CN107974193A - A kind of ultraviolet light for glass color mirror cures pigmented finiss and its application - Google Patents
A kind of ultraviolet light for glass color mirror cures pigmented finiss and its application Download PDFInfo
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- CN107974193A CN107974193A CN201810013327.0A CN201810013327A CN107974193A CN 107974193 A CN107974193 A CN 107974193A CN 201810013327 A CN201810013327 A CN 201810013327A CN 107974193 A CN107974193 A CN 107974193A
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- acrylate
- cures
- ultraviolet light
- coating
- pigmented finiss
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/48—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
- C03C2217/485—Pigments
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
Abstract
The present invention discloses a kind of ultraviolet light for glass color mirror and cures pigmented finiss, includes acrylate oligomer, reactive acrylate monomer, photoinitiator, pigment and auxiliary agent.The coating is environment friendly and pollution-free, and minute surface flow leveling is good, it can be achieved that rapid UV-curing coloring, coating has the characteristics that good flat appearance, hardness height, resistance to marring, strong adhesive force, upper plating property are excellent after curing.The invention further relates to utilize glass color mirror made from the coating and preparation method thereof.
Description
Technical field
The invention belongs to radiation curable coating technical field, and in particular to a kind of ultraviolet light for glass color mirror（UV）Gu
Change pigmented finiss and its application.
Background technology
Glass color mirror also has dicoration, therefore be increasingly subject to the green grass or young crops of people well in addition to having the function of mirror
Look at.At present, the production method of glass color mirror is mainly the baking-type pigmented finiss for first containing solvent in the coated on one side of glass, Gu
Change it is dry after form colored coating, then aluminize on colored coating surface, the coat of metal such as silver.But this method contain it is organic
Solvent, VOC emission is big, can cause atmosphere pollution, is unfavorable for health, and paint solidification drying time is grown, high energy consumption.
The content of the invention
Offer one kind is be provided and is used for glass with technology growth requirement, the purpose of the present invention in view of the deficiencies of the prior art
The ultraviolet light of color mirror cures pigmented finiss.The coating is environment friendly and pollution-free, and VOC free release, minute surface flow leveling is good, is coated on glass
Behind surface, photochemical polymerization reaction can occur in very short time through UV radiation, realize that rapid curing colours, coating has after curing
There is the features such as flat appearance, hardness are high, resistance to marring is good, strong adhesive force, excellent upper plating property, fully meet the use of mirror industry processed
It is required that.It is to substitute in addition, having the characteristics that energy consumption is low, production efficiency is high, equipment investment is low, pollution-free using UV curing technologies
The fabulous selection of tradition mirror technique.
A kind of ultraviolet light for glass color mirror cures pigmented finiss, comprising：Acrylate oligomer 20-70wt%, reaction
Property acrylate monomer 10-50wt%, photoinitiator 2-10wt%, pigment 1-20wt%, auxiliary agent 0-5wt%.
Photochemical polymerization reacts field, cured product（Usually membranaceous or coating）Property depend critically upon participation polymerization
The raw material type of reaction, and there is also difference for the performance on different substrate materials.The above-mentioned ultraviolet light of the present invention cures coloring
In coating, acrylate oligomer and reactive acrylate monomer form the basis that photochemical polymerization reacts, and determine coloring
The performance of coating.
The ultraviolet light of the present invention cures in pigmented finiss, and acrylate oligomer is selected from epoxy acrylate, polyurethane third
Combination more than one or both of olefin(e) acid ester and polyester acrylate.
Applicable epoxy acrylate includes bisphenol A type epoxy acrylate, Epoxy Phenolic Acrylates, epoxychloropropane
Modified epoxy acrylic ester, such as particularly preferred Epoxy Phenolic Acrylates, EAM-2160W（Originate from the limited public affairs of Taiwan Changxing chemistry
Department）Deng.Applicable urethane acrylate includes two functional group's aliphatic urethane acrylates, trifunctional aliphatic poly ammonia
Ester acrylate, two functional group's aromatic urethane acrylates, trifunctional aromatic urethane acrylate 2-9 functional groups
Aliphatic urethane acrylate, 2-9 functional groups aromatic urethane acrylate, particularly preferred B-151（Originate from Guangzhou Boxing
Science and Technology Ltd.）、PP2208（It is rich into new material Science and Technology Ltd. to originate from Dongguan）.Applicable polyester acrylate includes two
Functional group's polyester acrylate, trifunctional group polyester acrylate 2-9 functional groups polyester acrylate, particularly preferred W2500b
（Originate from Guangzhou five-element's new material Science and Technology Ltd.）、B-581L（Originate from Guangzhou Boxing Science and Technology Ltd.）Deng.
Considered based on application performances such as hardness, adhesive force, minute surface levellings, acrylate oligomer cures in ultraviolet light to be coloured
Content in coating is preferably 40-60wt%.
The reactive acrylate monomer is selected from（Methyl）Hydroxy-ethyl acrylate,（Methyl）In hydroxypropyl acrylate
One or more kinds of combinations.
Considered based on factors such as photocuring reaction activity, reactive acrylate monomer cures in ultraviolet light in pigmented finiss
Content be preferably 20-45wt%.
Photoinitiator is not particularly limited, those known in UV curing field can be used to be suitable for propylene
The photoinitiator of esters of gallic acid Photocurable composition, such as benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenone
Photoinitiator, benzophenones light trigger, benzoic ether photoinitiator etc..It is poor that the efficiency of initiation of different photoinitiators exists
It is different, but on the basis of definite photocuring reaction raw material, the species and its dosage of photoinitiator to those skilled in the art and
Speech is easily definite.
Pigment type is not particularly limited, those convention pigments in existing glass color mirror, Ke Yishi can be used
Inorganic pigment or organic pigment, or both combinations.Exemplarily, pigment may be selected from titanium dioxide, carbon black, red
Combination more than one or both of toner, yellow toner, blue toner, purple toner, phthalocyanine blue, dark green, ultramarine.It is excellent
Selection of land, content of the pigment in ultraviolet light cures pigmented finiss is 2-10wt%.
In addition to above-mentioned four kinds of required components, ultraviolet light of the invention cure pigmented finiss can according to practical application needs,
Optionally（optionally）Those conven-tional adjuvants in glass color mirror pigmented finiss are added, including（But not limited to this）：Levelling
Agent, defoamer, adhesion promoter, photosensitivity promotor, wetting dispersing agent etc..Preferably, auxiliary agent cures coloring in ultraviolet light and applies
Content in material is 2-5wt%.
The ultraviolet light that the present invention is used for glass color mirror cures pigmented finiss, can be prepared by by the way that each component is uniformly mixed.
Typically, its preparation method comprises the following steps：Under the conditions of lucifuge, by acrylate oligomer, reactive acrylate monomer,
Mix with photoinitiator, stirred evenly at 50-80 DEG C；Add pigment and auxiliary agent, after being thoroughly mixed uniformly, grind so that
Fineness requirement needed for its satisfaction（Such as, less than 1um）, filtering, obtains the pigmented finiss.
The ultraviolet light that the present invention is used for glass color mirror cures pigmented finiss green non-pollution, and minute surface flow leveling is excellent, Gu
Coating has the advantages that flat appearance, hardness are high, resistance to marring is good, upper plating property is good after change, easy to use, efficient.
Correspondingly, the invention further relates to above-mentioned ultraviolet light to cure application of the pigmented finiss in glass color mirror is made.
Further, the present invention also aims to provide a kind of production method of glass color mirror, including：What is cleaned
The ultraviolet light of the glass surface coating present invention cures pigmented finiss, infrared levelling or natural levelling, and coloring is formed after UV cures
Coating, then plates the coats of metal such as one layer of aluminium, silver on colored coating surface.
In the above method, the coating can use conventional coating coating processes of the prior art, such as showering, roller coat
Deng preferred showering inversion process.The coating thickness of pigmented finiss usually can be 10-100um.Without limitation, infrared levelling
For temperature between 20-150 DEG C, flow time is 0.1-10 minutes.Under uv radiation, polymerization occurs for pigmented finiss of the invention anti-
Should, so as to fulfill rapid curing.As the light source for assigning energy, for preferably dominant wavelength in the range of 200-420nm, example includes mercury
The various light sources such as lamp, metal halide lamp, halogen lamp.The coat of metal can use conventionally depositing process of the prior art and equipment
To realize, vacuum coating equipment such as can be used, this belongs to known technology to those skilled in the art.
Go bad since the coat of metal easily scratches or occur chemical reaction during glass color mirror use by foreign object, glass color
The production method of mirror can further comprise metal coating surface increase protective coating the step of.Preferably, in coat of metal table
Face is coated with protective coating, and protective coating is formed after cure/dry.It is further preferable that the protective coating, which is ultraviolet light, cures painting
Material, the cure/dry are that UV cures.
It is further preferred that the ultraviolet-curing paint includes：Fluorine-containing ester oligomer 20-70wt%, reactivity
Acrylate monomer 10-50wt%, photoinitiator 2-10wt%, filler 2-20wt%, auxiliary agent 2-5wt%.
Wherein, fluorine-containing ester oligomer in fluorine-containing epoxy acrylate and fluorochemical urethane acrylate one
Kind or its mixture.Particularly suitablely, the fluorine-containing epoxy acrylate is limited by Zhuhai east really photocuring new material share
The DC112 of company's production, the fluorochemical urethane acrylate are the B- produced by Guangzhou Boxing new material Science and Technology Ltd.
864.The reactive acrylate monomer is selected from：（Methyl）Hydroxy-ethyl acrylate,（Methyl）Hydroxypropyl acrylate, isoborneol
Base（Methyl）Acrylate, tri (propylene glycol) diacrylate, propylene glycol diacrylate, neopentyl glycol two（Methyl）Third
Olefin(e) acid ester, 1,6 hexanediyl esters, phthalic acid diethylene glycol diacrylate, trimethylolpropane tris acrylic acid
Ester, ethoxyquin trimethylolpropane trimethacrylate, the third oxidation trimethylolpropane trimethacrylate, three acrylic acid of pentaerythrite
Combination more than one or both of ester, dipentaerythritol triacrylate.Photoinitiator and auxiliary agent, which can use, hereinbefore to be carried
To ultraviolet light cure pigmented finiss in those classifications.Filler be selected from talcum powder, flatting silica, anti-scratch wax powder, blanc fixe,
One or more in bentonite etc..
The protective coating obtained using above-mentioned ultraviolet-curing paint has hardness height, the good, strong adhesive force of resistance to marring etc.
Advantage, and resistance to acid and alkali and water boiling resistance are excellent, it is easy to use, efficient.
Corresponding with above-mentioned production method, the invention further relates to the glass color mirror as made from above-mentioned production method.
Embodiment
The present invention is described in further detail below in conjunction with specific embodiment, but should not be construed as protecting the present invention
Protect the limitation of scope.
, ultraviolet light cure pigmented finiss preparation
Embodiment 1
Under the conditions of lucifuge, in terms of the gross mass of final coating, by the urethane acrylate of 45wt%（B-151）, 22wt% first
The BASF TPO photoinitiators mixing of base hydroxypropyl acrylate, the hydroxyethyl methacrylate of 20wt% and 5wt%, is warming up to 55
DEG C, stir evenly.Then the levelling agent of 1.8wt% is added（BYK3510）, 1wt% dispersant（BYK163）, 0.2wt% defoaming
Agent（BYK055）And 5% red toner, be sufficiently stirred, high speed dispersion, be ground to fineness and be less than 1um, filter, obtain ultraviolet
Photocuring encrimson.
Embodiment 2
Under the conditions of lucifuge, in terms of the gross mass of final coating, by the Epoxy Phenolic Acrylates of 30wt%（EAM-2160W）、
The polyester acrylate of 30wt%（W2500b）, the hydroxypropyl acrylate of 10wt%, the hydroxyethyl methacrylate of 18wt%, 2wt%
BASF TPO and 3wt% 1173 photoinitiators of Ciba mixing, be warming up to 60 DEG C, stir evenly.Then add 1.5wt%'s
Levelling agent（BYK333）, 1.2wt% dispersant（BYK2009）, 0.3wt% defoamer（BYK085）And 4% yellow color
Powder, is sufficiently stirred, high speed dispersion, is ground to fineness and is less than 1um, filtering, obtains ultraviolet light and cures yellow paint.
Embodiment 3
Under the conditions of lucifuge, in terms of the gross mass of final coating, by the urethane acrylate of 16wt%（PP2208）, 25wt% it is poly-
Ester acrylate（B-581L）, the hydroxy propyl methacrylate of 20wt%, the hydroxyethyl methacrylate of 20wt%, the BASF of 3wt%
1173 photoinitiators of the Ciba mixing of TPO and 3wt%, is warming up to 60 DEG C, stirs evenly.Then the levelling agent of 1wt% is added
（BYK333）, 1.8wt% dispersant（BYK2009）, 0.2wt% defoamer（BYK085）And 10% purple toner, fill
Divide stirring, high speed dispersion, is ground to fineness and is less than 1um, filtering, obtains ultraviolet light and cures purple paint.
2nd, the making of glass color mirror and performance characterization
2.1 coloring
By the coating of embodiment 1-3 respectively by curtain coater showering in the one side of the glass cleaned, thickness control at about 50 μm,
Inversion is handled, 60 DEG C of infrared levellings, then using 3 wavelength as the mercury lamp of 260-340nm, power for 16.8KW be radiating light source into
Row UV cures, and curing rate is controlled in 10m/min.After curing, colored coating is formed.
With reference to respective standard, the hardness, appearance and adhesive force of colored coating are tested, as a result as shown in table 1.
Table 1
It can see by the test result in table 1, cure pigmented finiss using the ultraviolet light of the present invention consolidates in glass surface through UV
Change forms colored coating, and flat appearance is smooth, and hardness is high, and strong adhesive force.
2.2 plated film
Glass formed with colored coating is placed in vacuum coating equipment（Model HF2100 (originates from Shantou City East Guangdong vacuum equipment
Manufacturing Co., Ltd）In, the aluminium film that a layer thickness is about 20um is plated, up to glass color mirror.
With reference to respective standard, adhesive force and color mirror improvement of visual effect to aluminium film are tested, as a result as shown in table 2.
Table 2
As shown in table 2, the colored coating that is formed in glass surface of pigmented finiss is cured using the ultraviolet light of the present invention, thereon plating property
It is good, strong adhesive force between aluminium film and colored coating.Also, obtained glass color mirror has excellent visual effect.
2.3 protective coating
The preparation of ultraviolet-curing paint as protective coating：, will in terms of the gross mass of final coating under the conditions of lucifuge
The fluorochemical urethane acrylate of 45wt%（B-864）, the hydroxypropyl acrylate of 10wt%, 20wt% hydroxyethyl methacrylate,
The BASF TPO photoinitiators mixing of the neopentylglycol diacrylate and 5wt% of 12wt%, is warming up to 55 DEG C, stirs evenly.So
The levelling agent of 2wt% is added afterwards（BYK3510）, 0.8wt% dispersant（BYK163）, 0.2wt% defoamer（BYK055）, with
And 5% flatting silica（OK500）, it is sufficiently stirred, high speed dispersion, is ground to fineness and is less than 1um, filters.
The glass color mirror made using the encrimson using embodiment 1 is example object, by ultraviolet-curing paint roller coat
In the aluminium coat surface of glass color mirror, thickness control is at about 40 μm, then using 3 wavelength as 260-340nm, power 16.8KW
Mercury lamp carry out UV curings for radiating light source, curing rate control obtains the glass color mirror with protective coating in 10m/min.
Using respective standard, the performance of protective coating is tested, including it is hardness, appearance, adhesive force, acid resistance, resistance to
Alkalescence and water boiling resistance.As a result it is as shown in table 3.
Table 3
| Detection project | Testing result | Examination criteria |
| Hardness（H） | 2H | GB6739-1996 |
| Appearance | Flat smooth | Range estimation |
| Adhesive force（Level） | 0 | GB9286-1998 |
| Water boiling resistance（Boiling water, 24h） | Paint film is without delamination, blistering | GB1733-1993 |
| Alkali resistance（10% NaOH, 24h） | Corrosion-free stain | GB/T9274 |
| Acid resistance（10% hydrochloric acid, 24h） | Corrosion-free stain | GB/T9274 |
It can see from the detection data of table 3, protective coating has higher hardness, and appearance condition is good, strong adhesive force, and whole band
The glass color mirror for having protective coating has excellent acid resistance, alkali resistance and water boiling resistance, and application performance is good.
Claims (14)
1. a kind of ultraviolet light for glass color mirror cures pigmented finiss, comprising：Acrylate oligomer 20-70wt%, reactivity
Acrylate monomer 10-50wt%, photoinitiator 2-10wt%, pigment 1-20wt%, auxiliary agent 0-5wt%.
2. ultraviolet light according to claim 1 cures pigmented finiss, it is characterised in that：The acrylate oligomer choosing
Combination from more than one or both of epoxy acrylate, urethane acrylate and polyester acrylate.
3. ultraviolet light according to claim 2 cures pigmented finiss, it is characterised in that：The epoxy acrylate is selected from
Bisphenol A type epoxy acrylate, Epoxy Phenolic Acrylates, epoxychloropropane modified epoxy acrylate, the polyurethane
Acrylate is selected from two functional group's aliphatic urethane acrylates, 2 functional group of trifunctional aliphatic urethane acrylate
Aliphatic urethane acrylate, two functional group's aromatic urethane acrylates, trifunctional aromatic urethane acrylic acid
Ester 2-9 functional groups aromatic urethane acrylate, the polyester acrylate are two functional group's polyester acrylates, three officials
Polyester acrylate 2-9 functional groups polyester acrylate can be rolled into a ball.
4. ultraviolet light according to claim 1 cures pigmented finiss, it is characterised in that：The acrylate oligomer choosing
Combination from more than one or both of EAM-2160W, B-151, PP2208, W2500b, B-581L.
5. ultraviolet light according to claim 1 cures pigmented finiss, it is characterised in that：The reactive acrylate is single
Body is selected from（Methyl）Hydroxy-ethyl acrylate,（Methyl）Combination more than one or both of hydroxypropyl acrylate.
6. the ultraviolet light any one of claim 1-5 cures application of the pigmented finiss in glass color mirror is made.
7. a kind of production method of glass color mirror, including：In any one of the glass surface coating claim 1-5 cleaned institute
The ultraviolet light stated cures pigmented finiss, infrared levelling or natural levelling, and colored coating is formed after UV cures, is then applied in coloring
Layer surface plates one layer of coat of metal.
8. production method according to claim 7, it is characterised in that：The coat of metal is aluminium, silver or zinc.
9. production method according to claim 7, it is characterised in that：Further comprise increasing in metal coating surface and protect
The step of coating.
10. production method according to claim 9, it is characterised in that：Protective coating is coated with metal coating surface, Gu
Protective coating is formed after change/drying.
11. production method according to claim 10, it is characterised in that：The protective coating is that ultraviolet light cures painting
Material, the cure/dry are that UV cures.
12. production method according to claim 11, it is characterised in that the ultraviolet-curing paint includes：It is fluorine-containing
Acrylate oligomer 20-70wt%, reactive acrylate monomer 10-50wt%, photoinitiator 2-10wt%, filler 2-
20wt%, auxiliary agent 2-5wt%.
13. production method according to claim 12, it is characterised in that：The fluorine-containing ester oligomer, which is selected from, to be contained
Fluorine epoxy acrylate and one kind or its mixture in fluorochemical urethane acrylate.
14. a kind of glass color mirror, is prepared by the production method any one of claim 7-13.
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| CN2791040Y (en) * | 2005-04-30 | 2006-06-28 | 田拥军 | Colour coated glass |
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