CN108410328A - A kind of UV whites painting design, preparation method and coating process - Google Patents
A kind of UV whites painting design, preparation method and coating process Download PDFInfo
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- CN108410328A CN108410328A CN201810232775.XA CN201810232775A CN108410328A CN 108410328 A CN108410328 A CN 108410328A CN 201810232775 A CN201810232775 A CN 201810232775A CN 108410328 A CN108410328 A CN 108410328A
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- ultrawhite
- priming paint
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- paint
- photoinitiator
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of UV whites painting design, adheres to the low paint of clear priming paint, UV ultrawhites by UV high and UV ultrawhite finishing coats form.UV high adheres to transparent priming using modified epoxy acrylic ester, two official's aliphatic polyurethanes, pure acrylate, 1,6 hexanediyl esters, hydroxyethyl methacrylate as film forming binder;UV ultrawhite priming paint is using modified epoxy acrylic ester, two official's polyester acrylates, pure acrylate, 1,6 hexanediyl esters, two diacrylates of Poly-propylene glycol as film forming binder;UV ultrawhite finishing coats are using modified epoxy acrylic ester, two official's aliphatic polyurethanes, pure acrylate, trimethylolpropane trimethacrylate, two diacrylates of Poly-propylene glycol as film forming binder, by using multiple application, the UV priming paint and UV finishing coats of different function are combined, cure respectively film forming by ultraviolet light, it is good to form adhesive force, good leveling property, the white coating of high l value low b-values.
Description
Technical field
The invention belongs to UV technical field of coatings, and in particular to a kind of UV whites painting design, preparation method and application work
Skill.
Background technology
Uv radiation curing technology is a kind of completely new green environmental protection technique, and the ultraviolet light using technology production cures
Coating, abbreviation UV coating.Currently, the development in China has been enter into the new era, and people's good life needs are increasingly extensive, to substance
Culture life proposes requirements at the higher level.Cabinet, furniture, timber industry more and more use UV curing process to carry out plank
Environmentally protective application is decorated in protection.White cabinet and white furniture liked by Market Consumer very much, then how to distinguish white
The color form and aspect of color furniturePeople were mainly by the difference for visually carrying out perceived color in the past, but in current mechanization digitization
Application in, mainstream is increasingly becomed with instrument to survey color data, because it is precisely and unique.Color difference meter is widely used in
The color management field of the industries such as plastic cement, printing, paint, printing ink, weaving, dyeing clothing, according to the Lab of the CIE colour spaces, Lch
Principle measures aberration △ E and △ the Lab values for showing sample and sample.Be suitble to the inside and outside portion's color aesthetics of enterprise and
Data management and control.Automatic color distortion relatively between model and tested product, export △ E after tri- groups of data of L, a, b and colorimetric,
Tetra- groups of △ L, △ a, △ b chromatism datas.The size of △ E total color differences, △ L+ indicate partially white, and △ L- indicate partially black, and △ a+ indicate inclined
Red, △ a- indicate partially green, and △ b+ indicate partially yellow, and △ b- indicate partially blue.In simple terms, it is exactly that L values are higher, and whiteness is higher;B values
Smaller, Huang value is smaller.Current UV white coatings many on the market are after UV applications, because to pass through the multiple of ultraviolet light
Irradiation solidification, coating meeting accelerated ageing and xanthochromia, with color difference meter measured data, L values are low, and b values are high, and color form and aspect are not white enough, partially
Huang influences the beautiful appearance and visual effect of furniture.
Invention content
For the UV white coatings application existing in the prior art defect above problem easy to aging with xanthochromia, the present invention carries
For a kind of UV whites painting design, preparation method and coating process, which adheres to clear priming paint, UV ultrawhites bottom by UV high
Paint and UV ultrawhite finishing coats composition, cross and use multiple application, and it is good to obtain adhesive force, good leveling property, and the white of high l value low b-values applies
Layer.
The present invention is achieved by the following technical solutions:
A kind of UV whites painting design adheres to the low paint of clear priming paint, UV ultrawhites by UV high and UV ultrawhite finishing coats forms, described
UV high adheres to clear priming paint, and prescription quality percentage is:
Fatty acid modified epoxy acrylate:10-25%
Two official's aliphatic polyurethanes:10-25%
Pure acrylate:10-20%
1,6 hexanediol diacrylate:10-20%
Hydroxyethyl methacrylate:5-10%
Talcum powder:10-20%
Photoinitiator 1173:2-8%
Auxiliary agent:1-5%
The summation of all of above component is 100%;
The low paint of the UV ultrawhites, prescription quality percentage are:
Fatty acid modified epoxy acrylate:10-25%
Two official's polyester acrylates:10-25%
1,6 hexanediol diacrylate:10-20%
Two diacrylates of Poly-propylene glycol:5-10%
Rutile type titanium white:30-50%
Photoinitiator TPO:1-8%
Photoinitiator 754:1-4%
Auxiliary agent:1-5%
The summation of all of above component is 100%;
The UV ultrawhites finishing coat, prescription quality percentage are:
Six official's aliphatic polyurethanes:10-25%
Two official's aliphatic polyurethanes:10-25%
Trimethylolpropane trimethacrylate:10-20%
Two diacrylates of Poly-propylene glycol:5-10%
Rutile type titanium white:20-40%
Flatting silica:5-10%
Photoinitiator TPO:1-8%
Photoinitiator 754:1-8%
Auxiliary agent:1-5%
The summation of all of above component is 100%.
Further:The UV high adhere to clear priming paint, UV ultrawhites it is low paint or UV ultrawhite finishing coats in auxiliary agent include levelling agent,
Antifoaming agent, substrate wetting agents, dispersant, stabilizer or surface slip agent.
The present invention also provides the preparation methods of above-mentioned white painting design, and the quality proportioning that clear priming paint is adhered to according to UV high will
Each component is put into reaction kettle successively, is heated to 40-60 DEG C, and high-speed stirred is disperseed 2 hours, is obtained UV high and is adhered to clear priming paint;
Each component is put into reaction kettle successively according to the quality proportioning of UV ultrawhite priming paint, is heated to 40-60 DEG C, high-speed stirred point
It dissipates 2 hours, obtains UV ultrawhite priming paint;Each component is put into reaction kettle successively according to the quality proportioning of UV ultrawhite finishing coats, is added
Heat to 40-60 DEG C, disperse 2 hours, obtains UV ultrawhite finishing coats by high-speed stirred.
The present invention also provides the coating process of UV white painting designs, include the following steps:Roller coating UV high adheres to clear priming paint,
Semi-solid preparation → roller coating UV ultrawhite priming paint cures simultaneously sanding → roller coating UV ultrawhite priming paint, cures simultaneously sanding → roller coating UV ultrawhites bottom
Paint, semi-solid preparation → roller coating UV ultrawhite finishing coats, solidification → finished product.
UV high adheres to transparent priming using modified epoxy acrylic ester, two official's aliphatic polyurethanes, pure acrylate, 1,6-
As film forming binder, film-forming flexibility is good for hexanediyl ester, hydroxyethyl methacrylate, and adhesive force is good and timber knot
It gets togather and is combined between UV ultrawhite priming paint, play fine and close combine of forming a connecting link.
UV ultrawhite priming paint is using modified epoxy acrylic ester, two official's polyester acrylates, pure acrylate, 1,6-HD
As film forming binder, wherein modified epoxy acrylate resin is Zhong Shan sections field for diacrylate, two diacrylates of Poly-propylene glycol
Chemical industry 4268, two official's polyester acrylates are vast and boundless brightness new material HT7203, their levelling wetabilitys are good, and flexibility is good, solidification speed
Degree is fast, and color inhibition is good.Titanium dioxide is U.S. of U.S. gift connection 595, it is a chloridising production rutile type titanium white, it is covered
Power is strong, and whiteness is high, easily disperses, and weatherability is strong.Photoinitiator is TPO and 754, and TPO is in UV white coatings, deep cure effect
Rate is high, non yellowing;754 be a macromolecular photoinitiator, and surface cure is good, and residual smell is small.Film forming binder, titanium dioxide, light
Initiator, auxiliary agent are collocated with each other, roller coating application 3 times, and by ultraviolet radiation-curable 3 times, xanthochromia is smaller, obtains strong covering power,
Whiteness is high, and Huang is worth low, the white background paint film of good leveling property.
UV ultrawhite finishing coats are using modified epoxy acrylic ester, two official's aliphatic polyurethanes, pure acrylate, trihydroxy methyl third
Alkane triacrylate, two diacrylates of Poly-propylene glycol are as film forming binder, wherein six official's aliphatic polyurethane Changxing chemical industry are
6196-100, two official's aliphatic polyurethanes are Allnex4883, and in UV resins, aliphatic polyurethane, yellowing resistance is best.
Select yellowing resistance excellent in UV ultrawhite finishing coats, curing rate is fast, and the high 6196-100 of case hardness and excellent open air are resistance to
Long property and color inhibition, while wearability is had both, flexibility and good adhesive force are as matrix resin, 595 titanium dioxides of arranging in pairs or groups,
TPO and 754 photoinitiators, roller coating application one time obtain strong covering power by ultraviolet radiation-curable, and the high xanthochromia of whiteness is small
(high l value low b-values), the good film of flatness.
UV whites painting design provided by the invention, by using multiple application, the UV priming paint and UV finishing coats of different function
It is combined, cures respectively film forming by ultraviolet light, to good, the good leveling property that forms adhesive force, the white of high l value low b-values applies
Layer keeps white cabinet and white furniture Color whiteness height, yellowing small, and painting effect is good.
Specific implementation mode
The present invention is described in further details with reference to specific embodiment.
Embodiment 1
UV high adheres to transparent priming:
Fatty acid modified epoxy acrylate:18%
Two official's aliphatic polyurethanes:17%
Pure acrylate:12%
1,6 hexanediol diacrylate:13%
Hydroxyethyl methacrylate:10%
1250 mesh talcum powder:20%
Photoinitiator:5%
Auxiliary agent:5%
UV ultrawhite priming paint:
Modified epoxy acrylic ester:18%
Two official's polyester acrylates:12%
1,6 hexanediol diacrylate:10%
Two diacrylates of Poly-propylene glycol:10%
Import rutile type titanium white:40%
Photoinitiator:7%
Auxiliary agent:3%
UV ultrawhite finishing coats:
Six official's aliphatic polyurethanes:19%
Two official's aliphatic polyurethanes:11%
Trimethylolpropane trimethacrylate:10%
Two diacrylates of Poly-propylene glycol:10%
Import rutile type titanium white:35%
Import flatting silica:7%
Photoinitiator:6%
Auxiliary agent:2%
Each component is put into reaction kettle by the quality proportioning for adhering to clear priming paint according to UV high successively, is heated to 40-60
DEG C, high-speed stirred is disperseed 2 hours, is obtained UV high and is adhered to clear priming paint, and sealing storage is protected from light, spare.
Each component is put into reaction kettle successively according to the quality proportioning of UV ultrawhite priming paint, is heated to 40-60 DEG C, high speed
It is dispersed with stirring 2 hours, obtains UV ultrawhite priming paint, it is protected from light sealing storage, it is spare.
Each component is put into reaction kettle successively according to the quality proportioning of UV ultrawhite finishing coats, is heated to 40-60 DEG C, high speed
It is dispersed with stirring 2 hours, obtains UV ultrawhite finishing coats, be protected from light sealing storage, it is spare.
Embodiment 2
UV high adheres to clear priming paint:
Modified epoxy acrylic ester:20%
Two official's aliphatic polyurethanes:15%
Pure acrylate:10%
1,6 hexanediol diacrylate:15%
Hydroxyethyl methacrylate:10%
1250 mesh talcum powder:20%
Photoinitiator:5%
Auxiliary agent:5%
UV ultrawhite priming paint:
Modified epoxy acrylic ester:15%
Two official's polyester acrylates:15%
1,6 hexanediol diacrylate:10%
Two diacrylates of Poly-propylene glycol:10%
Import rutile type titanium white:40%
Photoinitiator:8%
Auxiliary agent:2%
UV ultrawhite finishing coats:
Six official's aliphatic polyurethanes:20%
Two official's aliphatic polyurethanes:10%
Trimethylolpropane trimethacrylate:10%
Two diacrylates of Poly-propylene glycol:10%
Import rutile type titanium white:35%
Import flatting silica:6%
Photoinitiator:7%
Auxiliary agent:2%
Preparation method reference implementation example 1.
To implementing involved painting design above application is carried out according to following coating process:
Using birch and poplar composite plate as base material, roller coating UV high adhesion primers, semi-solid preparation;Roller coating UV ultrawhite priming paint;Solidification
And sanding;Roller coating UV ultrawhites priming paint again cures simultaneously sanding;Roller coating UV ultrawhite priming paint, semi-solid preparation;Roller coating UV ultrawhite finishing coats, Gu
Change, obtains finished product.
Gained UV coating is subjected to application according to coating process of the present invention to painting object, film is fully cured latter 24 hours
Paint film property is as follows:
Note:Cross-hatching *, adhesive force are divided into 0-5 grades, and 0 grade preferably, and 5 grades worst.
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the scope of the present invention
It is defined, under the premise of not departing from design spirit of the present invention, those of ordinary skill in the art are to technical scheme of the present invention
The various modifications made and improvement should all be fallen into the protection domain of claims of the present invention determination.
Claims (4)
1. a kind of UV whites painting design, which is characterized in that adhere to the low paint of clear priming paint, UV ultrawhites and UV ultrawhite finishing coat groups by UV high
At the UV high adheres to clear priming paint, and prescription quality percentage is:
Fatty acid modified epoxy acrylate:10-25%
Two official's aliphatic polyurethanes:10-25%
Pure acrylate:10-20%
1,6 hexanediol diacrylate:10-20%
Hydroxyethyl methacrylate:5-10%
Talcum powder:10-20%
Photoinitiator 1173:2-8%
Auxiliary agent:1-5%
The summation of all of above component is 100%;
The low paint of the UV ultrawhites, prescription quality percentage are:
Fatty acid modified epoxy acrylate:10-25%
Two official's polyester acrylates:10-25%
1,6 hexanediol diacrylate:10-20%
Two diacrylates of Poly-propylene glycol:5-10%
Rutile type titanium white:30-50%
Photoinitiator TPO:1-8%
Photoinitiator 754:1-4%
Auxiliary agent:1-5%
The summation of all of above component is 100%;
The UV ultrawhites finishing coat, prescription quality percentage are:
Six official's aliphatic polyurethanes:10-25%
Two official's aliphatic polyurethanes:10-25%
Trimethylolpropane trimethacrylate:10-20%
Two diacrylates of Poly-propylene glycol:5-10%
Rutile type titanium white:20-40%
Flatting silica:5-10%
Photoinitiator TPO:1-8%
Photoinitiator 754:1-8%
Auxiliary agent:1-5%
The summation of all of above component is 100%.
2. UV whites painting design according to claim 1, it is characterised in that:The UV high adheres to clear priming paint, UV ultrawhites
Auxiliary agent in low paint or UV ultrawhite finishing coats includes levelling agent, antifoaming agent, substrate wetting agents, dispersant, stabilizer or surface slip
Agent.
3. the preparation method of white painting design described in claim 1, which is characterized in that adhere to the matter of clear priming paint according to UV high
Amount proportioning puts into each component in reaction kettle successively, is heated to 40-60 DEG C, and high-speed stirred is disperseed 2 hours, obtains UV high attachments
Clear priming paint;Each component is put into reaction kettle successively according to the quality proportioning of UV ultrawhite priming paint, is heated to 40-60 DEG C, high speed
It is dispersed with stirring 2 hours, obtains UV ultrawhite priming paint;Each component is put into reaction kettle successively according to the quality proportioning of UV ultrawhite finishing coats
In, it is heated to 40-60 DEG C, high-speed stirred is disperseed 2 hours, and UV ultrawhite finishing coats are obtained.
4. the coating process of UV whites painting design described in claim 1, it is characterised in that:Include the following steps:Roller coating UV
Height adheres to clear priming paint, and semi-solid preparation → roller coating UV ultrawhite priming paint cures simultaneously sanding → roller coating UV ultrawhite priming paint, solidification and sanding → roller
Apply UV ultrawhite priming paint, semi-solid preparation → roller coating UV ultrawhite finishing coats, solidification → finished product.
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Cited By (5)
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CN110180766A (en) * | 2019-05-07 | 2019-08-30 | 天津君盛天成科技发展有限公司 | A kind of coating process of LED-UV |
CN113861808A (en) * | 2021-10-22 | 2021-12-31 | 天津中晶建筑材料有限公司 | Roller coating UV white primer with excellent UV ink wettability and preparation method thereof |
CN114149727A (en) * | 2021-11-25 | 2022-03-08 | 上海展辰涂料有限公司 | Full UV coating system for wooden door, preparation method and coating process |
CN115537058A (en) * | 2022-09-06 | 2022-12-30 | 上海展辰涂料有限公司 | Ultra-yellow-resistant stain-resistant ultraviolet curing coating system |
CN115572524A (en) * | 2022-11-05 | 2023-01-06 | 上海立邦长润发涂料有限公司 | UV vacuum spraying anti-cracking transparent primer |
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CN115537058B (en) * | 2022-09-06 | 2023-09-26 | 上海展辰涂料有限公司 | Ultra-yellow-resistant and stain-resistant ultraviolet curing coating system |
CN115572524A (en) * | 2022-11-05 | 2023-01-06 | 上海立邦长润发涂料有限公司 | UV vacuum spraying anti-cracking transparent primer |
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