CN105670471A - Waterborne radiation curing coating decorating plate and preparation method thereof - Google Patents
Waterborne radiation curing coating decorating plate and preparation method thereof Download PDFInfo
- Publication number
- CN105670471A CN105670471A CN201610173325.9A CN201610173325A CN105670471A CN 105670471 A CN105670471 A CN 105670471A CN 201610173325 A CN201610173325 A CN 201610173325A CN 105670471 A CN105670471 A CN 105670471A
- Authority
- CN
- China
- Prior art keywords
- confining bed
- white
- coating
- primer layer
- radiation curable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/065—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects having colour interferences or colour shifts or opalescent looking, flip-flop, two tones
- B05D5/066—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects having colour interferences or colour shifts or opalescent looking, flip-flop, two tones achieved by multilayers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/06—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
- B05D7/546—No clear coat specified each layer being cured, at least partially, separately
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
- B05D7/58—No clear coat specified
- B05D7/586—No clear coat specified each layer being cured, at least partially, separately
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
- C09D171/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0871—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2502/00—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Plant Pathology (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention provides a waterborne radiation curing coating decorating plate and a preparation method thereof. The waterborne radiation curing coating decorating plate comprises a bamboo grass wood baseplate and a closed layer and/or a white closed layer and a finish layer which are sequentially coated on the surface of the bamboo grass wood baseplate, each of the closed layer and/or the white closed layer and the finish layer comprises a waterborne radiation curing coating, and the waterborne radiation curing coating is composed of, by weight, 1-40 wt% of acrylate monomer, 30-50 wt% of one ore multiple of water-soluble acrylate prepolymer, organosilicon modified waterborne acrylate polymer and oil-in-water acrylate prepolymer emulsion, 3-10 wt% of photoinitiator and 2-41 wt% of one or multiple of water or alcohol solvent. The waterborne radiation curing coating decorating plate is environment-friendly, has better mechanical performance, good antibacterial performance, fouling resistance and heat resistance and is high in color and pattern expressiveness.
Description
Technical field
The present invention relates to decorative panel and preparation method thereof, particularly relate to aqueous radiation curable coating decorative panel and preparation method thereof.
Background technology
Radiation curable coating decorative panel is state-of-the art ornament materials in the market, radiation curable coating has surface property and high curing rate, normal temperature cure, the feature such as energy-conservation of excellence, adopt radiation curable coating to carry out the decorative panel of surface treatment and have good functional: be anti-scratch, heat-resisting etc., but the preparation of the coating of existing radiation curable coating decorative panel need to regulate viscosity by reactive diluent, has certain zest and toxicity; Reactive diluent can cause the contraction of dope layer volume in the curing process simultaneously.
Along with the raising of people's living standard, not only the demand of radiation curable coating decorative panel is strengthened, also the function of radiation curable coating decorative panel, environmental-protecting performance etc. be there has also been higher requirement simultaneously. Therefore, each production link to radiation curable coating decorative panel, the requirement of the construction link of engineering is also more and more higher, and the functional requirement that product needed is shown is more and more higher, and existing radiation curable coating decorative panel is difficult to meet the demand that consumer is growing.
Summary of the invention
Present invention seek to address that problem as described above. It is an object of the invention to provide aqueous radiation curable coating decorative panel and preparation method thereof, this decorative panel adopts aqueous radiation curable coating to carry out surface treatment, environmental protection, has better mechanical performance, has good antibacterial, anti-soil, the performance such as anti-scratch, mildew resistance, thermostability concurrently; Simultaneously color, pattern representability are good. This aqueous radiation curable coating decorative panel can control easily in work progress, and construction technology is simpler, environmental protection.
According to an aspect of the present invention, it is provided that aqueous radiation curable coating decorative panel, described decorative panel includes bamboo vegetation substrate and is coated with the confining bed being contained in its surface and/or white confining bed and top coat layer successively;
Wherein, described confining bed and/or white confining bed and described top coat layer all comprise aqueous radiation curable coating, and described aqueous radiation curable coating includes following component, and the content of each component is expressed as follows with percentage by weight:
Wherein, described aqueous radiation curable coating also includes following component, and the content of each component is expressed as follows with percentage by weight:
Pigment 0～35wt%;
Filler 0～35wt%;
Auxiliary agent 0～5wt%.
Wherein, the first attachment primer layer is included successively between described confining bed and/or white confining bed and described top coat layer, second white confining bed and/or coloured coating are wherein, described first attachment primer layer, between described confining bed and/or white confining bed and described second white confining bed and/or coloured coating, described second white confining bed and/or coloured coating adhere between primer layer and described top coat layer at described second white confining bed and/or coloured coating described first;
Described first attachment primer layer, the second white confining bed and/or coloured coating all comprise described aqueous radiation curable coating.
Wherein, described confining bed and/or white confining bed and described top coat layer between include coloured coating, described coloured coating described confining bed and/or white confining bed and described top coat layer between;
Described coloured coating comprises described aqueous radiation curable coating.
Wherein, also including the second attachment primer layer between described second white confining bed and/or coloured coating and described top coat layer, described second attachment primer layer comprises described aqueous radiation curable coating.
Wherein, transfer film and the 3rd attachment primer layer is also included successively between described second attachment primer layer and described top coat layer, described transfer film adheres between primer layer and described 3rd attachment primer layer described second, and described 3rd attachment primer layer is between described transfer film and described top coat layer;
Described 3rd attachment primer layer comprises described aqueous radiation curable coating.
Wherein, described bamboo vegetation substrate includes solid wood board, MDF, plywood, particieboard, multi-layer sheet, bamboo plank, lagging plate, melamine plate, wood wool board, wood fine plate, bamboo fibre board, stalk board etc.
Wherein, described confining bed, white confining bed, second white confining bed thickness be 0.001～500 micron, described first attachment primer layer, the second attachment primer layer, the 3rd thickness adhering to primer layer are 0.001～200 micron, the thickness of described coloured coating is 0.001～200 micron, and the thickness of described top coat layer is 0.001～500 micron.
According to another aspect of the present invention, it is provided that the manufacture method of aqueous radiation curable coating decorative panel, comprise the following steps:
At external coating confining bed and/or the white confining bed of bamboo vegetation substrate, solidify, form confining bed and/or white confining bed, external coating finish paint at described confining bed and/or white confining bed, solidify, form top coat layer, and then form described aqueous radiation curable coating decorative panel; Or
External coating confining bed and/or white confining bed at bamboo vegetation substrate, solidify, form confining bed and/or white confining bed, external coating attachment primer layer at described confining bed and/or white confining bed, solidify, form the first attachment primer layer, external coating white confining bed and/or coloured coating at the first described attachment primer layer, solidify, form the second white confining bed and/or coloured coating, external coating finish paint at described second white confining bed and/or coloured coating, solidify, form top coat layer, and then form described aqueous radiation curable coating decorative panel, or
External coating confining bed and/or white confining bed at bamboo vegetation substrate, solidify, form confining bed and/or white confining bed, at the external coating coloured coating of described confining bed and/or white confining bed, solidify, form coloured coating, external coating finish paint at described coloured coating, solidify, form top coat layer, and then form described aqueous radiation curable coating decorative panel; Or
External coating confining bed and/or white confining bed at bamboo vegetation substrate, solidify, form confining bed and/or white confining bed, external coating attachment primer layer at described confining bed and/or white confining bed, solidify, form the first attachment primer layer, external coating white confining bed and/or coloured coating at the first described attachment primer layer, solidify, form the second white confining bed and/or coloured coating, external coating attachment primer layer at described second white confining bed and/or coloured coating, solidify, form the second attachment primer layer, external coating finish paint at the second described attachment primer layer, solidify, form top coat layer, and then form described aqueous radiation curable coating decorative panel,Or
External coating confining bed and/or white confining bed at bamboo vegetation substrate, solidify, form confining bed and/or white confining bed, external coating attachment primer layer at described confining bed and/or white confining bed, solidify, form the first attachment primer layer, external coating white confining bed and/or coloured coating at the first described attachment primer layer, solidify, form the second white confining bed and/or coloured coating, external coating attachment primer layer at described second white confining bed and/or coloured coating, solidify, form the second attachment primer layer, surface laminating transfer film at the second described attachment primer layer, solidify, remove base load film, form transfer rete, primer is adhered at described transfer rete external coating, solidify, form the 3rd attachment primer layer, at the described 3rd external coating finish paint adhering to primer layer, solidify, form top coat layer, and then form described aqueous radiation curable coating decorative panel.
Wherein, described manufacture method is further comprising the steps of:
Before confining bed described in application and/or white confining bed, carry out fixed thick sanding, dedusting, benefit soil, solidify; Before the first attachment primer layer, the second attachment primer layer described in application, carry out sanding, dedusting.
Decorative panel according to the decorative panel of the present invention includes bamboo vegetation substrate and is coated with the confining bed being contained in its surface and/or white confining bed and top coat layer successively; Wherein, described confining bed and/or white confining bed and described top coat layer all comprise aqueous radiation curable coating, and described aqueous radiation curable coating includes following component, and the content of each component is expressed as follows with percentage by weight:
Also including following component, the content of each component is expressed as follows with percentage by weight:
Pigment 0～35wt%;
Filler 0～35wt%;
Auxiliary agent 0～5wt%.
Wherein, acrylate monomer includes butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer, 2-(Acryloyloxy)ethanol, hydroxyethyl methylacrylate (HEMA), ethoxylated bisphenol A dimethylacrylate, tri (propylene glycol) diacrylate, propylene glycol diacrylate (DPGDA), neopentylglycol diacrylate, third oxidation neopentylglycol diacrylate, double, two (diethylene glycol) diacrylate of phthalic acid, three (2-ethoxy) isocyanuric acid triacrylate, 1,6 hexanediyl ester, trimethylolpropane trimethacrylate (TMPTA), 2-phenoxyethyl acrylate (PHEA), ethoxyquin trimethylolpropane trimethacrylate, third oxidation trimethylolpropane trimethacrylate, pentaerythritol triacrylate, dipentaerythritol acrylate, 2-HEMA phosphate ester, Polyethylene Glycol (600) dimethylacrylate (PEG (600) DMA), TEGDMA, Polyethylene Glycol (200) dimethylacrylate (PEG (200) DMA), ethoxyquin tetramethylol methane tetraacrylate (PET5EO4A), dioxy Lu Huan omega-diol diacrylate, third aoxidizes one or more in neopentylglycol diacrylate.
Wherein, water-soluble acrylic ester prepolymer includes one or more in soluble epoxide acrylate, aqueous polyurethane acrylate, aqueous unsaturated polyester (UP) acrylate, aqueous amino acrylates, water-borne acrylate copolymer, fluorine modified aqueous acrylate copolymer.
Wherein, organic-silicon-modified water-soluble acrylic ester polymer includes one or more in organic silicon modified aqueous polyester acrylate, organic silicon modified aqueous amino acrylates, organic silicon modified aqueous acrylate copolymer, organic silicon modified aqueous epoxy acrylate, fluosilicic modified aqueous acrylic acid ester copolymer, organic silicon modified aqueous polyurethane acrylate.
Wherein, oil-in-water acrylic ester prepolymer emulsion includes one or more in oil-in-water Epoxy-Acrylate Emulsion, oil-in-water polyurethane-acrylate emulsion, oil-in-water polyester acrylate emulsion, oil-in-water amino acrylates, oil-in-water acrylate copolymer.
Wherein, light trigger includes benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzil dimethyl ketal, from 1-Phenylethanone., 2,2-dimethoxy-2-phenyl acetophenone, 2,2-diethoxy-2-phenyl acetophenone, 1,1-dichloroacetophenone, 1-hydroxy acetophenone, 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-(4-isopropyl phenyl)-2-hydroxy-2-methyl-1-acetone, 1-[4-(2-hydroxyl-oxethyl) phenyl]-2-hydroxy-2-methyl-1-acetone, 2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone, 2-benzyl-2-dimethylamino-1-(4-morpholino phenyl)-1-butanone, 2-tert-butyl group anthraquinone, 1-chloroanthraquinone, 2-amyl anthraquinone, 2,4-dimethyl thioxanthone, 2,4-diethyl thioxanthone, 2-isopropyl thioxanthone, 4-isopropyl thioxanthone, 2-chloro thioxanthone, 2,4-diisopropyl thioxanthone, benzophenone, 4-chlorobenzophenone, to methyl benzophenone, 4-benzoyl-4 '-dimethyl diphenyl sulfide, 2,4,6-trimethyl benzoyl diphenyl base phosphine oxide, double, two (2,4,6-trimethylbenzoyl)-phenyl phosphine oxide, two (2,6-dimethylbenzoyl)-2,4,4-trimethylpentylphosphine oxide, 2,4,6-trimethylbenzoyl phenyl ethyoxyl phosphine oxide, methyl benzoylbenzoate, one or more in methyl o-benzoylbenzoate.
Wherein, pigment includes one or more in titanium dioxide, carbon black, iron oxide red, iron oxide yellow, ultramarine blue powder, ultramarine green powder, phthalocyanine blue powder, the green powder of the phthalein mountain valley with clumps of trees and bamboo, palm fibre chrome yellow powder, organic red, organic bloom, green organic powder, aqueous copper bronze, water aluminum-silver slurry powder, pearl essence.
Wherein, filler includes one or more in Pulvis Talci, Kaolin, flatting silica, aqueous delustring slurry, abrasion-resistant powder.
Wherein, auxiliary agent includes thickening agent, levelling agent, substrate wetting agents, defoamer, one or more in wetting dispersing agent, adhesion promoter, UV absorbent.
Wherein, thickening agent includes: one or both in PUR40, aerosil; Levelling agent includes: one or more in BYK348, BYK308N, CF736W; , substrate wetting agents includes: one or more in BYK190, CU190W, CJ60W, A80; Defoamer includes: one or more in BYK028, CD761SW, TEGO450; Wetting dispersing agent includes one or more in EFKA4010, BYK190, CU190W, CJ60W, WD264; UV absorbent includes one or more in 5050,5151,951,3310.
Wherein, in the manufacture method of the aqueous radiation curable coating decorative panel of the present invention, being cured as ultraviolet light or electronic beam curing, wherein the solidification power of ultraviolet light is 2～50KW, the curing rate of ultraviolet light 0.2～50 m/min.
Wherein, acrylate monomer, water-soluble acrylic ester prepolymer, organic silicon modified aqueous acrylate polymer, oil-in-water acrylic ester prepolymer emulsion and light trigger are main film forming matter; In the present invention; by using water as solution; coordinate specific film forming matter; and by the rational proportion of water, alcoholic solvent and the component such as organic silicon modified aqueous acrylate polymer and oil-in-water acrylic ester prepolymer emulsion; manufacture the radiation curable coating of environmental protection; and it being applied on bamboo vegetation substrate material so that this water paint forms aqueous radiation-curable couting fine and close, that have rich colors, that have defencive function on bamboo vegetation substrate.
The aqueous radiation curable coating decorative panel of the present invention, has good pattern and color representation power, the smooth densification in surface, has good antibacterial, anti-soil, anti-scratch, waterproof, mildew-resistant, heat resistance concurrently, can be widely applied to all kinds of decorative environment; Manufacturing process is simple, it is adaptable to batch production, and the feature of environmental protection, good energy saving property.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearly, technical scheme in the embodiment of the present invention will be clearly and completely described below, obviously, described embodiment is a part of embodiment of the present invention, rather than whole embodiments. Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under not making creative work premise, broadly fall into the scope of protection of the invention. It should be noted that when not conflicting, the embodiment in the application and the feature in embodiment can combination in any mutually.
The specific embodiment of decorative panel according to the present invention and manufacture method thereof is given below.
Embodiment 1 aqueous radiation curable coating white oak pattern decorative plate 1
Decorative panel 1: with bamboo vegetation substrate for substrate, surface can include confining bed, the first attachment primer layer, white confining bed, the second attachment primer layer, transfer film, the 3rd attachment primer layer, top coat layer successively. Wherein, decorative panel 1 can need to arrange above layers according to function. It is to describe the component of each layer and dependency relation in detail, above layers being illustrated in the present embodiment, but is not intended that the restriction to decorative panel 1. Such as, decorative panel 1 can include confining bed, top coat layer successively.
Wherein, confining bed, the first attachment primer layer, white confining bed, the second attachment primer layer, the 3rd attachment primer layer, top coat layer all comprise aqueous radiation curable coating, respectively X1, X2, X3, X2, X2, X4;
Aqueous radiation curable coating X1 includes following components and content:
Water-soluble polyester acrylate 20%, soluble polyurethane acrylate 8%, soluble epoxide acrylate 20%, TMPTA2%, EO-TMODA3%, HEMA3%, 2-hydroxy-2-methyl-1-acetone 5%, EFKA40102%, ethanol 10%, pure water 14%, PUR402%, Pulvis Talci 10%, A801%.
Aqueous radiation curable coating X2 includes following components and content:
Soluble epoxide acrylate 20%; HMEA10%; PEG (200) DMA15%, soluble polyurethane acrylate 15%, water-soluble modified acrylate 15%; 1-hydroxy-cyclohexyl-phenyl ketone 3%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 6%, double; two (2.4.6-trimethylbenzoyl)-phenyl phosphine oxide 1%, EFKA40101%; adhesion promoter 4%, ethanol 10%.
Aqueous radiation curable coating X3 includes following components and content:
Water-soluble polyester acrylate 10%; soluble polyurethane acrylate 8%; soluble epoxide acrylate 10%; TMPTA2%; EO-TMODA4%, HEMA3%, 2-hydroxy-2-methyl-1-acetone 2%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 3%, EFKA40101%, pure water 11%, PUR403%, Pulvis Talci 22%, pearl essence 10%, A801%.
Aqueous radiation curable coating X4 includes following components and content:
Fluosilicic modified soluble acrylate 15%; fluorine richness water-soluble acrylic ester copolymer 25%; PEG (600) DMA15%; PHEA10%, flatting silica 3.5%, aqueous delustring slurry 15%; 1-hydroxy-cyclohexyl-phenyl ketone 3.2%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2.5%, BYK1900.3%, TEGO4500.2%, BYK3480.3%, ethanol 10%.
Wherein, the thickness of the confining bed of decorative panel 1 is 60 microns, and the thickness of the first attachment primer layer is 8 microns, the thickness of white confining bed is 50 microns, the thickness of the second attachment primer layer is 15 microns, and the thickness of the 3rd attachment primer layer is 10 microns, the thickness of top coat layer 30 microns.
The manufacture method of aqueous radiation curable coating white oak pattern decorative plate 1:
Bamboo vegetation substrate is carried out fixed thick sanding, dedusting, at its external coating confining bed, comprises coating X1, enters linear velocity 10 ms/min, the uv cure machine of the double, two mercury lamp of 9.6KW, solidifies, sanding, dedusting, then adhere to primer layer at its external coating first, comprise coating X2, enter linear velocity 10 ms/min, the mono-mercury lamp uv cure machine of 9.6KW, semi-solid preparation, then at its external coating white confining bed, comprise coating X3, enter linear velocity 10 ms/min, 11.2KW gallium lamp, gallium lamp, hydrargyrum lamp, the uv cure machine of mercury lamp, solidifies, sanding, dedusting, then adhere to primer layer at its external coating second, comprise coating X2, enter linear velocity 10 ms/min, the uv cure machine of the double, two mercury lamp of 9.6KW, semi-solid preparation, then its surface utilize can the transfer film of transfer interpreter laminating white oak pattern of glue-spreading, enter linear velocity 10 ms/min, 16.8KW gallium lamp, gallium lamp, ferrum lamp, the uv cure machine of mercury lamp, solidifies, and removes base load film, then adheres to primer layer at its external coating the 3rd, comprise coating X2, enters linear velocity 10 ms/min, 11.2KW gallium lamp, the uv cure machine of gallium lamp, semi-solid preparation, then at its external coating top coat layer, comprise coating X4, enter linear velocity 10 ms/min, 16.8KW gallium lamp, gallium lamp, ferrum lamp, hydrargyrum lamp, the uv cure machine of mercury lamp, solidifies, then tests, pasting protective film, namely becomes the decorative panel 1 of aqueous radiation curable coating white oak pattern.
Embodiment 2 aqueous radiation curable coating silkwood decorative panel 2
Decorative panel 2: with bamboo vegetation substrate for substrate, surface can include confining bed, the first white confining bed, the first attachment primer layer, the second white confining bed, the second attachment primer layer, transfer film, the 3rd attachment primer layer, top coat layer successively;
Wherein, confining bed, the first white confining bed, the first attachment primer layer, the second white confining bed, the second attachment primer layer, the 3rd attachment primer layer, top coat layer all comprise aqueous radiation curable coating, are respectively as follows: X6, X7, X8, X7, X8, X8, X9;
Aqueous radiation curable coating X6 includes following components and content:
Water-soluble polyester acrylate 10%, soluble polyurethane acrylate 8%, soluble epoxide acrylate 10%, TMPTA2%, EO-TMODA4%, HEMA3%, 2-hydroxy-2-methyl-1-acetone 5%, EFKA40101%, pure water 11%, PUR403%, Pulvis Talci 32%, A801%.
Aqueous radiation curable coating X7 includes following components and content:
Soluble epoxide acrylate 20%; oil-in-water urethane acrylate 10%; PEG (600) DMA20%, white pearlescent powder 10%, Pulvis Talci 25%; 1-hydroxy-cyclohexyl-phenyl ketone 3%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 3%, double; two (2.4.6-trimethylbenzoyl)-phenyl phosphine oxide 1.8%, adhesion promoter 1%; TEGO4500.2%, BYK0281%, pure water 5%.
Aqueous radiation curable coating X8 includes following components and content:
Soluble epoxide acrylate 25%; HMEA10%; PEG (200) DMA15%, soluble polyurethane acrylate 10%, water-soluble modified acrylate 17%; 1-hydroxy-cyclohexyl-phenyl ketone 3%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 6%, double; two (2.4.6-trimethylbenzoyl)-phenyl phosphine oxide 1%, EFKA40101%; adhesion promoter 2%, pure water 5%.Ethanol 5%.
Aqueous radiation curable coating X9 includes following components and content:
Fluosilicic modified soluble acrylate 20%; Si modification water-soluble acrylic ester copolymer 25%; PEG (600) DMA18%; PHEA10%; 1-hydroxy-cyclohexyl-phenyl ketone 3.2%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 3%, BYK1900.3%, TEGO4500.2%, BYK3480.3%, ethanol 10%, pure water 5%.
Wherein, the thickness of the confining bed of decorative panel 2 is 10 microns, the thickness of the first white confining bed is 30 microns, the thickness of the first attachment primer layer is 12 microns, the thickness of the second white confining bed is 80 microns, the thickness of the second attachment primer layer is 10 microns, and the thickness of the 3rd attachment primer layer is 20 microns, the thickness of top coat layer 50 microns
The manufacture method of aqueous radiation curable coating silkwood decorative panel 2:
Bamboo vegetation substrate is carried out fixed thick sanding, dedusting, enter and mend soil machine benefit soil, enter the uv cure machine of linear velocity 15 ms/min, the mono-mercury lamp of 7.2KW, semi-solid preparation, again at its external coating confining bed, comprise coating X6, enter the uv cure machine of linear velocity 15 ms/min, the double, two gallium lamp of 9.6KW, solidify, again at its external coating the first white confining bed, comprise coating X7, enter the uv cure machine of linear velocity 15 ms/min, the double, two gallium lamp of 9.6KW, solidify, sanding, dedusting, then adhere to primer layer at its external coating first, comprise coating X8, enter linear velocity 10 ms/min, the mono-mercury lamp uv cure machine of 9.6KW, semi-solid preparation, then at its external coating the second white confining bed, comprise coating X7, enter linear velocity 15 ms/min, 16.8KW gallium lamp, gallium lamp, ferrum lamp, the uv cure machine of mercury lamp, solidifies, sanding, dedusting, then adhere to primer layer at its external coating second, comprise coating X8, enter linear velocity 15 ms/min, 11.2KW the uv cure machine of double, two mercury lamps, semi-solid preparation, then its surface utilize can glue-spreading transfer interpreter laminating silkwood transfer film, enter linear velocity 15 ms/min, 16.8KW gallium lamp, gallium lamp, ferrum lamp, the uv cure machine of mercury lamp, solidifies, and removes base load film, then adheres to primer layer at its external coating the 3rd, comprise coating X8, enters linear velocity 15 ms/min, 11.2KW gallium lamp, the uv cure machine of gallium lamp, semi-solid preparation, then at its external coating top coat layer, comprise coating X9, enter linear velocity 15 ms/min, 16.8KW gallium lamp, gallium lamp, ferrum lamp, hydrargyrum lamp, the uv cure machine of mercury lamp, solidifies, then tests, pasting protective film, namely becomes the decorative panel 2 of aqueous radiation curable coating silkwood pattern.
Embodiment 3 aqueous radiation curable coating light green color decorative panel 3
Decorative panel 3: with bamboo vegetation substrate for substrate, surface can include confining bed, white confining bed, coloured coating, top coat layer successively;
Wherein, confining bed, white confining bed, coloured coating, top coat layer all comprise aqueous radiation curable coating, are respectively as follows: X10, X11, X12, X13;
Aqueous radiation curable coating X10 includes following components and content:
Water-soluble polyester acrylate 9%, soluble polyurethane acrylate 9%, soluble epoxide acrylate 10%, TMPTA2%, EO-TMODA3%, HEMA3%, 2-hydroxy-2-methyl-1-acetone 5%, EFKA40101%, pure water 12%, PUR403%, Pulvis Talci 32%, A801%.
Aqueous radiation curable coating X11 includes following components and content:
Soluble epoxide acrylate 12%; oil-in-water urethane acrylate 18%, PEG (600) DMA20%, white pearlescent powder 6%; titanium dioxide 25%; Pulvis Talci 4%, 1-hydroxy-cyclohexyl-phenyl ketone 3%, 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 3%; double; two (2.4.6-trimethylbenzoyl)-phenyl phosphine oxide 1.8%; adhesion promoter 1%, TEGO4500.2%, BYK0281%, pure water 5%.
Aqueous radiation curable coating X12 includes following components and content:
Aqueous polyurethane acrylate copolymer 1 8%; organic-silicon-modified water-soluble acrylic ester copolymer 22%; DPGDA10%; PHEA5%; titanium dioxide 20%, the green powder 5% of the phthalein mountain valley with clumps of trees and bamboo, 1-hydroxy-cyclohexyl-phenyl ketone 4%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 4%, dispersant WD2642%, ethanol 5%, pure water 5%.
Aqueous radiation curable coating X13 includes following components and content:
Fluosilicic modified soluble acrylate 16%; fluorine richness water-soluble acrylic ester copolymer 29%; PEG (600) DMA18%; PHEA10%; 1-hydroxy-cyclohexyl-phenyl ketone 3.2%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 3%, BYK1900.3%, TEGO4500.2%, BYK3480.3%, ethanol 10%, pure water 5%.
Wherein, the thickness of the seal coat of decorative panel 3 is 10 microns, and the thickness of white confining bed is 70 microns, and the thickness of coloured coating is 25 microns, the thickness of top coat layer 50 microns.
The manufacture method of aqueous radiation curable coating light green color decorative panel 3:
Bamboo vegetation substrate is carried out fixed thick sanding, dedusting, enter and mend soil machine benefit soil, enter linear velocity 15 ms/min, the uv cure machine of the mono-mercury lamp of 7.2KW, semi-solid preparation, again at its external coating confining bed, comprise coating X10, enter linear velocity 15 ms/min, the uv cure machine of the double, two gallium lamp of 9.6KW, solidify, again at its external coating white confining bed, comprise coating X11, enter linear velocity 15 ms/min, 16.8KW gallium lamp, gallium lamp, ferrum lamp, the uv cure machine of mercury lamp, solidify, again at its external coating coloured coating X12, enter linear velocity 15 ms/min, 16.8KW gallium lamp, gallium lamp, the uv cure machine of ferrum lamp, semi-solid preparation, again at its external coating top coat layer, comprise coating X13, enter linear velocity 15 ms/min, 16.8KW gallium lamp, gallium lamp, ferrum lamp, hydrargyrum lamp, the uv cure machine of mercury lamp, solidify, testing, pasting protective film, namely become: aqueous radiation curable coating light green color decorative panel 3.
It addition, the component of the aqueous radiation curable coating of the decorative panel use of the present invention and weight/mass percentage composition can also represent by the form of form, specifically include
Table 1
In sum, compared with traditional radiation curable coating decorative panel, the aqueous radiation curable coating decorative panel environmental protection of the present invention, there is better mechanical performance, have good antibacterial, anti-soil, the performance such as anti-scratch, mildew resistance, thermostability concurrently; Simultaneously color, pattern representability are good. This aqueous radiation curable coating decorative panel can control Gel-coating film spraying easily in work progress, and construction technology is simpler, environmental protection.
Last it is noted that in this article, term " includes ", " comprising " or its any other variant are intended to comprising of nonexcludability, so that comprise the process of a series of key element, method, article or equipment not only include those key elements, but also include other key elements being not expressly set out, or also include the key element intrinsic for this process, method, article or equipment. When there is no more restriction, statement " including ... " key element limited, it is not excluded that there is also other identical element in including the process of described key element, method, article or equipment.
Above example only in order to technical scheme to be described, is not intended to limit. Although the present invention being described in detail with reference to previous embodiment, it will be understood by those within the art that: the technical scheme described in foregoing embodiments still can be modified by it, or wherein portion of techniques feature is carried out equivalent replacement; And these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (10)
1. aqueous radiation curable coating decorative panel, it is characterised in that described decorative panel includes bamboo vegetation substrate and is coated with the confining bed being contained in its surface and/or white confining bed and top coat layer successively;
Wherein, described confining bed and/or white confining bed and described top coat layer all comprise aqueous radiation curable coating, and described aqueous radiation curable coating includes following component, and the content of each component is expressed as follows with percentage by weight:
2. aqueous radiation curable coating decorative panel according to claim 1, it is characterised in that described aqueous radiation curable coating also includes following component, and the content of each component is expressed as follows with percentage by weight:
Pigment 0～35wt%;
Filler 0～35wt%;
Auxiliary agent 0～5wt%.
3. aqueous radiation curable coating decorative panel according to claim 1, it is characterized in that, the first attachment primer layer is included successively between described confining bed and/or white confining bed and described top coat layer, second white confining bed and/or coloured coating, wherein, described first attachment primer layer is between described confining bed and/or white confining bed and described second white confining bed and/or coloured coating, and described second white confining bed and/or coloured coating adhere between primer layer and described top coat layer described first;
Described first attachment primer layer, the second white confining bed and/or coloured coating all comprise described aqueous radiation curable coating.
4. aqueous radiation curable coating decorative panel according to claim 1, it is characterized in that, including coloured coating between described confining bed and/or white confining bed and described top coat layer, described coloured coating is between described confining bed and/or white confining bed and described top coat layer;
Described coloured coating comprises described aqueous radiation curable coating.
5. aqueous radiation curable coating decorative panel according to claim 3, it is characterized in that, also including the second attachment primer layer between described second white confining bed and/or coloured coating and described top coat layer, described second attachment primer layer comprises described aqueous radiation curable coating.
6. aqueous radiation curable coating decorative panel according to claim 5, it is characterized in that, transfer film and the 3rd attachment primer layer is also included successively between described second attachment primer layer and described top coat layer, described transfer film adheres between primer layer and described 3rd attachment primer layer described second, and described 3rd attachment primer layer is between described transfer film and described top coat layer;
Described 3rd attachment primer layer comprises described aqueous radiation curable coating.
7. the aqueous radiation curable coating decorative panel according to any one of claim 1 to 6, it is characterized in that, described bamboo vegetation substrate includes solid wood board, MDF, plywood, particieboard, multi-layer sheet, bamboo plank, lagging plate, melamine plate, wood wool board, wood fine plate, bamboo fibre board, stalk board etc.
8. the aqueous radiation curable coating decorative panel according to claim 1 to 7, it is characterized in that, described confining bed, white confining bed, second white confining bed thickness be 0.001～500 micron, described first attachment primer layer, the second attachment primer layer, the 3rd thickness adhering to primer layer are 0.001～200 micron, the thickness of described coloured coating is 0.001～200 micron, and the thickness of described top coat layer is 0.001～500 micron.
9. the preparation method of the aqueous radiation curable coating decorative panel according to any one of claim 1 to 8, it is characterised in that comprise the following steps:
At external coating confining bed and/or the white confining bed of bamboo vegetation substrate, solidify, form confining bed and/or white confining bed, external coating finish paint at described confining bed and/or white confining bed, solidify, form top coat layer, and then form described aqueous radiation curable coating decorative panel;Or
External coating confining bed and/or white confining bed at bamboo vegetation substrate, solidify, form confining bed and/or white confining bed, external coating attachment primer layer at described confining bed and/or white confining bed, solidify, form the first attachment primer layer, external coating white confining bed and/or coloured coating at the first described attachment primer layer, solidify, form the second white confining bed and/or coloured coating, external coating finish paint at described second white confining bed and/or coloured coating, solidify, form top coat layer, and then form described aqueous radiation curable coating decorative panel, or
External coating confining bed and/or white confining bed at bamboo vegetation substrate, solidify, form confining bed and/or white confining bed, at the external coating coloured coating of described confining bed and/or white confining bed, solidify, form coloured coating, external coating finish paint at described coloured coating, solidify, form top coat layer, and then form described aqueous radiation curable coating decorative panel; Or
External coating confining bed and/or white confining bed at bamboo vegetation substrate, solidify, form confining bed and/or white confining bed, external coating attachment primer layer at described confining bed and/or white confining bed, solidify, form the first attachment primer layer, external coating white confining bed and/or coloured coating at the first described attachment primer layer, solidify, form the second white confining bed and/or coloured coating, external coating attachment primer layer at described second white confining bed and/or coloured coating, solidify, form the second attachment primer layer, external coating finish paint at the second described attachment primer layer, solidify, form top coat layer, and then form described aqueous radiation curable coating decorative panel, or
External coating confining bed and/or white confining bed at bamboo vegetation substrate, solidify, form confining bed and/or white confining bed, external coating attachment primer layer at described confining bed and/or white confining bed, solidify, form the first attachment primer layer, external coating white confining bed and/or coloured coating at the first described attachment primer layer, solidify, form the second white confining bed and/or coloured coating, external coating attachment primer layer at described second white confining bed and/or coloured coating, solidify, form the second attachment primer layer, surface laminating transfer film at the second described attachment primer layer, solidify, remove base load film, form transfer rete, primer is adhered at described transfer rete external coating, solidify, form the 3rd attachment primer layer, at the described 3rd external coating finish paint adhering to primer layer, solidify, form top coat layer, and then form described aqueous radiation curable coating decorative panel.
10. the manufacture method of aqueous radiation curable coating decorative panel according to claim 9, it is characterised in that described manufacture method is further comprising the steps of:
Before confining bed described in application and/or white confining bed, carry out fixed thick sanding, dedusting, benefit soil, solidify; Before the first attachment primer layer, the second attachment primer layer described in application, carry out sanding, dedusting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610173325.9A CN105670471B (en) | 2016-03-23 | 2016-03-23 | Water-based radiation curable coating decorative panel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610173325.9A CN105670471B (en) | 2016-03-23 | 2016-03-23 | Water-based radiation curable coating decorative panel and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105670471A true CN105670471A (en) | 2016-06-15 |
| CN105670471B CN105670471B (en) | 2018-05-15 |
Family
ID=56214960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610173325.9A Active CN105670471B (en) | 2016-03-23 | 2016-03-23 | Water-based radiation curable coating decorative panel and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105670471B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384182A (en) * | 2017-08-08 | 2017-11-24 | 湖南邦弗特新材料技术有限公司 | A kind of outdoor heavy bamboo timber floor and preparation method thereof |
| CN107718265A (en) * | 2016-08-11 | 2018-02-23 | 南通奥王节能建筑材料科技发展有限公司 | A kind of sound-absorbing integrated board and preparation method thereof |
| CN109366637A (en) * | 2018-11-23 | 2019-02-22 | 浙江农林大学 | Bamboo veneer, Bamboo veneer glued board and their preparation method |
| CN111876003A (en) * | 2020-03-02 | 2020-11-03 | 杨建波 | Additive for decoration material and decoration material thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04117469A (en) * | 1990-09-07 | 1992-04-17 | Dainippon Ink & Chem Inc | Ink for printing corrugated cardboard and method for printing corrugated cardboard therewith |
| CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| CN203854397U (en) * | 2014-01-10 | 2014-10-01 | 珠海市佳伟力环保科技有限公司 | Radiation curing and transferring decorative plate |
| CN104989045A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing transfer-printing high-gloss decoration plate and manufacturing method thereof |
-
2016
- 2016-03-23 CN CN201610173325.9A patent/CN105670471B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04117469A (en) * | 1990-09-07 | 1992-04-17 | Dainippon Ink & Chem Inc | Ink for printing corrugated cardboard and method for printing corrugated cardboard therewith |
| CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| CN203854397U (en) * | 2014-01-10 | 2014-10-01 | 珠海市佳伟力环保科技有限公司 | Radiation curing and transferring decorative plate |
| CN104989045A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing transfer-printing high-gloss decoration plate and manufacturing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 刘秀生 等: "《涂装技术与应用》", 30 April 2007, 机械工业出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107718265A (en) * | 2016-08-11 | 2018-02-23 | 南通奥王节能建筑材料科技发展有限公司 | A kind of sound-absorbing integrated board and preparation method thereof |
| CN107384182A (en) * | 2017-08-08 | 2017-11-24 | 湖南邦弗特新材料技术有限公司 | A kind of outdoor heavy bamboo timber floor and preparation method thereof |
| CN109366637A (en) * | 2018-11-23 | 2019-02-22 | 浙江农林大学 | Bamboo veneer, Bamboo veneer glued board and their preparation method |
| CN109366637B (en) * | 2018-11-23 | 2021-04-16 | 浙江农林大学 | Bamboo veneer, bamboo veneer plywood and preparation method thereof |
| CN111876003A (en) * | 2020-03-02 | 2020-11-03 | 杨建波 | Additive for decoration material and decoration material thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105670471B (en) | 2018-05-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101941339B (en) | Ultraviolet light cured transfer printing film and preparation method and application thereof | |
| CN105647257A (en) | Water-based radiation-cured coating and use thereof | |
| CN105885494B (en) | Radiation curing fluosilicic coating and its preparation method and application | |
| CN101100583B (en) | High-adhesion ultraviolet radiation polyurethane double-solidifying carpentry paint and preparation method thereof | |
| CN201679177U (en) | UV cured transfer film metal decorative board | |
| CN201208874Y (en) | Printing decorated sheet by ultraviolet light curing | |
| CN100431834C (en) | Decorative sheet and process for producing the same | |
| CN101235672B (en) | Ultraviolet light curing overlay film decorative board for wall and method for making same | |
| CN104194613A (en) | Recoatable UV-curing colored one-step-coating aluminum powder paint and preparation method thereof | |
| CN202500289U (en) | Ultra violet curing colored decorative plate | |
| CN102206462B (en) | Metal UV (Ultraviolet) coating | |
| EP3456789B1 (en) | Build materials having a metallic appearance for 3d printing | |
| CN105670471A (en) | Waterborne radiation curing coating decorating plate and preparation method thereof | |
| CN107974193A (en) | A kind of ultraviolet light for glass color mirror cures pigmented finiss and its application | |
| CN106243931A (en) | Anion UV coating and using method thereof and purposes | |
| CN104559741B (en) | UV (ultraviolet) finishing varnish for laser roller coating | |
| CN102220084A (en) | Photocureable coating and curing method thereof | |
| CN105860778B (en) | Aqueous radiation curable coating decorative panel and preparation method thereof | |
| CN104371508A (en) | Weather-resistant coating composite film | |
| CN103265873A (en) | UV (Ultraviolet) light white finish | |
| CN103131224A (en) | Ultraviolet curable electrosilvering coating substituting for electroplating or vacuum plating and application thereof | |
| CN108410328A (en) | A kind of UV whites painting design, preparation method and coating process | |
| CN202391056U (en) | Ultraviolet curing painting decorative plate | |
| CN201566396U (en) | UV curing colored PVC decorative sheet | |
| CN105623337B (en) | Waterborne radiation curing coating decorative plate and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |