CN103866939B - A kind of new type of safe decorative glass plate and preparation method thereof - Google Patents
A kind of new type of safe decorative glass plate and preparation method thereof Download PDFInfo
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- CN103866939B CN103866939B CN201410095550.6A CN201410095550A CN103866939B CN 103866939 B CN103866939 B CN 103866939B CN 201410095550 A CN201410095550 A CN 201410095550A CN 103866939 B CN103866939 B CN 103866939B
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Abstract
The present invention relates to a kind of safety glass decorative panel and preparation method thereof.One deck ultraviolet light polymerization adhesion primer is coated with in surface of ordinary glass; glue under ultraviolet light polymerization adhesion primer coating surface is coated with one deck ultraviolet light polymerization film; gel coating surface transfer one deck ultra-violet curing transfer film under ultraviolet light polymerization film; there is the gluing of one deck ultraviolet light polymerization film at ultra-violet curing transfer film external coating, have one deck ultraviolet light polymerization protective topcoat at ultraviolet light polymerization film size coat external coating.New type of safe decorative glass plate of the present invention has that required production site is little, equipment investment is low, production efficiency is high, less energy consumption and pollution-free; Safety glass decorative panel can reach the intensity of tempered glass, durability of coating is good, Heat stability is good, color pattern abundant, paint film is plentiful, hardness is high, scratch resistance, easy to clean and nonflammable advantage, has better decorative effect and defencive function than the tempered-glass decorative plate generally used at present.
Description
Technical field
The invention belongs to constructional materials decorative panel field, particularly a kind of new type of safe decorative glass plate of producing of external coating ultraviolet-curing paint (be called for short UV coating) and preparation method thereof.
Background technology
Along with the development of building trade and the requirement of people to living space environment more and more higher, glass is applied more and more widely in fields such as door and window, curtain wall and interior decorations.And the hidden danger of simple glass greatly limit its scope of application.Tempered glass due to intensity high, heat-resistant stability is good, and safety factor is high, is more and more subject to the favor in market, but tempered glass is expensive, and can not repeat processing use, limit its development speed to a certain extent.At present, the coating that decorative glass plate uses is mostly one-component coating, baking-type coating and two-component coating etc., and because its rate of drying is slow, production efficiency is low, occupied ground area is large, and containing a large amount of solvent, high pollution high energy consumption; UV coating is a kind of not containing the environment-friendly and green coating of VOC, has curing rate fast, the advantages such as energy consumption is low, and equipment investment is low, and paint film property is good; As Chinese patent CN202449997U discloses a kind of decorative glass plate adopting numerial code spray drawing to make, this product adopts two component epoxy series plastics gloss oil as the attachment silane coupling agent of glass, and then adopt serigraphy digital jet ink, this product solves the difficult problem that UV coating is difficult at this surface compact hard material of glass adhere to, but bicomponent epoxy resin curing rate is slow, and production efficiency is low, construction is difficult, and numerial code spray drawing pattern is single, ornamental difference.
Summary of the invention
Object of the present invention is intended to solve the problem, and provides a kind of a kind of new type of safe decorative glass plate having security performance and decorate properties concurrently, can reach the intensity of tempered glass.
Another object of the present invention is to provide a kind of preparation method of novel safety glass decorative panel.
New type of safe decorative glass plate of the present invention is coated with one deck ultraviolet light polymerization adhesion primer in surface of ordinary glass; glue under ultraviolet light polymerization adhesion primer coating surface is coated with one deck ultraviolet light polymerization film; gel coating surface transfer one deck ultra-violet curing transfer film under ultraviolet light polymerization film; there is the gluing of one deck ultraviolet light polymerization film at ultra-violet curing transfer film external coating, have one deck ultraviolet light polymerization protective topcoat at ultraviolet light polymerization film size coat external coating.
The thickness of described simple glass is 2 ~ 20mm.
Described ultraviolet light polymerization adhesion primer adopts the technique application of roller coat, spraying or showering, and thickness is 10 ~ 100um.
Under described ultraviolet light polymerization film, glue adopts the technique application of roller coat, spraying or showering, and thickness is 10 ~ 100um.
Described ultra-violet curing transfer film adopts the mode of transfer interpreter or manual pad pasting ultra-violet curing transfer film to be transferred to the tempered-glass decorative plate surface of glue under the ultraviolet light polymerization film being coated with and installing.
Described ultraviolet light polymerization film gluing adopts the technique application of roller coat, spraying or showering, and thickness is 10 ~ 100um.
Described ultraviolet light polymerization protective topcoat adopts the technique application of roller coat, spraying or showering, and thickness is 10 ~ 100um, gloss be 10 ~ 100 degree adjustable.
The preparation method of new type of safe decorative glass plate of the present invention, its step comprises surface of ordinary glass and cleans, application ultraviolet light polymerization adhesion primer in surface of ordinary glass, photocuring, glue under ultraviolet light polymerization adhesion primer coating surface application ultraviolet light polymerization film, infrared levelling or natural levelling, glue surface transfer ultra-violet curing transfer film under ultraviolet light polymerization film, photocuring, remove base load film, in the gluing of ultra-violet curing transfer film external coating film, photocuring, at ultraviolet light polymerization film size coat external coating ultraviolet light polymerization protective topcoat, infrared levelling or natural levelling, photocuring, described infrared levelling is that infrared levelling temperature is adjusted to 20 ~ 150 DEG C, flow time 0.1 ~ 10 minute,
Described photocuring is that the ultraviolet tube of employing 1 ~ 63 ~ 20kw and the metal halogen fluorescent tube of 0 ~ 33 ~ 20kw irradiate, and irradiates speed 1 ~ 20 m/min.
The preparation method of new type of safe decorative glass plate of the present invention comprises the following steps:
(1), surface of ordinary glass cleans;
(2), application ultraviolet light polymerization adhesion primer on the simple glass of step (1);
(3), photocuring;
(4), glue under application ultraviolet light polymerization film on the simple glass of step (3);
(5), infrared levelling or natural levelling;
(6), transfer printing ultra-violet curing transfer film on the simple glass of step (5);
(7), photocuring;
(8), base load film is removed;
(9), application ultraviolet light polymerization film gluing on the simple glass of step (8);
(10), photocuring;
(11), application ultraviolet light polymerization protective topcoat on the simple glass of step (10);
(12), infrared levelling or natural levelling;
(13), photocuring;
(14), check;
(15), pack.
Glue, the gluing of ultraviolet light polymerization film, ultraviolet light polymerization protective topcoat under the ultraviolet light polymerization adhesion primer used in the present invention, ultraviolet light polymerization film, by weight percentage: described ultraviolet light polymerization adhesion primer is made up of the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and filler 5 ~ 50%; Under described ultraviolet light polymerization film, glue is made up of the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and filler 5 ~ 50%; Described ultraviolet light polymerization film gluing is made up of the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and filler 5 ~ 50%; Described ultraviolet light polymerization protective topcoat: the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and filler 5 ~ 50% formed.
Wherein acrylic ester prepolymer is one or more the above mixtures in urethane acrylate, epoxy acrylate, polyester acrylate, amino acrylates, acrylate copolymer (fluoro-acrylate copolymer), fluorochemical urethane acrylate, fluorine-containing epoxy acrylate, fluorine-containing polyester acrylate, fluorine-containing amino acrylates fluoro-acrylate copolymer.
Wherein acrylate monomer is: butyl acrylate, Isooctyl acrylate monomer, hydroxyethyl methacrylate, iso-bornyl acrylate, two contracting three propyl alcohol diacrylates, propylene glycol diacrylate, third oxidation neopentylglycol diacrylate, different certain herbaceous plants with big flowers base acrylate, 1, 6 hexylene glycol omega-diol diacrylates, two (diethylene glycol) diacrylate of phthalic acid, trimethylolpropane triacrylate, ethoxyquin trimethylolpropane triacrylate, third oxidation trimethylolpropane triacrylate, pentaerythritol triacrylate, one in dipentaerythritol triacrylate or its mixture.
Wherein light trigger is one in Ciba1173, Ciba184, Ciba369, Ciba907, Ciba819, TPO, ITX of Qi Ba fine chemistry company of Switzerland or its mixture.
Wherein auxiliary agent is one in levelling agent, defoamer, adhesion promoter, photosensitivity promotor, wetting dispersing agent or its any mixture.
Wherein filler is one or more in French chalk, flatting silica, anti-scratch wax powder, blanc fixe, swell soil.
The ultra-violet curing transfer film that the present invention uses consists of the following components: base load film, release layer, ultraviolet-curing paint topping, ultraviolet light polymerization decoration layer, ultraviolet-curing paint background color layer, it is characterized in that, by weight percentage: described release layer is made up of the mixture of cellulose family 20 ~ 50%, wax class 1 ~ 30%, silicone oil 0 ~ 10%, butanone 10 ~ 20%, ethyl acetate 5 ~ 15%, acrylic ester prepolymer 5 ~ 20%, acrylate monomer 5 ~ 20%, light trigger 1 ~ 6%; Described uv protection layer is made up of the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 6%, auxiliary agent 0 ~ 2%, filler 0 ~ 50%, butanone 0 ~ 10%, ethyl acetate 0 ~ 15%; Described ultraviolet light polymerization decoration layer is made up of the mixture of acrylic ester prepolymer 10 ~ 60%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2%, filler 0 ~ 50%, toner 5 ~ 30%, butanone 0 ~ 10% and ethyl acetate 0 ~ 15%; Described ultraviolet-curing paint background color layer is made up of the mixture of acrylic ester prepolymer 10 ~ 50%, acrylate monomer 10 ~ 40%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2%, filler 0 ~ 30%, toner 5 ~ 30%, butanone 0 ~ 10%, ethyl acetate 0 ~ 15%.
Described base load film is the one in polypropylene screen, polyethylene film, polychloroethylene film, PETG film.
Described cellulose family is methylcellulose, and described wax class is modified paraffin, palm wax or their mixture; Described silicone oil is selected from least one in the group that methyl-silicone oil, polymethylphenyl siloxane fluid, hydroxy silicon oil etc. form.
Described acrylic ester prepolymer is one or more the above mixtures in urethane acrylate, epoxy acrylate, polyester acrylate, amino acrylates, fluorochemical urethane acrylate, fluorine-containing epoxy acrylate, fluorine-containing polyester acrylate, fluorine-containing amino acrylates.
Described acrylate monomer is: butyl acrylate, Isooctyl acrylate monomer, hydroxy-ethyl acrylate, hydroxyethyl methacrylate, iso-bornyl acrylate, two contracting three propyl alcohol diacrylates, propylene glycol diacrylate, third oxidation neopentylglycol diacrylate, different certain herbaceous plants with big flowers base acrylate, 1, 6 hexylene glycol omega-diol diacrylates, two (diethylene glycol) diacrylate of phthalic acid, trimethylolpropane triacrylate, ethoxyquin trimethylolpropane triacrylate, third oxidation trimethylolpropane triacrylate, pentaerythritol triacrylate, one in dipentaerythritol triacrylate or its mixture.
Described light trigger is one in Ciba1173, Ciba184, Ciba369, Ciba907, Ciba819, TPO, ITX of Qi Ba fine chemistry company of Switzerland or its mixture.
Described auxiliary agent is one in levelling agent, defoamer, adhesion promoter, photosensitivity promotor, wetting dispersing agent or its any mixture.
Described filler is one or more in French chalk, flatting silica, anti-scratch wax powder, blanc fixe, swell soil.
Described toner comprises: one or more in inorganic pigment, organic pigment, aluminium silver powder, pearl essence.
Inspection:
Whether the safety glass decorative panel that inspection makes is qualified.
Packaging:
According to product specification and require to finished product packing.
The safety glass decorative panel produced by said method has that safety factor is high, good weatherability, Heat stability is good, color pattern are abundant, paint film is plentiful, hardness is high, scratch resistance and nonflammable advantage, has better decorative effect and defencive function than the tempered-glass decorative plate generally used at present.
The preparation method of new type of safe decorative glass plate of the present invention has curing rate soon, and production efficiency is high, and energy consumption is low, the free of contamination advantage of environmental protection.Decorative panel intensity of the present invention is high, durability of coating good, Heat stability is good, color pattern abundant, paint film is plentiful, hardness is high, scratch resistance, easy to clean and nonflammable advantage, has better decorative effect and defencive function than the tempered-glass decorative plate generally used at present.
accompanying drawing illustrates:
Fig. 1 is the structure cross-sectional schematic of new type of safe decorative glass plate of the present invention.
Reference numeral
1, glue 4, ultra-violet curing transfer film 5, ultraviolet light polymerization film gluing 6, ultraviolet light polymerization protective topcoat under simple glass 2, ultraviolet light polymerization adhesion primer 3, ultraviolet light polymerization film.
Detailed description of the invention
Following content will elaborate to specific embodiments of the invention in conjunction with Figure of description:
Embodiment 1. imitates wood grain safety glass decorative panel
Refer to Fig. 1.Simple glass thickness is 10mm, first simple glass 1 is removed surface and oil contaminant, again at surface of ordinary glass roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 20um, enter and 2 7.5kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidification, glue 3 under the ultraviolet light polymerization film being 25um in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness again, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, under ultraviolet light polymerization film, on glue, transfer printing one deck prints grained ultra-violet curing transfer film 4 again, enter and 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 2 16.8kw metal halid lamps (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidification, remove base load film, on ultra-violet curing transfer film, roller coat a layer thickness is the ultraviolet light polymerization film gluing 5 of 15um again, enter and 2 9.6kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidification, in the gluing of ultraviolet light polymerization film, showering a layer thickness is 100um again, gloss is the ultraviolet light polymerization protective topcoat 6 of 100 degree, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, enter and 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 2 16.8kw metal halid lamps (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidification, criterion of acceptability is reached through test rating, packaging, obtain imitative wood grain safety glass decorative panel finished product.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: urethane acrylate 25%, epoxy acrylate 20%, hydroxyethyl methacrylate 30%, iso-bornyl acrylate 13%, French chalk 5%, Ciba11735%, levelling agent 0.5%, adhesion promoter 0.5%, defoamer 0.5%, wetting dispersing agent 0.5%.
Under ultraviolet light polymerization film, the percentage by weight of glue consists of: polyester acrylate 20%, epoxy acrylate 25%, two contracting three propyl alcohol diacrylates 30%, butyl acrylate 18%, TPO3%, ITX2%, levelling agent 0.5%, photosensitivity promotor 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization film gluing consists of: acrylate copolymer 43%, urethane acrylate 10%, trimethylolpropane triacrylate 20%, butyl acrylate 5%, hydroxyethyl methacrylate 15%, Ciba1845%, levelling agent 0.5%, adhesion promoter 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization protective topcoat consists of: epoxy acrylate 35%, urethane acrylate 15%; pentaerythritol triacrylate 20%, the third oxidation trimethylolpropane triacrylate 25%, Ciba1844%; levelling agent 0.5%, defoamer 0.5%.
Ultra-violet curing transfer film used adopts gravure application to make, and base load film is polypropylene screen.
Mould release is by weight percentage: methylcellulose 41%, modified paraffin 20%, butanone 18%, ethyl acetate 5%, amino acrylates 5%, butyl acrylate 10%, Ciba11731%.
Ultraviolet light polymerization topping is by weight percentage: amino acrylates 10%, acrylate copolymer 50%, hydroxyethyl methacrylate 9.5%, acrylic acid trifluoro ethyl ester 10%, TPO5%, levelling agent 0.2%, dispersing agent 0.3%, flatting silica 5%.
Ultraviolet light polymerization patterned layer is by weight percentage: amino acrylates 5%, urethane acrylate 25%, acrylate copolymer 15%, tri (propylene glycol) diacrylate 10%, propylene glycol diacrylate 9.8%, Ciba11732%, TPO3%, levelling agent 0.1%, dispersing agent 0.1%, French chalk 5%, iron white powder 25%.
Ultraviolet light polymerization background color layer is by weight percentage: epoxy acrylate 10%, amino acrylates 17.5%, acrylate copolymer 15%, ethoxyquin trimethylolpropane triacrylate 15%, propylene glycol diacrylate 10%, Ciba1842%, TPO3%, levelling agent 0.2%, yellow powder 25%, ethyl acetate 2.3%.
embodiment 2. parian safety glass decorative panel
Refer to Fig. 1.Simple glass thickness is 5mm, first simple glass 1 is removed surface and oil contaminant, again at surface of ordinary glass roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 15um, enter and 2 9.6kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidification, glue 3 under the ultraviolet light polymerization film being 20um in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness again, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, under ultraviolet light polymerization film, on glue, transfer printing one deck is printed on marbled ultra-violet curing transfer film 4 again, enter and 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 1 16.8kw metal halid lamp (iron lamp) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidification, remove base load film, on ultra-violet curing transfer film, roller coat a layer thickness is the ultraviolet light polymerization film gluing 5 of 20um again, enter and 2 16.8kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidification, in the gluing of ultraviolet light polymerization film, roller coat is coated with a layer thickness is again 30um, gloss is the ultraviolet light polymerization protective topcoat 6 of 20 degree, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, enter and 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 1 16.8kw metal halid lamp (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidification, criterion of acceptability is reached through test rating, packaging, obtain the tempered-glass decorative board finished product of parian.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: polyester acrylate 20%, epoxy acrylate 25%, hydroxy-ethyl acrylate 30%, methylisobomyl acrylate 10%, French chalk 8.5%, Ciba11735%, levelling agent 0.3%, adhesion promoter 0.5%, defoamer 0.2%, wetting dispersing agent 0.5%.
Under ultraviolet light polymerization film, the percentage by weight of glue consists of: urethane acrylate 20%, polyester acrylate 25%, propylene glycol diacrylate 30%, tri (propylene glycol) diacrylate 18%, TPO3%, Ciba9072%, levelling agent 0.5%, photosensitivity promotor 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization film gluing consists of: acrylate copolymer 35%, epoxy acrylate 10%, trimethylolpropane triacrylate 20%, butyl acrylate 8%, hydroxyethyl methacrylate 15%, Ciba1845%, levelling agent 0.5%, adhesion promoter 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization protective topcoat consists of: fluorochemical urethane acrylate 45%, and acrylic acid hexafluoro butyl ester 20%, third is oxidized trimethylolpropane triacrylate 25%, Ciba1844%, levelling agent 0.5%, defoamer 0.5%.
Ultra-violet curing transfer film used adopts gravure application to make, and base load film is polypropylene screen.
Mould release is by weight percentage: methylcellulose 40%, modified paraffin 15%, butanone 20%, ethyl acetate 5%, amino acrylates 9%, butyl acrylate 10%, Ciba1841%.
Ultraviolet light polymerization topping is by weight percentage: epoxy acrylate 10%, acrylate copolymer 50%, hydroxy-ethyl acrylate 9.5%, butyl acrylate 10%, ITX5%, levelling agent 0.2%, dispersing agent 0.3%, flatting silica 5%.
Ultraviolet light polymerization patterned layer is by weight percentage: polyester acrylate 5%, urethane acrylate 25%, acrylate copolymer 15%, tri (propylene glycol) diacrylate 10%, propylene glycol diacrylate 9.8%, Ciba11732%, TPO3%, levelling agent 0.1%, dispersing agent 0.1%, French chalk 5%, red powder 25%.
Ultraviolet light polymerization background color layer is by weight percentage: urethane acrylate 10%, polyester acrylate 17.5%, acrylate copolymer 15%, ethoxyquin trimethylolpropane triacrylate 15%, propylene glycol diacrylate 10%, Ciba3692%, TPO3%, levelling agent 0.2%, carbon black 25%, ethyl acetate 2.3%.
embodiment 3. imitative metal laser effect safety glass decorative panel
Refer to Fig. 1.Simple glass thickness is 15mm, first simple glass 1 is removed surface and oil contaminant, again at surface of ordinary glass roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 30um, enter and 2 9.6kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidification, glue 3 under the ultraviolet light polymerization film being 15um in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness again, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, under ultraviolet light polymerization film, on glue, transfer printing one deck is printed on the radium-shine ultra-violet curing transfer film 4 of metal again, enter and 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 1 16.8kw metal halid lamp (iron lamp) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidification, remove base load film, on ultra-violet curing transfer film, roller coat a layer thickness is the ultraviolet light polymerization film gluing 5 of 10um again, enter and 2 16.8kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidification, in the gluing of ultraviolet light polymerization film, spraying is coated with a layer thickness is again 40um, gloss is the ultraviolet light polymerization protective topcoat 6 of 90 degree, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, enter and 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 1 16.8kw metal halid lamp (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidification, criterion of acceptability is reached through test rating, packaging, obtain the safety glass decorative panel finished product of imitative metal laser effect.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: urethane acrylate 20%, acrylate copolymer 25%, 1,6 hexylene glycol omega-diol diacrylates 20%, dipentaerythritol triacrylate 13.5%, French chalk 15%, Ciba1845%, levelling agent 0.5%, adhesion promoter 0.5%, defoamer 0.2%, wetting dispersing agent 0.3%.
Under ultraviolet light polymerization film, the percentage by weight of glue consists of: epoxy acrylate 20%, polyester acrylate 25%, different certain herbaceous plants with big flowers base acrylate 33%, tri (propylene glycol) diacrylate 15%, TPO3%, Ciba3692%, levelling agent 0.5%, adhesion promoter 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization film gluing consists of: acrylate copolymer 35%, urethane acrylate 10%, ethoxyquin trimethylolpropane triacrylate 23%, butyl acrylate 5%, hydroxyethyl methacrylate 15%, Ciba1845%, levelling agent 0.5%, adhesion promoter 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization protective topcoat consists of: fluorochemical urethane acrylate 45%, iso-bornyl acrylate 20%, pentaerythritol triacrylate 25%, Ciba1844%, levelling agent 0.5%, defoamer 0.5%.
Ultra-violet curing transfer film used adopts gravure application to make, and base load film is polypropylene screen.
Mould release is by weight percentage: methylcellulose 40%, modified paraffin 15%, butanone 20%, ethyl acetate 5%, amino acrylates 9%, butyl acrylate 10%, Ciba1841%.
Ultraviolet light polymerization topping is by weight percentage: epoxy acrylate 10%, acrylate copolymer 50%, hydroxy-ethyl acrylate 9.5%, butyl acrylate 10%, ITX5%, levelling agent 0.2%, dispersing agent 0.3%, flatting silica 5%.
Ultraviolet light polymerization patterned layer is by weight percentage: polyester acrylate 5%, urethane acrylate 25%, acrylate copolymer 15%, tri (propylene glycol) diacrylate 10%, propylene glycol diacrylate 9.8%, Ciba11732%, TPO3%, levelling agent 0.1%, dispersing agent 0.1%, French chalk 5%, aluminium silver powder 25%.
Ultraviolet light polymerization background color layer is by weight percentage: urethane acrylate 10%, polyester acrylate 17.5%, acrylate copolymer 15%, ethoxyquin trimethylolpropane triacrylate 15%, propylene glycol diacrylate 10%, Ciba3692%, TPO3%, levelling agent 0.2%, golden pearl essence 25%, ethyl acetate 2.3%.
The above, be only preferred embodiment of the present invention, and all equalizations done according to shape of the present invention, structure, feature and spirit change and modify, and all should be included within protection scope of the present invention.
Claims (16)
1. a novel safety glass decorative panel, it is characterized in that: described decorative panel scribbles multilayer ultraviolet photocureable material in surface of ordinary glass and reaches the intensity of tempered glass, described surface of ordinary glass is coated with one deck ultraviolet light polymerization adhesion primer, glue under ultraviolet light polymerization adhesion primer coating surface is coated with one deck ultraviolet light polymerization film, gel coating surface transfer one deck ultra-violet curing transfer film under ultraviolet light polymerization film, the gluing of one deck ultraviolet light polymerization film is had at ultra-violet curing transfer film external coating, one deck ultraviolet light polymerization protective topcoat is had at ultraviolet light polymerization film size coat external coating.
2. safety glass decorative panel according to claim 1, it is characterized in that, described ultraviolet light polymerization adhesion primer by weight percentage, wherein: the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and filler 5 ~ 50%.
3. safety glass decorative panel according to claim 1, it is characterized in that, under described ultraviolet light polymerization film, glue by weight percentage, wherein: the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 5% and filler 0 ~ 50%.
4. safety glass decorative panel according to claim 1, it is characterized in that, the gluing of described ultraviolet light polymerization film by weight percentage, wherein: the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 5% and filler 0 ~ 50%.
5. safety glass decorative panel according to claim 1; it is characterized in that; described ultraviolet light polymerization protective topcoat by weight percentage, wherein: the mixture of fluorinated acrylate prepolymer 10 ~ 80%, fluorinated acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and filler 0 ~ 50%.
6. safety glass decorative panel according to claim 1; it is characterized in that described ultra-violet curing transfer film consists of the following components: base load film; release layer, ultraviolet-curing paint topping, ultraviolet light polymerization decoration layer, ultraviolet-curing paint background color layer.
7. safety glass decorative panel according to claim 1, is characterized in that: the thickness of described ultraviolet light polymerization adhesion primer is 10 ~ 100um.
8. safety glass decorative panel according to claim 1, is characterized in that: under described ultraviolet light polymerization film, the thickness of glue is 10 ~ 100um.
9. safety glass decorative panel according to claim 1, is characterized in that: the thickness of described ultraviolet light polymerization film gluing is 10 ~ 100um.
10. safety glass decorative panel according to claim 1, is characterized in that: the thickness of described ultraviolet light polymerization protective topcoat is 10 ~ 100um, coating gloss with the metering of 60 degree of Grossmeters be 10 ~ 120 degree adjustable.
11. safety glass decorative panels according to claim 6, is characterized in that: described base load film is the one in polypropylene screen, polyethylene film, polychloroethylene film, PETG film.
12. safety glass decorative panels according to claim 6, it is characterized in that, the thickness of described release layer is preferably 1 ~ 10um; Consisting of by weight percentage: the mixture of cellulose family 20 ~ 50%, wax class 1 ~ 30%, silicone oil 0 ~ 10%, butanone 10 ~ 20%, ethyl acetate 5 ~ 15%, acrylic ester prepolymer 5 ~ 20%, acrylate monomer 5 ~ 20%, light trigger 1 ~ 6%.
13. safety glass decorative panels according to claim 6; it is characterized in that, described ultraviolet-curing paint topping consisting of by weight percentage: the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 6%, auxiliary agent 0 ~ 2%, filler 0 ~ 50%, butanone 0 ~ 10%, ethyl acetate 0 ~ 15%.
14. safety glass decorative panels according to claim 6, it is characterized in that, described ultraviolet light polymerization decoration layer, consisting of by weight percentage: the mixture of acrylic ester prepolymer 10 ~ 60%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2%, filler 0 ~ 50%, toner 5 ~ 30%, butanone 0 ~ 10% and ethyl acetate 0 ~ 15%.
15. safety glass decorative panels according to claim 6, it is characterized in that, described ultraviolet-curing paint background color layer, consisting of by weight percentage: the mixture of acrylic ester prepolymer 10 ~ 50%, acrylate monomer 10 ~ 40%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2%, filler 0 ~ 30%, toner 5 ~ 30%, butanone 0 ~ 10%, ethyl acetate 0 ~ 15%.
The preparation method of 16. 1 kinds of a kind of novel safety glass decorative panels according to any one of claim 1 ~ 15, it is characterized in that, the step of described method comprises:
1) surface of ordinary glass cleans;
2) application ultraviolet light polymerization adhesion primer in surface of ordinary glass;
3) first time photocuring;
4) glue under ultraviolet light polymerization adhesion primer coating surface application ultraviolet light polymerization film, infrared levelling or natural levelling;
5) glue surface transfer ultra-violet curing transfer film under ultraviolet light polymerization film;
6) second time photocuring;
7) base load film is removed, in the gluing of ultra-violet curing transfer film external coating film;
8) third time photocuring;
9) at ultraviolet light polymerization film size coat external coating ultraviolet light polymerization protective topcoat, infrared levelling or natural levelling;
10) the 4th photocuring;
Wherein said infrared levelling infrared levelling temperature is adjusted to 20 ~ 150 DEG C, flow time 0.1 ~ 10 minute;
Described photocuring is that the ultraviolet tube of employing 1 ~ 63 ~ 20kw and the metal halogen fluorescent tube of 0 ~ 33 ~ 20kw irradiate, and irradiates speed 1 ~ 20 m/min.
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| CN201410095550.6A CN103866939B (en) | 2014-03-14 | 2014-03-14 | A kind of new type of safe decorative glass plate and preparation method thereof |
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| CN201410095550.6A CN103866939B (en) | 2014-03-14 | 2014-03-14 | A kind of new type of safe decorative glass plate and preparation method thereof |
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| CN103866939A CN103866939A (en) | 2014-06-18 |
| CN103866939B true CN103866939B (en) | 2016-02-17 |
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| CN105368299A (en) * | 2015-12-11 | 2016-03-02 | 珠海东胜科技有限公司 | Ultraviolet light-cured glass decorative sheet, and preparation method and applications thereof |
| CN106000835A (en) * | 2016-06-30 | 2016-10-12 | 卓达新材料科技集团威海股份有限公司 | Photo-curing film-covered panel improvement process |
| CN109437589A (en) * | 2018-11-12 | 2019-03-08 | 浙江中港玻璃有限公司 | A kind of production technology of glass |
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| JP2009215873A (en) * | 2008-03-06 | 2009-09-24 | Zhuhai Dongcheng Uv Materials Co Ltd | Ultraviolet light curing overlay film decorative board for wall, and its manufacturing method |
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| CN103508680A (en) * | 2012-06-18 | 2014-01-15 | 胜华科技股份有限公司 | Glass reinforced coating and reinforced glass cutting piece with glass reinforced coating |
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| JP2009215873A (en) * | 2008-03-06 | 2009-09-24 | Zhuhai Dongcheng Uv Materials Co Ltd | Ultraviolet light curing overlay film decorative board for wall, and its manufacturing method |
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| CN103508680A (en) * | 2012-06-18 | 2014-01-15 | 胜华科技股份有限公司 | Glass reinforced coating and reinforced glass cutting piece with glass reinforced coating |
| CN102777009A (en) * | 2012-07-26 | 2012-11-14 | 珠海东诚光固化材料有限公司 | Ultraviolet light polymerization multicolor wallpaper |
| CN202878805U (en) * | 2012-07-26 | 2013-04-17 | 珠海东诚光固化材料有限公司 | Photocuring double-faced colored pattern glass |
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Address after: 519050 Zhuhai City, Sichuan Province, chemical industry zone Patentee after: Zhuhai Dongcheng light curing new materials Limited by Share Ltd Address before: 519050 Zhuhai City, Sichuan Province, chemical industry zone Patentee before: Zhuhai Dongcheng UV Materials Co., Ltd. |
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