CN100999643A - Crystal whisker wear-resistant ultraviolet ray solidified paint and preparation process thereof - Google Patents
Crystal whisker wear-resistant ultraviolet ray solidified paint and preparation process thereof Download PDFInfo
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- CN100999643A CN100999643A CN 200610156034 CN200610156034A CN100999643A CN 100999643 A CN100999643 A CN 100999643A CN 200610156034 CN200610156034 CN 200610156034 CN 200610156034 A CN200610156034 A CN 200610156034A CN 100999643 A CN100999643 A CN 100999643A
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- crystal whisker
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- ultraviolet ray
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- resistant ultraviolet
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Abstract
The present invention is one kind of ultraviolet cured antiwear crystal whisker paint and its preparation process, and belongs to the field of light cured paint technology. The ultraviolet cured paint has crystal whisker filled to raise the antiwear performance, and consists of mainly photosensitive oligomer, active diluent, photoinitiator, crystal whisker, stuffing and assistant. It may be applied onto the surface of timber, high density board, metal, glass or ceramic to form coating with excellent performance, including high toughness and high antiwear property. In addition, the paint has no organic solvent and is environment friendly and convenient in use.
Description
Technical field
A kind of crystal whisker wear-resistant ultraviolet ray solidified paint and preparation method thereof relates to a kind of wear-resistant paint that can be used for timber, density board, metal, glass, ceramic surface, belongs to the light solidifying coating technical field of composite materials.
Background technology
(UV) is coating material solidified for UV-light, and it is a kind of pollution-free, resource-saving, less energy-consumption, the safe and reliable friendly type coating of high-tech green environment, and its society and environmental benefit are huge; This product meets world's material technology trend, is coating circle new growth point, and the huge fund research and development are just competitively thrown in countries in the world.Now, on the occasion of advocate energetically because of the scarcity of China's energy, resource make up Sustainable development, conservation-minded society when, UV is coating material solidified has applied significance.The coating material solidified output of whole world UV was about 300,000 tons in 2005, and wherein Chinese about 100,000 tons, and annual with the speed increment more than 25%.In China, surpass the coating material solidified application that is used for the floor of UV of 70% sales volume, and also there are many problems in the wear resistance of current UV curing Floor paint.Study a kind of ultraviolet-curing paint that is applied to surface such as timber, density board, pottery, be the target of domestic and international coating circle pursuit with the wear resistance on surfaces such as comprehensive raising timber, density board, pottery always.The present invention mainly selects special wear-resisting crystal whisker materials for use, is equipped with photosensitive oligomer and filler etc. and has prepared the high-performance abrasion-proof ultraviolet-curing paint.
Summary of the invention
The purpose of this invention is to provide a kind of crystal whisker wear-resistant ultraviolet ray solidified paint and preparation method thereof, select that crystal whisker materials and the compound preparation of high performance photosensitive oligomer are a kind of to have better wear resistance, a more high-intensity whisker ultraviolet-curing paint for use.
Technical scheme of the present invention: a kind of crystal whisker wear-resistant ultraviolet ray solidified paint, (%) is as follows for the composition of its each component and weight percent:
Photosensitive oligomer 35～50
Reactive thinner 28～42
Light trigger 3～9
Whisker 5～18
Filler 3～16
Auxiliary agent 1～1.5
Described photosensitive oligomer is one or more in epoxy acrylic oligoesters, urethane acrylate quasi-oligomer, the polyester acrylic oligoesters; Described reactive thinner is in tripropylene glycol diacrylate, Viscoat 295,1,6 hexanediol diacrylate, pentaerythritol triacrylate, neopentylglycol diacrylate, the Isooctyl acrylate monomer two kinds or several; Described light trigger is benzophenones/amines system, benzil two ketals, Benzoin ethyl ether, 1-hydroxyl-phenylcyclohexane ethyl ketone, α, one or more in alpha-alpha-dimethyl-α hydroxy acetophenone, the thioxanthones; Described whisker is a kind of in calcium carbonate crystal whisker, potassium titanate crystal whisker, the ZnOw, and diameter range is 0.5～2 μ m, and length range is 20～40 μ m, carries out the surface modification treatment mistake by silane coupling agent or titanate coupling agent; Described filler is one or more in hollow glass microbead, silicon-dioxide, the elastic particle; Described auxiliary agent comprises wetting dispersing agent, anti-settling agent, flow agent and defoamer.Wetting dispersing agent is the derivatives class of polymer unsaturated polyester carboxylic-acid or poly carboxylic acid/amine; Anti-settling agent is organobentonite class or polyethylene wax; Flow agent is silicone based or polyacrylate(s); Defoamer is silicone based.
The preparation method of crystal whisker wear-resistant ultraviolet ray solidified paint of the present invention: by the composition and the weight percent of above-mentioned each component, reactive thinner, the wetting dispersing agent that adds in the component by proportioning in mixing tank mixes earlier, add gradually while stirring through surface-treated whisker, add filler, high speed dispersion is even, add anti-settling agent, flow agent and defoamer in photosensitive oligomer, the auxiliary agent then, adding light trigger again continues to mix, homodisperse, packing promptly makes crystal whisker wear-resistant ultraviolet ray solidified paint.
Beneficial effect of the present invention: the coating performance excellence that crystal whisker wear-resistant ultraviolet ray solidified paint of the present invention forms at timber, density board, metal, glass, ceramic surface, toughening effect is obvious, the wear resisting property of filming is greatly improved, its wear resistance can reach 0.005～0.02g/ (500r, 750g).Crystal whisker wear-resistant ultraviolet ray solidified paint of the present invention does not add organic solvent, helps environmental protection, and easy construction, has tangible environmental benefit, social benefit and economic benefit.
Embodiment
Embodiment 1
A kind of crystal whisker wear-resistant ultraviolet ray solidified paint (weight percent) is by urethane acrylate oligomer 20%, epoxy acrylate oligomer 20%, tripropylene glycol diacrylate 15%, Viscoat 295 10%, 1,6 hexanediol diacrylate 9%, calcium carbonate crystal whisker 15%, filler 5%, 1-hydroxyl-phenylcyclohexane ethyl ketone 4.5%, wetting dispersing agent 0.4%, anti-settling agent 0.6%, flow agent 0.3%, defoamer 0.2% is formulated.The preparation method is with above-mentioned.
Embodiment 2
A kind of crystal whisker wear-resistant ultraviolet ray solidified paint (weight percent) is by urethane acrylate oligomer 46%, tripropylene glycol diacrylate 8%, neopentylglycol diacrylate 8%, Viscoat 295 6%, Isooctyl acrylate monomer 6%, potassium titanate crystal whisker 5%, filler 15%, α, alpha-alpha-dimethyl-α hydroxy acetophenone 5%, wetting dispersing agent 0.2%, anti-settling agent 0.4%, flow agent 0.2%, defoamer 0.2% is formulated.The preparation method is with above-mentioned.
Embodiment 3
A kind of crystal whisker wear-resistant ultraviolet ray solidified paint (weight percent) is by epoxy acrylate oligomer 27%, polyester acrylic ester oligomer 8%, tripropylene glycol diacrylate 10%, 1,6 hexanediol diacrylate 13%, Viscoat 295 5%, pentaerythritol triacrylate 4%, Isooctyl acrylate monomer 5%, calcium carbonate crystal whisker 10%, filler 10%, benzophenone 3%, tertiary amine acrylate 2%, α, alpha-alpha-dimethyl-α hydroxy acetophenone 2%, wetting dispersing agent 0.2%, anti-settling agent 0.4%, flow agent 0.2%, defoamer 0.2% is formulated.The preparation method is with above-mentioned.
Embodiment 4
A kind of crystal whisker wear-resistant ultraviolet ray solidified paint (weight percent) is by urethane acrylate oligomer 40%, epoxy acrylate oligomer 10%, tripropylene glycol diacrylate 12%, 1,6 hexanediol diacrylate 12%, Viscoat 295 7%, Isooctyl acrylate monomer 5%, ZnOw 7%, filler 3%, benzil two ketals 3%, wetting dispersing agent 0.2%, anti-settling agent 0.35%, flow agent 0.25%, defoamer 0.2% is formulated.The preparation method is with above-mentioned.
Claims (8)
1, a kind of crystal whisker wear-resistant ultraviolet ray solidified paint is characterized in that the composition of each component and weight percent are:
Photosensitive oligomer 35～50
Reactive thinner 28～42
Light trigger 3～9
Whisker 5～18
Filler 3～16
Auxiliary agent 1～1.5
2, crystal whisker wear-resistant ultraviolet ray solidified paint according to claim 1 is characterized in that described photosensitive oligomer is: one or more in epoxy acrylic oligoesters, urethane acrylate quasi-oligomer, the polyester acrylic oligoesters.
3, crystal whisker wear-resistant ultraviolet ray solidified paint according to claim 1, it is characterized in that described reactive thinner is in tripropylene glycol diacrylate, Viscoat 295,1,6 hexanediol diacrylate, pentaerythritol triacrylate, neopentylglycol diacrylate, the Isooctyl acrylate monomer two kinds or several.
4, crystal whisker wear-resistant ultraviolet ray solidified paint according to claim 1, it is characterized in that described light trigger is: benzophenones/amines system, benzil two ketals, Benzoin ethyl ether, 1-hydroxyl-phenylcyclohexane ethyl ketone, α, one or more in alpha-alpha-dimethyl-α hydroxy acetophenone, the thioxanthones.
5, crystal whisker wear-resistant ultraviolet ray solidified paint according to claim 1, it is characterized in that described whisker is: a kind of in calcium carbonate crystal whisker, potassium titanate crystal whisker, the ZnOw, diameter range is 0.5～2 μ m, length range is 20～40 μ m, by silane coupling agent or titanate coupling agent through the surface modification treatment mistake.
6, crystal whisker wear-resistant ultraviolet ray solidified paint according to claim 1 is characterized in that described filler is one or more in hollow glass microbead, silicon-dioxide, the elastic particle.
7, crystal whisker wear-resistant ultraviolet ray solidified paint according to claim 1 is characterized in that described auxiliary agent is wetting dispersing agent, anti-settling agent, flow agent, defoamer; Wetting dispersing agent is the derivatives class of polymer unsaturated polyester carboxylic-acid or poly carboxylic acid/amine; Anti-settling agent is organobentonite class or polyethylene wax; Flow agent is silicone based or polyacrylate(s); Defoamer is silicone based.
8, the preparation method of the described crystal whisker wear-resistant ultraviolet ray solidified paint of claim 1, it is characterized in that composition and weight percent according to described each component of claim 1, in mixing tank, press the reactive thinner in the proportioning adding component earlier, wetting dispersing agent mixes, add gradually while stirring through surface-treated whisker, add filler, high speed dispersion is even, add photosensitive oligomer then, anti-settling agent in the auxiliary agent, flow agent and defoamer, adding light trigger again continues to mix, homodisperse, packing promptly makes crystal whisker wear-resistant ultraviolet ray solidified paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610156034 CN100999643A (en) | 2006-12-30 | 2006-12-30 | Crystal whisker wear-resistant ultraviolet ray solidified paint and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610156034 CN100999643A (en) | 2006-12-30 | 2006-12-30 | Crystal whisker wear-resistant ultraviolet ray solidified paint and preparation process thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN100999643A true CN100999643A (en) | 2007-07-18 |
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| CN 200610156034 Pending CN100999643A (en) | 2006-12-30 | 2006-12-30 | Crystal whisker wear-resistant ultraviolet ray solidified paint and preparation process thereof |
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Cited By (28)
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|---|---|---|---|---|
| CN101942261A (en) * | 2010-08-24 | 2011-01-12 | 上海雅达特种涂料有限公司 | Ultraviolet curing coating |
| CN102146226A (en) * | 2010-12-28 | 2011-08-10 | 西安航天三沃化学有限公司 | Ultraviolet-cured high-adhesion scraping-resistant agent for heat insulating film |
| CN102264850A (en) * | 2008-12-23 | 2011-11-30 | Posco公司 | Ultraviolet curable resin composition for transparent color-painted steel sheet, and steel sheet using same |
| CN102516837A (en) * | 2011-12-19 | 2012-06-27 | 成都展辰化工有限公司 | Ultraviolet (UV) cured roller coating embellishing clear finish coating |
| CN101570653B (en) * | 2008-04-29 | 2012-10-03 | 汉达精密电子(昆山)有限公司 | Fingerprint resisting ultraviolet curing paint and operating method thereof |
| CN102942836A (en) * | 2012-11-28 | 2013-02-27 | 长沙岱勒新材料科技有限公司 | Photo-cured coating, photo-cured wire saw made of same and preparation method and device thereof |
| CN103333590A (en) * | 2013-07-01 | 2013-10-02 | 江苏达胜热缩材料有限公司 | Heat-resistant insulating paint with fast curing speed |
| CN103396737A (en) * | 2013-07-10 | 2013-11-20 | 淮南联合大学 | High temperature resistant ultraviolet curing coating and preparation method of same |
| CN103525257A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Stone surface crystallization ultraviolet photocurable coating and preparation method thereof |
| CN103834276A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | UV (Ultra Violet) curable coating good in adhesion and high in curing speed and preparation method thereof |
| CN103881028A (en) * | 2014-04-01 | 2014-06-25 | 张家港康得新光电材料有限公司 | Abrasion-proof optical material, preparation method and application of optical material |
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| CN104152034A (en) * | 2014-08-28 | 2014-11-19 | 苏州洛特兰新材料科技有限公司 | Ultraviolet curing acrylic ester composition paint used for ceramic |
| CN104177992A (en) * | 2014-08-28 | 2014-12-03 | 苏州洛特兰新材料科技有限公司 | Radiation curable acrylate resin coating for ceramics |
| CN104178018A (en) * | 2014-09-09 | 2014-12-03 | 苏州圣谱拉新材料科技有限公司 | Acrylic coating for ceramic |
| CN104194615A (en) * | 2014-09-09 | 2014-12-10 | 苏州圣谱拉新材料科技有限公司 | Metalized ceramic paint |
| CN104530959A (en) * | 2014-12-11 | 2015-04-22 | 惠州市长润发涂料有限公司 | Anti-sinking UV transparent primer |
| CN104817938A (en) * | 2015-04-30 | 2015-08-05 | 广西高农机械有限公司 | Glass-surface wear-proof ultraviolet curing coating for spraying machines |
| CN105176336A (en) * | 2015-10-20 | 2015-12-23 | 苏州群力防滑材料有限公司 | Multifunctional hardware coating material |
| CN104292400B (en) * | 2014-09-22 | 2016-11-23 | 南京航空航天大学 | Photocuring 3 D-printing material that a kind of CNT strengthens and preparation method thereof |
| CN107474605A (en) * | 2017-08-18 | 2017-12-15 | 华南师范大学 | A kind of optical fiber doping coating layer material and preparation method thereof |
| CN110128935A (en) * | 2019-05-24 | 2019-08-16 | 临沂优彩新能源环保科技有限公司 | A kind of UV ceramics special surface treating agent |
| CN110938340A (en) * | 2018-09-21 | 2020-03-31 | 独山县玉水鸿浩门业有限公司 | Door panel uv anti-cracking paint and preparation method thereof |
| CN112521851A (en) * | 2020-12-15 | 2021-03-19 | 北京化工大学常州先进材料研究院 | Super-hydrophobic super-wear-resistant anti-fog coating composition and application thereof |
| CN112680103A (en) * | 2020-12-15 | 2021-04-20 | 北京化工大学常州先进材料研究院 | Ultrahigh-strength hydrophobic antifogging coating composition and application thereof |
| CN115304985A (en) * | 2022-08-15 | 2022-11-08 | 广东新纪源复合材料股份有限公司 | Acrylate wear-resistant anti-fouling coating and preparation method thereof |
| CN116218333A (en) * | 2023-01-10 | 2023-06-06 | 江南大学 | Photo-curing coating and preparation method thereof |
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2006
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| CN101570653B (en) * | 2008-04-29 | 2012-10-03 | 汉达精密电子(昆山)有限公司 | Fingerprint resisting ultraviolet curing paint and operating method thereof |
| CN102264850A (en) * | 2008-12-23 | 2011-11-30 | Posco公司 | Ultraviolet curable resin composition for transparent color-painted steel sheet, and steel sheet using same |
| CN102264850B (en) * | 2008-12-23 | 2014-05-21 | Posco公司 | Ultraviolet curable resin composition for transparent color-painted steel sheet, and steel sheet using same |
| CN101942261A (en) * | 2010-08-24 | 2011-01-12 | 上海雅达特种涂料有限公司 | Ultraviolet curing coating |
| CN102146226A (en) * | 2010-12-28 | 2011-08-10 | 西安航天三沃化学有限公司 | Ultraviolet-cured high-adhesion scraping-resistant agent for heat insulating film |
| CN102516837A (en) * | 2011-12-19 | 2012-06-27 | 成都展辰化工有限公司 | Ultraviolet (UV) cured roller coating embellishing clear finish coating |
| CN102942836A (en) * | 2012-11-28 | 2013-02-27 | 长沙岱勒新材料科技有限公司 | Photo-cured coating, photo-cured wire saw made of same and preparation method and device thereof |
| CN103333590A (en) * | 2013-07-01 | 2013-10-02 | 江苏达胜热缩材料有限公司 | Heat-resistant insulating paint with fast curing speed |
| CN103333590B (en) * | 2013-07-01 | 2016-06-08 | 江苏达胜热缩材料有限公司 | The high temperature insulation coating that a kind of curing rate is fast |
| CN103396737A (en) * | 2013-07-10 | 2013-11-20 | 淮南联合大学 | High temperature resistant ultraviolet curing coating and preparation method of same |
| CN103525257A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Stone surface crystallization ultraviolet photocurable coating and preparation method thereof |
| CN103834276A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | UV (Ultra Violet) curable coating good in adhesion and high in curing speed and preparation method thereof |
| CN103834276B (en) * | 2014-03-04 | 2016-03-30 | 芜湖市艾德森自动化设备有限公司 | The fast UV of the good curing speed of a kind of sticking power is coating material solidified and preparation method thereof |
| CN103881028A (en) * | 2014-04-01 | 2014-06-25 | 张家港康得新光电材料有限公司 | Abrasion-proof optical material, preparation method and application of optical material |
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| CN104152034A (en) * | 2014-08-28 | 2014-11-19 | 苏州洛特兰新材料科技有限公司 | Ultraviolet curing acrylic ester composition paint used for ceramic |
| CN104177992A (en) * | 2014-08-28 | 2014-12-03 | 苏州洛特兰新材料科技有限公司 | Radiation curable acrylate resin coating for ceramics |
| CN104178018A (en) * | 2014-09-09 | 2014-12-03 | 苏州圣谱拉新材料科技有限公司 | Acrylic coating for ceramic |
| CN104194615A (en) * | 2014-09-09 | 2014-12-10 | 苏州圣谱拉新材料科技有限公司 | Metalized ceramic paint |
| CN104292400B (en) * | 2014-09-22 | 2016-11-23 | 南京航空航天大学 | Photocuring 3 D-printing material that a kind of CNT strengthens and preparation method thereof |
| CN104530959A (en) * | 2014-12-11 | 2015-04-22 | 惠州市长润发涂料有限公司 | Anti-sinking UV transparent primer |
| CN104817938A (en) * | 2015-04-30 | 2015-08-05 | 广西高农机械有限公司 | Glass-surface wear-proof ultraviolet curing coating for spraying machines |
| CN105176336A (en) * | 2015-10-20 | 2015-12-23 | 苏州群力防滑材料有限公司 | Multifunctional hardware coating material |
| CN107474605A (en) * | 2017-08-18 | 2017-12-15 | 华南师范大学 | A kind of optical fiber doping coating layer material and preparation method thereof |
| CN110938340A (en) * | 2018-09-21 | 2020-03-31 | 独山县玉水鸿浩门业有限公司 | Door panel uv anti-cracking paint and preparation method thereof |
| CN110128935A (en) * | 2019-05-24 | 2019-08-16 | 临沂优彩新能源环保科技有限公司 | A kind of UV ceramics special surface treating agent |
| CN112521851A (en) * | 2020-12-15 | 2021-03-19 | 北京化工大学常州先进材料研究院 | Super-hydrophobic super-wear-resistant anti-fog coating composition and application thereof |
| CN112680103A (en) * | 2020-12-15 | 2021-04-20 | 北京化工大学常州先进材料研究院 | Ultrahigh-strength hydrophobic antifogging coating composition and application thereof |
| CN112521851B (en) * | 2020-12-15 | 2022-03-15 | 北京化工大学常州先进材料研究院 | Super-hydrophobic super-wear-resistant anti-fog coating composition and application thereof |
| CN115304985A (en) * | 2022-08-15 | 2022-11-08 | 广东新纪源复合材料股份有限公司 | Acrylate wear-resistant anti-fouling coating and preparation method thereof |
| CN116218333A (en) * | 2023-01-10 | 2023-06-06 | 江南大学 | Photo-curing coating and preparation method thereof |
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