CN105368299A - Ultraviolet light-cured glass decorative sheet, and preparation method and applications thereof - Google Patents
Ultraviolet light-cured glass decorative sheet, and preparation method and applications thereof Download PDFInfo
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- CN105368299A CN105368299A CN201510924953.1A CN201510924953A CN105368299A CN 105368299 A CN105368299 A CN 105368299A CN 201510924953 A CN201510924953 A CN 201510924953A CN 105368299 A CN105368299 A CN 105368299A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention relates to an ultraviolet light-cured glass decorative sheet, and a preparation method thereof. According to the preparation method, glass surface is coated with a layer of an ultraviolet light-cured adhesive priming paint; the surface of the layer of the ultraviolet light-cured adhesive priming paint is coated with a layer of an ultraviolet light-cured bonding glue; the surface of the layer of the ultraviolet light-cured bonding glue is coated with a layer of an ultraviolet light-cured transfer printing film via transfer printing; and the surface of the ultraviolet light-cured transfer printing film is coated with a layer of an ultraviolet light-cured film upper glue; the surface of the layer of the ultraviolet light-cured film upper glue is coated with a layer of an ultraviolet light-cured finish paint. According to an application method, the surface of the layer of the ultraviolet light-cured finish paint is coated with cement paste, and then the ultraviolet light-cured glass decorative sheet is pasted onto an object directly until cement solidification is realized. Needed production field is small; equipment cost is low; production efficiency is high; energy consumption is low; no pollution is caused; combustion is not easily caused; a problem that glass can not be glued with cement directly is solved; construction is convenient; cost is low; and resources are saved.
Description
Technical field
The invention belongs to material of construction decorative sheet field, a kind of decorative glass plate particularly prepared at glass surface application ultraviolet-curing paint (be called for short UV coating) and Synthesis and applications thereof.
Background technology
At present, the coating that decorative glass plate uses is mostly single-component coating, baking-type coating and two-component coating etc., and because its rate of drying is slow, production efficiency is low, occupied ground area is large, and containing a large amount of solvent, high pollution high energy consumption; UV coating is a kind of not containing the environment-friendly and green coating of volatile organic compounds, has curing speed fast, the advantages such as energy consumption is low, and facility investment is low, and paint film property is good; As Chinese patent CN202449997U discloses a kind of decorative glass plate adopting numerial code spray drawing to make, this product adopts two component epoxy series plastics gloss oil as the attachment silane coupling agent of glass, and then adopt silk screen printing digital jet ink, this product solves the difficult problem that UV coating is difficult at this surface compact hard material of glass adhere to, but bicomponent epoxy resin curing speed is slow, and production efficiency is low, construction is difficult, and numerial code spray drawing pattern is single, the defects such as ornamental difference.
Tradition adhering glass have two kinds of techniques, Yi Zhongshi: on glass, apply traditional glass glue, such as epoxies, acrylic acid or the like, silicone glass cement, after solidification, glass clung.This glass cement connects glass and adherend by chemical bond, and bonding strength is very high, but exists expensive, and curing speed is slow, pollutes the shortcomings such as large.Another is: on glass, make intersecting parallels grid, and this material is as fiber, and nylon, plastics etc., and fixing with the epoxy glue of two-pack, are clung glass by cement.It is loaded down with trivial details to there is making grid in this technique, the defect that cost is high, and bonding strength is not high, and the time one is long, and glass is easy to be separated with cement, causes damage and endangers.
Decorative glass plate prepared by the present invention has environment friendly and pollution-free, and production efficiency is high, and pattern enriches, by force ornamental, can design arbitrarily according to personal like; Meanwhile, owing to the addition of solidifying agent in finish paint, the isocyano in solidifying agent can with cement generation chemical reaction, the advantages such as bonding strength is very high, and durability degree is good, easy construction, cheap.
Summary of the invention
Object of the present invention is intended to solve the problem, and provides a kind of ultraviolet curing glass decorative sheet and preparation method thereof.
Another object of the present invention is to provide a kind of cementitious constructional method of ultraviolet curing glass decorative sheet.
Ultraviolet curing glass decorative sheet of the present invention comprises: glass, ultraviolet light polymerization adhesion primer, ultraviolet light polymerization bonded adhesives, ultra-violet curing transfer film, the gluing of ultraviolet light polymerization film, UV-curable finish coat; Described UV-light decorative glass plate is coated with one deck ultraviolet light polymerization adhesion primer at glass surface, one deck ultraviolet light polymerization bonded adhesives is coated with at ultraviolet light polymerization adhesion primer coatingsurface, at ultraviolet light polymerization bonded adhesives coatingsurface transfer printing one deck ultra-violet curing transfer film, there is the gluing of one deck ultraviolet light polymerization film at ultra-violet curing transfer film external coating, have one deck UV-curable finish coat at ultraviolet light polymerization film size coat external coating.
Described glass is simple glass, toughened glass, laminated glass, mat glass, silica glass, the one in synthetic glass.
Described ultraviolet light polymerization adhesion primer adopts the technique application of roller coat, spraying or showering, and thickness is 1 ~ 200um.
Described ultraviolet light polymerization bonded adhesives adopts the technique application of roller coat, spraying or showering, and thickness is 1 ~ 200um.
Described ultra-violet curing transfer film adopts the mode of transfer machine or manual pad pasting ultra-violet curing transfer film to be transferred to the tempered-glass decorative plate surface of glue under the ultraviolet light polymerization film being coated with and installing.
Described ultra-violet curing transfer film is the one in parian type, imitative wood grain type, jade stone-type, artificial granite type, radium-shine class transfer film.
Described ultraviolet light polymerization film gluing adopts the technique application of roller coat, spraying or showering, and thickness is 1 ~ 200um.
Described UV-curable finish coat adopts the technique application of roller coat, spraying or showering, and thickness is 1 ~ 200um, coating gloss with 60 degree Grossmeters measure be 10 ~ 120 degree adjustable.
The present invention also provides a kind of preparation method of ultraviolet curing glass decorative sheet, comprises the following steps:
1) glass surface treatment;
2) first time photocuring is carried out after application ultraviolet light polymerization adhesion primer on the glass surface;
3) glue under ultraviolet light polymerization adhesion primer coatingsurface application ultraviolet light polymerization film, infrared levelling or natural levelling;
4) under ultraviolet light polymerization film, after glue surface transfer ultra-violet curing transfer film, second time photocuring is carried out;
5) after the gluing of ultra-violet curing transfer film external coating film, third time photocuring is carried out;
6) at ultraviolet light polymerization film size coat external coating UV-curable finish coat, infrared levelling or natural levelling;
7) the 4th photocuring; Inspection, packaging.
Further, described step 3) or 6) infrared levelling be infrared levelling temperature is adjusted to 20 ~ 150 DEG C, flow time 0.1 ~ 10 minute.
Further, described step 2) or 4) or 5) or 7) described in photocuring be that the ultraviolet tube of employing 1 ~ 63 ~ 20kw and the metal halogen fluorescent tube of 0 ~ 33 ~ 20kw are combined into row and irradiate, irradiate speed 1 ~ 20 m/min.
The ultraviolet light polymerization adhesion primer used in the present invention, ultraviolet light polymerization bonded adhesives, the gluing of ultraviolet light polymerization film, ultraviolet light polymerization protective topcoat, by weight percentage: described ultraviolet light polymerization adhesion primer is made up of the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and silicone coupling agents 1 ~ 5%.Described ultraviolet light polymerization bonded adhesives is made up of the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 5% and filler 0 ~ 50%; Described ultraviolet light polymerization film gluing by acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 5% and filler 0 ~ 50% mixture formed; Described ultraviolet light polymerization protective topcoat is made up of the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and solidifying agent 1 ~ 5%.
Wherein acrylic ester prepolymer is one or more the above mixtures in epoxy acrylate, urethane acrylate, amino acrylates, polyester acrylate, pure acrylate;
Wherein acrylate monomer is butyl acrylate, Isooctyl acrylate monomer, (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, (methyl) iso-bornyl acrylate, two contracting three propyl alcohol diacrylates, one contracting two propyl alcohol diacrylates, propylene glycol diacrylate, (the third oxidation) neopentylglycol diacrylate, different certain herbaceous plants with big flowers base acrylate, 1, 6 hexanediyl esters, two (Diethylene Glycol) diacrylate of phthalic acid, Viscoat 295, (ethoxyquin) Viscoat 295, (the third oxidation) Viscoat 295, pentaerythritol triacrylate, Dipentaerythritol triacrylate, one or more above mixtures in Dipentaerythritol tetraacrylate,
Wherein light trigger comprises 2-hydroxy-2-methyl-1-phenyl-1-acetone (1173), 1-hydroxycyclohexyl phenyl ketone (184), 2-phenyl benzyl-2-dimethyl amine-1-(4-morpholine benzyl phenyl) butanone (369), phenyl two (2, 4, 6-trimethylbenzoyl) phosphine oxide (819), 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone (907), 2-isopropyl thioxanthone (ITX), 2, 4, 6-trimethylbenzoy-dipheny phosphine oxide (TPO), a, a-dimethoxy-a-phenyl acetophenone (651), two 2, one or more above mixtures in the 6-bis-fluoro-3-pyrroles luxuriant titanium of phenyl two (784),
Wherein silicone coupling agents comprises vinyltriethoxysilane, vinyltrimethoxy silane, vinyl three ('beta '-methoxy oxyethyl group) silane, γ-aminopropyltrimethoxysilane, γ-aminopropyl triethoxysilane, 3-aminopropyl trimethoxysilane, 3-glycydoxy Trimethoxy silane, γ-methacryloxy Trimethoxy silane, γ-aminopropyltriethoxy diethoxy silane, diethylin is for Union carbide A-162, anilinomethyl triethoxysilane, phenyltrimethoxysila,e, phenyl triethoxysilane, one or more above mixtures in titanate coupling agent,
Wherein filler is one or more the above mixtures in talcum powder, flatting silica, anti-scratch wax powder, process white, wilkinite;
Wherein auxiliary agent is one or more above mixtures of flow agent, wetting dispersing agent, adhesion promoter, defoamer;
Wherein solidifying agent comprise tolylene diisocyanate (TDI), diphenylmethanediisocyanate (MDI), different Buddhist diisocyanates (IPDI), hexamethylene diisocyanate (HDI), hexamethylene diisocyanate trimer (HDI tripolymer), containing the one in the urethane acrylate of free isocyanate groups.
The construction method of installation of ultraviolet curing glass decorative sheet of the present invention is at UV-curable finish coat surface-coated grout, is affixed in bonded object, treats that cement solidification firmly can be clung with bonded object.
Wherein, grout by weight percentage, wherein: ordinary Portland cement 10 ~ 80%, flyash 10 ~ 20%, fine sand 10 ~ 50%, methyl cellulose ether 0.5 ~ 1%, the mixture of dispersed latex powder 0.5 ~ 1%.
The making method of the ultraviolet curing glass decorative sheet produced by aforesaid method has curing speed soon, and production efficiency is high, and energy consumption is low, the free of contamination advantage of environmental protection.
The construction method of installation of ultraviolet curing glass decorative sheet of the present invention solves the problem that glass and cement cannot be directly bonding, by cement and UV-curable finish coat generation chemical crosslink reaction, make it have bonding strength high, persistence is good, easy construction, the advantage such as cheap.
Accompanying drawing explanation
Fig. 1 is the structure cross-sectional schematic of ultraviolet curing glass decorative sheet of the present invention.
Reference numeral
1. glass, 2. ultraviolet light polymerization adhesion primer, 3. ultraviolet light polymerization bonded adhesives, 4. ultra-violet curing transfer film, the 5. gluing of ultraviolet light polymerization film, 6. UV-curable finish coat.
Embodiment
Following content will elaborate to specific embodiments of the invention in conjunction with Figure of description:
Embodiment 1. imitates wood grain decorative glass plate
Refer to Fig. 1.Simple glass thickness is selected to be 5mm, first simple glass 1 is removed surface and oil contaminant, again at surface of ordinary glass roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 30um, enter and 2 11kw UV-light (high voltage mercury lamp) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidification, glue 3 under the ultraviolet light polymerization film being 10um in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness again, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, under ultraviolet light polymerization film, on glue, transfer printing one deck prints grained ultra-violet curing transfer film 4 again, enter and 2 16.8kw UV-light (high voltage mercury lamp) and 2 16.8kw metal halid lamps (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidification, remove base load film, on ultra-violet curing transfer film, roller coat a layer thickness is the ultraviolet light polymerization film gluing 5 of 10um again, enter and 2 9.6kw UV-light (high voltage mercury lamp) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidification, in the gluing of ultraviolet light polymerization film, showering a layer thickness is 100um again, gloss is the UV-curable finish coat 6 of 100 degree, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, enter and 2 16.8kw UV-light (high voltage mercury lamp) and 2 16.8kw metal halid lamps (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidification, criterion of acceptability is reached through test rating, packaging, obtain imitative wood grain glass decoration board finished product.
At imitative wood grain decorative glass plate surface (coating) precoating grout, be affixed on above primary coat, treat grout cures, just can by firmly bonding with primary coat for imitative wood grain decorative glass plate.
The weight percent of ultraviolet light polymerization adhesion primer consists of: urethane acrylate 25%, epoxy acrylate 10%; polyester acrylate 20%; iso-bornyl acrylate 35%; 2,4,6-trimethylbenzoy-dipheny phosphine oxide (TPO) 2%; 2-hydroxy-2-methyl-1-phenyl-1-acetone (1173) 5%; flow agent 0.5%, defoamer 0.5%, γ-methacryloxy Trimethoxy silane 2%.
Under ultraviolet light polymerization film, the weight percent of glue consists of: pure acrylate 30%, epoxy acrylate 15%; two contracting three propyl alcohol diacrylates 30%; butyl acrylate 18%; 2,4,6-trimethylbenzoy-dipheny phosphine oxide (TPO) 3%; 2-isopropyl thioxanthone (ITX) 2%; flow agent 0.5%, dispersion agent 1%, defoamer 0.5%.
The weight percent of ultraviolet light polymerization film gluing consists of: polyester acrylate 43%, urethane acrylate 10%, ethoxyquin Viscoat 295 20%, butyl acrylate 5%, hydroxyethyl methylacrylate 15%, 2-hydroxy-2-methyl-1-phenyl-1-acetone (1173) 5%, flow agent 0.5%, dispersion agent 1%, defoamer 0.5%.
The weight percent of ultraviolet light polymerization protective topcoat consists of: epoxy acrylate 30%, urethane acrylate 15%; pentaerythritol triacrylate 20%; third oxidation Viscoat 295 25%; 1-hydroxycyclohexyl phenyl ketone (184) 4%; flow agent 0.5%; defoamer 0.5%, different Buddhist diisocyanates (IPDI) 5%.
The weight percent of grout consists of: ordinary Portland cement 50%, flyash 10%, fine sand 39%, methyl cellulose ether 0.5%, dispersed latex powder 0.5%.
Imitative wood grain type ultra-violet curing transfer film is provided by Zhuhai Dongcheng UV Materials Co., Ltd..
embodiment 2. artificial granite stone decorative glass plate
Refer to Fig. 1.Toughened glass thickness is selected to be 5mm, first toughened glass 1 is removed surface and oil contaminant, again at toughened glass surface roller coating one deck ultraviolet light polymerization adhesion primer 2, thickness is 45um, enter and 2 13kw UV-light (high voltage mercury lamp) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidification, glue 3 under the ultraviolet light polymerization film being 50um in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness again, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, under ultraviolet light polymerization film, on glue, transfer printing one deck is printed on the ultra-violet curing transfer film 4 of grouan line again, enter and 2 16.8kw UV-light (high voltage mercury lamp) and 1 16.8kw metal halid lamp (iron lamp) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidification, remove base load film, on ultra-violet curing transfer film, roller coat a layer thickness is the ultraviolet light polymerization film gluing 5 of 45um again, enter and 2 16.8kw UV-light (high voltage mercury lamp) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidification, in the gluing of ultraviolet light polymerization film, roller coat is coated with a layer thickness is again 10um, gloss is the UV-curable finish coat 6 of 20 degree, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, enter and 2 16.8kw UV-light (high voltage mercury lamp) and 1 16.8kw metal halid lamp (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidification, criterion of acceptability is reached through test rating, packaging, obtain the tempered-glass decorative board finished product of artificial granite.
At artificial granite decorative glass plate surface (coating) precoating grout, be affixed on above primary coat, treat grout cures, just can be firmly bonding with primary coat by artificial granite decorative glass plate.
The weight percent of ultraviolet light polymerization adhesion primer consists of: polyester acrylate 20%, urethane acrylate 30%, Hydroxyethyl acrylate 30%, methylisobomyl acrylate 10%, 2-hydroxy-2-methyl-1-phenyl-1-acetone (1173) 5%, flow agent 0.3%, defoamer 0.2%, wetting dispersing agent 0.5%, 3-glycydoxy Trimethoxy silane 4%.
Under ultraviolet light polymerization film, the weight percent of glue consists of: urethane acrylate
20%, polyester acrylate 25%; propylene glycol diacrylate 30%; tri (propylene glycol) diacrylate 18%; 2; 4,6-trimethylbenzoy-dipheny phosphine oxide (TPO) 3%, 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone (907) 2%; flow agent 1.5%, defoamer 0.5%.
The weight percent of ultraviolet light polymerization film gluing consists of: pure acrylate 35%, epoxy acrylate 10%, Viscoat 295 20%, butyl acrylate 8%, hydroxyethyl methylacrylate 15%, 1-hydroxycyclohexyl phenyl ketone (184) 5%, flow agent 0.5%, defoamer 1.5%.
The weight percent of ultraviolet light polymerization protective topcoat consists of: urethane acrylate 45%; butyl acrylate 20%; third oxidation Viscoat 295 20%; 1-hydroxycyclohexyl phenyl ketone (184) 4%; flow agent 0.5%; defoamer 0.5%, containing the urethane acrylate 10% of free isocyanate groups.
The weight percent of grout consists of: ordinary Portland cement 30%, flyash 20%, fine sand 48%, methyl cellulose ether 1%, dispersed latex powder 1%.
Artificial granite type ultra-violet curing transfer film is provided by Zhuhai Dongcheng UV Materials Co., Ltd..
embodiment 3. imitative metal laser effect decorative glass plate
Refer to Fig. 1.Synthetic glass thickness is 5mm, first synthetic glass 1 is removed surface
Greasy dirt, again at synthetic glass surface roller coating one deck ultraviolet light polymerization adhesion primer 2, thickness is 30um, enter and 2 9.6kw UV-light (high voltage mercury lamp) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidification, glue 3 under the ultraviolet light polymerization film being 15um in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness again, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, under ultraviolet light polymerization film, on glue, transfer printing one deck is printed on the radium-shine ultra-violet curing transfer film 4 of metal again, enter and 2 16.8kw UV-light (high voltage mercury lamp) and 1 16.8kw metal halid lamp (iron lamp) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidification, remove base load film, on ultra-violet curing transfer film, roller coat a layer thickness is the ultraviolet light polymerization film gluing 5 of 10um again, enter and 2 16.8kw UV-light (high voltage mercury lamp) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidification, in the gluing of ultraviolet light polymerization film, spraying is coated with a layer thickness is again 40um, gloss is the UV-curable finish coat 6 of 90 degree, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, enter and 2 16.8kw UV-light (high voltage mercury lamp) and 1 16.8kw metal halid lamp (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidification, criterion of acceptability is reached through test rating, packaging, obtain the shatter proof glass decorative sheet finished product of imitative metal laser effect.
At imitative metal laser effect decorative glass plate surface (coating) precoating grout, be affixed on above primary coat, treat grout cures, just can by firmly bonding with primary coat for imitative metal laser effect decorative glass plate.
The weight percent of ultraviolet light polymerization adhesion primer consists of: urethane acrylate 20%, polyester acrylate 35%, 1,6 hexanediyl esters 20%, Dipentaerythritol triacrylate 18%, 1-hydroxycyclohexyl phenyl ketone (184) 5%, flow agent 0.5%, defoamer 0.5%, vinyltriethoxysilane 1%.
Under ultraviolet light polymerization film, the weight percent of glue consists of: epoxy acrylate 20%,
Pure acrylate 25%; different certain herbaceous plants with big flowers base acrylate 33%; tri (propylene glycol) diacrylate 15%; 2; 4,6-trimethylbenzoy-dipheny phosphine oxide (TPO) 3%, 2-phenyl benzyl-2-dimethyl amine-1-(4-morpholine benzyl phenyl) butanone (369) 2%; flow agent 1.5%, defoamer 0.5%.
The weight percent of ultraviolet light polymerization film gluing consists of: amino acrylates 35%, urethane acrylate 10%, ethoxyquin Viscoat 295 29%, butyl acrylate 5%, hydroxyethyl methylacrylate 15%, 1-hydroxycyclohexyl phenyl ketone (184) 5%, flow agent 0.5%, defoamer 0.5%.
The weight percent of UV-curable finish coat consists of: urethane acrylate 45%, epoxy acrylate 35%, pentaerythritol triacrylate 10%, 1-hydroxycyclohexyl phenyl ketone (184) 4%, flow agent 0.5%, defoamer 0.5%, hexamethylene diisocyanate (HDI) 5%.
The weight percent of grout consists of: ordinary Portland cement 75%, flyash 10%, fine sand 13.5%, methyl cellulose ether 0.7%, dispersed latex powder 0.8%.
Radium-shine metal effect ultra-violet curing transfer film is provided by Zhuhai Dongcheng UV Materials Co., Ltd..
The above, be only preferred embodiment of the present invention, and all equalizations done according to shape of the present invention, structure, feature and spirit change and modify, and all should be included within protection scope of the present invention.
Claims (15)
1. a ultraviolet curing glass decorative sheet, is characterized in that: described UV-light decorative glass plate comprises: glass, ultraviolet light polymerization adhesion primer, ultraviolet light polymerization bonded adhesives, ultra-violet curing transfer film, the gluing of ultraviolet light polymerization film, UV-curable finish coat; One deck ultraviolet light polymerization adhesion primer is coated with at described glass surface, at primer coating external coating one deck ultraviolet light polymerization bonded adhesives, at ultraviolet light polymerization bonded adhesives coatingsurface transfer printing one deck ultra-violet curing transfer film, there is the gluing of one deck ultraviolet light polymerization film at ultra-violet curing transfer film external coating, have one deck UV-curable finish coat at ultraviolet light polymerization film size coat external coating.
2. ultraviolet curing glass decorative sheet according to claim 1, it is characterized in that, described ultraviolet light polymerization adhesion primer by weight percentage, wherein: the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and silicone coupling agents 1 ~ 5%.
3. ultraviolet curing glass decorative sheet according to claim 1, it is characterized in that, described ultraviolet light polymerization bonded adhesives by weight percentage, wherein: the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 5% and filler 0 ~ 50%; The gluing of described ultraviolet light polymerization film by weight percentage, wherein: the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 5% and filler 0 ~ 50%.
4. ultraviolet curing glass decorative sheet according to claim 1, it is characterized in that, described UV-curable finish coat by weight percentage, wherein: the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and solidifying agent 1 ~ 5%.
5. ultraviolet curing glass decorative sheet according to claim 1, is characterized in that: the thickness of described ultraviolet light polymerization adhesion primer is 1 ~ 200um; The thickness of described ultraviolet light polymerization bonded adhesives is 1 ~ 200um; The thickness of described ultraviolet light polymerization film gluing is 1 ~ 200um; The thickness of described UV-curable finish coat is 1 ~ 200um, coating gloss with the metering of 60 degree of Grossmeters be 10 ~ 120 degree adjustable.
6. the ultraviolet curing glass decorative sheet according to any one of claim 2 ~ 4, is characterized in that: described acrylic ester prepolymer comprises: one or more in epoxy acrylate, urethane acrylate, amino acrylates, polyester acrylate, pure acrylate, described acrylate monomer comprises: butyl acrylate, Isooctyl acrylate monomer, (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, (methyl) iso-bornyl acrylate, two contracting three propyl alcohol diacrylates, one contracting two propyl alcohol diacrylates, propylene glycol diacrylate, (the third oxidation) neopentylglycol diacrylate, different certain herbaceous plants with big flowers base acrylate, 1, 6 hexanediyl esters, two (Diethylene Glycol) diacrylate of phthalic acid, Viscoat 295, (ethoxyquin) Viscoat 295, (the third oxidation) Viscoat 295, pentaerythritol triacrylate, Dipentaerythritol triacrylate, one or more in Dipentaerythritol tetraacrylate.
7. the ultraviolet curing glass decorative sheet according to any one of claim 2 ~ 4, it is characterized in that: described light trigger comprises: 2-hydroxy-2-methyl-1-phenyl-1-acetone (1173), 1-hydroxycyclohexyl phenyl ketone (184), 2-phenyl benzyl-2-dimethyl amine-1-(4-morpholine benzyl phenyl) butanone (369), phenyl two (2, 4, 6-trimethylbenzoyl) phosphine oxide (819), 2-methyl isophthalic acid-[4-(methyl thio) phenyl]-2-(4-morpholinyl)-1-acetone (907), 2-isopropyl thioxanthone (ITX), 2, 4, 6-trimethylbenzoy-dipheny phosphine oxide (TPO), a, a-dimethoxy-a-phenyl acetophenone (651) two 2, one or more in the 6-bis-fluoro-3-pyrroles luxuriant titanium of phenyl two (784), described auxiliary agent comprises: one or more of flow agent, wetting dispersing agent, adhesion promoter, defoamer.
8. ultraviolet curing glass decorative sheet according to claim 2, it is characterized in that: described silicone coupling agents comprises: vinyltriethoxysilane, vinyltrimethoxy silane, vinyl three ('beta '-methoxy oxyethyl group) silane, γ-aminopropyltrimethoxysilane, γ-aminopropyl triethoxysilane, 3-aminopropyl trimethoxysilane, 3-glycydoxy Trimethoxy silane, γ-methacryloxy Trimethoxy silane, γ-aminopropyltriethoxy diethoxy silane, diethylin is for Union carbide A-162, anilinomethyl triethoxysilane, phenyltrimethoxysila,e, phenyl triethoxysilane, one or more in titanate coupling agent.
9. decorative glass plate according to claim 3, is characterized in that: described filler comprises: one or more in talcum powder, flatting silica, anti-scratch wax powder, process white, wilkinite.
10. decorative glass plate according to claim 4, is characterized in that: described solidifying agent comprises: tolylene diisocyanate (TDI), diphenylmethanediisocyanate (MDI), different Buddhist diisocyanates (IPDI), hexamethylene diisocyanate (HDI), hexamethylene diisocyanate trimer (HDI tripolymer), containing the one in the urethane acrylate of free isocyanate groups.
The preparation method of 11. 1 kinds of ultraviolet curing glass decorative sheets, is characterized in that, the step of described preparation method comprises:
1) glass surface treatment;
2) first time photocuring is carried out after application ultraviolet light polymerization adhesion primer on the glass surface;
3) glue under ultraviolet light polymerization adhesion primer coatingsurface application ultraviolet light polymerization film, infrared levelling;
4) under ultraviolet light polymerization film, after glue surface transfer ultra-violet curing transfer film, second time photocuring is carried out;
5) after the gluing of ultra-violet curing transfer film external coating film, third time photocuring is carried out;
6) at ultraviolet light polymerization film size coat external coating UV-curable finish coat, infrared levelling or natural levelling;
7) the 4th photocuring.
The preparation method of 12. ultraviolet curing glass decorative sheets according to claim 11, is characterized in that, described step 3) or 6) infrared levelling be infrared levelling temperature is adjusted to 20 ~ 150 DEG C, flow time 0.1 ~ 10 minute.
The preparation method of 13. ultraviolet curing glass decorative sheets according to claim 11, it is characterized in that, described step 2) or 4) or 5) or 7) described in photocuring be the ultraviolet tube of employing 1 ~ 63 ~ 20kw and the metal halogen fluorescent tube of 0 ~ 33 ~ 20kw be combined into row irradiate, irradiate speed 1 ~ 20 m/min.
The installation method of 14. 1 kinds of ultraviolet curing glass decorative sheets according to claim 1, it is characterized in that: the installation method of described ultraviolet curing glass decorative sheet is at UV-curable finish coat surface-coated grout, be affixed in bonded object, treat that grout cures firmly can cling with bonded object.
The installation method of 15. ultraviolet curing glass decorative sheets according to claim 14, it is characterized in that: described grout by weight percentage, wherein: ordinary Portland cement 10 ~ 80%, flyash 10 ~ 20%, fine sand 10 ~ 50%, methyl cellulose ether 0.5 ~ 1%, the mixture of dispersed latex powder 0.5 ~ 1%.
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| CN108148498A (en) * | 2017-12-22 | 2018-06-12 | 北京首创纳米科技有限公司 | A kind of photochromic glass coating and preparation method thereof |
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| CN114835408B (en) * | 2022-04-29 | 2023-08-15 | 江苏秀强玻璃工艺股份有限公司 | Preparation process of underglaze-like durable decorative glass panel |
| CN114716855A (en) * | 2022-05-24 | 2022-07-08 | 洁士美建材科技有限公司 | Waterproof coating for waterproofing buildings |
| CN116948459A (en) * | 2023-08-24 | 2023-10-27 | 武汉华工图像技术开发有限公司 | High-performance low-temperature ink suitable for inorganic sheet and preparation and use methods thereof |
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