CN102777009A - Ultraviolet light polymerization multicolor wallpaper - Google Patents
Ultraviolet light polymerization multicolor wallpaper Download PDFInfo
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- CN102777009A CN102777009A CN2012102623099A CN201210262309A CN102777009A CN 102777009 A CN102777009 A CN 102777009A CN 2012102623099 A CN2012102623099 A CN 2012102623099A CN 201210262309 A CN201210262309 A CN 201210262309A CN 102777009 A CN102777009 A CN 102777009A
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Abstract
The invention relates to a method for preparing and using an ultraviolet light polymerization multicolor pattern wallpaper which at least comprises a base load film, a mold release agent layer, an ultraviolet light polymerization coating protective layer, an ultraviolet light polymerization coating decorative pattern layer and an ultraviolet light polymerization coating base color. The preparation method comprises the following steps of: 1) coating the mold release layer on the base load film and solidifying infrared rays; 2) coating the ultraviolet light polymerization coating protective layer and solidifying the ultraviolet light after finishing a step 1); 3) coating the ultraviolet light polymerization coating decorative pattern layer and solidifying the ultraviolet light after finishing a step 2); 4) coating the ultraviolet light polymerization coating base color and solidifying the ultraviolet light after finishing a step 3), so as to obtain a product. The ultraviolet light polymerization multicolor pattern wallpaper has the advantages of rich color patterns and full colours, scratch resistance, good weather resistance, excellent fire resistance and being moistureproof; and the ultraviolet light polymerization multicolor pattern wallpaper is reusable; compared with a traditional wallpaper, the wallpaper disclosed by the invention can be used as a decorative material in a kitchen and a washroom where oil or water vapor is heavy.
Description
Technical field
The present invention relates to a kind of preparation method of wallpaper, particularly utilize the ultraviolet Technology preparation to have multiple multicolour pattern wallpaper.
Background technology
Along with the continuous development of science and technology, living standard improve constantly the continuous improvement of habitat condition; People more and more pursue indoor decorative beauty; And wallpaper often has been used as indoor ornament materials, and wallpaper is as a kind of ornament materials, and oneself is widely used in the decoration field.
Traditional wallpaper product mainly is made up of tack coat and plastic flower lamina, and its major defect is:
1, hygroscopicity is strong, so that is easy to come off, and pollutes variable color and lacks third dimension and dull coloring, distributes harmful chemical components such as benzene, xylenes.Therefore, have influence on interior decoration beautiful effect and environment protecting significantly;
2, wear-resisting scratch-resisting property is bad, and people tend on wallpaper, leave scratch when cleaning wallpaper; Tend to make the pattern blurring on the wallpaper after time is permanent, influence attractive in appearance, in case wallpaper is scraped damage; The humidity resistance of metope also can be had a greatly reduced quality, and reduces the application life of wallpaper;
3, in addition, traditional wallpaper does not possess anti-flammability, very easily causes fire, after use, brings greatest trouble and worry for people.
Chinese patent 200720056865.5 disclosed a kind of fabricbase wallpapers, it comprises that basic unit, adhesive layer and surface decoration layer, wallpaper basic unit are fabric nonwoven cloth cloth from bottom to top in proper order, or general looped fabric composite PVC layer.Wallpaper tensile strength improves; And have protection against the tide, wear-resisting, a advantage that tensile strength is high; Also has a kind of environmental protection wallpaper; Its base material is the scrubbing resistance base material, forms with the PVC layer that is compounded on the bottom paper by strengthening wood fibre paper bottom, at the scrubbing resistance substrate surface one deck water color ink decorating printing layer is arranged.The described water color ink decorating printing of described base material layer is to be printed on the PVC laminar surface.Its major defect is:
Owing to used inflammable base material, this wallpaper does not still have waterproof and fire-retardant performance.
Combination properties such as present wallpaper is difficult to take into account good decorative property, and is wear-resisting again, and waterproof and fire resistance are good, and ageing-resistant, service time is long.
Summary of the invention
To the above-mentioned defective of wallpaper, the inventor is based on the research of engaging in Related product for many years, exploitation and marketing experience, and warp is research and design in many ways, finds out technical scheme of the present invention finally.
Main purpose of the present invention is that heat transfer film is applied on the wallpaper, and it is fast to utilize UV-curing technology to have a curing rate, and energy consumption is low, and equipment investment is low; Advantages such as the place area occupied is little, and paint film property is good solve the problem that existing wallpaper can not be taken into account above-mentioned performance, propose a kind of easy to use; Color pattern is abundant, has and can clean, can be not damaged; Stable performance, ageing-resistant, and the preparation and the method for using of the good wallpaper of waterproof and fire resistance.
The objective of the invention is to realize like this: the preparation method of the colorful wallpaper of a kind of ultraviolet light polymerization; It is characterized by: it is characterized in that: it is mainly formed at least and includes: the base load film; Parting agent layer; The ultraviolet-curing paint topping, ultraviolet light polymerization decorative pattern layer, ultraviolet-curing paint background color layer.Its preparation methods steps is: 1) on the base load film, be coated with mould release, infrared lamp solidifies; 2) after step 1) finishes, coating ultraviolet light coating protection layer, uviol lamp solidifies; 3) in step 2) finish after, coating ultraviolet light polymerization decorative pattern layer, uviol lamp solidifies; 4) after step 3) finishes, coating ultraviolet-curing paint background color layer, uviol lamp solidifies, and promptly gets product.
Described base load film is a kind of in polypropylene screen, polyethylene film, polychloroethylene film, the PETG film.
The thickness of described parting agent layer is preferably 1 ~ 10 micron; Consisting of by weight percentage: the mixture of cellulose family 20～50%, wax class 1～30%, silicone oil 0～10%, butanone 10～20%, ethyl acetate 5～15%, acrylic ester prepolymer 5～20%, acrylate monomer 5～20%, light trigger 1～6%.
The thickness of described ultraviolet-curing paint topping is preferably 1 ~ 100 micron; Glossiness is preferably 0 ~ 120 °; Consisting of by weight percentage: the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～6%, auxiliary agent 0～2%, filler 0～50%, butanone 0～10%, ethyl acetate 0～15%.
Described ultraviolet-curing paint decorative pattern layer thickness is preferably 5 ~ 200 microns; Consisting of by weight percentage: the mixture of acrylic ester prepolymer 10～60%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2%, filler 0～50%, toner 5～30%, resin 5～30%, butanone 0～10% and ethyl acetate 0～15%.
Described ultraviolet-curing paint background color layer thickness is preferably 5 ~ 200 microns; Consisting of by weight percentage: the mixture of acrylic ester prepolymer 10～50%, acrylate monomer 10～40%, light trigger 1～5%, auxiliary agent 0～2%, filler 0～30%, toner 5～30%, resin 5～50%, butanone 0～10%, ethyl acetate 0～15%.
Described acrylic ester prepolymer is a kind of or its mixture of epoxy acrylate, urethane acrylate, fluorine-containing epoxy acrylate, fluorochemical urethane acrylic acid ester, amino acrylates.
Described acrylate monomer is (methyl) hydroxy-ethyl acrylate, butyl acrylate, acrylic acid, different certain herbaceous plants with big flowers base acrylic acid ester, 1,6-omega-diol diacrylate, (propoxyl group) neopentylglycol diacrylate, three a kind of or its mixture in two propyl alcohol diacrylates, ethoxyquin trimethylolpropane triacrylate, the tetramethylol methane tetraacrylate that contracts.
Described light trigger is a kind of or its mixture in benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenones light trigger, Benzophenones light trigger, the benzoic ether photoinitiator.
Described auxiliary agent is a kind of or its mixture in levelling agent, antifoaming agent, the wetting dispersing agent.
Described filler is a kind of or its mixture in French chalk, calcium carbonate, the barium sulfate.
Described toner is carbon black, iron white powder, ashen indigo plant, former Huang, a kind of in bright red.
Described resin is a kind of or its mixture in epoxy acrylate, urethane acrylate, the amino acrylates.
Described preparation method is: 1) to the preliminary treatment of base load film, on the base load film, evenly be coated with or the printing release layer, carry out infrared curing then, obtain release layer on the base load film; 2) even coating or printing ultraviolet solidifying protection paint on release layer carry out UV-irradiation then and solidify, and obtain the ultraviolet-curing paint topping; 3) even coating or printing ultraviolet light polymerization decorative pattern layer on the ultraviolet-curing paint topping carry out UV-irradiation then and solidify, and obtain ultraviolet light polymerization decorative pattern layer; 4) even coating or printing ultraviolet light polymerization background color coating on ultraviolet light polymerization decorative pattern layer carry out UV-irradiation then and solidify, and obtain ultraviolet light polymerization background color layer; 5) check, at ultraviolet light polymerization background color laminating diaphragm, packing.
Described uviol lamp is that power is at least a in the high-pressure sodium lamp of 3 ~ 20kw, the metal halid lamp that power is 3 ~ 20kw; The optical source wavelength of used lamp is 200 ~ 600 nanometers.
Described method for using step is: 1) metope is carried out surfacing according to conventional method; 2) application ultraviolet cured adhesive on the metope after step 1) is handled sticks on the ultraviolet light polymerization colourful pattern wallpaper of removing packaging film on the metope; 3) carry out ultraviolet light polymerization; 4) remove the base load film.
Described ultraviolet cured adhesive is by weight percentage: acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 60%, light trigger 1 ~ 6%, auxiliary agent 0 ~ 2% and filler 0 ~ 50%.
Description of drawings
Fig. 1 is a ultraviolet light polymerization colourful pattern wallpaper hierarchy sketch map of the present invention.
The specific embodiment
For making the object of the invention, technical scheme and advantage clearer, below in conjunction with accompanying drawing and specific embodiment, to further explain of the present invention.
Fig. 1 is a ultraviolet light polymerization colourful pattern wallpaper hierarchy sketch map of the present invention.As shown in the figure, the hierarchy of ultraviolet light polymerization colourful pattern wallpaper is followed successively by: 1, base load film, 2, parting agent layer, 3, the ultraviolet light polymerization topping, 4, ultraviolet-curing paint decorative pattern layer, 5, ultraviolet-curing paint background color layer constitutes.In the accompanying drawing 1, label 6 is packaging films of ultraviolet light polymerization colourful pattern wallpaper.
Below, specify ultraviolet light polymerization colourful pattern wallpaper manufacture craft of the present invention through specific embodiment:
Embodiment 1:
The structure of parian colourful pattern wallpaper can be referring to Fig. 1.It may further comprise the steps by concrete preparation method:
1) polypropylene screen (base load film) is toasted to collect in advance under 120 ° of C contracts, destatic.
2) the polypropylene screen surface that obtains in step 1) is coating or printing mould release evenly, carries out infrared curing then, and the infrared rays heating-up temperature transfers to 60 ℃, and flow time 1 minute obtains thickness after mould release is fully solidified and be 1 micron parting agent layer;
Parting agent layer is formed: the mixture of methylcellulose 41%, modified paraffin 20%, butanone 18%, ethyl acetate 5%, fluorine-containing amino acrylates 5%, butyl acrylate 10%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 1%.
3) in step 2) even coating in parting agent layer surface or printing ultraviolet light polymerization protection layer for paint; Carry out ultraviolet light polymerization then; Its curing process is: the model that will scribble uv protection layer passes the ultraviolet tube (high-pressure sodium lamp) that 1 ~ 33 ~ 20kw is housed at a high speed; Carry out illumination in the photo solidification machine of the metal halogen fluorescent tube of 0 ~ 33 ~ 20kw, the ultraviolet light polymerization protection layer for paint is solidified, obtain thickness and be 10 microns ultraviolet light polymerization topping; The wavelength of used light source is 300 ~ 400nm, and the transmission speed of photo solidification machine is 1 ~ 200 meter/minute;
Ultraviolet light coating protection layer is formed:
The mixture of fluorine-containing epoxy acrylate 20%, fluorochemical urethane acrylic acid ester 40%, ethoxyquin trimethylolpropene triacrylate (EO-TMPTA) 16%, the third oxidation trimethylolpropene triacrylate (PO-TMPTA) 20%, 1-hydroxy-cyclohexyl phenyl ketone 3%, BYK 052 0.5%, Disperbykl 03 0.5%;
4) evenly coating or printing ultraviolet-curing paint decorative pattern layer on step 3) ultraviolet-curing paint topping surface carry out ultraviolet light polymerization then, and its curing process is identical with step 3), obtain thickness and be 1 micron decorative pattern layer;
Ultraviolet-curing paint decorative pattern layer is formed:
The mixture of fluorine-containing epoxy acrylate 18.5%, fluorochemical urethane acrylic acid ester 25%, the third oxidation neopentylglycol diacrylate (PO-NPGDA) 15%, two (diethylene glycol) diacrylates (PDDA) 15% of phthalic acid, 1-hydroxy-cyclohexyl phenyl ketone 3%, 2,4 diisopropyl thioxanthones 3%, BYK052 0.2%, Disperbyk 103 0.3%, carbon black M-E 10%, polyamide 10%;
5) step 4) be coated with decorative pattern laminar surface evenly coating or printing ultraviolet-curing paint background color layer, carry out ultraviolet light polymerization then, the same step 3) of curing process obtains thickness and is 10 microns ultraviolet light polymerization background color layer.
Ultraviolet-curing paint background color layer is formed:
Fluorine-containing epoxy acrylate 10%, fluorine-containing amino acrylates 25%, acrylate copolymer 5%, ethoxyquin trimethylolpropane triacrylate (EO-TMPT A) 15%, propylene glycol diacrylate (DPGDA) 9.8%, 1-hydroxy-cyclohexyl phenyl ketone 3%, 2; The mixture of 4,6 one trimethylbenzoyl diphenyl phosphine oxide TPO 3%, BYK 052 0.2%, iron white powder 22%, polyamide 7.2%.
The product of present embodiment can be used as the ornament materials of kitchen, washroom, indoor wall, has waterproof, protection against the tide, fire-retardant, anti-excellent properties such as scrape.
Embodiment 2:
The method for making of present embodiment is with embodiment 1, and different is that the ultraviolet-curing paint topping is different with the composition of ultraviolet-curing paint decorative pattern layer, and it is formed as follows:
Ultraviolet light coating protection layer is formed: fluorine-containing amino acrylates 10%, acrylate copolymer 10%, fluoro-acrylate copolymer 50%, methacrylic acid play ethyl ester (MHEA) 9.5%, acrylic acid trifluoro ethyl ester 10%, 1 hydroxy-cyclohexyl phenyl ketone 5%; The mixture of BYK 052 0.2%, Disperbyk 103 0.3%, GIFU the delustring wax slurry of company (Japanese GIFU) delustring auxiliary agent 5%.
Ultraviolet-curing paint decorative pattern layer is formed: amino acrylates 5%, fluorine-containing amino acrylates 25%, acrylate copolymer 5%, tri (propylene glycol) diacrylate (TPGDA) 10%, propylene glycol diacrylate (DPGDA) 9.8%, 1 monohydroxy cyclohexyl phenyl ketone 2%, 2; 4,6 one trimethylbenzoyl diphenyl phosphine oxides (TPO) 3%, BYK 052 0.1%, Disperbyk 103 O.1%, the mixture of French chalk 5%, iron white powder 25%, polyamide 10%.
Embodiment 3:
The method for making of present embodiment is with embodiment 1, and wherein ultraviolet-curing paint pattern decorative layer thickness changes 10 microns into, and it is formed as follows:
Ultraviolet-curing paint decorative pattern layer is formed: fluorochemical urethane acrylic acid ester 23%, polyester acrylate 15%, dipentaerythritol acrylate (DPHA) 10.4%, 1; 6 hexanediyl esters (HDDA) 15%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, 2; The mixture of 4,6 one trimethylbenzoyl diphenyl phosphine oxides 3%, BYK 052 0.2%, Disperbyk 103 0.3%, carbon black 0.1%, iron white powder 20%, vinyl chloride vinylacetate 4%, polyamide 5%, butanone 2%.
Embodiment 4:
The method for making of present embodiment is with embodiment 1, and wherein ultraviolet-curing paint pattern decorative layer thickness changes 10 microns into, and it is formed as follows:
Ultraviolet-curing paint decorative pattern layer is formed: fluorine-containing epoxy acrylate 10%, fluorochemical urethane acrylic acid ester 23%, propylene glycol diacrylate (DPGDA) 12%, 1 monohydroxy cyclohexyl phenyl ketone 2%, 2; 4,6 one trimethylbenzoyl diphenyl phosphine oxides 3%, BYK 052 0.3%, kybrepsiD 103 O.1%, the mixture of bright red 1%, carbon black 0.1%, iron white powder 21%, calcium carbonate 3%, polyamide 10%, butanone 4.5%, ethyl acetate 10%.
Embodiment 5:
The method for making of present embodiment is with embodiment 1, and wherein the base load film changes the PETG film into, and ultraviolet light polymerization pattern decorative layer thickness changes 20 microns into, and the composition of ultraviolet light polymerization pattern decorative layer and ultraviolet light background color layer changes into as follows:
Ultraviolet-curing paint decorative pattern layer is formed: fluorochemical urethane acrylic acid ester 15%, amino acrylates 15%, acrylic acid hexafluoro butyl ester 15%, dodecafluorhe-ptylacrylate 20%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, 2; The mixture of 4,6 trimethylbenzoyl diphenyl phosphine oxides 2.7%, BYK 052 0.2%, Disperbyk 103 0.1%, illusion-colour pearly-lustre 20%, polyamide 10%.
Ultraviolet-curing paint background color layer is formed: fluorine-containing epoxy acrylate 15%, ethoxyquin trimethylolpropane triacrylate (EO-TMPTA) 32%, propylene glycol diacrylate (DPGDA) 5%, 1-hydroxy-cyclohexyl phenyl ketone 2%, 2; 4; 6 trimethylbenzoyl diphenyl phosphine oxides 3%, iron white powder 20%, French chalk 5%, the mixture of polyamide 18%.
Embodiment 6:
The method for making of present embodiment is with embodiment 5, and wherein the composition of ultraviolet-curing paint pattern decorative layer changes into as follows:
Ultraviolet-curing paint decorative pattern layer is formed: acrylate copolymer 12%, fluorochemical urethane acrylic acid ester 12.4%, polyester acrylate 10%, Isooctyl acrylate monomer (EHA) 10%, ethoxyquin trimethylolpropane triacrylate (EO-TMPT A) 15%, methacrylic acid 10%, 1-hydroxy-cyclohexyl phenyl ketone 2%, 2; The mixture of 4,6 trimethylbenzoyl diphenyl phosphine oxides 3%, BYK 052 0.3%, transparent iron oxide red 5%, polyamide 20.3%.
Embodiment 7:
The method for making of present embodiment is with embodiment 1, and different is the composition of ultraviolet-curing paint pattern decorative layer and ultraviolet light coating background color layer, and it is formed as follows:
Ultraviolet-curing paint decorative pattern layer is formed: fluorochemical urethane acrylic acid ester 14.5%, fluorine-containing epoxy acrylate 15%, acrylic acid hexafluoro butyl ester 15%, methacrylic acid hexafluoro butyl ester 15%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, 2; The mixture of 4,6 trimethylbenzoyl diphenyl phosphine oxides 3%, BYK 052 0.2%, butanone 0.3%, silver powder 15%, thermoplastic acrylic 20%.
Ultraviolet-curing paint background color layer is formed: fluorine-containing polyester acrylate 15%, fluorine-containing amino acrylates 27.7%, trifluoroethyl methacrylate 7%, propylene glycol diacrylate (DPGDA) 20%, 1-hydroxy-cyclohexyl phenyl ketone 2%, 2; 4-diisopropyl thia humulone 3%, BYK 052 are O.1%; Disperbyk 103 0.2%, carbon black 8%, French chalk 2%, the mixture of polyamide 15%.
Embodiment 8:
The method for making of present embodiment is with embodiment 7, and wherein the composition of ultraviolet-curing paint pattern decorative layer changes into as follows:
Ultraviolet-curing paint decorative pattern layer is formed: fluoro-acrylate copolymer 15%, amino acrylates 16.1%, dipentaerythritol acrylate (DPHA) 15%, dodecafluorhe-ptylacrylate 20%, 1-hydroxy-cyclohexyl phenyl ketone 2%, 2; The mixture of 4,6 trimethylbenzoyl diphenyl phosphine oxides 2%, BYK 052 0.2%, Disperbyk 103 0.2%, bronze 18%, polyamide 10%, thermoplastic acrylic 1.5%.
Embodiment 9:
Present embodiment is intended to explain method for using of the present invention, and its step is following:
1) metope is carried out surfacing according to conventional method;
2) application ultraviolet cured adhesive on the metope after step 1) is handled sticks on the product of the embodiment 1 that removes packaging film on the metope;
3) carry out ultraviolet light polymerization, its curing process is: using power is that 1 ~ 5kw hand-held ultraviolet lamp solidifies appearance irradiation metope, irradiation distance 10 ~ 15cm, irradiation time 10 ~ 30s;
4) remove the base load film.
Ultraviolet cured adhesive is formed: urethane acrylate 50%, hydroxy-ethyl acrylate 35%, 2; 4,6 one trimethylbenzoyl diphenyl phosphine oxides 3%, BYK 0520.2%, Disperbyk 103 0.2%, French chalk 2%, blanc fixe 2%.
In sum; The ultraviolet light polymerization colourful pattern wallpaper Material Strength that adopts method of the present invention to prepare is high; Have that good weatherability, the feature of environmental protection are good, rich patterns, paint film is plentiful, hardness is high, scratch resistance, be prone to cleaning, advantage such as nonflammable, than the wallpaper that generally uses at present better decorative effect and protection effect is arranged.
The above is merely preferred embodiment of the present invention, and all equalizations of being done according to shape of the present invention, structure, characteristic and spirit change and modify, and all should be included within protection scope of the present invention.
Claims (15)
1. the preparation and the method for using of a ultraviolet light polymerization colourful pattern wallpaper; It is characterized in that: it is mainly formed at least and includes: the base load film; Parting agent layer, ultraviolet-curing paint topping, ultraviolet-curing paint decorative pattern layer, ultraviolet-curing paint background color layer.Its preparation methods steps is:
1) on the base load film, be coated with mould release, infrared lamp solidifies; 2) after step 1) finishes, coating ultraviolet light coating protection layer, uviol lamp solidifies; 3) in step 2) finish after, coating ultraviolet light polymerization decorative pattern layer, uviol lamp solidifies; 4) after step 3) finishes, coating ultraviolet-curing paint background color layer, uviol lamp solidifies, and promptly gets product.
2. base load film according to claim 1 is a kind of in polypropylene screen, polyethylene film, polychloroethylene film, the PETG film.
3. the thickness of parting agent layer according to claim 1 is preferably 1 ~ 10 micron; Consisting of by weight percentage: the mixture of cellulose family 20～50%, wax class 1～30%, silicone oil 0～10%, butanone 10～20%, ethyl acetate 5～15%, acrylic ester prepolymer 5～20%, acrylate monomer 5～20%, light trigger 1～6%.
4. cellulose family according to claim 3 is a methylcellulose; Described wax class is a kind of in modified paraffin, the palm wax; Described silicone oil is a kind of in methyl-silicone oil, polymethylphenyl siloxane fluid, the hydroxy silicon oil; Described light trigger is a kind of or its mixture in benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenones light trigger, Benzophenones light trigger, the benzoic ether photoinitiator; Described acrylic ester prepolymer is a kind of or its mixture of epoxy acrylate, urethane acrylate, fluorine-containing epoxy acrylate, fluorochemical urethane acrylic acid ester, amino acrylates; Described acrylate monomer is (methyl) hydroxy-ethyl acrylate, butyl acrylate, acrylic acid, different certain herbaceous plants with big flowers base acrylic acid ester, 1,6-omega-diol diacrylate, (propoxyl group) neopentylglycol diacrylate, three a kind of or its mixture in two propyl alcohol diacrylates, ethoxyquin trimethylolpropane triacrylate, the tetramethylol methane tetraacrylate that contracts.
5. the thickness of ultraviolet light coating protection layer according to claim 1 is preferably 1 ~ 100 micron; Glossiness is preferably 0 ~ 120 °; Consisting of by weight percentage: the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～6%, auxiliary agent 0～2%, filler 0～50%, butanone 0～10%, ethyl acetate 0～15%.
6. acrylic ester prepolymer according to claim 5 is a kind of or its mixture of epoxy acrylate, urethane acrylate, fluorine-containing epoxy acrylate, fluorochemical urethane acrylic acid ester, amino acrylates; Described acrylate monomer is (methyl) hydroxy-ethyl acrylate, butyl acrylate, acrylic acid, different certain herbaceous plants with big flowers base acrylic acid ester, 1,6-omega-diol diacrylate, (propoxyl group) neopentylglycol diacrylate, three a kind of or its mixture in two propyl alcohol diacrylates, ethoxyquin trimethylolpropane triacrylate, the tetramethylol methane tetraacrylate that contracts; Described light trigger is a kind of or its mixture in benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenones light trigger, Benzophenones light trigger, the benzoic ether photoinitiator; Described auxiliary agent is a kind of or its mixture in levelling agent, antifoaming agent, the wetting dispersing agent; Described filler is a kind of or its mixture in French chalk, calcium carbonate, the barium sulfate.
7. ultraviolet-curing paint decorative pattern layer thickness according to claim 1 is preferably 5 ~ 200 microns; Consisting of by weight percentage: the mixture of acrylic ester prepolymer 10～60%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2%, filler 0～50%, toner 5～30%, resin 5～30%, butanone 0～10% and ethyl acetate 0～15%.
8. acrylic ester prepolymer according to claim 7 is a kind of or its mixture of epoxy acrylate, urethane acrylate, fluorine-containing epoxy acrylate, fluorochemical urethane acrylic acid ester, amino acrylates; Described acrylate monomer is (methyl) hydroxy-ethyl acrylate, butyl acrylate, acrylic acid, different certain herbaceous plants with big flowers base acrylic acid ester, 1,6-omega-diol diacrylate, (propoxyl group) neopentylglycol diacrylate, three a kind of or its mixture in two propyl alcohol diacrylates, ethoxyquin trimethylolpropane triacrylate, the tetramethylol methane tetraacrylate that contracts; Described light trigger is a kind of or its mixture in benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenones light trigger, Benzophenones light trigger, the benzoic ether photoinitiator; Described auxiliary agent is a kind of or its mixture in levelling agent, antifoaming agent, the wetting dispersing agent; Described filler is a kind of or its mixture in French chalk, calcium carbonate, the barium sulfate; Described toner is carbon black, iron white powder, ashen indigo plant, former Huang, a kind of or its mixture in bright red; Described resin is a kind of or its mixture in epoxy acrylate, urethane acrylate, amino acrylates, fluorine-containing epoxy acrylate, the fluorochemical urethane acrylic acid ester.
9. ultraviolet-curing paint background color layer thickness according to claim 1 is preferably 5 ~ 200 microns; Consisting of by weight percentage: the mixture of acrylic ester prepolymer 10～50%, acrylate monomer 10～40%, light trigger 1～5%, auxiliary agent 0～2%, filler 0～30%, toner 5～30%, resin 5～50%, butanone 0～10%, ethyl acetate 0～15%.
10. acrylic ester prepolymer according to claim 9 is a kind of or its mixture of epoxy acrylate, urethane acrylate, fluorine-containing epoxy acrylate, fluorochemical urethane acrylic acid ester, amino acrylates; Described acrylate monomer is (methyl) hydroxy-ethyl acrylate, butyl acrylate, acrylic acid, different certain herbaceous plants with big flowers base acrylic acid ester, 1,6-omega-diol diacrylate, (propoxyl group) neopentylglycol diacrylate, three a kind of or its mixture in two propyl alcohol diacrylates, ethoxyquin trimethylolpropane triacrylate, the tetramethylol methane tetraacrylate that contracts; Described light trigger is a kind of or its mixture in benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenones light trigger, Benzophenones light trigger, the benzoic ether photoinitiator; Described auxiliary agent is a kind of or its mixture in levelling agent, antifoaming agent, the wetting dispersing agent; Described filler is a kind of or its mixture in French chalk, calcium carbonate, the barium sulfate; Described toner is carbon black, titanium white powder, ashen indigo plant, former Huang, a kind of in bright red; Described resin is a kind of or its mixture in epoxy acrylate, urethane acrylate, amino acrylates, fluorine-containing epoxy acrylate, the fluorochemical urethane acrylic acid ester.
11. preparation method according to claim 1 is: 1) to the preliminary treatment of base load film, on the base load film, evenly be coated with or the printing release layer, carry out infrared curing then, obtain release layer on the base load film
2) even coating or printing ultraviolet solidifying protection paint on release layer carry out UV-irradiation then and solidify, and obtain the ultraviolet-curing paint topping;
3) even coating or printing ultraviolet light polymerization decorative pattern layer on the ultraviolet-curing paint topping carry out UV-irradiation then and solidify, and obtain ultraviolet light polymerization decorative pattern layer;
4) even coating or printing ultraviolet light polymerization background color coating on ultraviolet light polymerization decorative pattern layer carry out UV-irradiation then and solidify, and obtain ultraviolet light polymerization background color layer;
5) check, at ultraviolet light polymerization background color laminating diaphragm, packing.
12. infrared curing according to claim 11 is that the infrared rays heating-up temperature is transferred to 20 ~ 150 ℃, flow time 0.01 ~ 10 minute fully solidifies release layer; Described uviol lamp is that power is at least a in the high-pressure sodium lamp of 3 ~ 20kw, the metal halid lamp that power is 3 ~ 20kw; The optical source wavelength of used lamp is 200 ~ 600 nanometers.
13. method for using step according to claim 1 is: 1) metope is carried out surfacing according to conventional method; 2) application ultraviolet cured adhesive on the metope after step 1) is handled sticks on the ultraviolet light polymerization colourful pattern wallpaper of removing packaging film on the metope; 3) carry out ultraviolet light polymerization; 4) remove the base load film.
14. ultraviolet cured adhesive according to claim 13 is formed by weight percentage: acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 60%, light trigger 1 ~ 6%, auxiliary agent 0 ~ 2% and filler 0 ~ 50%.
15. acrylic ester prepolymer according to claim 14 is a kind of or its mixture of epoxy acrylate, urethane acrylate, fluorine-containing epoxy acrylate, fluorochemical urethane acrylic acid ester, amino acrylates; Described acrylate monomer is (methyl) hydroxy-ethyl acrylate, butyl acrylate, acrylic acid, different certain herbaceous plants with big flowers base acrylic acid ester, 1,6-omega-diol diacrylate, (propoxyl group) neopentylglycol diacrylate, three a kind of or its mixture in two propyl alcohol diacrylates, ethoxyquin trimethylolpropane triacrylate, the tetramethylol methane tetraacrylate that contracts; Described light trigger is a kind of or its mixture in benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenones light trigger, Benzophenones light trigger, the benzoic ether photoinitiator; Described auxiliary agent is a kind of or its mixture in levelling agent, antifoaming agent, the wetting dispersing agent; Described filler is a kind of or its mixture in French chalk, calcium carbonate, the barium sulfate.
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| CN2012102623099A CN102777009A (en) | 2012-07-26 | 2012-07-26 | Ultraviolet light polymerization multicolor wallpaper |
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| CN2012102623099A CN102777009A (en) | 2012-07-26 | 2012-07-26 | Ultraviolet light polymerization multicolor wallpaper |
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| CN2012102623099A Pending CN102777009A (en) | 2012-07-26 | 2012-07-26 | Ultraviolet light polymerization multicolor wallpaper |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103555152A (en) * | 2013-09-27 | 2014-02-05 | 上海乘鹰新材料有限公司 | UV light-cured transfer adhesive composition |
| CN103866939A (en) * | 2014-03-14 | 2014-06-18 | 珠海东诚光固化材料有限公司 | Novel safety glass decorative sheet and preparation method thereof |
| CN103866938A (en) * | 2012-12-07 | 2014-06-18 | 北京科实医学图像技术研究所 | Colorized convex and concave type wallpaper |
| CN104695287A (en) * | 2015-02-27 | 2015-06-10 | 珠海市沛天力装饰材料有限公司 | Wallpaper capable of being repeatedly written |
| CN105505091A (en) * | 2015-11-25 | 2016-04-20 | 安徽索亚装饰材料有限公司 | Wallpaper containing a porous silicon carbide-polylactic acid porous fiber modified acrylic resin emulsion coating |
| CN107297968A (en) * | 2016-04-15 | 2017-10-27 | 鸿富锦精密工业（深圳）有限公司 | Composite surface treatment method |
| CN107297967A (en) * | 2016-04-15 | 2017-10-27 | 鸿富锦精密工业（深圳）有限公司 | composite surface treatment method |
| CN107488389A (en) * | 2017-08-17 | 2017-12-19 | 东莞市卓艺印刷制品有限公司 | A kind of antibacterial transfer film and preparation method thereof |
| CN110195499A (en) * | 2019-04-22 | 2019-09-03 | 苏州前航实业有限公司 | A kind of environment protection type multifunctional wall paper |
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| CN103866938A (en) * | 2012-12-07 | 2014-06-18 | 北京科实医学图像技术研究所 | Colorized convex and concave type wallpaper |
| CN103555152A (en) * | 2013-09-27 | 2014-02-05 | 上海乘鹰新材料有限公司 | UV light-cured transfer adhesive composition |
| CN103866939A (en) * | 2014-03-14 | 2014-06-18 | 珠海东诚光固化材料有限公司 | Novel safety glass decorative sheet and preparation method thereof |
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| CN105505091A (en) * | 2015-11-25 | 2016-04-20 | 安徽索亚装饰材料有限公司 | Wallpaper containing a porous silicon carbide-polylactic acid porous fiber modified acrylic resin emulsion coating |
| CN107297968A (en) * | 2016-04-15 | 2017-10-27 | 鸿富锦精密工业（深圳）有限公司 | Composite surface treatment method |
| CN107297967A (en) * | 2016-04-15 | 2017-10-27 | 鸿富锦精密工业（深圳）有限公司 | composite surface treatment method |
| CN107488389A (en) * | 2017-08-17 | 2017-12-19 | 东莞市卓艺印刷制品有限公司 | A kind of antibacterial transfer film and preparation method thereof |
| CN110195499A (en) * | 2019-04-22 | 2019-09-03 | 苏州前航实业有限公司 | A kind of environment protection type multifunctional wall paper |
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Inventor after: Tan Haoya Inventor after: Li Jing Inventor before: Tan Haoya Inventor before: Lin Gaoxian |
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Application publication date: 20121114 |