CN101210145A - Optical solidifying fluorine-carbon paint and its preparing method and use - Google Patents
Optical solidifying fluorine-carbon paint and its preparing method and use Download PDFInfo
- Publication number
- CN101210145A CN101210145A CNA2006101716090A CN200610171609A CN101210145A CN 101210145 A CN101210145 A CN 101210145A CN A2006101716090 A CNA2006101716090 A CN A2006101716090A CN 200610171609 A CN200610171609 A CN 200610171609A CN 101210145 A CN101210145 A CN 101210145A
- Authority
- CN
- China
- Prior art keywords
- fluorine
- acrylate
- coating
- mixture
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y02P20/121—
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention pertains to the coating field, in particular to a uv-curing fluorocarbon coating used for protecting and decorating building materials requiring high weatherability and a preparation method thereof. The main contents of the uv-curing fluorocarbon coating comprise fluorine-containing (methyl) acrylic acid modified prepolymer, reactive (fluorine-containing) acrylate monomer, photoinitiator, pigment, filler, addition agent, etc. Coating compositions of different mixture ratios are applied to building materials requiring high weatherability such as coil sheet, aluminum profile, aluminium plastic plates, plastic-steel profile, etc., and are characterized by thick paint film, rich colors, high hardness, good scratching resistance, weatherability, stain resistance, etc. Meanwhile, due to adopting uv-curing coating technology, the invention has the advantages of small production field, low equipment cost, high production efficiency, low energy consumption, and no pollution.
Description
Technical field
The invention belongs to paint field, particularly be used for the material of construction protection of requirement high-weatherability and optical solidifying fluorine-carbon paint of decorating and preparation method thereof.
Background technology
At present, fluorocarbon coating comprises four types: the one, and the hot setting fluorocarbon coating, the patent US6255398B1 of Germany BASF (BASF) company application discloses a kind of fluorine-carbon coil coating, this coating is main film forming substance with polyvinylidene difluoride (PVDF) (PVDF resin), there is the energy consumption height in fusion plastification film forming under 232～250 ℃ of high temperature, shortcomings such as production efficiency is low, facility investment is high, contaminate environment; The 2nd, the normal-temperature curing bi-component fluorocarbon coating, Chinese patent CN1580154A discloses a kind of fluorocarbon coating, three fluoro-resin by hydroxyl or the hydroxyl on the tetrafluoro resin and hexamethylene diisocyanate tripolymer carry out the chemical reaction film forming, and this fluorocarbon coating has shortcomings such as curing speed is slow, solvent is high, construction inconvenience; The 3rd, the ambient cure mono component fluorocarbon coating, Chinese patent CN1696220A discloses a kind of mono component fluorocarbon coating, carry out copolymerization by fluorine-containing methacrylic acid monomer and acrylate monomer, obtain fluoroacrylic resin, the coating of producing with this fluorine resin is the same with acrylic resin paint, can the self-vulcanizing film forming, needn't use solidifying agent, simplify constructing operation, saved construction cost; Chinese patent CN1401713A discloses a kind of mono-component aqueous nano-fluorine carbon coating, this coating is filmogen with the aqueous vinyl fluorine carbon emulsion, nano material is as material modified, be used for the application on surfaces such as building inside and outside wall, concrete structure, metal, chemical crosslink reaction does not take place in ambient cure mono component fluorocarbon coating film process, and paint film property is relatively poor relatively, simultaneously, curing speed is slow, and production efficiency is low.
Summary of the invention
Purpose one of the present invention provides optical solidifying fluorine-carbon paint, by spraying, roller coat, showering or brush behind substrate surface, with UV-light or radiation of visible light, making films, and the photochemical polymerization reaction takes place, in the utmost point short period of time (a few second), solidify characteristics such as filming after the curing has that paint film is plentiful, rich color, hardness height, resistance to marring are good, weathering resistance and contamination resistance are good.Simultaneously, adopt the photocuring coating process, it is little to have a required production site, and facility investment is low, production efficiency height, less energy consumption, free of contamination advantage.
Another object of the present invention provides a kind of preparation method of optical solidifying fluorine-carbon paint.
An also purpose of the present invention provides the purposes of optical solidifying fluorine-carbon paint.
Optical solidifying fluorine-carbon paint of the present invention is formed and content is:
Fluorine-containing modified prepolymers 20～80wt%
Reactive acrylate monomer, reactive fluorinated acrylate monomer or their mixture
10～60wt％
Light trigger 2～10wt%
Pigment 0～40wt%
Filler 0～30wt%
Auxiliary agent 0～3wt%
Described reactive acrylate monomer is contained the acrylate of 1～6 acryl or their mixture;
Described reactive fluorinated acrylate monomer is to contain the fluorinated acrylate of 1～6 acryl or their mixture;
In the above-mentioned coating component, described fluorine-containing modified prepolymers is that make with ordinary method or commercially available, be selected from fluorine-containing epoxy acrylate, fluorine-containing epoxy methacrylates, fluorochemical urethane acrylate, the fluorochemical urethane methacrylic ester, fluorine-containing polyester acrylate, fluorine-containing polyester methacrylate, fluorine-containing amino acrylates, fluorine-containing amino methyl acrylate, the mixture of one or more in the fluoro-acrylate copolymer.
The described acrylate that contains 1～6 acryl is: 1. single functionality monomer, as butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer (EHA), hydroxyethyl methylacrylate (MHEA), Hydroxyethyl acrylate (HEA), trifluoroethyl methacrylate, vinylformic acid trifluoro ethyl ester, methacrylic acid hexafluoro butyl ester, vinylformic acid hexafluoro butyl ester, methacrylic acid ten difluoro heptyl esters or dodecafluorhe-ptylacrylate etc.; 2. two functionality monomer, as tri (propylene glycol) diacrylate (TPGDA), propylene glycol diacrylate (DPGDA), neopentylglycol diacrylate (NPGDA), the third oxidation neopentylglycol diacrylate (PO-NPGDA), two (Diethylene Glycol) diacrylates (PDDA) of phthalic acid or 1,6 hexanediyl ester (HDDA) etc.; 3. polyfunctionality monomer is as Viscoat 295 (TMPTA), ethoxyquin Viscoat 295 (EO-TMPTA), the third oxidation Viscoat 295 (PO-TMPTA), pentaerythritol triacrylate (PETA) or dipentaerythritol acrylate (DPHA) etc.Usually use with one or more the mixture in the above-mentioned acrylate monomer.
The described fluorinated acrylate that contains 1～6 acryl is: trifluoroethyl methacrylate, vinylformic acid trifluoro ethyl ester, methacrylic acid hexafluoro butyl ester, vinylformic acid hexafluoro butyl ester, methacrylic acid ten difluoro heptyl esters, dodecafluorhe-ptylacrylate.Usually use with one or more the mixture in the above-mentioned fluorinated acrylate monomer.
Described light trigger is benzoin dimethylether (as Ciba 651); 2-hydroxy-2-methyl-1-phenyl-1-acetone (as Ciba 1173); 1-hydroxyl-cyclohexyl-phenyl ketone (as Ciba 184); isopropyl thioxanthone (as Ciba ITX); thio-phenyl-to oxygen azo-cycle acetone (as Ciba 369); 2-methyl isophthalic acid-[4-methylthio group phenyl]-2-morpholinyl-1-acetone (as Ciba 907); 2; 4; 6 (trimethylbenzoyl) diphenyl phosphine oxide (as the BASF TPO of BASF Aktiengesellschaft); two one (2; 6 one dimethyl benzene first phthalidyls)-2; 4,4 one tri-methyl-amyl oxygen unicorns (as Ciba 819); benzophenone; the 4-chlorobenzophenone; 4-methyldiphenyl ketone; 4-dimethylamino-ethyl benzoate; the different monooctyl ester of 4-dimethylaminobenzoic acid; diethylamine modification Viscoat 295 or their any mixture.
Above-mentioned light trigger Ciba 1173, Ciba 184, Ciba 369, Ciba 651, Ciba 819, Ciba907 or Ciba ITX are the products of Switzerland Ciba company.
Described pigment is mineral dye, pigment dyestuff, bronze (copper powder), silver powder (aluminium powder), pearlescence, fluorescent material, illusion-colour pigment, reflective pigment or their any mixture.
Described mineral dye comprises titanium dioxide, carbon black; Pigment dyestuff comprises phthalocyanine blue, green, the brown chrome yellow of the phthalein mountain valley with clumps of trees and bamboo, and is bright red.
Described filler is talcum powder or flatting silica.
Described flatting silica is the German Degussa OK of company 500.
Described auxiliary agent comprises flow agent, defoamer and/or wetting dispersing agent.Wherein flow agent institute add-on is 0～1wt%, and defoamer is 0～0.5wt%, and wetting dispersing agent is 0～3wt%.
Described flow agent is German Bi Ke BYK of chemical company 306 or BYK 358.
Described defoamer is German Bi Ke BYK of chemical company 055 or the modest DEUCHEM2700 of company of Taiwan moral.
Described wetting dispersing agent is the German Bi Ke Disperbyk of chemical company 163.
Preparation method's step of optical solidifying fluorine-carbon paint of the present invention is:
(1) light trigger that will account for the fluorine-containing modified prepolymers of total system 20～80wt%, the reactive acrylate monomer of 10～60wt%, reactive fluorinated acrylate monomer or their mixture and 2～10wt% mixes, be warming up to 50～60 ℃, stir;
(2) in the system of step (1), add the auxiliary agent that accounts for total system 0～3wt%, stir fully until dissolving fully;
(3) will account for the filler of total system 0～30wt% and the pigment of 0～40wt% again and join in the system of step (2), stir, disperse, grind, filter, obtain optical solidifying fluorine-carbon paint.
Photocuring light source when optical solidifying fluorine-carbon paint composition of the present invention is used is UV-light or visible light; The application mode is spraying, roller coat, showering or brushing etc.
Optical solidifying fluorine-carbon paint of the present invention can be widely used in metal coiled material, aluminium section bar, aluminium-plastic panel, plastic-steel section bar etc. require the material of construction of high-weatherability, have that paint film is plentiful, characteristics such as rich color, hardness height, resistance to marring are good, weathering resistance and contamination resistance are good.Simultaneously, adopt the photocuring coating process, it is little to have a required production site, and facility investment is low, production efficiency height, less energy consumption, free of contamination advantage.
Embodiment
Embodiment 1
(1) will account for the fluorine-containing epoxy methacrylates of total system 30wt%, the fluorochemical urethane acrylate of 10wt%, the Isooctyl acrylate monomer of 45wt%, the vinylformic acid trifluoro ethyl ester of 10wt% and the Ciba1173 of 2.5wt% and Ciba 184 light triggers of 2wt% mixes, be warming up to 50～60 ℃, stir;
(2) adding accounts for the BYK 055 of total system 0.2wt% and the BYK 306 of 0.3wt% in the system of step (1), stirs fully until dissolving fully; Disperse, filter, obtain the high light fluorocarbon coating of photocuring.
Fluorine-containing epoxy methacrylates 30wt%
Fluorochemical urethane acrylate 10wt%
Isooctyl acrylate monomer 45wt%
Vinylformic acid trifluoro ethyl ester 10wt%
Ciba 1173 2.5wt％
Ciba 184 2wt％
BYK 055 0.2wt％
BYK 306 0.3wt％
Embodiment 2
(1) will account for the EO-TMPTA of HDDA, 30wt% of fluorine-containing amino acrylates, 20wt% of fluorochemical urethane methacrylic ester, the 20wt% of total system 20wt% and Ciba 184 light triggers of 4wt% and mix, be warming up to 50～60 ℃, stir;
(2) add the DEUCHEM 2700 of Disperbyk 163, the 0.2wt% account for total system 0.5wt% in the system of step (1), the BYK358 of 0.3wt% stirs fully until dissolving fully;
(3) OK 500 that will account for total system 5wt% again joins in the system of step (2), stirs, and disperses, and emulsification is filtered, and obtains the mute light fluorocarbon coating of photocuring.
Fluorochemical urethane methacrylic ester 20wt%
Fluorine-containing amino acrylates 20wt%
HDDA 20wt％
EO-TMPTA 30wt％
OK 500 5wt％
Ciba 184 4wt％
Disperbyk 163 0.5wt％
DEUCHEM 2700 0.2wt％
BYK 358 0.3wt％
Embodiment 3
(1) the BASF TPO light trigger that will account for Ciba 184, the 2wt% of the vinylformic acid hexafluoro butyl ester of TMPTA, 6wt% of TPGDA, 10wt% of fluorine-containing amino methyl acrylate, 10wt% of fluorine-containing polyester acrylate, the 10wt% of fluorine-containing epoxy acrylate, the 20wt% of total system 10wt% and 2wt% mixes, be warming up to 50～60 ℃, stir;
(2) in the system of step (1), add the Disperbyk 163 that accounts for total system 0.5wt%, the BYK 055 of 0.2wt%, the BYK306 of 0.3wt% stirs fully until dissolving fully;
(3) will account for the 3000 order talcum powder of total system 6wt%, the titanium dioxide of 22wt%, the phthalocyanine blue of 1wt% again and join in the system of step (2), stir, disperse, grind, filter, obtain the blue fluorocarbon coating of photocuring.
Fluorine-containing epoxy acrylate 10wt%
Fluorine-containing polyester acrylate 20wt%
Fluorine-containing amino methyl acrylate 10wt%
TPGDA 10wt％
TMPTA 10wt％
Vinylformic acid hexafluoro butyl ester 6wt%
Ciba 184 2wt％
BASF TPO 2wt％
3000 order talcum powder 6wt%
Titanium dioxide 22wt%
Phthalocyanine blue 1wt%
Disperbyk 163 0.5wt％
BYK 055 0.2wt％
BYK 306 0.3wt％
Embodiment 4
(1) Ciba 819 light triggers that will account for Ciba 184, the 1wt% of the methacrylic acid ten difluoro heptyl esters of DPHA, 5wt% of PO-NPGDA, 5wt% of fluorine-containing polyester methacrylate, 25wt% of fluorochemical urethane acrylate, the 20wt% of total system 30wt% and 3wt% mix, be warming up to 50～60 ℃, stir;
(2) in the system of step (1), add the Disperbyk 163 that accounts for total system 0.5wt%, the BYK 055 of 0.2wt%, the BYK358 of 0.3wt% stirs fully until dissolving fully;
(3) silver powder that will account for total system 10wt% again joins in the system of step (2), stirs, and disperses, and filters, and obtains photocuring silver color fluorocarbon coating.
Fluorochemical urethane acrylate 30wt%
Fluorine-containing polyester methacrylate 20wt%
PO-NPGDA 25wt％
DPHA 5wt％
Methacrylic acid ten difluoro heptyl ester 5wt%
Ciba 184 3wt％
Ciba 819 1wt％
Silver powder 10wt%
Disperbyk 163 0.5wt％
BYK 055 0.2wt％
BYK 358 0.3wt％
Embodiment 5
(1) Ciba 369 light triggers that will account for Ciba 651, the 2wt% of the EO-TMPTA of TPGDA, 10wt% of fluoro-acrylate copolymer, 20wt% of total system 60wt% and 3wt% mix, and are warming up to 50～60 ℃, stir;
(2) in the system of step (1), add the Disperbyk 163 that accounts for total system 0.5wt%, the DEUCHEM 2700 of 0.2wt%, the BYK358 of 0.3wt% stirs fully until dissolving fully;
(3) fluorescent material that will account for total system 4wt% again joins in the system of step (2), stirs, and disperses, and filters, and obtains photocuring fluorescence fluorocarbon coating.
Fluoro-acrylate copolymer 60wt%
TPGDA 20wt％
EO-TMPTA 10wt％
Ciba 651 3wt％
Ciba 369 2wt％
Fluorescent material 4wt%
Disperbyk 163 0.5wt％
DEUCHEM 2700 0.2wt％
BYK 358 0.3wt％
The embodiment effect
Adopt mode applications such as spraying, roller coat, showering or brushing, the excessive useable solvents of viscosity during construction (butanone: dilution butylacetate=1: 1), coating thickness is 5～100um, effect is as follows behind ultraviolet light polymerization:
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Testing method |
| Set time (s) | 2 | 3 | 4 | 3 | 5 | Company standard |
| Hardness (H) | 2 | 3 | 2 | 3 | 2 | GB 6739-1996 |
| Gloss or color | Gao Guang | Mute light | Blue | Flash effect | Fluorescent effect | Company standard |
| Sticking power (level) | 0 | 0 | 0 | 0 | 0 | GB 9286-1998 |
| Wear resistance (mg) | 0.003 | 0.002 | 0.003 | 0.003 | 0.002 | GB 1768-1989 |
| Water tolerance (240h) | No change | No change | No change | No change | No change | GB 1733-1993 |
| Alkali resistance (72h) | No change | No change | No change | No change | No change | GB 9265-1988 |
| Abrasion resistance (2000 times) | No change | No change | No change | No change | No change | GB 9266-1988 |
| Artificial weathering ageing resistance (2000h) | No change | No change | No change | No change | No change | GB 1865-1997 |
| Contamination resistance, % | 1 | 2 | 2 | 1 | 2 | GB 9780-1988 |
。
Claims (10)
1. an optical solidifying fluorine-carbon paint is characterized in that, this system component and content are:
Fluorine-containing modified prepolymers 20～80wt%
Reactive acrylate monomer, reactive fluorinated acrylate monomer or their mixture
10～60wt％
Light trigger 2～10wt%
Pigment 0～40wt%
Filler 0～30wt%
Auxiliary agent 0～3wt%
Described reactive acrylate monomer is contained the acrylate of 1～6 acryl or their mixture;
Described reactive fluorinated acrylate monomer is to contain the fluorinated acrylate of 1～6 acryl or their mixture.
2. coating according to claim 1, it is characterized in that: described fluorine-containing modified prepolymers is selected from fluorine-containing epoxy acrylate, fluorine-containing epoxy methacrylates, the fluorochemical urethane acrylate, fluorochemical urethane methacrylic ester, fluorine-containing polyester acrylate, fluorine-containing polyester methacrylate, fluorine-containing amino acrylates, fluorine-containing amino methyl acrylate, the mixture of one or more in the fluoro-acrylate copolymer.
3. coating according to claim 1, it is characterized in that: the described acrylate that contains 1～6 acryl is: butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer, hydroxyethyl methylacrylate, Hydroxyethyl acrylate, trifluoroethyl methacrylate, the vinylformic acid trifluoro ethyl ester, methacrylic acid hexafluoro butyl ester, vinylformic acid hexafluoro butyl ester, methacrylic acid ten difluoro heptyl esters, dodecafluorhe-ptylacrylate, tri (propylene glycol) diacrylate, propylene glycol diacrylate, neopentylglycol diacrylate, the third oxidation neopentylglycol diacrylate, two (Diethylene Glycol) diacrylates of phthalic acid, 1,6 hexanediyl ester, Viscoat 295, the ethoxyquin Viscoat 295, the third oxidation Viscoat 295, pentaerythritol triacrylate or dipentaerythritol acrylate;
The described fluorinated acrylate that contains 1～6 acryl is: trifluoroethyl methacrylate, vinylformic acid trifluoro ethyl ester, methacrylic acid hexafluoro butyl ester, vinylformic acid hexafluoro butyl ester, methacrylic acid ten difluoro heptyl ester or dodecafluorhe-ptylacrylates.
4. coating according to claim 1; it is characterized in that: described light trigger is a benzoin dimethylether; 2-hydroxy-2-methyl-1-phenyl-1-acetone; 1-hydroxyl-cyclohexyl-phenyl ketone; isopropyl thioxanthone; thio-phenyl-to oxygen azo-cycle acetone; 2-methyl isophthalic acid-[4-methylthio group phenyl]-2-morpholinyl-1-acetone; 2; 4; 6 (trimethylbenzoyl) diphenyl phosphine oxide; two one (2; 6 one dimethylbenzoyls)-2; 4,4 one tri-methyl-amyl oxygen unicorns; benzophenone; the 4-chlorobenzophenone; 4-methyldiphenyl ketone; 4-dimethylamino-ethyl benzoate; the different monooctyl ester of 4-dimethylaminobenzoic acid; diethylamine modification Viscoat 295 or their any mixture.
5. coating according to claim 1 is characterized in that: described pigment is mineral dye, pigment dyestuff, bronze, silver powder, pearlescence, fluorescent material, illusion-colour pigment, reflective pigment or their any mixture.
6. coating according to claim 1 is characterized in that: described filler is talcum powder or flatting silica.
7. coating according to claim 1 is characterized in that: described auxiliary agent comprises flow agent, defoamer and/or wetting dispersing agent.
8. coating according to claim 7 is characterized in that: described flow agent is BYK 306 or BYK358; Described defoamer is BYK 055 or DEUCHEM 2700; Described wetting dispersing agent is Disperbyk163.
9. the preparation method according to each described coating of claim 1～8 is characterized in that, steps of the method are:
(1) light trigger that will account for the fluorine-containing modified prepolymers of total system 20～80wt%, the reactive acrylate monomer of 10～60wt%, reactive fluorinated acrylate monomer or their mixture and 2～10wt% mixes, be warming up to 50～60 ℃, stir;
(2) in the system of step (1), add the auxiliary agent that accounts for total system 0～3wt%, stir fully until dissolving fully;
(3) will account for the filler of total system 0～30wt% and the pigment of 0～40wt% and join in the system of step (2), stir, disperse, grind, filter, obtain optical solidifying fluorine-carbon paint.
10. purposes according to the described coating of claim 1～8, it is characterized in that: described application of paints is in the application on metal coiled material, aluminium section bar, aluminium-plastic panel, plastic-steel section bar surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101716090A CN100562547C (en) | 2006-12-31 | 2006-12-31 | Optical solidifying fluorine-carbon paint and its production and use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101716090A CN100562547C (en) | 2006-12-31 | 2006-12-31 | Optical solidifying fluorine-carbon paint and its production and use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101210145A true CN101210145A (en) | 2008-07-02 |
| CN100562547C CN100562547C (en) | 2009-11-25 |
Family
ID=39610403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101716090A Expired - Fee Related CN100562547C (en) | 2006-12-31 | 2006-12-31 | Optical solidifying fluorine-carbon paint and its production and use |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100562547C (en) |
Cited By (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634267A (en) * | 2012-04-12 | 2012-08-15 | 番禺南沙殷田化工有限公司 | Antifouling and anti-fingerprint coating composite capable of being applied to touch screen panel and preparation method of antifouling and anti-fingerprint coating |
| CN102780244A (en) * | 2012-07-11 | 2012-11-14 | 山东洁阳新能源有限公司 | Domestic photovoltaic power generation system |
| CN102786841A (en) * | 2012-08-24 | 2012-11-21 | 苏州金海薄膜科技发展有限公司 | Scratch-resistant and stain-repellent ink and preparation method thereof |
| CN103087626A (en) * | 2013-01-31 | 2013-05-08 | 安徽蓝柯复合材料有限公司 | UV (Ultraviolet) varnish and preparation method thereof |
| CN103102446A (en) * | 2013-03-01 | 2013-05-15 | 湖北乾兴化工有限公司 | Hydroxylated acrylic resin for automobile refinishing varnish and preparation method of hydroxylated acrylic resin |
| CN103224722A (en) * | 2013-04-26 | 2013-07-31 | 珠海东诚光固化材料有限公司 | UV-curable fluorocarbon solar cell back-side protective film paint |
| CN103465538A (en) * | 2013-07-27 | 2013-12-25 | 乐凯胶片股份有限公司 | Window film adhered onto outer side of window glass |
| CN103525289A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Insulating UV (ultraviolet) varnish and preparation method thereof |
| CN103525286A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | UV gloss paint for priming on metal surface and preparation method thereof |
| CN103525291A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Conductivity type UV (ultraviolet) curing paint and preparation method thereof |
| CN103540181A (en) * | 2013-09-30 | 2014-01-29 | 浙江佑谦特种材料有限公司 | Ocean antifouling paint for surface of ship and spraying method thereof |
| CN103820776A (en) * | 2014-03-20 | 2014-05-28 | 湖州巨力铝型材有限公司 | Method for modifying aluminium profile for buildings |
| CN103834277A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | Wear-resistant anti-cracking ultraviolet curing multipurpose coating and preparation method thereof |
| CN103923459A (en) * | 2014-03-20 | 2014-07-16 | 湖州巨力铝型材有限公司 | Preparation method of powder spray-coating thermal insulation aluminum profile with carved patterns on the surface |
| CN103937391A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Antibacterial self-dry paint and preparation method thereof |
| CN103937376A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Paint with anti-corrosion property and its preparation method |
| CN104194613A (en) * | 2014-08-13 | 2014-12-10 | 江苏宏泰高分子材料有限公司 | Recoatable UV-curing colored one-step-coating aluminum powder paint and preparation method thereof |
| CN104559381A (en) * | 2014-12-26 | 2015-04-29 | 常熟市福王制冷器材有限公司 | Compressor |
| CN104790809A (en) * | 2015-03-13 | 2015-07-22 | 四川省川源塑胶有限公司 | Aluminum plastic composite profile/PVC profile and machining method thereof |
| CN104804637A (en) * | 2015-05-20 | 2015-07-29 | 湖南松井新材料有限公司 | Super stain resistance ultraviolet curing coating |
| CN104910797A (en) * | 2015-06-09 | 2015-09-16 | 成都纳硕科技有限公司 | Flame-retardant fluorescent ultraviolet-curable water-based coating |
| CN105400254A (en) * | 2015-11-27 | 2016-03-16 | 宁波双人新材料有限公司 | Weather-proof polyester powder coating and preparation method thereof |
| CN105482681A (en) * | 2016-01-19 | 2016-04-13 | 卓达新材料科技集团有限公司 | UV (ultraviolet) building coating and preparation method thereof |
| CN105482655A (en) * | 2016-01-19 | 2016-04-13 | 卓达新材料科技集团有限公司 | UV (ultraviolet) building coating with high adhesive force and preparation method of coating |
| CN105566962A (en) * | 2015-12-20 | 2016-05-11 | 中国海洋石油总公司 | Photo-curable paint with low refractive index |
| CN106479325A (en) * | 2016-11-02 | 2017-03-08 | 北京石油化工学院 | A kind of photocuring metallic paint and preparation method and application |
| CN106497191A (en) * | 2016-11-17 | 2017-03-15 | 上海衡峰氟碳材料有限公司 | A kind of ultraviolet light polymerization fluorocarbon coating and preparation method thereof |
| CN106634537A (en) * | 2015-10-30 | 2017-05-10 | 上海亚彤新材料科技有限公司 | Coating for metal coiled material |
| CN106634459A (en) * | 2016-11-22 | 2017-05-10 | 天长市金陵电子有限责任公司 | UV-curing electrostatic spraying paint |
| CN106622920A (en) * | 2015-10-30 | 2017-05-10 | 上海亚彤新材料科技有限公司 | Coating process for metal coiled material |
| CN107476755A (en) * | 2016-06-07 | 2017-12-15 | 河北政硕建材有限公司 | A kind of fluorine carbon Buddha's warrior attendant net and its production technology |
| CN107936821A (en) * | 2018-01-06 | 2018-04-20 | 珠海东诚光固化新材料股份有限公司 | A kind of optical solidifying fluorine-carbon paint for being used for outdoor steel wire |
| CN107962885A (en) * | 2017-11-02 | 2018-04-27 | 苏州太平洋印务有限公司 | A kind of double-colored nested typography of glass panel |
| CN107974193A (en) * | 2018-01-06 | 2018-05-01 | 珠海东诚光固化新材料股份有限公司 | A kind of ultraviolet light for glass color mirror cures pigmented finiss and its application |
| CN108129981A (en) * | 2018-01-06 | 2018-06-08 | 珠海东诚光固化新材料股份有限公司 | For the ultraviolet-curing paint of the protection of glass mirror containing the coat of metal |
| CN108598975A (en) * | 2018-04-21 | 2018-09-28 | 陈安相 | A kind of corrosion resistant novel heat-insulation substation casing of high-efficiency ageing-resistant |
| CN109161315A (en) * | 2018-08-07 | 2019-01-08 | 太仓佩琦涂料有限公司 | UV curing pearl coating and preparation method thereof |
| CN109679523A (en) * | 2018-12-07 | 2019-04-26 | 江西昊泽光学膜科技有限公司 | A kind of hydrophilic protective films and preparation method thereof |
| CN109929130A (en) * | 2019-03-11 | 2019-06-25 | 江苏斯迪克新材料科技股份有限公司 | High water droplet contact angle, cured film easily then and preparation method thereof |
| CN110330866A (en) * | 2019-07-02 | 2019-10-15 | 中安瑞材(北京)科技有限公司 | Photocuring self-spraying paint liquid material and preparation method thereof, photocuring self-spraying paint |
| CN111944391A (en) * | 2020-08-18 | 2020-11-17 | 上海协承昌化工有限公司 | UV coating and edge sealing process thereof |
| CN111940269A (en) * | 2020-08-25 | 2020-11-17 | 苏州欧普照明有限公司 | Paint film preparation method, paint film, lamp accessory and lamp |
| CN112552814A (en) * | 2020-12-11 | 2021-03-26 | 南雄市沃太化工有限公司 | Photocuring matte super-wear-resistant coating and preparation method and application thereof |
| CN112745705A (en) * | 2020-12-14 | 2021-05-04 | 安徽庆润新材料技术有限公司 | Fluoropolymer nanoparticle modified photocuring fluorocarbon coating and preparation method thereof |
| CN115991958A (en) * | 2022-10-26 | 2023-04-21 | 浙江中聚材料有限公司 | Novel fluorine-containing weather-resistant coating and preparation and use methods thereof |
| CN116554763A (en) * | 2023-04-12 | 2023-08-08 | 滁州金桥德克新材料有限公司 | Composite for protecting metal substrate and application method thereof |
-
2006
- 2006-12-31 CN CNB2006101716090A patent/CN100562547C/en not_active Expired - Fee Related
Cited By (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634267A (en) * | 2012-04-12 | 2012-08-15 | 番禺南沙殷田化工有限公司 | Antifouling and anti-fingerprint coating composite capable of being applied to touch screen panel and preparation method of antifouling and anti-fingerprint coating |
| CN102780244A (en) * | 2012-07-11 | 2012-11-14 | 山东洁阳新能源有限公司 | Domestic photovoltaic power generation system |
| CN102786841A (en) * | 2012-08-24 | 2012-11-21 | 苏州金海薄膜科技发展有限公司 | Scratch-resistant and stain-repellent ink and preparation method thereof |
| CN103087626A (en) * | 2013-01-31 | 2013-05-08 | 安徽蓝柯复合材料有限公司 | UV (Ultraviolet) varnish and preparation method thereof |
| CN103087626B (en) * | 2013-01-31 | 2016-05-04 | 和县创智科技信息服务有限公司 | A kind of UV varnish and preparation method thereof |
| CN103102446B (en) * | 2013-03-01 | 2017-10-20 | 湖北乾兴化工有限公司 | A kind of car refinishing paint Hydroxylated acrylic resin and preparation method thereof |
| CN103102446A (en) * | 2013-03-01 | 2013-05-15 | 湖北乾兴化工有限公司 | Hydroxylated acrylic resin for automobile refinishing varnish and preparation method of hydroxylated acrylic resin |
| CN103224722A (en) * | 2013-04-26 | 2013-07-31 | 珠海东诚光固化材料有限公司 | UV-curable fluorocarbon solar cell back-side protective film paint |
| CN103224722B (en) * | 2013-04-26 | 2016-09-21 | 珠海东诚光固化材料有限公司 | Ultraviolet light polymerization fluorine carbon solar cell backside protecting film coating |
| CN103465538A (en) * | 2013-07-27 | 2013-12-25 | 乐凯胶片股份有限公司 | Window film adhered onto outer side of window glass |
| CN103465538B (en) * | 2013-07-27 | 2016-05-11 | 乐凯胶片股份有限公司 | A kind of fenestrated membrane that adheres to glass pane outside |
| CN103525286A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | UV gloss paint for priming on metal surface and preparation method thereof |
| CN103540181A (en) * | 2013-09-30 | 2014-01-29 | 浙江佑谦特种材料有限公司 | Ocean antifouling paint for surface of ship and spraying method thereof |
| CN103525291A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Conductivity type UV (ultraviolet) curing paint and preparation method thereof |
| CN103540181B (en) * | 2013-09-30 | 2015-11-04 | 浙江佑谦特种材料有限公司 | A kind of marine antifouling coating for marine surface and spraying method |
| CN103525289A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Insulating UV (ultraviolet) varnish and preparation method thereof |
| CN103834277A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | Wear-resistant anti-cracking ultraviolet curing multipurpose coating and preparation method thereof |
| CN103923459A (en) * | 2014-03-20 | 2014-07-16 | 湖州巨力铝型材有限公司 | Preparation method of powder spray-coating thermal insulation aluminum profile with carved patterns on the surface |
| CN103820776A (en) * | 2014-03-20 | 2014-05-28 | 湖州巨力铝型材有限公司 | Method for modifying aluminium profile for buildings |
| CN103937376A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Paint with anti-corrosion property and its preparation method |
| CN103937391A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Antibacterial self-dry paint and preparation method thereof |
| CN104194613A (en) * | 2014-08-13 | 2014-12-10 | 江苏宏泰高分子材料有限公司 | Recoatable UV-curing colored one-step-coating aluminum powder paint and preparation method thereof |
| CN104559381A (en) * | 2014-12-26 | 2015-04-29 | 常熟市福王制冷器材有限公司 | Compressor |
| CN104790809A (en) * | 2015-03-13 | 2015-07-22 | 四川省川源塑胶有限公司 | Aluminum plastic composite profile/PVC profile and machining method thereof |
| CN104804637A (en) * | 2015-05-20 | 2015-07-29 | 湖南松井新材料有限公司 | Super stain resistance ultraviolet curing coating |
| CN104910797A (en) * | 2015-06-09 | 2015-09-16 | 成都纳硕科技有限公司 | Flame-retardant fluorescent ultraviolet-curable water-based coating |
| CN106634537A (en) * | 2015-10-30 | 2017-05-10 | 上海亚彤新材料科技有限公司 | Coating for metal coiled material |
| CN106622920A (en) * | 2015-10-30 | 2017-05-10 | 上海亚彤新材料科技有限公司 | Coating process for metal coiled material |
| CN105400254A (en) * | 2015-11-27 | 2016-03-16 | 宁波双人新材料有限公司 | Weather-proof polyester powder coating and preparation method thereof |
| CN105400254B (en) * | 2015-11-27 | 2017-08-18 | 宁波双人新材料有限公司 | A kind of weatherable polyether powder coating and preparation method thereof |
| CN105566962A (en) * | 2015-12-20 | 2016-05-11 | 中国海洋石油总公司 | Photo-curable paint with low refractive index |
| CN105482655A (en) * | 2016-01-19 | 2016-04-13 | 卓达新材料科技集团有限公司 | UV (ultraviolet) building coating with high adhesive force and preparation method of coating |
| CN105482681A (en) * | 2016-01-19 | 2016-04-13 | 卓达新材料科技集团有限公司 | UV (ultraviolet) building coating and preparation method thereof |
| CN107476755A (en) * | 2016-06-07 | 2017-12-15 | 河北政硕建材有限公司 | A kind of fluorine carbon Buddha's warrior attendant net and its production technology |
| CN106479325A (en) * | 2016-11-02 | 2017-03-08 | 北京石油化工学院 | A kind of photocuring metallic paint and preparation method and application |
| CN106497191A (en) * | 2016-11-17 | 2017-03-15 | 上海衡峰氟碳材料有限公司 | A kind of ultraviolet light polymerization fluorocarbon coating and preparation method thereof |
| CN106634459A (en) * | 2016-11-22 | 2017-05-10 | 天长市金陵电子有限责任公司 | UV-curing electrostatic spraying paint |
| CN107962885A (en) * | 2017-11-02 | 2018-04-27 | 苏州太平洋印务有限公司 | A kind of double-colored nested typography of glass panel |
| CN107936821A (en) * | 2018-01-06 | 2018-04-20 | 珠海东诚光固化新材料股份有限公司 | A kind of optical solidifying fluorine-carbon paint for being used for outdoor steel wire |
| CN107974193A (en) * | 2018-01-06 | 2018-05-01 | 珠海东诚光固化新材料股份有限公司 | A kind of ultraviolet light for glass color mirror cures pigmented finiss and its application |
| CN108129981A (en) * | 2018-01-06 | 2018-06-08 | 珠海东诚光固化新材料股份有限公司 | For the ultraviolet-curing paint of the protection of glass mirror containing the coat of metal |
| CN108598975A (en) * | 2018-04-21 | 2018-09-28 | 陈安相 | A kind of corrosion resistant novel heat-insulation substation casing of high-efficiency ageing-resistant |
| CN109161315A (en) * | 2018-08-07 | 2019-01-08 | 太仓佩琦涂料有限公司 | UV curing pearl coating and preparation method thereof |
| CN109679523A (en) * | 2018-12-07 | 2019-04-26 | 江西昊泽光学膜科技有限公司 | A kind of hydrophilic protective films and preparation method thereof |
| CN109929130A (en) * | 2019-03-11 | 2019-06-25 | 江苏斯迪克新材料科技股份有限公司 | High water droplet contact angle, cured film easily then and preparation method thereof |
| CN109929130B (en) * | 2019-03-11 | 2021-10-22 | 江苏斯迪克新材料科技股份有限公司 | High-water-drop contact angle easy-to-adhere hardened film and preparation method thereof |
| CN110330866A (en) * | 2019-07-02 | 2019-10-15 | 中安瑞材(北京)科技有限公司 | Photocuring self-spraying paint liquid material and preparation method thereof, photocuring self-spraying paint |
| CN111944391A (en) * | 2020-08-18 | 2020-11-17 | 上海协承昌化工有限公司 | UV coating and edge sealing process thereof |
| CN111940269A (en) * | 2020-08-25 | 2020-11-17 | 苏州欧普照明有限公司 | Paint film preparation method, paint film, lamp accessory and lamp |
| CN112552814A (en) * | 2020-12-11 | 2021-03-26 | 南雄市沃太化工有限公司 | Photocuring matte super-wear-resistant coating and preparation method and application thereof |
| CN112745705A (en) * | 2020-12-14 | 2021-05-04 | 安徽庆润新材料技术有限公司 | Fluoropolymer nanoparticle modified photocuring fluorocarbon coating and preparation method thereof |
| CN115991958A (en) * | 2022-10-26 | 2023-04-21 | 浙江中聚材料有限公司 | Novel fluorine-containing weather-resistant coating and preparation and use methods thereof |
| CN115991958B (en) * | 2022-10-26 | 2024-03-08 | 浙江中聚材料有限公司 | Novel fluorine-containing weather-resistant coating and preparation and use methods thereof |
| CN116554763A (en) * | 2023-04-12 | 2023-08-08 | 滁州金桥德克新材料有限公司 | Composite for protecting metal substrate and application method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100562547C (en) | 2009-11-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100562547C (en) | Optical solidifying fluorine-carbon paint and its production and use | |
| CN102153899B (en) | Ultraviolet-curable water-based colored paint composition | |
| CN101941339B (en) | Ultraviolet light cured transfer printing film and preparation method and application thereof | |
| CN101235672B (en) | Ultraviolet light curing overlay film decorative board for wall and method for making same | |
| CN103059713A (en) | Ultraviolet light-cured self-cleaning coating, and preparation method and application thereof | |
| CN101982513B (en) | Finish paint composite and preparation method and use method thereof | |
| CN201208874Y (en) | Printing decorated sheet by ultraviolet light curing | |
| CN105885494A (en) | Radiation curing silicon fluoride coating and preparation method and application thereof | |
| CN1487033A (en) | Ultraviolet ray cured paint for surface treatment or alumium ou aluminium sections | |
| CN104559741B (en) | UV (ultraviolet) finishing varnish for laser roller coating | |
| CN104194613A (en) | Recoatable UV-curing colored one-step-coating aluminum powder paint and preparation method thereof | |
| CN101158210A (en) | Ultraviolet curing chromatic wall decoration board and preparation method thereof | |
| CN102220084A (en) | Photocureable coating and curing method thereof | |
| CN105331154A (en) | High-weather-resistant UV (ultraviolet) coating for decorative plate and preparation method of high-weather-resistant UV coating | |
| CN201068629Y (en) | Ultraviolet light curing colorful decorative board for wall | |
| CN104845451A (en) | LED photocured inkjet ink suitable for high-speed ink jetting | |
| CN105860778B (en) | Aqueous radiation curable coating decorative panel and preparation method thereof | |
| CN101633813A (en) | Composite ultraviolet curing waterborne wood coating and production method thereof | |
| CN103131224A (en) | Ultraviolet curable electrosilvering coating substituting for electroplating or vacuum plating and application thereof | |
| CN103897579A (en) | Improved waterborne polyurethane UV light-cured woodware coating | |
| CN105713507A (en) | Single-color paint coating and preparation method thereof | |
| CN106995655A (en) | No-solvent type UV cure coating compositions and coating | |
| TWI393753B (en) | Uv curable color coating composition | |
| CN103627301A (en) | UV (ultraviolet) curing finishing coating for photos | |
| CN105199474A (en) | Metal sheet UV (ultraviolet curing) printing ink and use method of metal sheet UV printing ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: ZHUHAI DONGCHENG UV MATERIALS CO., LTD. Free format text: FORMER NAME: ZHUHAI DONGCHENG CHEMICAL CO., LTD. |
|
| CP03 | Change of name, title or address |
Address after: 519050 Zhuhai City, Sichuan Province, South Water Chemical Industry Zone Patentee after: Zhuhai Dongcheng UV Materials Co., Ltd. Address before: 519050 Zhuhai City, Sichuan Province, chemical industry zone Patentee before: Zhuhai Dongcheng Chemical Co., Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 519050 Zhuhai City, Sichuan Province, South Water Chemical Industry Zone Patentee after: Zhuhai Dongcheng light curing new materials Limited by Share Ltd Address before: 519050 Zhuhai City, Sichuan Province, South Water Chemical Industry Zone Patentee before: Zhuhai Dongcheng UV Materials Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20091125 Termination date: 20191231 |