CN103525286A - UV gloss paint for priming on metal surface and preparation method thereof - Google Patents
UV gloss paint for priming on metal surface and preparation method thereof Download PDFInfo
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- CN103525286A CN103525286A CN201310457024.5A CN201310457024A CN103525286A CN 103525286 A CN103525286 A CN 103525286A CN 201310457024 A CN201310457024 A CN 201310457024A CN 103525286 A CN103525286 A CN 103525286A
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Abstract
A UV (ultraviolet) gloss paint for priming on a metal surface is prepared from the following raw materials in parts by weight: 30 to 35 parts of urethane acrylate, 14 to 18 parts of polyester acrylate, 30 to 35 parts of polyether acrylate, 20 to 24 parts of trimethylolpropane triacrylate, 1 to 2 parts of phosphate ester, 1 to 2 parts of lemon oil, 1 to 2 parts of mandarin oil, 5 to 8 parts of benzil dimethyl ketal, 1 to 2 parts of allyl glycidyl ether, 2 to 3 parts of vinyltriethoxysilane and 4 to 5 parts of dispersing auxiliary. The gloss paint disclosed by the invention has excellent chemical resistance and heat resistance; a coating of the gloss paint has excellent cohesiveness on the metal surface, is difficult to fall off and is uniform; the UV gloss paint is sprayed on the metal surface, a metal substrate product does not need to be subjected to electroforming or polishing and can achieve the same attachment effect with a product subjected to electroforming or polishing; therefore, not only is the process saved, but also cost is reduced.
Description
Technical field
The invention belongs to paint field, relate in particular to and a kind ofly for metallic surface, beat bottom UV gloss oil and preparation method thereof.
Background technology
Development along with market economy, there is great variety in paint field, wherein UV coating has the advantages such as curing speed is fast, energy-conservation, ambient cure, superior performance, environmental protection, on it, ray velocity is fast, rete luminance brightness is high, and dry rear face is firm heat-resisting, and refractive power is effective, make ground produce strong main body sense, be widely used in the fields such as chemical industry, machinery, electronics light industry, communication.Due to its environment-friendly advantage, UV solidifies and to have obtained the strong support of relevant environment rules and the close attention of industry member, and UV radiation curing material is in market requirement rapid growth, and UV Radiation-curing system is just with multiple technologies combination, to overcome some defect, meet actual application.Now in printing industry; the packing that can make UV obtains some special effects: high glossiness, good ink protection feature, the slipping that can add control and rub resistance, low smell or do not have smell, low extract maybe cannot detect extract, and the provide protection to ink.
Current UV solidify material is various, but still in various degree exist some problems, such as: Organic pollutants, xanthochromia, explosive look, not low temperature resistant, the series of problems such as cost is high, corrosion-resistant, all need to continue improvement for different purposes, reduce production costs, expand purposes.
Summary of the invention
What the object of the present invention is to provide a kind of strong adhesion beats bottom UV gloss oil and preparation method thereof for metallic surface.
Technical scheme of the present invention is as follows:
A bottom UV gloss oil is beaten in metallic surface, it is characterized in that being made by the raw material of following weight part: urethane acrylate 30-35, polyester acrylate 14-18, polyether acrylate 30-35, Viscoat 295 20-24, phosphoric acid ester 1-2, lemon oil 1-2, mandarin oil 1-2, benzoin dimethylether 5-8, propenyl glycidyl ether 1-2, vinyltriethoxysilane 2-3, dispersing auxiliary 4-5;
Described dispersing auxiliary is made by the raw material of following weight part: bamboo charcoal powder 4-5, jade powder 2-3, Flos Rosae Rugosae quintessence oil 1-2, xitix 1-2, pentaerythritol triacrylate 4-5, alcohol ester 12 3-4, Silane coupling agent KH550 1-2, ethyl acetate 14-18; Preparation method puts into 10-15% hydrochloric acid soln by bamboo charcoal powder, jade powder to steep 3-4 hour, takes out, with deionized water wash repeatedly, dry, be added in ethyl acetate, grind to obtain 20-40 μ m slurry, in slurry, add other remaining component, be heated to 50-55 ℃, stir 40-50 minute; Continue to be warming up to 70-75 ℃, stirring reaction 1-2 hour, obtains.
The described preparation method who beats bottom UV gloss oil for metallic surface, it is characterized in that comprising the following steps: other composition except benzoin dimethylether is mixed, be warming up to 60-70 ℃, under 600-700 rev/min, stir 15-20 minute, cool to 40 ℃ and add again below benzoin dimethylether, continue to stir 10-15 minute, obtain.
Beneficial effect of the present invention
Gloss oil of the present invention has good chemical resistance, resistance toheat, films metallic surface is had to good adhesive property, and difficult drop-off, films evenly; This UV gloss oil is sprayed on metallic surface, and metal bottom product does not need through electroforming or polishing, and can reach with through electroforming or the same adhesion effect of polishing, has not only saved operation, and has reduced cost.
Embodiment
A bottom UV gloss oil is beaten in metallic surface, by following weight part (kilogram) raw material make: urethane acrylate 33, polyester acrylate 15, polyether acrylate 33, Viscoat 295 22, phosphoric acid ester 1, lemon oil 1, mandarin oil 1, benzoin dimethylether 6, propenyl glycidyl ether 1, vinyltriethoxysilane 2, dispersing auxiliary 4.5;
Described dispersing auxiliary by following weight part (kilogram) raw material make: bamboo charcoal powder 4, jade powder 2, Flos Rosae Rugosae quintessence oil 2, xitix 1.5, pentaerythritol triacrylate 4.6, alcohol ester 12, Silane coupling agent KH550 1.4, ethyl acetate 16; Preparation method puts into 14% hydrochloric acid soln by bamboo charcoal powder, jade powder to steep 3 hours, takes out, and uses deionized water wash 5 times, dry, be added in ethyl acetate, grind to obtain 25 μ m slurries, in slurry, add other remaining component, be heated to 53 ℃, stir 44 minutes; Continue to be warming up to 72 ℃, stirring reaction 2 hours, obtains.
The described preparation method who beats bottom UV gloss oil for metallic surface, comprises the following steps: other composition except benzoin dimethylether is mixed, be warming up to 65 ℃, under 600 revs/min, stir 19 minutes, cool to 25 ℃ and add again benzoin dimethylether, continue to stir 13 minutes, obtain.
This metallic surface is beaten bottom UV gloss oil and can be adopted the form of construction work of roller coating, showering, spraying to construct.The gloss oil painting making by above scheme is contained in sticking power on plank and is all better than secondary, resistance to 75% ethanol is more than 24 hours, alkaline-resisting 24 hours above, acidproof more than 48 hours, the cold cycling that tolerates subzero 40 degree and 40 degree does not ftracture for 10 times, resistance to 15% salt solution is more than 60 hours, hardness can regulate between 3H at 2HB, and abrasion resistance index turns above 4000.
Claims (2)
1. for metallic surface, beat a bottom UV gloss oil, it is characterized in that being made by the raw material of following weight part: urethane acrylate 30-35, polyester acrylate 14-18, polyether acrylate 30-35, Viscoat 295 20-24, phosphoric acid ester 1-2, lemon oil 1-2, mandarin oil 1-2, benzoin dimethylether 5-8, propenyl glycidyl ether 1-2, vinyltriethoxysilane 2-3, dispersing auxiliary 4-5;
Described dispersing auxiliary is made by the raw material of following weight part: bamboo charcoal powder 4-5, jade powder 2-3, Flos Rosae Rugosae quintessence oil 1-2, xitix 1-2, pentaerythritol triacrylate 4-5, alcohol ester 12 3-4, Silane coupling agent KH550 1-2, ethyl acetate 14-18; Preparation method puts into 10-15% hydrochloric acid soln by bamboo charcoal powder, jade powder to steep 3-4 hour, takes out, with deionized water wash repeatedly, dry, be added in ethyl acetate, grind to obtain 20-40 μ m slurry, in slurry, add other remaining component, be heated to 50-55 ℃, stir 40-50 minute; Continue to be warming up to 70-75 ℃, stirring reaction 1-2 hour, obtains.
2. the preparation method who beats bottom UV gloss oil for metallic surface according to claim 1, it is characterized in that comprising the following steps: other composition except benzoin dimethylether is mixed, be warming up to 60-70 ℃, under 600-700 rev/min, stir 15-20 minute, cool to 40 ℃ and add again below benzoin dimethylether, continue to stir 10-15 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310457024.5A CN103525286A (en) | 2013-09-30 | 2013-09-30 | UV gloss paint for priming on metal surface and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310457024.5A CN103525286A (en) | 2013-09-30 | 2013-09-30 | UV gloss paint for priming on metal surface and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN103525286A true CN103525286A (en) | 2014-01-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310457024.5A Pending CN103525286A (en) | 2013-09-30 | 2013-09-30 | UV gloss paint for priming on metal surface and preparation method thereof |
Country Status (1)
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| CN (1) | CN103525286A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103788844A (en) * | 2014-02-13 | 2014-05-14 | 芜湖市宝艺游乐科技设备有限公司 | High-hardness wear-resistant UV (Ultraviolet)-curable coating material and preparation method thereof |
| CN107400457A (en) * | 2017-08-31 | 2017-11-28 | 安徽骏飞标识设计制作有限公司 | One kind beats bottom UV gloss oil and preparation method thereof for metal surface |
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| CN1470571A (en) * | 2003-04-09 | 2004-01-28 | 湖南文理学院 | Method for preparing ultraviolet photocurable coating |
| CN1528831A (en) * | 2003-09-28 | 2004-09-15 | 四川汇源光通信股份有限公司 | Transparent ultrauiolet cured coating and preparing method thereof |
| CN1718642A (en) * | 2005-07-15 | 2006-01-11 | 黄德欢 | Method of in situ nano-modifying UV ray solidifying paint |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103788844A (en) * | 2014-02-13 | 2014-05-14 | 芜湖市宝艺游乐科技设备有限公司 | High-hardness wear-resistant UV (Ultraviolet)-curable coating material and preparation method thereof |
| CN107400457A (en) * | 2017-08-31 | 2017-11-28 | 安徽骏飞标识设计制作有限公司 | One kind beats bottom UV gloss oil and preparation method thereof for metal surface |
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Application publication date: 20140122 |
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