CN101851466A - Antistatic abrasion-resistant UV coating and preparation method thereof - Google Patents
Antistatic abrasion-resistant UV coating and preparation method thereof Download PDFInfo
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Abstract
The invention specifically relates to an antistatic abrasion-resistant UV coating and a preparation method thereof, and belongs to the field of materials. The antistatic abrasion-resistant UV coating comprises the following components in percentage by mass: 5 to 35 percent of multifunctional polyurethane acrylate, 15 to 45 percent of epoxy acrylate, 10 to 40 percent of reactive diluent, 2 to 12 percent of photoinitiator, 0.5 to 3 percent of other additives, 5 to 25 percent of conductive nano-attapulgite powder, and 0.05 to 0.5 percent of silane coupling agent. The coating of the invention has an appearance of white liquid or light yellow liquid; the surface resistance of a coat prepared by the coating of the invention is 4.8*10<6> to 6.5*10 <8> ohms; the 100-revolution weight loss in the Taber abrasion resistance test is 0.0045 to 0.0075 gram; and the surface hardness is more than or equal to 3 H; and the coating does not change after dipping in 5 percent sodium hydroxide for 24 hours. The antistatic abrasion-resistant UV coating of the invention has the advantages of simple preparation, low cost, convenient use, good effect and wide application prospect.
Description
Technical field
The invention belongs to the material field, be specifically related to a kind of antistatic abrasion-resistant UV coating and preparation method thereof.
Background technology
Antistatic coating is one group of volume specific resistance special functional coating within the specific limits.Its research record the earliest is the conductive resin patent of announcing in the U.S..Japan works out silver system for a long time and charcoal is main antistatic coating, and is applied to electronic industry and military field.China's research is in this respect started late, but development is very fast, and especially since the nineties national compulsory required Oil Tank to adopt antistatic coating, this class coating application aspect Oil Tank developed rapidly.
Simultaneously, along with the widespread use of development of high-tech and macromolecular material,, also very outstanding as factory building, the computer house electrostatic problem of electronic apparatus in some electron trades, static causes the electronic devices and components infringement even lost efficacy, and has hindered production process and quality product.And the Operation theatre of printing house, textile mills, pharmaceutical factory and hospital all requires clean dustless, no static.In the past, the method for pasting anti-electrostatic sheet material was adopted in the place in needs employing conductive flooring mostly; The general employing based on wood substrate in this floor sticked the mode of antistatic pad pasting then or adopted several big classes such as all-metal material (steel, aluminium alloy), PVC plastics class, all has drawbacks such as decorative effect difference or price be high.
Whether antistatic coating has electroconductibility by its filmogen is divided into two classes: be film forming matter and needn't add the eigenmode antistatic coating of electro-conductive material in addition by the polymkeric substance with electroconductibility 1), there are a lot of difficulties in synthetic, the construction of this type of coating, and cost is also than higher; What 2) application was maximum is addition type, and it is the mixture of conductive filler material, insulativity film forming matter, auxiliary agent and solvent, utilizes the electric action of conductive filler material to produce anti-static effect, and wherein the difference according to conductive filler material is divided into following a few class again:
The static conducting agent of organic class;
Charcoal through-stone China ink, carbon black, charcoal fiber;
Metal species silver, nickel, copper;
The metal oxide coating.
Above-mentioned antistatic coating kind respectively has relative merits.The metallic stuffing class is owing to it costs an arm and a leg, uses than great, easy oxidation and be restricted.At present, very active aspect the research of composition metal filler material, as materials such as silver bag granulated glass spherees, reduced cost, saved resource, however, it is mainly used in military aspect at present.Though charcoal series filler low price has dark, the difficult dispersion of color, the unsettled shortcoming of electrical property.The present invention adopts nanometer conductive material---the conduction attapulgite is as conductive filler material, and attapulgite has another name called polygorskite or Palygorskite, be a kind of layer of chain-like structure contain Shuifu County's zeopan clay mineral.It has the attribute of nano material, is the natural nano structure mineral material with nanochannel structure, and its surperficial adsorbable conducting material becomes conduction " attapulgite ".Utilize this material, obtain UV coating, relatively approach the eigenmode antistatic coating by the inorganic-organic hybridization technology.
Summary of the invention
It is simple to the purpose of this invention is to provide a kind of preparation, and cost is low, and is easy to use, effective antistatic abrasion-resistant UV coating, and this preparation methods.
The mass percent of antistatic abrasion-resistant UV coating of the present invention consists of:
Multifunctional urethane acrylate 5%-35%; Be preferably 35%;
Epoxy acrylate 15%-45%; Be preferably 20%;
Reactive thinner 10%-40%; Be preferably 35%;
Light trigger 2%-12%; Be preferably 4.9%;
Other auxiliary agent 0.5%-3%; Be preferably 0.05%;
Conductive nano attapulgite 5%-25%; Be preferably 5%;
Silane coupling agent 0.05-0.5% is preferably 0.05%.
The preparation method of above-mentioned antistatic abrasion-resistant UV coating: silane coupling agent, reactive thinner are added in the clean vessel together, (1200 rev/mins at a high speed, 30 minutes) be uniformly dispersed, slowly add the conductive nano attapulgite, (1200 rev/mins) disperse to rise to 50 ℃ up to the mixing liquid temperature at a high speed, slowly add multifunctional urethane acrylate, epoxy acrylate, light trigger, other auxiliary agent stirs.
Described reactive thinner is TMPTA (Viscoat 295), PETA (pentaerythritol triacrylate), TPGDA (tri (propylene glycol) diacrylate), DPHA (dipentaerythritol acrylate), HDDA (hexanediyl ester), NPGDA (neopentylglycol diacrylate), EO-TMPTA (ethoxylated trimethylolpropane triacrylate), IBOMA (isobornyl methacrylate), IBOA (isobornyl acrylate), DPGDA (propylene glycol diacrylate), NPGDA (neopentylglycol diacrylate), among the PO-NPGDA (ethoxylated neopentylglycol diacrylate) one or more.
Described light trigger is 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation, 1-hydroxyl-cyclohexyl-phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, benzophenone, 2-phenyl benzyl-2-dimethyl amine-1-(4-morpholine benzyl phenyl) butanone, benzoin dimethylether, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone, 2-isopropyl thioxanthone, two (2; 4,6-trimethylbenzoyl)-in the phenyl phosphine oxide, dimethyl ethyl aminobenzoate one or more.
Described other auxiliary agent, be meant dispersion agent, comprise Disperbyk110, Disperbyk130, Disperbyk160, Disperbyk164, Disperbyk184, Disperbyk190, Disperbyk192, Anti-Terra-P, Anti-Terra-207, Anti-Terra-202, the Disperbyk2000 of German Bi Ke (BYK) chemical company; Deuchem Co., Ltd. 904,904S, DP-983; The Solsperse3000 of Avecia company, Solsperse17000, Solsperse27000, Solsperse32000; Flow agent comprises Disperbyk323, Disperbyk300, Disperbyk310, Disperbyk3100, the Disperbyk3200 of German Bi Ke (BYK) chemical company; Defoamer comprises Disperbyk050, the Disperbyk051 of EFKA-2022, German Bi Ke (BYK) chemical company of Defom5400, the Defom5400 of Deuchem Co., Ltd. and Dutch EFKA (EFKA) auxiliary agent company, one or more the combination among Disperbyk052, the Disperbyk055.
At present, generally with inorganic conductive material graphite or zinc powder or conduction mica, it uses in UV coating, and coating is difficult to solidify, and the big strength of coating that influenced of dosage, has reduced wear resistance.The present invention adopts the conductive nano attapulgite, adopts silane coupling agent to handle activation, adds other raw material one again and reacts formulatedly, adopts the UV mode to solidify during use.Overcome in the past coating and be difficult to solidify, antistatic effect is poor, the defective that wears no resistance.Coating of the present invention is to choose the abrasion-resistant UV coating that UV mode solidified antistatic property is adopted in brand-new being suitable for that starting material and proportioning combine meticulously by the contriver.In addition, because reaching identical antistatic effect add-on, can reduce coating of the present invention than other conductive agent dosage, so be generally metal or antistatic PVC material with present antistatic floor, decorative effect is poor, and the cost height is compared, and the abrasion-resistant UV coating that adopts antistatic property not only can all kinds of floors of application, home decoration, reduce the electrostatic adsorption of ground, be convenient to sweep, also saved cost in the face of dust.
The abrasion-resistant UV coating performance of antistatic property of the present invention:
Project | Performance |
Outward appearance | Milky white or pale yellow liquid |
TABER wear-resisting (100 change) | 0.0045-0.0075 gram |
Hardness | ??≥3H |
Alkali resistance (5% sodium hydroxide, 24 hours) | No change |
Surface resistivity | ??4.8×10 6-6.5×10 8Ohm |
Embodiment
Further specify the present invention below in conjunction with embodiment, and unrestricted the present invention.
Embodiment 1:
Title material | Add-on |
Multifunctional urethane acrylate | ??35 |
Epoxy acrylate | ??20 |
Reactive thinner | ??35 |
Light trigger | ??4.9 |
The conductive nano attapulgite | ??5 |
Silane coupling agent | ??0.05 |
Other auxiliary agent | ??0.05 |
Lacquer man's skill: silane coupling agent, reactive thinner are added in the clean vessel together, high speed dispersion is even, slowly add the conductive nano attapulgite, high speed dispersion rises to 50 ℃ up to the mixing liquid temperature, slowly adds multifunctional urethane acrylate, epoxy acrylate, light trigger and stirs.
Performance test methods: above-mentioned coating is coated with into the coating of 40 micron thickness with film caster on clean sheet glass, UV solidifies that (the plate face is accepted irradiation energy assurance 〉=400mj/cm
2), after placing 24 hours under 20 ℃ of environment, carry out Performance Detection.
Performance: coatingsurface resistance is 6.5 * 10
8Ohm, weightless 0.0045 gram, surface hardness 〉=3H, 24 hours no changes of 5% soaking with sodium hydroxide are changeed in the wear-resisting test 100 of Taber.
Embodiment 2:
Title material | Add-on |
Multifunctional urethane acrylate | ??25 |
Epoxy acrylate | ??20 |
Reactive thinner | ??35 |
Light trigger | ??2.90 |
The conductive nano attapulgite | ??16 |
Silane coupling agent | ??0.10 |
Other auxiliary agents | ??1 |
Lacquer man's skill: silane coupling agent, reactive thinner are added in the clean vessel together, high speed dispersion is even, slowly add the conductive nano attapulgite, high speed dispersion rises to 50 ℃ up to the mixing liquid temperature, slowly adds multifunctional urethane acrylate, epoxy acrylate, light trigger and stirs.
Performance test methods: above-mentioned coating is coated with into the coating of 40 micron thickness with film caster on clean sheet glass, UV solidifies that (the plate face is accepted irradiation energy assurance 〉=400mj/cm
2), after placing 24 hours under 20 ℃ of environment, carry out Performance Detection.
Performance: coatingsurface resistance is 5 * 10
7Ohm, weightless 0.0075 gram, surface hardness 〉=3H, 24 hours no changes of 5% soaking with sodium hydroxide are changeed in the wear-resisting test 100 of Taber.
Embodiment 3:
Title material | Add-on |
Multifunctional urethane acrylate | ??5 |
Epoxy acrylate | ??45 |
Reactive thinner | ??35 |
Title material | Add-on |
Light trigger | ??4.1 |
The conductive nano attapulgite | ??10 |
Silane coupling agent | ??0.10 |
Other auxiliary agents | ??0.8 |
Lacquer man's skill: silane coupling agent, reactive thinner are added in the clean vessel together, high speed dispersion is even, slowly add the conductive nano attapulgite, high speed dispersion rises to 50 ℃ up to the mixing liquid temperature, slowly adds multifunctional urethane acrylate, epoxy acrylate, light trigger and stirs.
Performance test methods: above-mentioned coating is coated with into the coating of 40 micron thickness with film caster on clean sheet glass, UV solidifies that (the plate face is accepted irradiation energy assurance 〉=400mj/cm
2), after placing 24 hours under 20 ℃ of environment, carry out Performance Detection.
Performance: coatingsurface resistance is 4.8 * 10
6Ohm, weightless 0.0055 gram, surface hardness 〉=3H, 24 hours no changes of 5% soaking with sodium hydroxide are changeed in the wear-resisting test 100 of Taber.
Claims (5)
1. an antistatic abrasion-resistant UV coating is characterized in that, the mass percent of described antistatic abrasion-resistant UV coating consists of:
Multifunctional urethane acrylate 5%-35%;
Epoxy acrylate 15%-45%;
Reactive thinner 10%-40%;
Light trigger 2%-12%;
Other auxiliary agent 0.5%-3%;
Conductive nano attapulgite 5%-25%;
Silane coupling agent 0.05-0.5%.
2. the preparation method of the described antistatic abrasion-resistant UV coating of claim 1, it is characterized in that, silane coupling agent, reactive thinner are added in the clean vessel together, high speed dispersion is even, slowly add the conductive nano attapulgite, high speed dispersion rises to 50 ℃ up to the mixing liquid temperature, slowly adds multifunctional urethane acrylate, epoxy acrylate, light trigger, and other auxiliary agent stirs.
3. the preparation method of the described antistatic abrasion-resistant UV coating of claim 1, it is characterized in that described reactive thinner is a Viscoat 295, pentaerythritol triacrylate, tri (propylene glycol) diacrylate, dipentaerythritol acrylate, hexanediyl ester, neopentylglycol diacrylate, ethoxylated trimethylolpropane triacrylate, isobornyl methacrylate, isobornyl acrylate, propylene glycol diacrylate, neopentylglycol diacrylate, in the ethoxylated neopentylglycol diacrylate one or more.
4. the preparation method of the described antistatic abrasion-resistant UV coating of claim 1; it is characterized in that; described light trigger is 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation; 1-hydroxyl-cyclohexyl-phenyl ketone; 2-hydroxy-2-methyl-1-phenyl-1-acetone; benzophenone; 2-phenyl benzyl-2-dimethyl amine-1-(4-morpholine benzyl phenyl) butanone; benzoin dimethylether; 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone; the 2-isopropyl thioxanthone; two (2; 4, the 6-trimethylbenzoyl)-phenyl phosphine oxide; in the dimethyl ethyl aminobenzoate one or more.
5. the preparation method of the described antistatic abrasion-resistant UV coating of claim 1 is characterized in that, described other auxiliary agent is a dispersion agent, flow agent, one or more in the defoamer.
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