2; 4-diethyl thioxanthone, 2-isopropyl thioxanthone, 4-isopropyl thioxanthone, 2-chloro thioxanthone, 2, at least a in the group that 4-diisopropyl thioxanthone is formed.
At least a in the group that described benzophenone light trigger is selected from benzophenone, 4-chlorobenzophenone, form methyldiphenyl ketone, 4-benzoyl-4 '-dimethyl diphenyl sulfide.
Described acylphosphanes oxygen compound light trigger is selected from 2,4,6-trimethylbenzoyl diphenyl phosphine oxide, two (2; 4, the 6-trimethylbenzoyl)-phenyl phosphine oxide, two (2, the 6-dimethylbenzoyl)-2; 4; 4-tri-methyl-amyl phosphine oxide, 2,4, at least a in the group that 6-trimethylbenzoyl phenyl ethoxy phosphine oxide is formed.
Described benzoic ether light trigger is benzoylbenzoic acid methyl esters, methyl o-benzoylbenzoate or their mixture.
Wherein said auxiliary agent is the antifoaming agent (like BYK052, BYK055 or their mixture etc.) of the levelling agent (like BYK306, BYK358 or their mixture etc.) of German Bi Ke chemical company, German Bi Ke chemical company and/or the wetting dispersing agent (like Disperbyk 103, Disperbyk 163 or their mixture etc.) of German Bi Ke chemical company.
Wherein said filler is powder body materials such as French chalk, calcium carbonate, barium sulfate or flatting silica.
The ultraviolet light polymerization air brushing decorative panel of the utility model can be widely used in fields such as interior exterior wall, ground, table top.The ultraviolet light polymerization air brushing decorative panel of the utility model has rich patterns, and have that coating adhesion is good, third dimension is strong, hardness is high, scratch resistance, advantage such as corrosion-resistant, durable in use.
Description of drawings
Fig. 1. the structural representation of the ultraviolet light polymerization air brushing decorative panel of the utility model.
Reference numeral
1. primer coating is clearly adhered in the sealing of decorative panel matrix 2. ultraviolet light polymerizations
3. ultraviolet light polymerization gel coating 4. patterned layer
5. ultraviolet light polymerization topcoat 6. diaphragms
The specific embodiment
Embodiment 1. landscape painting air brushing ultraviolet light polymerization decorative ceramic boards
See also Fig. 1.With the porcelain plate is decorative panel matrix 1, earlier that porcelain plate sand milling is smooth and remove the dust on surface, is that the ultraviolet light polymerization of 5 μ m adheres to primer coating 2 clearly at surface roller coating one layer thickness again; 2 9.6kw uviol lamps (high-pressure sodium lamp) are equipped with in entering, and transmission speed is in 50 meters/minute the photo solidification machine, behind the ultraviolet light polymerization; Adhere to clearly at ultraviolet light polymerization that surface roller coating one layer thickness of primer coating is the ultraviolet light polymerization gel coating 3 of 5 μ m again, get into that 2 9.6kw uviol lamps (high-pressure sodium lamp), transmission speed are arranged is in 50 meters/minute the photo solidification machine; Behind the ultraviolet light polymerization, utilize computer that the landscape painting of its storage is plotted in the surface of described ultraviolet light polymerization gel coating through the air brushing machine with printing ink, obtain the patterned layer 4 of landscape painting; Naturally put 3 hours, make the painting printing ink drying after, spray the ultraviolet light polymerization topcoat 5 that a layer thickness is 200 μ m (gloss be 20 degree) again on the surface of printing pattern layer; 2 12kw uviol lamps (high-pressure sodium lamp) are equipped with in entering; Transmission speed is in 50 meters/minute the photo solidification machine, behind the ultraviolet light polymerization, to reach criterion of acceptability through test rating; Paste polypropylene diaphragm 6, promptly get landscape painting air brushing ultraviolet light polymerization ceramic decoration board finished product.
The ultraviolet light polymerization sealing is adhered to clearly, and the percentage by weight of priming paint consists of: epoxy acrylate 10%, EO-TMPTA 52%, French chalk 30%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 6%, BYK 0551% and Disperbyk 1631%.
The percentage by weight of ultraviolet cured adhesive consists of: epoxy acrylate 46%, urethane acrylate 34%, TMPTA 5%, TPGDA 12%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 1%, BYK306 1% and BYK055 1%.
The percentage by weight of ultraviolet light polymerization finish paint consists of: amino acrylates 10%, fluorochemical urethane acrylic acid ester 32%, acrylate copolymer 30%, PETA 10%, flatting silica 15%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 1% and 2; 4,6-trimethylbenzoyl diphenyl phosphine oxide 2%.
Embodiment 2. figure painting air brushing ultraviolet light polymerization ceramic decorative panels
See also Fig. 1.With the ceramic plate is decorative panel matrix 1, earlier that ceramic plate sand milling is smooth and remove the dust on surface, and the ultraviolet light polymerization that sprays a layer thickness again on the surface and be 100 μ m adheres to primer coating 2 clearly; 2 9.6kw uviol lamps (high-pressure sodium lamp) are equipped with in entering, and transmission speed is in 5 meters/minute the photo solidification machine, behind the ultraviolet light polymerization; Adhere to clearly at ultraviolet light polymerization that the surface of primer coating sprays the ultraviolet light polymerization gel coating 3 that a layer thickness is 10 μ m again, get into that 2 9.6kw uviol lamps (high-pressure sodium lamp), transmission speed are arranged is in 5 meters/minute the photo solidification machine; Behind the ultraviolet light polymerization, utilize computer that personage's pattern of its storage is plotted in the surface of described ultraviolet light polymerization gel coating through the air brushing machine with printing ink, obtain the patterned layer 4 of personage's pattern; Naturally put 3 hours, make the painting printing ink drying after, spray the ultraviolet light polymerization topcoat 5 that a layer thickness is 5 μ m (gloss be 40 degree) again on the surface of printing pattern layer; 2 12kw uviol lamps (high-pressure sodium lamp) are equipped with in entering; Transmission speed is in 5 meters/minute the photo solidification machine, behind the ultraviolet light polymerization, to reach criterion of acceptability through test rating; Paste polypropylene diaphragm 6, promptly get figure painting air brushing ultraviolet light polymerization ceramic decorative panel finished product.
The ultraviolet light polymerization sealing is adhered to clearly, and the percentage by weight of priming paint consists of: epoxy acrylate 9%, urethane acrylate 20%, TPGDA 31%, EO-TMPTA 29%, French chalk 5%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 4%, BYK 055 1% and Disperbyk 103 1%.
The percentage by weight of ultraviolet cured adhesive consists of: epoxy acrylate 21%, acrylate copolymer 14%, TMPTA 48%, TPGDA 12%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 1%, benzil dimethyl ketal 1% and 2-benzyl-2-dimethylamino-1-(4-morpholinyl phenyl)-1-butanone 3%.
The percentage by weight of ultraviolet light polymerization finish paint consists of: fluorine-containing epoxy acrylate 15%, fluorochemical urethane acrylic acid ester 22%, TPGDA 17%, EO-TMPTA 30%, flatting silica 11.5%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 4%, BYK 0550.3% and Disperbyk 1030.2%.
Embodiment 3. abstract painting air brushing ultraviolet light polymerizations half porcelain decorative panel
See also Fig. 1.With half porcelain plate is decorative panel matrix 1, earlier that half porcelain plate sand milling is smooth and remove the dust on surface, is that the ultraviolet light polymerization of 20 μ m adheres to primer coating 2 clearly at surface roller coating one layer thickness again; 2 9.6kw uviol lamps (high-pressure sodium lamp) are equipped with in entering, and transmission speed is in 20 meters/minute the photo solidification machine, behind the ultraviolet light polymerization; Adhere to clearly at ultraviolet light polymerization that surface roller coating one layer thickness of primer coating is the ultraviolet light polymerization gel coating 3 of 20 μ m again, get into that 2 9.6kw uviol lamps (high-pressure sodium lamp), transmission speed are arranged is in 20 meters/minute the photo solidification machine; Behind the ultraviolet light polymerization; Utilize computer that the abstract painting of its storage is plotted in the surface of described ultraviolet light polymerization gel coating through the air brushing machine with printing ink, obtain the patterned layer 4 of abstract painting, put naturally 3 hours; After making the painting printing ink drying; Be the ultraviolet light polymerization topcoat 5 (gloss is 100 degree) of 30 μ m at surface roller coating one layer thickness of printing pattern layer again, get into 2 12kw uviol lamps (high-pressure sodium lamp) are housed that transmission speed is in 20 meters/minute the photo solidification machine; Behind the ultraviolet light polymerization; Reach criterion of acceptability through test rating, paste polypropylene diaphragm 6, promptly get abstract painting air brushing ultraviolet light polymerization half porcelain decorative panel finished product.
The ultraviolet light polymerization sealing is adhered to clearly, and the percentage by weight of priming paint consists of: epoxy acrylate 28%, urethane acrylate 19%, HDDA 22%, TPGDA 10%, French chalk 10%, barium sulfate 5%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 4.5%, BYK 0550.5% and Disperbyk 1631%.
The percentage by weight of ultraviolet cured adhesive consists of: epoxy acrylate 14.5%, acrylate copolymer 20%, TMPTA 40%, TPGDA 20%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, benzil dimethyl ketal 2%, 2-benzyl-2-dimethylamino-1-(4-morpholinyl phenyl)-1-butanone 1%, BYK306 0.2% and BYK055 0.3%.
The percentage by weight of ultraviolet curing transparent finish paint consists of: fluorine-containing epoxy acrylate 15%, fluorochemical urethane acrylic acid ester 30%, fluoro-acrylate copolymer 10%, TMPTA 25%, NPGDA14%, 1-hydroxy-cyclohexyl phenyl ketone 5%, BYK 055 0.4% and BYK 306 0.6%.
Claims (6)
1. ultraviolet light polymerization air brushing decorative panel; It is characterized in that: in the surfaces coated of decorative panel matrix the ultraviolet light polymerization sealing is housed and adheres to primer coating clearly; Adhering to clearly in described ultraviolet light polymerization sealing, the surfaces coated of primer coating is equipped with the ultraviolet cured adhesive coating; Surperficial air brushing at described ultraviolet light polymerization gel coating has patterned layer, in the surfaces coated of described patterned layer the ultraviolet light polymerization topcoat is housed.
2. ultraviolet light polymerization air brushing decorative panel according to claim 1, it is characterized in that: polypropylene diaphragm or polyethylene protective film are posted in the surface of described ultraviolet light polymerization topcoat.
3. ultraviolet light polymerization air brushing decorative panel according to claim 1 is characterized in that: described decorative panel matrix is selected from a kind of in porcelain plate, half porcelain plate, ceramic plate, type ceramic scutum.
4. ultraviolet light polymerization air brushing decorative panel according to claim 1 is characterized in that: the sealing of described ultraviolet light polymerization adheres to clearly that the thickness of primer coating is 5～100 μ m.
5. ultraviolet light polymerization air brushing decorative panel according to claim 1 is characterized in that: the thickness of described ultraviolet light polymerization gel coating is 5～100 μ m.
6. ultraviolet light polymerization air brushing decorative panel according to claim 1 is characterized in that: the thickness of described ultraviolet light polymerization topcoat is 5～200 μ m, and gloss is 10～100 degree, 60 degree gloss meters.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011204967241U CN202391056U (en) | 2011-12-02 | 2011-12-02 | Ultraviolet curing painting decorative plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011204967241U CN202391056U (en) | 2011-12-02 | 2011-12-02 | Ultraviolet curing painting decorative plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202391056U true CN202391056U (en) | 2012-08-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011204967241U Expired - Fee Related CN202391056U (en) | 2011-12-02 | 2011-12-02 | Ultraviolet curing painting decorative plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN202391056U (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104533043A (en) * | 2014-12-03 | 2015-04-22 | 珠海东诚光固化材料有限公司 | Decoration board and preparation method thereof |
| CN104989046A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing transfer-printing matte decoration plate and manufacturing method thereof |
| CN105644248A (en) * | 2015-09-28 | 2016-06-08 | 吴景标 | Ink jetting colored painting technology |
| CN106013672A (en) * | 2015-11-30 | 2016-10-12 | 珠海市佳伟力环保科技有限公司 | Radiation curable coating decorative board |
| JP2017166214A (en) * | 2016-03-16 | 2017-09-21 | 日新製鋼株式会社 | Method of manufacturing decorative building board |
| CN111037471A (en) * | 2019-12-06 | 2020-04-21 | 蒙娜丽莎集团股份有限公司 | Preparation method of color-spray UV (ultraviolet) bright ceramic board painting |
-
2011
- 2011-12-02 CN CN2011204967241U patent/CN202391056U/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104533043A (en) * | 2014-12-03 | 2015-04-22 | 珠海东诚光固化材料有限公司 | Decoration board and preparation method thereof |
| CN104989046A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing transfer-printing matte decoration plate and manufacturing method thereof |
| CN104989046B (en) * | 2014-12-29 | 2017-10-03 | 中关村人居环境工程与材料研究院 | A kind of ultra-violet curing transfer dumb light decorative panel and its manufacture method |
| CN105644248A (en) * | 2015-09-28 | 2016-06-08 | 吴景标 | Ink jetting colored painting technology |
| CN106013672A (en) * | 2015-11-30 | 2016-10-12 | 珠海市佳伟力环保科技有限公司 | Radiation curable coating decorative board |
| JP2017166214A (en) * | 2016-03-16 | 2017-09-21 | 日新製鋼株式会社 | Method of manufacturing decorative building board |
| CN111037471A (en) * | 2019-12-06 | 2020-04-21 | 蒙娜丽莎集团股份有限公司 | Preparation method of color-spray UV (ultraviolet) bright ceramic board painting |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120822 Termination date: 20161202 |
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| CF01 | Termination of patent right due to non-payment of annual fee |