CN103866939A - Novel safety glass decorative sheet and preparation method thereof - Google Patents
Novel safety glass decorative sheet and preparation method thereof Download PDFInfo
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- CN103866939A CN103866939A CN201410095550.6A CN201410095550A CN103866939A CN 103866939 A CN103866939 A CN 103866939A CN 201410095550 A CN201410095550 A CN 201410095550A CN 103866939 A CN103866939 A CN 103866939A
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Abstract
The invention relates to a novel safety glass decorative sheet and a preparation method thereof. The novel safety glass decorative sheet is characterized in that a layer of ultraviolet curing adhesive primer is coated to a common glass surface; a layer of ultraviolet curing adhesive under film is coated to the surface of the coating of the ultraviolet curing adhesive primer; a layer of ultraviolet curing transfer film is transferred to the surface of the coating of the ultraviolet curing adhesive under film; a layer of ultraviolet curing adhesive above film is coated to the surface of the ultraviolet curing transfer film; a layer of ultraviolet curing protective finishing paint is coated to the surface of the coating of the ultraviolet curing adhesive above film. The novel safety glass decorative sheet provided by the invention has the advantages that the required production site is small, the equipment investment is low, the production efficiency is high, the energy consumption is low, and no pollution is generated, can reach the strength of tempered glass, and good in weather fastness of the coatings, high in heat stability, rich in color and pattern, full in film, high in hardness, capable of resisting scratches, easy to clean, and non-inflammable; compared with traditional commonly used tempered glass decorative sheets, the novel safety glass decorative sheet has a better decorative effect and protection function.
Description
Technical field
The invention belongs to constructional materials decorative panel field, a kind of new type of safe decorative glass plate that particularly external coating ultraviolet-curing paint (being called for short UV coating) is produced and preparation method thereof.
Background technology
Along with development and the people of building trade are more and more higher to the requirement of living space environment, glass is applied more and more widely in fields such as door and window, curtain wall and interior decorations.And the hidden danger of simple glass has limited its scope of application greatly.Tempered glass is because intensity is high, and heat-resistant stability is good, and safety factor is high, is more and more subject to the favor in market, and still, tempered glass is expensive, and can not repeat processing use, limits to a certain extent its development speed.At present, the coating that decorative glass plate uses is mostly one-component coating, baking-type coating and two-component coating etc., and because its rate of drying is slow, production efficiency is low, occupied ground area is large, and contains a large amount of solvents, high pollution high energy consumption; The advantages such as UV coating is a kind of environment-friendly and green coating that does not contain VOC, has curing rate fast, and energy consumption is low, and equipment investment is low, and paint film property is good; As Chinese patent CN202449997U discloses a kind of decorative glass plate that adopts numerial code spray drawing to make, this product adopts the adhere to silane coupling agent of two component epoxy series plastics gloss oil as glass, and then employing serigraphy digital jet ink, this product has solved the difficult problem that UV coating is difficult to adhere at this surface compact hard material of glass, but bicomponent epoxy resin curing rate is slow, and production efficiency is low, construction is difficult, and numerial code spray drawing pattern is single, ornamental poor.
Summary of the invention
Object of the present invention is intended to address the above problem, and a kind of a kind of new type of safe decorative glass plate that has security performance and decorate properties concurrently is provided, and can reach the intensity of tempered glass.
A further object of the present invention is to provide a kind of preparation method of novel safety glass decorative panel.
New type of safe decorative glass plate of the present invention is to be coated with one deck ultraviolet light polymerization adhesion primer in surface of ordinary glass; be coated with glue under one deck ultraviolet light polymerization film at ultraviolet light polymerization adhesion primer coating surface; gel coating surface transfer one deck ultra-violet curing transfer film under ultraviolet light polymerization film; there is the gluing of one deck ultraviolet light polymerization film at ultra-violet curing transfer film external coating, be coated with one deck ultraviolet light polymerization protection finish paint at ultraviolet light polymerization film gluing coating surface.
The thickness of described simple glass is 2～20mm.
Described ultraviolet light polymerization adhesion primer adopts the technique application of roller coat, spraying or showering, and thickness is 10～100um.
Under described ultraviolet light polymerization film, glue adopts the technique application of roller coat, spraying or showering, and thickness is 10～100um.
Described ultra-violet curing transfer film adopts the mode of transfer interpreter or manual pad pasting ultra-violet curing transfer film to be transferred to the tempered-glass decorative plate surface that is coated with glue under the ultraviolet light polymerization film installing.
Described ultraviolet light polymerization film gluing adopts the technique application of roller coat, spraying or showering, and thickness is 10～100um.
Described ultraviolet light polymerization protection finish paint adopts the technique application of roller coat, spraying or showering, and thickness is 10～100um, and gloss is that 10～100 degree are adjustable.
The preparation method of new type of safe decorative glass plate of the present invention, its step comprises that surface of ordinary glass is clean, application ultraviolet light polymerization adhesion primer in surface of ordinary glass, photocuring, glue under ultraviolet light polymerization adhesion primer coating surface application ultraviolet light polymerization film, infrared levelling or natural levelling, glue surface transfer ultra-violet curing transfer film under ultraviolet light polymerization film, photocuring, remove base load film, in the gluing of ultra-violet curing transfer film external coating film, photocuring, at ultraviolet light polymerization film gluing coating surface application ultraviolet light polymerization protection finish paint, infrared levelling or natural levelling, photocuring, described infrared levelling is that infrared levelling temperature is adjusted to 20～150 DEG C, flow time 0.1～10 minute,
Described photocuring is to adopt the ultraviolet tube of 1～6 3～20kw and the metal halogen fluorescent tube of 0～3 3～20kw to irradiate, 1～20 m/min of irradiation speed.
The preparation method of new type of safe decorative glass plate of the present invention comprises the following steps:
(1), surface of ordinary glass is clean;
(2), application ultraviolet light polymerization adhesion primer on the simple glass of step (1);
(3), photocuring;
(4), glue under application ultraviolet light polymerization film on the simple glass of step (3);
(5), infrared levelling or natural levelling;
(6), transfer printing ultra-violet curing transfer film on the simple glass of step (5);
(7), photocuring;
(8), remove base load film;
(9), application ultraviolet light polymerization film gluing on the simple glass of step (8);
(10), photocuring;
(11), application ultraviolet light polymerization protection finish paint on the simple glass of step (10);
(12), infrared levelling or natural levelling;
(13), photocuring;
(14), inspection;
(15), packaging.
Glue, the gluing of ultraviolet light polymerization film, ultraviolet light polymerization protection finish paint under the ultraviolet light polymerization adhesion primer that uses in the present invention, ultraviolet light polymerization film, by weight percentage: described ultraviolet light polymerization adhesion primer is made up of the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2% and filler 5～50%; Under described ultraviolet light polymerization film, glue is made up of the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2% and filler 5～50%; Described ultraviolet light polymerization film gluing is made up of the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2% and filler 5～50%; Described ultraviolet light polymerization protection finish paint: the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2% and filler 5～50% forms.
Wherein acrylic ester prepolymer is one or more the above mixtures in urethane acrylate, epoxy acrylate, polyester acrylate, amino acrylates, acrylate copolymer (fluoro-acrylate copolymer), fluorochemical urethane acrylate, fluorine-containing epoxy acrylate, fluorine-containing polyester acrylate, fluorine-containing amino acrylates fluoro-acrylate copolymer.
Wherein acrylate monomer is: butyl acrylate, Isooctyl acrylate monomer, hydroxyethyl methacrylate, iso-bornyl acrylate, two contracting three propyl alcohol diacrylates, propylene glycol diacrylate, the third oxidation neopentylglycol diacrylate, different certain herbaceous plants with big flowers base acrylate, 1, 6 hexylene glycol omega-diol diacrylates, two (diethylene glycol) diacrylates of phthalic acid, trimethylolpropane triacrylate, ethoxyquin trimethylolpropane triacrylate, the third oxidation trimethylolpropane triacrylate, pentaerythritol triacrylate, a kind of or its mixture in dipentaerythritol triacrylate.
Wherein light trigger is a kind of or its mixture in Ciba 1173, Ciba 184, Ciba 369, Ciba 907, Ciba 819, TPO, the ITX of Qi Ba fine chemistry company of Switzerland.
Wherein auxiliary agent is a kind of or its any mixture in levelling agent, defoamer, adhesion promoter, photosensitivity promotor, wetting dispersing agent.
Wherein filler is one or more in French chalk, flatting silica, anti-scratch wax powder, blanc fixe, swell soil.
The ultra-violet curing transfer film that the present invention uses consists of the following components: base load film, release layer, ultraviolet-curing paint topping, ultraviolet light polymerization decorative pattern layer, ultraviolet-curing paint background color layer, it is characterized in that, by weight percentage: described release layer is by the compositions of mixtures of cellulose family 20～50%, wax class 1～30%, silicone oil 0～10%, butanone 10～20%, ethyl acetate 5～15%, acrylic ester prepolymer 5～20%, acrylate monomer 5～20%, light trigger 1～6%; Described uv protection layer is made up of the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～6%, auxiliary agent 0～2%, filler 0～50%, butanone 0～10%, ethyl acetate 0～15%; Described ultraviolet light polymerization decorative pattern layer is made up of the mixture of acrylic ester prepolymer 10～60%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2%, filler 0～50%, toner 5～30%, butanone 0～10% and ethyl acetate 0～15%; Described ultraviolet-curing paint background color layer is made up of the mixture of acrylic ester prepolymer 10～50%, acrylate monomer 10～40%, light trigger 1～5%, auxiliary agent 0～2%, filler 0～30%, toner 5～30%, butanone 0～10%, ethyl acetate 0～15%.
Described base load film is the one in polypropylene screen, polyethylene film, polychloroethylene film, PETG film.
Described cellulose family is methylcellulose, and described wax class is modified paraffin, palm wax or their mixture; Described silicone oil is selected from least one in the group that methyl-silicone oil, polymethylphenyl siloxane fluid, hydroxy silicon oil etc. form.
Described acrylic ester prepolymer is one or more the above mixtures in urethane acrylate, epoxy acrylate, polyester acrylate, amino acrylates, fluorochemical urethane acrylate, fluorine-containing epoxy acrylate, fluorine-containing polyester acrylate, fluorine-containing amino acrylates.
Described acrylate monomer is: butyl acrylate, Isooctyl acrylate monomer, hydroxy-ethyl acrylate, hydroxyethyl methacrylate, iso-bornyl acrylate, two contracting three propyl alcohol diacrylates, propylene glycol diacrylate, the third oxidation neopentylglycol diacrylate, different certain herbaceous plants with big flowers base acrylate, 1, 6 hexylene glycol omega-diol diacrylates, two (diethylene glycol) diacrylates of phthalic acid, trimethylolpropane triacrylate, ethoxyquin trimethylolpropane triacrylate, the third oxidation trimethylolpropane triacrylate, pentaerythritol triacrylate, a kind of or its mixture in dipentaerythritol triacrylate.
Described light trigger is a kind of or its mixture in Ciba 1173, Ciba 184, Ciba 369, Ciba 907, Ciba 819, TPO, the ITX of Qi Ba fine chemistry company of Switzerland.
Described auxiliary agent is a kind of or its any mixture in levelling agent, defoamer, adhesion promoter, photosensitivity promotor, wetting dispersing agent.
Described filler is one or more in French chalk, flatting silica, anti-scratch wax powder, blanc fixe, swell soil.
Described toner comprises: one or more in inorganic pigment, organic pigment, aluminium silver powder, pearl essence.
Inspection:
Whether the safety glass decorative panel that inspection is made is qualified.
Packaging:
According to the specification of product and require to finished product packing.
The safety glass decorative panel of producing by said method has that safety factor is high, good weatherability, Heat stability is good, color pattern is abundant, paint film is plentiful, hardness is high, scratch resistance and nonflammable advantage, has better decorative effect and defencive function than the tempered-glass decorative plate generally using at present.
It is fast that the preparation method of new type of safe decorative glass plate of the present invention has curing rate, and production efficiency is high, and energy consumption is low, the free of contamination advantage of environmental protection.Decorative panel intensity of the present invention is high, durability of coating good, Heat stability is good, color pattern abundant, paint film is plentiful, hardness is high, scratch resistance, easy to clean and nonflammable advantage, has better decorative effect and defencive function than the tempered-glass decorative plate generally using at present.
brief description of the drawings:
Fig. 1 is the structure cross-sectional schematic of new type of safe decorative glass plate of the present invention.
Reference numeral
1, glue 4, ultra-violet curing transfer film 5, ultraviolet light polymerization film gluing 6, ultraviolet light polymerization protection finish paint under simple glass 2, ultraviolet light polymerization adhesion primer 3, ultraviolet light polymerization film.
Detailed description of the invention
Following content elaborates to specific embodiments of the invention in connection with Figure of description:
The imitative wood grain safety glass decorative panel of embodiment 1.
Refer to Fig. 1.Simple glass thickness is 10mm, first simple glass 1 is removed to surface and oil contaminant, again at surface of ordinary glass roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 20um, enter 2 7.5kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidifying, glue 3 under the ultraviolet light polymerization film that is 25um in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness again, it is levelling 1 minute under the infrared levelling line of 80 DEG C in temperature, under ultraviolet light polymerization film, on glue, transfer printing one deck prints grained ultra-violet curing transfer film 4 again, enter 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 2 16.8kw metal halid lamps (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidifying, remove base load film, the ultraviolet light polymerization film gluing 5 that roller coat a layer thickness is 15um on ultra-violet curing transfer film again, enter 2 9.6kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidifying, in the gluing of ultraviolet light polymerization film, showering a layer thickness is 100um again, gloss is the ultraviolet light polymerization protection finish paint 6 of 100 degree, it is levelling 1 minute under the infrared levelling line of 80 DEG C in temperature, enter 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 2 16.8kw metal halid lamps (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidifying, reach criterion of acceptability through test rating, packaging, must imitate wood grain safety glass decorative panel finished product.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: urethane acrylate 25%, epoxy acrylate 20%, hydroxyethyl methacrylate 30%, iso-bornyl acrylate 13%, French chalk 5%, Ciba 1,173 5%, levelling agent 0.5%, adhesion promoter 0.5%, defoamer 0.5%, wetting dispersing agent 0.5%.
Under ultraviolet light polymerization film, the percentage by weight of glue consists of: polyester acrylate 20%, epoxy acrylate 25%, two contracting three propyl alcohol diacrylates 30%, butyl acrylate 18%, TPO 3%, ITX 2%, levelling agent 0.5%, photosensitivity promotor 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization film gluing consists of: acrylate copolymer 43%, urethane acrylate 10%, trimethylolpropane triacrylate 20%, butyl acrylate 5%, hydroxyethyl methacrylate 15%, Ciba184 5%, levelling agent 0.5%, adhesion promoter 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization protection finish paint consists of: epoxy acrylate 35%, urethane acrylate 15%; pentaerythritol triacrylate 20%, the third oxidation trimethylolpropane triacrylate 25%, Ciba184 4%; levelling agent 0.5%, defoamer 0.5%.
Ultra-violet curing transfer film used adopts intaglio printing fabrication techniques, and base load film is polypropylene screen.
Mould release is by weight percentage: methylcellulose 41%, modified paraffin 20%, butanone 18%, ethyl acetate 5%, amino acrylates 5%, butyl acrylate 10%, Ciba1173 1%.
Ultraviolet light polymerization topping is by weight percentage: amino acrylates 10%, acrylate copolymer 50%, hydroxyethyl methacrylate 9.5%, acrylic acid trifluoro ethyl ester 10%, TPO 5%, levelling agent 0.2%, dispersing agent 0.3%, flatting silica 5%.
Ultraviolet light polymerization patterned layer is by weight percentage: amino acrylates 5%, urethane acrylate 25%, acrylate copolymer 15%, tri (propylene glycol) diacrylate 10 %, propylene glycol diacrylate 9.8 %, Ciba1173 2 %, TPO 3 %, levelling agent 0.1%, dispersing agent 0.1%, French chalk 5%, iron white powder 25%.
Ultraviolet light polymerization background color layer is by weight percentage: epoxy acrylate 10%, amino acrylates 17.5%, acrylate copolymer 15%, ethoxyquin trimethylolpropane triacrylate 15 %, propylene glycol diacrylate 10 %, Ciba 184 2%, TPO 3%, levelling agent 0.2%, yellow powder 25%, ethyl acetate 2.3%.
Refer to Fig. 1.Simple glass thickness is 5mm, first simple glass 1 is removed to surface and oil contaminant, again at surface of ordinary glass roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 15um, enter 2 9.6kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidifying, glue 3 under the ultraviolet light polymerization film that is 20um in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness again, it is levelling 1 minute under the infrared levelling line of 80 DEG C in temperature, under ultraviolet light polymerization film, on glue, transfer printing one deck is printed on marbled ultra-violet curing transfer film 4 again, enter 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 1 16.8kw metal halid lamp (iron lamp) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidifying, remove base load film, the ultraviolet light polymerization film gluing 5 that roller coat a layer thickness is 20um on ultra-violet curing transfer film again, enter 2 16.8kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidifying, in the gluing of ultraviolet light polymerization film, roller coat painting a layer thickness is 30um again, gloss is the ultraviolet light polymerization protection finish paint 6 of 20 degree, it is levelling 1 minute under the infrared levelling line of 80 DEG C in temperature, enter 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 1 16.8kw metal halid lamp (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 15 ms/min, after solidifying, reach criterion of acceptability through test rating, packaging, obtain the tempered-glass decorative board finished product of parian.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: polyester acrylate 20%, epoxy acrylate 25%, hydroxy-ethyl acrylate 30%, methyl iso-bornyl acrylate 10%, French chalk 8.5%, Ciba 1,173 5%, levelling agent 0.3%, adhesion promoter 0.5%, defoamer 0.2%, wetting dispersing agent 0.5%.
Under ultraviolet light polymerization film, the percentage by weight of glue consists of: urethane acrylate 20%, polyester acrylate 25%, propylene glycol diacrylate 30%, tri (propylene glycol) diacrylate 18%, TPO 3%, Ciba 907 2%, levelling agent 0.5%, photosensitivity promotor 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization film gluing consists of: acrylate copolymer 35%, epoxy acrylate 10%, trimethylolpropane triacrylate 20%, butyl acrylate 8%, hydroxyethyl methacrylate 15%, Ciba184 5%, levelling agent 0.5%, adhesion promoter 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization protection finish paint consists of: fluorochemical urethane acrylate 45%, acrylic acid hexafluoro butyl ester 20%, the third oxidation trimethylolpropane triacrylate 25%, Ciba184 4%, levelling agent 0.5%, defoamer 0.5%.
Ultra-violet curing transfer film used adopts intaglio printing fabrication techniques, and base load film is polypropylene screen.
Mould release is by weight percentage: methylcellulose 40%, modified paraffin 15%, butanone 20%, ethyl acetate 5%, amino acrylates 9%, butyl acrylate 10%, Ciba 184 1%.
Ultraviolet light polymerization topping is by weight percentage: epoxy acrylate 10%, acrylate copolymer 50%, hydroxy-ethyl acrylate 9.5%, butyl acrylate 10%, ITX 5%, levelling agent 0.2%, dispersing agent 0.3%, flatting silica 5%.
Ultraviolet light polymerization patterned layer is by weight percentage: polyester acrylate 5%, urethane acrylate 25%, acrylate copolymer 15%, tri (propylene glycol) diacrylate 10 %, propylene glycol diacrylate 9.8 %, Ciba1173 2 %, TPO 3 %, levelling agent 0.1%, dispersing agent 0.1%, French chalk 5%, red powder 25%.
Ultraviolet light polymerization background color layer is by weight percentage: urethane acrylate 10%, polyester acrylate 17.5%, acrylate copolymer 15%, ethoxyquin trimethylolpropane triacrylate 15 %, propylene glycol diacrylate 10 %, Ciba 369 2%, TPO 3%, levelling agent 0.2%, carbon black 25%, ethyl acetate 2.3%.
Refer to Fig. 1.Simple glass thickness is 15mm, first simple glass 1 is removed to surface and oil contaminant, again at surface of ordinary glass roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 30um, enter 2 9.6kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidifying, glue 3 under the ultraviolet light polymerization film that is 15um in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness again, it is levelling 1 minute under the infrared levelling line of 80 DEG C in temperature, under ultraviolet light polymerization film, on glue, transfer printing one deck is printed on the radium-shine ultra-violet curing transfer film 4 of metal again, enter 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 1 16.8kw metal halid lamp (iron lamp) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidifying, remove base load film, the ultraviolet light polymerization film gluing 5 that roller coat a layer thickness is 10um on ultra-violet curing transfer film again, enter 2 16.8kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidifying, in the gluing of ultraviolet light polymerization film, spraying painting a layer thickness is 40um again, gloss is the ultraviolet light polymerization protection finish paint 6 of 90 degree, it is levelling 1 minute under the infrared levelling line of 80 DEG C in temperature, enter 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 1 16.8kw metal halid lamp (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidifying, reach criterion of acceptability through test rating, packaging, must imitate the safety glass decorative panel finished product of metal laser effect.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: urethane acrylate 20%, acrylate copolymer 25%, 1,6 hexylene glycol omega-diol diacrylates 20%, dipentaerythritol triacrylate 13.5%, French chalk 15%, Ciba 184 5%, levelling agent 0.5%, adhesion promoter 0.5%, defoamer 0.2%, wetting dispersing agent 0.3%.
Under ultraviolet light polymerization film, the percentage by weight of glue consists of: epoxy acrylate 20%, polyester acrylate 25%, different certain herbaceous plants with big flowers base acrylate 33%, tri (propylene glycol) diacrylate 15%, TPO 3%, Ciba 369 2%, levelling agent 0.5%, adhesion promoter 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization film gluing consists of: acrylate copolymer 35%, urethane acrylate 10%, ethoxyquin trimethylolpropane triacrylate 23%, butyl acrylate 5%, hydroxyethyl methacrylate 15%, Ciba184 5%, levelling agent 0.5%, adhesion promoter 1%, defoamer 0.5%.
The percentage by weight of ultraviolet light polymerization protection finish paint consists of: fluorochemical urethane acrylate 45%, iso-bornyl acrylate 20%, pentaerythritol triacrylate 25%, Ciba184 4%, levelling agent 0.5%, defoamer 0.5%.
Ultra-violet curing transfer film used adopts intaglio printing fabrication techniques, and base load film is polypropylene screen.
Mould release is by weight percentage: methylcellulose 40%, modified paraffin 15%, butanone 20%, ethyl acetate 5%, amino acrylates 9%, butyl acrylate 10%, Ciba 184 1%.
Ultraviolet light polymerization topping is by weight percentage: epoxy acrylate 10%, acrylate copolymer 50%, hydroxy-ethyl acrylate 9.5%, butyl acrylate 10%, ITX 5%, levelling agent 0.2%, dispersing agent 0.3%, flatting silica 5%.
Ultraviolet light polymerization patterned layer is by weight percentage: polyester acrylate 5%, urethane acrylate 25%, acrylate copolymer 15%, tri (propylene glycol) diacrylate 10 %, propylene glycol diacrylate 9.8 %, Ciba1173 2 %, TPO 3 %, levelling agent 0.1%, dispersing agent 0.1%, French chalk 5%, aluminium silver powder 25%.
Ultraviolet light polymerization background color layer is by weight percentage: urethane acrylate 10%, polyester acrylate 17.5%, acrylate copolymer 15%, ethoxyquin trimethylolpropane triacrylate 15 %, propylene glycol diacrylate 10 %, Ciba 369 2%, TPO 3%, levelling agent 0.2%, golden pearl essence 25%, ethyl acetate 2.3%.
The above, be only preferred embodiment of the present invention, and all equalizations of doing according to shape of the present invention, structure, feature and spirit change and modify, within all should being included in protection scope of the present invention.
Claims (17)
1. a novel safety glass decorative panel, is characterized in that: described decorative panel is scribble multilayer ultraviolet photocureable material and reach the intensity of tempered glass in surface of ordinary glass.
2. safety glass decorative panel according to claim 1; it is characterized in that: described surface of ordinary glass is coated with one deck ultraviolet light polymerization adhesion primer; be coated with glue under one deck ultraviolet light polymerization film at ultraviolet light polymerization adhesion primer coating surface; gel coating surface transfer one deck ultra-violet curing transfer film under ultraviolet light polymerization film; there is the gluing of one deck ultraviolet light polymerization film at ultra-violet curing transfer film external coating, be coated with one deck ultraviolet light polymerization protection finish paint at ultraviolet light polymerization film gluing coating surface.
3. safety glass decorative panel according to claim 1, it is characterized in that, described ultraviolet light polymerization adhesion primer by weight percentage, wherein: the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2% and filler 5～50%.
4. safety glass decorative panel according to claim 1, it is characterized in that, under described ultraviolet light polymerization film glue by weight percentage, wherein: the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～5% and filler 0～50%.
5. safety glass decorative panel according to claim 1, it is characterized in that, the gluing of described ultraviolet light polymerization film by weight percentage, wherein: the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～5% and filler 0～50%.
6. safety glass decorative panel according to claim 1; it is characterized in that; described ultraviolet light polymerization is protected finish paint by weight percentage, wherein: the mixture of fluorinated acrylate prepolymer 10～80%, fluorinated acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2% and filler 0～50%.
7. safety glass decorative panel according to claim 1; it is characterized in that: described ultra-violet curing transfer film consists of the following components: base load film; release layer, ultraviolet-curing paint topping, ultraviolet light polymerization decorative pattern layer, ultraviolet-curing paint background color layer.
8. safety glass decorative panel according to claim 1, is characterized in that: the thickness of described ultraviolet light polymerization adhesion primer is 10～100um.
9. safety glass decorative panel according to claim 1, is characterized in that: under described ultraviolet light polymerization film, the thickness of glue is 10～100um.
10. safety glass decorative panel according to claim 1, is characterized in that: the thickness of described ultraviolet light polymerization film gluing is 10～100um.
11. safety glass decorative panels according to claim 1, is characterized in that: the thickness of described ultraviolet light polymerization protection finish paint is 10～100um, coating gloss taking 60 degree Grossmeters meterings as 10 ~ 120 degree adjustable.
12. according to the safety glass decorative panel described in claim 1 or 7, it is characterized in that: described base load film is the one in polypropylene screen, polyethylene film, polychloroethylene film, PETG film.
13. according to the safety glass decorative panel described in claim 1 or 7, it is characterized in that, the thickness of described release layer is preferably 1 ~ 10um; Consisting of by weight percentage: the mixture of cellulose family 20～50%, wax class 1～30%, silicone oil 0～10%, butanone 10～20%, ethyl acetate 5～15%, acrylic ester prepolymer 5～20%, acrylate monomer 5～20%, light trigger 1～6%.
14. according to the safety glass decorative panel described in claim 1 or 7; it is characterized in that described uv protection layer consisting of by weight percentage: the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～6%, auxiliary agent 0～2%, filler 0～50%, butanone 0～10%, ethyl acetate 0～15%.
15. according to the safety glass decorative panel described in claim 1 or 7, it is characterized in that, described ultraviolet light polymerization decorative pattern layer, consisting of by weight percentage: the mixture of acrylic ester prepolymer 10～60%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2%, filler 0～50%, toner 5～30%, butanone 0～10% and ethyl acetate 0～15%.
16. according to the safety glass decorative panel described in claim 1 or 7, it is characterized in that, described ultraviolet-curing paint background color layer, consisting of by weight percentage: the mixture of acrylic ester prepolymer 10～50%, acrylate monomer 10～40%, light trigger 1～5%, auxiliary agent 0～2%, filler 0～30%, toner 5～30%, butanone 0～10%, ethyl acetate 0～15%.
17. 1 kinds according to the preparation method of a kind of novel safety glass decorative panel described in claim 1～16 any one, it is characterized in that, the step of described method comprises:
1) surface of ordinary glass is clean;
2) application ultraviolet light polymerization adhesion primer in surface of ordinary glass;
3) photocuring for the first time;
4) glue under ultraviolet light polymerization adhesion primer coating surface application ultraviolet light polymerization film, infrared levelling or natural levelling;
5) glue surface transfer ultra-violet curing transfer film under ultraviolet light polymerization film;
6) photocuring for the second time;
7) remove base load film, in the gluing of ultra-violet curing transfer film external coating film;
8) photocuring for the third time;
9) at ultraviolet light polymerization film gluing coating surface application ultraviolet light polymerization protection finish paint, infrared levelling or natural levelling;
10) the 4th photocuring;
Wherein said infrared levelling is that infrared levelling temperature is adjusted to 20～150 DEG C, flow time 0.1～10 minute;
Described photocuring is to adopt the ultraviolet tube of 1～6 3～20kw and the metal halogen fluorescent tube of 0～3 3～20kw to irradiate, 1～20 m/min of irradiation speed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410095550.6A CN103866939B (en) | 2014-03-14 | 2014-03-14 | A kind of new type of safe decorative glass plate and preparation method thereof |
Applications Claiming Priority (1)
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Cited By (4)
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| CN104989045A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing transfer-printing high-gloss decoration plate and manufacturing method thereof |
| CN105368299A (en) * | 2015-12-11 | 2016-03-02 | 珠海东胜科技有限公司 | Ultraviolet light-cured glass decorative sheet, and preparation method and applications thereof |
| CN106000835A (en) * | 2016-06-30 | 2016-10-12 | 卓达新材料科技集团威海股份有限公司 | Photo-curing film-covered panel improvement process |
| CN109437589A (en) * | 2018-11-12 | 2019-03-08 | 浙江中港玻璃有限公司 | A kind of production technology of glass |
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| CN102777009A (en) * | 2012-07-26 | 2012-11-14 | 珠海东诚光固化材料有限公司 | Ultraviolet light polymerization multicolor wallpaper |
| CN202878805U (en) * | 2012-07-26 | 2013-04-17 | 珠海东诚光固化材料有限公司 | Photocuring double-faced colored pattern glass |
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| JP2009215873A (en) * | 2008-03-06 | 2009-09-24 | Zhuhai Dongcheng Uv Materials Co Ltd | Ultraviolet light curing overlay film decorative board for wall, and its manufacturing method |
| CN101941339A (en) * | 2009-07-06 | 2011-01-12 | 珠海东诚光固化材料有限公司 | Ultraviolet light cured transfer printing film and preparation method and application thereof |
| CN103508680A (en) * | 2012-06-18 | 2014-01-15 | 胜华科技股份有限公司 | Glass reinforced coating and reinforced glass cutting piece with glass reinforced coating |
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| CN104989045A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing transfer-printing high-gloss decoration plate and manufacturing method thereof |
| CN104989045B (en) * | 2014-12-29 | 2018-01-30 | 中关村人居环境工程与材料研究院 | A kind of ultra-violet curing transfer bloom decorative panel and its manufacture method |
| CN105368299A (en) * | 2015-12-11 | 2016-03-02 | 珠海东胜科技有限公司 | Ultraviolet light-cured glass decorative sheet, and preparation method and applications thereof |
| CN106000835A (en) * | 2016-06-30 | 2016-10-12 | 卓达新材料科技集团威海股份有限公司 | Photo-curing film-covered panel improvement process |
| CN109437589A (en) * | 2018-11-12 | 2019-03-08 | 浙江中港玻璃有限公司 | A kind of production technology of glass |
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| CN103866939B (en) | 2016-02-17 |
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