CN100462414C - Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof - Google Patents

Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof Download PDF

Info

Publication number
CN100462414C
CN100462414C CN 200610152183 CN200610152183A CN100462414C CN 100462414 C CN100462414 C CN 100462414C CN 200610152183 CN200610152183 CN 200610152183 CN 200610152183 A CN200610152183 A CN 200610152183A CN 100462414 C CN100462414 C CN 100462414C
Authority
CN
China
Prior art keywords
acrylate
diluent
nano
antibacterial
glycol diacrylate
Prior art date
Application number
CN 200610152183
Other languages
Chinese (zh)
Other versions
CN1927971A (en
Inventor
刘红波
李荣先
缪国元
薛亚波
Original Assignee
深圳清华大学研究院;江苏晨光涂料有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 深圳清华大学研究院;江苏晨光涂料有限公司 filed Critical 深圳清华大学研究院;江苏晨光涂料有限公司
Priority to CN 200610152183 priority Critical patent/CN100462414C/en
Publication of CN1927971A publication Critical patent/CN1927971A/en
Application granted granted Critical
Publication of CN100462414C publication Critical patent/CN100462414C/en

Links

Abstract

本发明公开了一种紫外光固化纳米抗菌木器漆及其制备方法。 The present invention discloses a UV-curable wood coatings antibacterial nano their preparation. 这种紫外光固化纳米抗菌木器漆包括环氧丙烯酸酯、聚氨酯丙烯酸酯、稀释剂、无机纳米抗菌剂、无机纳米填料和光引发剂。 Such UV-curable wood coatings comprising nano antibacterial epoxy acrylates, urethane acrylates, diluents, inorganic nano antibacterial agents, inorganic nano filler and a photoinitiator. 其制备方法为,往稀释剂中加入无机纳米抗菌剂和无机纳米填料,并搅拌分散均匀,然后加入环氧丙烯酸酯、聚氨酯丙烯酸酯以及光引发剂混合均匀制成。 The preparation process, the diluent is added to the nano inorganic antibacterial agent and an inorganic nanofiller, and stirred uniformly dispersed, followed by addition of epoxy acrylate, urethane acrylate and a photoinitiator made uniformly mixed. 由于该木器漆加入了无机纳米抗菌剂,因而可以抑制细菌和微生物的生长繁殖,可起到长期有效的抗菌作用。 Since the addition of the inorganic nano Wood antibacterial agents, which can inhibit the growth and reproduction of bacteria and microorganisms, it can play an effective long-term antimicrobial effect.

Description

紫外光固化纳米抗菌木器漆及其制备方法 UV curing nano-antibacterial wood and preparation method

技术领域 FIELD

本发明属于紫外光固化木器漆技术领域,具体涉及一种紫外光固化纳米木器漆及其制备方法。 The present invention belongs to the technical field of UV-curable wood, wood coatings, and particularly relates to a method for preparing nano UV curing.

背景技术 Background technique

紫外光固化涂料是20世纪60年代开发的一种环保节能型涂料,它具有无或低挥发性有机化合物(VOC)排放、节省能源(能耗仅为热固化粉末涂料的1/5~1/10)、固化速度快(0.1〜10s)、适合流水线生产、固化温度低、适合涂覆热敏集材等优点。 UV-curable coatings are developed in the 1960s, an environmentally friendly energy-saving coating material, which has no or low volatile organic compound (VOC) emissions, energy savings (the energy consumption of a heat-curable powder coatings / 5 ~ 1 / 10), fast curing (0.1~10s), suitable for assembly line production, low curing temperature, suitable for coating heat-sensitive skidding, etc. 随着国家环保法规的日趋完善,减少涂料中挥发性有机化合物的使用己经成为必然的趋势, 而紫外光固化技术正是解决这一问题的有效措施之一。 With the gradual improvement of national environmental laws and regulations, to reduce volatile organic compounds in paints use has become an inevitable trend, and UV curing technology is one of the effective measures to solve this problem. 40年来,随着光固化技术的迅速发展,紫外光固化涂料已广泛应用于化工、机械、电子、轻工、通讯等领域,在木材、 金属、塑料、纸张、皮革上也得到大量应用。 40 years, with the rapid development of light-curing technology, UV-curable coatings have been widely used in chemical, machinery, electronics, light industry, telecommunications and other fields, in wood, metal, plastic, paper, leather has also been a large number of applications.

纳米材料作为一种新型的无机填料,由于其特殊结构,导致纳米粒子具有异常的特性,如表面效应、体积效应、宏观量子隧道效应、量子效应、界面效应以及有关光、电、 磁特性等。 As a new nanomaterials inorganic filler, because of its special structure, leading to nanoparticles having abnormal properties, such as surface effect, volume effect, macroscopic quantum tunneling effect, the quantum effect, and interfacial effects related to optical, electrical, magnetic properties and the like. 纳米材料在涂料中的应用能有效地改善和提高涂料的性能,而其中的纳米抗菌材料不仅可以改善涂料的性能,同时还使涂料具有杀菌的功效。 Nano-materials can improve the coating and to improve the application properties of the coating, and wherein the nano material can not only improve the performance of the coating, the coating also having a bactericidal effect. 目前关于纳米材料尤其是无机纳米抗菌材料与紫外光固化涂料相结合的产品还没有相关报道。 Currently nanomaterials, especially with an inorganic nano material combination of UV-curable coatings product has not yet reported.

紫外光固化木器漆(也即紫外光固化木器涂料)主要用于竹木家具、地板等木器的表面涂装。 UV-curable wood (i.e., UV-curable coatings) is mainly used for the surface coating wood furniture, floors of wood. 用于地板的涂料对耐磨性有较高的要求,目前多采用往其中加入无机耐磨粉的办法来提高其耐磨性,但难以均匀分散到涂料中从而难达到较好的效果。 Floor coatings for wear resistance have higher requirements, the current use of wear resistant inorganic approach powder was added thereto to improve the wear resistance, but it is difficult to uniformly disperse the coating material so as difficult to achieve good results. 而且由于木器长期裸露在空气中,即使在其表面涂覆一层木器漆,但是时间久了还是会在其表面滋生细菌和微生物等,从而影响环境的卫生甚至危害人体的健康。 And because the long-term wood exposed to the air, even in its surface coated with a layer of wood, but over time will still breed bacteria and microbes on its surface, thus affecting the environment, health and even endanger human health.

中国专利申请200410038047.3公开了一种"密度板材表面涂覆层的紫外光固化耐磨漆",该种漆采用重量百分比为5%〜50%的多官能团丙烯酸酯改性氨基树脂或多官能团甲基丙烯酸酯改性氨基树脂、5%〜50%的多官能团聚氨酯丙烯酸酯或多官能团聚氨酯甲基丙烯酸酯、5%〜50%的环氧丙烯酸酯或环氧甲基丙烯酸酯、10%〜50%的三官能团丙烯酸酯或三官能团甲基丙烯酸酯、1%〜10%的光引发剂、1%〜15%的无机耐磨粉、 以及其他助剂制成,该种漆同样存在上述问题。 Chinese Patent Application No. 200410038047.3 discloses a "sheet density UV curable abrasion resistant surface coating of paint," the kind of paint using 5% ~ 50 wt% of polyfunctional acrylate or polyfunctional amino resins modified methyl acrylate-modified amino resin, 5% ~ 50% multifunctional urethane acrylate or urethane methacrylate functional groups, 5% ~ 50% epoxy acrylate or epoxy methacrylate, 10% ~ 50% trifunctional acrylate or trifunctional methacrylate ester, a 1% ~ 10% of a photoinitiator, 1% ~ 15% of the wear resistant inorganic powder, and other additives, the kind of paint same problems listed above. 发明内容 SUMMARY

本发明的目的是提供一种耐磨性好且具有长效抗菌功能的紫外光固化纳米抗菌木器漆及其制备方法。 Object of the present invention is to provide a good wear resistance and having a long-lasting antibacterial function UV curing nano-antibacterial wood and its preparation method.

实现本发明目的中的提供一种紫外光固化纳米抗菌木器漆的技术方案是:本发明的紫外光固化纳米抗菌木器漆,其组分包括环氧丙烯酸酯、聚氨酯丙烯酸酯、稀释剂、无机纳米抗菌剂、无机纳米填料和光引发剂,以重量计各组分的份数是:环氧丙烯酸酯10〜 60份;聚氨酯丙烯酸酯10〜60份;稀释剂10〜60份;无机纳米抗菌剂1〜10份;无机纳米填料1〜10份;光引发剂1〜5份。 This object is achieved in providing a UV curable wood antibacterial nano technical solution: the present invention, ultraviolet curable antibacterial nano wood, which component comprises an epoxy acrylate, urethane acrylate, diluents, inorganic nano antibacterial agents, inorganic nano filler and a photoinitiator, parts by weight of the components is: 10~ 60 parts of epoxy acrylate; 10 to 60 parts of urethane acrylate; 10 to 60 parts diluent; nano inorganic antibacterial agent 1 ~ 10 parts; inorganic nanofiller 1~10 parts; ~ 5 parts of a photoinitiator.

上述环氧丙烯酸酯为双酚A环氧丙烯酸酯、溴化双酚A环氧丙烯酸酯、多元醇改 The epoxy acrylate is bisphenol A epoxy acrylate, brominated bisphenol A epoxy acrylate, modified polyols

性环氧丙烯酸酯、脂肪酸改性环氧丙烯酸酯中的一种或两种或三种或四种。 Epoxy acrylate, fatty acid modified epoxy acrylate is one or two or three or four. 上述聚氨酯丙烯酸酯为芳香族聚氨酯丙烯酸酯、脂肪族聚氨酯丙烯酸酯中的一种或两种。 The urethane acrylate is an aromatic urethane acrylate, aliphatic urethane acrylate is one or two.

上述稀释剂为单官能团稀释剂、或双官能团稀释剂、或三官能团稀释剂、或单官能团稀释剂和双官能团稀释剂的混合物、或单官能团稀释剂和三官能团稀释剂的混合物、 或双官能团稀释剂和三官能团稀释剂的混合物、或单官能团稀释剂和双官能团稀释剂和 The above-described diluents are monofunctional diluent or difunctional diluent, or trifunctional diluent, or a mixture of monofunctional diluent and difunctional diluent or diluent mixture monofunctional diluent and trifunctional or bifunctional a mixture of diluent and trifunctional diluents, monofunctional or difunctional diluent and a diluent and

三官能团稀释剂的混合物;其中的单官能团稀释剂为:丙烯酸丁酯、甲基丙烯酸丁酯、 丙烯酸乙酯、甲基丙烯酸乙酯、丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸縮水甘油酯、甲基丙烯酸縮水甘油酯、丙烯酸羟乙酯、甲基丙烯酸羟乙酯> 丙烯酸羟丙酯、甲基丙烯酸羟丙酯、或N-乙烯吡垸酮;双官能团稀释剂为:邻苯二甲酸二乙二醇二丙烯酸酯、邻苯二甲酸三丙二醇二丙烯酸酯、二丙二醇二丙烯酸酯、三丙二醇二丙烯酸酯、新戊二醇二 Trifunctional diluent mixture; wherein the diluent is a monofunctional: butyl acrylate, butyl methacrylate, ethyl acrylate, ethyl methacrylate, methyl acrylate, methyl methacrylate, glycidyl acrylate, glycidyl methacrylate, hydroxyethyl acrylate, hydroxyethyl methacrylate> hydroxypropyl acrylate, hydroxypropyl methacrylate, or N- vinyl ketone pyrazol embankment; difunctional diluents are: dimethyl phthalate ethylene glycol diacrylate phthalate, tripropylene glycol diacrylate, dipropylene glycol diacrylate, tripropylene glycol diacrylate, neopentyl glycol di

丙烯酸酯、丙氧基化新戊二醇二丙烯酸酯、1,6-己二醇二丙烯酸酯、1,4-丁二醇二丙烯 Acrylate, propoxylated neopentyl glycol diacrylate, 1,6-hexanediol diacrylate, 1,4-butanediol diacrylate

酸酯、乙氧基化双酚A二丙烯酸酯、二乙二醇二丙烯酸酯、或三乙二醇二丙烯酸酯;三官能团稀释剂为:三羟甲基丙垸三丙烯酸酯、乙氧基化三羟甲基丙垸三丙烯酸酯、季戊四醇三丙烯酸酯、或丙氧基化甘油三丙烯酸酯。 Esters, ethoxylated bisphenol A diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate or; trifunctional diluents are: embankment trimethylolpropane triacrylate, ethoxylated embankment of trimethylolpropane triacrylate, pentaerythritol triacrylate, or propoxylated glycerol triacrylate.

上述无机纳米抗菌剂为载银无机纳米抗菌剂、载锌无机纳米抗菌剂中的一种或两种。 The inorganic antimicrobial agent is nano silver nano inorganic antibacterial agent, the inorganic nano zinc contained one or two antibacterial agents. 上述无机纳米填料为纳米二氧化硅、纳米氧化锌、锐钛型纳米二氧化钛中的一种或 The inorganic nano silica nanofiller is a nano-zinc oxide, anatase titanium dioxide or

两种或三种。 Two or three. 上述光引发剂为二苯甲酮和叔胺的混合物、2-羟基-2-甲基-l-苯基-l-丙 Above photoinitiator is a mixture of benzophenone and tertiary amines, 2-methyl-propan -l- -l- phenyl

酮、1-羟基一环己基苯酮中的一种或两种或三种。 Ketone, 1-hydroxy-part of one or two or three of the phenyl ketone.

本发明的木器漆还具有分散剂和流平剂;以重量计的分散剂为0.3〜0.5份,以重量计的流平剂为0.1〜0.3份。 Wood present invention further includes a leveling agent and a dispersant; dispersant by weight of 0.3~0.5 parts by weight of leveling agent is 0.1~0.3 parts.

对于上述紫外光固化纳米抗菌木器漆,其制备方法具有以下步骤:①将上述液态的稀释剂加至搅拌罐中,然后往搅拌罐中加入上述粉状的无机纳米抗菌剂和上述无机纳米 Antibacterial nano respect to the UV-curable wood, having the following method of preparation: ① From the liquid diluent is added to a stirred tank, and then was added to the stirring tank of the powdery nano inorganic antibacterial agent and the inorganic nano

填料,并在温度为5'C〜50'C、搅拌速度为3000〜6000转/分钟的条件下使其在稀释剂中分散均匀;②往步骤①得到的分散后的混合物料中加入上述液态的环氧丙烯酸酯和上述聚氨酯丙烯酸酯,在温度为5〜5(TC、搅拌速度为500〜1000转/分钟的条件下混合均匀;③向步骤②得到的物料中加入上述光引发剂,在温度为5'C〜5(TC、搅拌速度为500〜 1000转/分钟的条件下混合均匀后过滤即得成品。 Filler, and at a temperature of 5'C~50'C, stirring speed was uniformly dispersed in the diluent at 3000~6000 rpm / min; ② the feed mixture to the dispersion obtained in the step ① was added to the liquid under the above-described epoxy acrylate and urethane acrylate, at a temperature of 5~5 (TC, stirring speed 500~1000 revolutions / minute uniformly mixed; ③ material obtained in step ② above is added a photoinitiator, in after filtration at a temperature of mixed 5'C~5 (TC, stirring speed of 1000 revolutions 500~ / minute to obtain the finished product.

本发明具有积极的效果:(i)本发明的木器漆符合化工行业标准《紫外光固化木器漆》(HG/T3655-1999)的相关要求,无毒,不会对人体造成危害。 The present invention has a positive effect: Wood (i) of the invention in line with the chemical industry standard "UV-curable wood" (HG / T3655-1999) the relevant requirements, non-toxic, will not cause harm to humans. (2)本发明的木器漆的填料为纳米填料,其它成分或者是液态物料,或者是粒径也为纳米级的分散状态的物料,故整个涂料在使用时其体系中的颗粒的粒径都比较小,因此施工性能较好,对各种基材均具有优良的附着力,而且粒径较小的纳米填料能非常均匀的分散到涂料中,固化后的机械强度增强,耐磨性得到很大的提高,按国家标准检测在本发明涂料的一个实施例中其附着力为(划格法)l级、摆杆硬度为0.83、耐磨性为(750g/50r) 0.013g、耐干热性为(90±2°C) l级。 Wood fillers (2) of the present invention, a nano filler, other ingredients or liquids, or materials having a particle size of nanometers is also a dispersed state, so that the entire coating system when using particles having a particle size of both is relatively small, thus better workability to various substrates have excellent adhesion, but also smaller particle size can be very uniform nanofiller is dispersed into a coating, after curing to enhance the mechanical strength, wear resistance is Great improvement, according to the national standard is detected adhesion (cross-hatch) level L, 0.83 pendulum hardness, wear resistance (750g / 50r) 0.013g, resistance to dry heat embodiment of the present invention in an embodiment of the coating It is of (90 ± 2 ° C) l level. (3)本发明的木器漆加入了无机纳米抗菌剂,因而可以抑制细菌和微生物的生长繁殖,对大肠杆菌和金黄葡萄球菌的抗菌率》99%,同时因为本发明的紫外光固化纳米抗菌粉体被固化在干膜中,故可起到长期有效的抗菌作用。 (3) Wood invention the inorganic nano antibacterial agent is added, it is possible to inhibit the growth and reproduction of bacteria and microorganisms, the antibacterial rates of E. coli and Staphylococcus aureus "99%, while the present invention is cured because the ultraviolet antibacterial nano powder body is cured dry film, it can play an effective long-term antimicrobial effect. (4)本发明的木器漆便于工业化生产,将物料混合时,只要环境温度在5'C〜5(TC,即无需对体系进行温度调节的操作。(5)因为本发明的木器漆用于竹木家具、木地板对各种基材均具有的优良的附着力,并且在生产和施工过程中对环境均无污染,故属于绿色环保产品。 Wood (4) of the present invention is suitable for mass production, when the materials are mixed, as long as the ambient temperature 5'C~5 (TC, i.e., without the need for temperature adjustment of the system operation. (5) Since the present invention is used in Wood bamboo furniture, wooden floors on various substrates have excellent adhesion and are non-polluting the environment in the production and construction process, and therefore belong to green products.

具体实施方式(实施例1) DESCRIPTION OF EMBODIMENTS (Example 1)

本实施例的紫外光固化纳米抗菌木器漆的组分如下:作为环氧丙烯酸酯的双酚A环氧丙烯酸酯;作为聚氨酯丙烯酸酯的芳香族聚氨酯丙烯酸酯SM6201;作为稀释剂的丙烯酸丁酯、三羟甲基丙烷三丙烯酸酯(TMPTA)和三丙二醇二丙烯酸酯(TPGDA):作为无机纳米抗菌剂的载银无机纳米抗菌剂;作为无机纳米填料的纳米氧化锌和纳米二氧化硅;作为光引发剂的2-羟基-2-甲基-1-苯基-1-丙酮(Darocurll73);作为分散剂的EFKA4010分散剂;作为流平剂的德谦837流平剂。 UV cured embodiment of the present antibacterial nano wood components as follows: bisphenol A epoxy acrylate, epoxy acrylate; an aromatic urethane acrylate, urethane acrylate SM6201; butyl acrylate as a diluent, trimethylol propane triacrylate (TMPTA) and tripropylene glycol diacrylate (TPGDA): as the inorganic antibacterial agent containing silver nano inorganic nano antibacterial agent; nano zinc oxide as the inorganic nanofiller and nanosilica; as a light initiator is 2-hydroxy-2-methyl-1-phenyl-1-propanone (Darocurll73); EFKA4010 as a dispersant dispersing agent; as a leveling agent Deuchem 837 leveling agent.

各组分具体重量份数为:双酚A环氧丙烯酸酯40份、芳香族聚氨酯丙烯酸酯15 份、丙烯酸丁酯10份、三羟甲基丙烷三丙烯酸酯(TMPTA) 5份、三丙二醇二丙烯酸酯(TPGDA) 20份、载银无机纳米抗菌剂l份、纳米氧化锌4份、纳米二氧化硅3份、2-羟基-2-甲基-1-苯基-1-丙酮(Darocur1173) 2份、EFKA4010分散剂0.3份、德谦837 流平剂Ol份。 In particular the components parts by weight of: bisphenol A epoxy acrylate 40 parts, 15 parts of an aromatic urethane acrylate, 10 parts of butyl acrylate, 5 parts of trimethylolpropane triacrylate (of TMPTA), tripropylene glycol acrylate (TPGDA) 20 parts of silver nano inorganic antibacterial agent l parts, 4 parts of nano-zinc oxide, nano silica 3 parts of 2-methyl-1-phenyl-1-propanone (Darocur 1173) 2 parts, EFKA4010 0.3 parts of a dispersant, Deuchem 837 parts of leveling agent flow Ol.

上述重量配比的紫外光固化纳米抗菌木器漆的制备方法的步骤为: Said step of UV-curable weight proportion of wood in the preparation of antibacterial nano as:

① 将液态的稀释剂丙烯酸丁酯、三羟甲基丙垸三丙烯酸酯(TMPTA)、三丙二醇二丙烯酸酯(TPGDA)和液态的EFKA4010分散剂以及液态的德谦837流平剂加至搅拌罐中, 然后往搅拌罐中加入粉状的纳米氧化锌、纳米二氧化硅和载银无机纳米抗菌剂,并在温度为环境温度15°C、搅拌速度为4500转/分钟(在其它实施例中搅拌速度可以是3000 转/分钟、或6000转/分钟等)的条件下使粉状物料在稀释剂中分散均匀。 ① The liquid diluent of butyl acrylate, trimethylolpropane triacrylate embankment (of TMPTA), tripropylene glycol diacrylate (of TPGDA) and a liquid dispersant, and a liquid EFKA4010 Deuchem 837 leveling agent added to a stirred tank and then added to a stirred tank powdered nano-zinc oxide, nano silica and nano inorganic antibacterial agent containing silver, is at ambient temperature and at 15 ° C, stirring speed of 4500 revolutions / min (in other embodiments stirring the powder material so that the speed may be 3000 rev / min or 6000 rev / min, etc.) are satisfied uniformly dispersed in the diluent.

② 往步骤①得到的分散后的混合物料中加入液态的双酚A环氧丙烯酸酯和芳香族聚氨酯丙烯酸酯SM6201,在环境温度为15°C、搅拌速度为700转/分钟(在其它实施例中搅拌速度可以是500转/分钟、或1000转/分钟等)的条件下混合均匀。 ② To a mixture of the compound obtained in the dispersing step ① was added a liquid bisphenol A epoxy acrylate and an aromatic urethane acrylate SM6201, at an ambient temperature of 15 ° C, stirring speed of 700 revolutions / min (in other embodiments mixed under stirring rate may be 500 rev / min or 1000 rev / min, etc.) conditions.

③ 向步骤②得到的物料中加入光引发剂2-羟基-2-甲基-l-苯基-1-丙酮(Darocur1173),在环境温度为15°C、搅拌速度为700转/分钟(在其它实施例中搅拌 The material obtained in step ② ③ adding photoinitiator -l- phenyl-2-methyl-1-propanone (Darocur 1173), at an ambient temperature of 15 ° C, stirring speed of 700 revolutions / min (at other embodiments stirred

速度可以是500转/分钟、或1000转/分钟等)的条件下混合均匀后过滤即得成品。 After uniformly mixing speed may be filtered at 500 rev / min or 1000 rev / min, etc.) conditions to obtain the finished product.

上述成品使用时可采用刷涂、喷涂、淋涂等方法施工,按国家标准检测本发明涂料的附着力(划格法)1级、摆杆硬度0.83、耐磨性(750g/50r) 0.013g、耐干热性(90 ±2°C) l级;对大肠杆菌和金黄葡萄球菌的抗菌率99.3%。 When using the above-described finished product can be brush, spray coating, curtain coating methods such as construction, according to the national standards testing adhesion coatings of the present invention (cross-hatch) stage 1, 0.83 pendulum hardness, wear resistance (750g / 50r) 0.013g , resistance to dry heat (90 ± 2 ° C) l level; Escherichia coli and Staphylococcus aureus antibacterial rate of 99.3%. (实施例2至实施例48) (Examples 2 to Example 48)

实施例2至实施例48的紫外光固化纳米抗菌木器漆的制备方法与实施例1基本相同,其各组份及相应的重量配比(以重量份数表示)的数谆见表1至表8,附着力、摆杆硬度、耐磨性、耐干热性以及对大肠杆菌和金黄葡萄球菌的抗菌率等性能测试的具体数据见表1至表8 (表中符号"/"表示无)。 Examples 2 to Wood prepared nano antibacterial UV curable Example 48 Example 1 is substantially the same, the number of the components and their respective weight ratio (expressed in parts by weight) in Table 1 to Table Zhun 8, adhesion, pendulum hardness, abrasion resistance, dry heat resistance and specific data on E. coli and Staphylococcus aureus antibacterial rate performance test are shown in table 1 to table 8 (table symbol "/" indicates no) .

其中实施例6、 10、 11中无分散剂以及流平剂,与有分散剂以及流平剂的相应实施例相比,耐磨性稍逊,但有关指标仍符合有关国家标准。 Wherein Example 6, 10, 11, no dispersant and leveling agent, compared to the corresponding embodiments dispersant and leveling agent, wear resistance slightly inferior, but still meets the indicators relevant national standards.

表l Table l

<table>table see original document page 8</column></row> <table> <Table> table see original document page 8 </ column> </ row> <table>

表2 Table 2

组分名称重量份及性能测试数据 实施例 7 8 9 10 11 12 Parts by weight of component names and the performance test data of Example 789,101,112

组分名称及重量份 环氧丙烯酸酯 多元醇改性环氧丙烯酸酯 40 25 35 15 10 60 Ingredient name and polyol-modified epoxy acrylate parts by weight of epoxy acrylate 402535151060

聚氨酯丙烯酸酯 脂肪族聚氨酯丙烯酸酯SM6202 15 25 60 35 15 40 Urethane acrylate, aliphatic urethane acrylate SM6202 15 25 60 35 15 40

单官能团稀释剂 丙烯酸丁酯 35 10 25 60 40 30 Butyl acrylate monofunctional diluent 351025604030

无机纳米抗菌剂 载银无机纳米抗菌剂 2 3 7 5 10 Inorganic antibacterial agent Silver Nano nano inorganic antibacterial agent 237510

无机纳米填料 锐钛型纳米二氧化钛 7 5 3 6 1 10 Inorganic nanofillers anatase titanium dioxide 7536110

光引发剂 l-羟基一环己基苯酮 2 3 3 2 5 A photoinitiator l- hydroxy phenyl ketone 23,325

分散剂 EFKA4010分散剂 0.3 0,4 0.5 0.4 0 0 EFKA4010 dispersant Dispersant 0.3 0.5 0.4 0 0 0,4

流平剂 德谦837流平剂 0.1 0.2 0.3 0.2 0 0 837 leveling agent Deuchem leveling agent 0.1 0.2 0.3 0.2 0 0

性能测试数据 (划格法)附着力(级) 1 1 1 1 Performance test data (cross-hatch) Adhesion (grade) 1 1 1 1

摆杆硬度 0.87 0.86 0.88 0.89 0.85 0.82 0.87 0.86 pendulum hardness 0.88 0.89 0.85 0.82

(750g/50r)耐磨性(g) 0馬 0.015 0.014 0.019 0.011 0.011 (750g / 50r) abrasion resistance (g) 0 0.015 0.014 0.019 0.011 0.011 Horse

(90±2°C)耐干热性(级) 1 1 , 1 】 (90 ± 2 ° C) Dry heat resistance (Class) 1 1, 1]

对大肠杆菌和金黄葡萄球菌的抗菌率(%) 99.5 99.4 99.3 99.5 99.7 99.6 E. coli and S. aureus to the antimicrobial rate (%) 99.5 99.4 99.3 99.5 99.7 99.6

表3 table 3

<table>table see original document page 10</column></row> <table> <Table> table see original document page 10 </ column> </ row> <table>

表4 Table 4

<table>table see original document page 11</column></row> <table> <Table> table see original document page 11 </ column> </ row> <table>

表5 table 5

<table>table see original document page 12</column></row> <table> <Table> table see original document page 12 </ column> </ row> <table>

表6 Table 6

<table>table see original document page 13</column></row> <table> 表7 <Table> table see original document page 13 </ column> </ row> <table> Table 7

<table>table see original document page 14</column></row> <table> <Table> table see original document page 14 </ column> </ row> <table>

表8 Table 8

<table>table see original document page 15</column></row> <table> <Table> table see original document page 15 </ column> </ row> <table>

Claims (9)

1.一种紫外光固化纳米抗菌木器漆,其特征在于:其组分包括环氧丙烯酸酯、聚氨酯丙烯酸酯、稀释剂、无机纳米抗菌剂、无机纳米填料和光引发剂,其中无机纳米抗菌剂为载银无机纳米抗菌剂、载锌无机纳米抗菌剂中的一种或两种;以重量计各组分的份数是:环氧丙烯酸酯10~60份,聚氨酯丙烯酸酯10~60份,稀释剂10~60份,无机纳米抗菌剂1~10份,无机纳米填料1~10份,光引发剂1~5份。 A UV-curable antibacterial nano wood, characterized in that: the components thereof include epoxy acrylate, urethane acrylate, diluents, inorganic nano antibacterial agents, inorganic nano filler and a photoinitiator, wherein the antimicrobial agent is an inorganic nano inorganic nano silver antibacterial agent, an antibacterial agent, inorganic nano zinc contained in one or two; parts by weight of the components are: 10 to 60 parts epoxy acrylate, 10 to 60 parts urethane acrylate diluted 10 to 60 parts agent, 1 to 10 parts inorganic nano antibacterial agents, inorganic nano filler 1 to 10 parts, 1 to 5 parts of a photoinitiator.
2、 根据权利要求1所述的紫外光固化纳米抗菌木器漆,其特征在于:环氧丙烯酸酯为双酚A环氧丙烯酸酯、溴化双酚A环氧丙烯酸酯、多元醇改性环氧丙烯酸酯、脂肪酸改性环氧丙烯酸酯中的一种或两种或三种或四种。 2, UV-curable antibacterial nano wood according claim 1, wherein: epoxy acrylate is bisphenol A epoxy acrylate, brominated bisphenol A epoxy acrylate, polyol-modified epoxy acrylate, fatty acid modified epoxy acrylate is one or two or three or four.
3、 根据权利要求1所述的紫外光固化纳米抗菌木器漆,其特征在于:聚氨酯丙烯酸酯为芳香族聚氨酯丙烯酸酯、脂肪族聚氨酯丙炜酸酯中的一种或两种。 3, the ultraviolet light curing according to claim 1, antibacterial nano wood, wherein: the aromatic urethane acrylate is a urethane acrylate, an aliphatic urethane or both the propionic acid ester Wei.
4、 根据权利要求1所述的紫外光固化纳米抗菌木器漆,其特征在于:所述稀释剂为单官能团稀释剂、或双官能团稀释剂、或三官能团稀释剂、或单官能团稀释剂和双官能团稀释剂的混合物、或单官能团稀释剂和三官能团稀释剂的混合物、或双官能团稀释剂和三官能团稀释剂的混合物、或单官能团稀释剂和双官能团稀释剂和三官能团稀释剂的混合物;其中的单官能团稀释剂为:丙烯酸丁酯、甲基丙烯酸丁酯、丙烯酸乙酯、甲基丙烯酸乙酯、丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸縮水甘油酯、甲基丙烯酸缩水甘油酯、丙烯酸羟乙酷、甲基丙烯酸羟乙酯、丙烯酸羟丙酯、lf基丙烯酸籽丙酯、或M-乙烯吡烷兩;双官能团稀释剂为:邻苯二甲酸二乙二醇二丙烯酸酯、邻苯二甲酸三内二醇二丙烯酸酯、二丙二醇二丙烯酸酯、三丙二醇二丙烯酸酯、新戊二醇二丙烯 4. The UV-curable claim antibacterial nano wood according to claim 1, wherein: the diluent is a monofunctional diluent, diluent or difunctional, trifunctional or diluent, or a monofunctional diluent and bis mixtures of diluents functional groups diluent mixture, or a monofunctional diluent and trifunctional diluent mixture, or a difunctional diluent and trifunctional diluent mixture, or a monofunctional diluent and difunctional diluent and trifunctional; wherein the monofunctional diluent is: butyl acrylate, butyl methacrylate, ethyl acrylate, ethyl methacrylate, methyl acrylate, methyl methacrylate, glycidyl acrylate, glycidyl methacrylate, cool ethyl acrylate, hydroxyethyl methacrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, acrylic seed LF propyl group, or an ethylene-pyrazol M- two alkoxy; difunctional diluents are: phthalic acid diethylene glycol diacrylate, the three phthalic glycol diacrylate, dipropylene glycol diacrylate, tripropylene glycol diacrylate, neopentyl glycol diacrylate 酸酯、丙氧基化新戊二醇二丙烯酸酯、1,6-己二醇二丙烯酸酯、1,4-丁二醇二丙烯酸酯、乙諷被化双酚A二丙烯酸酯、二乙二醇二丙烯酸酯、或三乙二醇二丙烯酸酯;三官能团稀释剂为:三羟甲基丙烷三丙烯酸酯、乙氧基化三羟甲基丙烷三丙烯酸酯、季戊四醇三丙烯酸酯、或丙氧基化甘油三丙烯酸酯。 Esters, propoxylated neopentyl glycol diacrylate, 1,6-hexanediol diacrylate, 1,4-butanediol diacrylate, bisphenol A B Bitterness was diacrylate, diethyl glycol diacrylate, triethylene glycol diacrylate or; trifunctional diluents are: trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, pentaerythritol triacrylate, or propyl propoxylated glycerol triacrylate.
5、 根据权利要求1所述的紫外光固化纳米抗菌木器漆,其特征在于:无机纳米填料为纳米二氧化硅、纳米氧化锌、锐钛型纳米二氧化钛中的一种或两种或三种。 5. The UV curable nanometers to claim 1, wherein said antibacterial Wood, wherein: the inorganic nanofiller nano silica, nano zinc oxide, anatase titanium dioxide, one or two or three.
6、 根据权利要求1所述的紫外光固化纳米抗菌木器漆,其特征在于:光引发剂为二苯甲酮和叔胺的混合物、2-羟基-2-甲基-i-苯基-l-丙酮、l-羟基一环己基苯酮中的—种或两辆或三种。 6, according to claim antibacterial nano UV curable wood according to claim 1, wherein: the photoinitiator is a mixture of benzophenone and a tertiary amine, 2-hydroxy-2-methyl-phenyl -l -i- - acetone, l- hydroxy-cyclohexyl phenyl ketone - one or two or three.
7、 由权利要求1所述的紫外光固化纳米抗菌木器漆的制备方法,具有以下歩骤: ①将液态的稀释剂加至搅拌蝤中,然后往搅拌權中加入粉状的无机纳米抗菌剂和无机纳米填料,并在戽境温度为5t^501C、攙拌速度为3000^6000转/分钟的条件下使粉状物料在稀释剂中分散均匀:②往歩骤①得到的分散后的混合物料中加入液态的环轼丙烯酸酯和聚氡酯丙烯酸酯,在环境温度为5〜501C、搅拌速度为500〜1000转/分钟的条件下混合均匀;③向歩骤②得到的物料中加入光引发剂,在环境温度为5〜50X:、搅拌速度为500〜1000转/分钟的条件下混合均匀后过滤即得成品。 ① inorganic nano antibacterial agent added to the stirred liquid diluent larva then added to the stirred powdery Right: 7 by ultraviolet light as claimed in claim 1, said method for preparing a cured antibacterial nano wood, having the following step ho to a mixture ② ① ho dispersion obtained after step of: powdered material and an inorganic nanofiller, and an ambient temperature of bucket 5t ^ 501C, stirred mix speed of 3000 ^ 6000 revolutions / minute in a diluent uniformly dispersed Shi added to the liquid feed cyclic acrylates and poly acrylate radon, at ambient temperature 5~501C, stirring speed is 500~1000 rpm / min mixed; ho material obtained in the step ③ ② was added light initiator, at ambient temperature 5~50X :, 500~1000 rpm stirring speed / uniformly mixed and filtered under minutes to obtain the finished product.
8、 根据权利要求7所述的紫外光固化纳米抗菌木器漆的制备方法,其特征在于: 歩骤①中的稀释剂为单官能团稀释剂、或双官能团稀释剂、或三官能团稀释剂、或单官能团稀释剂和双官能团稀释剂的混合物、或单官能团稀释剂和三官能团稀释剂的混合物、或双官能团稀释剂和三官能团稀释剂的混合物、或单官能团稀释剂和双官能团稀释剂和三官能团稀释剂的混合物;歩骤①中的无机纳米抗菌刑为载银无机纳米抗菌剂、载锌无机纳米抗菌剂中的一种或两种;步骤①中的无机纳米填料为纳米二氧化硅、纳米諷化锌、锐钛型纳米二氧化钛中的一种或两种或三种;歩骤②中的环氧丙烯酸酯为双盼A 环氧丙烯酸酯、溴化双酚A环氧丙烯酸酯、多元醇改性环氧丙烯酸酯、脂肪酸改性环筑丙烯酸酯中的一种或两种或三种或四种;歩骤②中的聚氨酯丙烯酸酡为芳香族 8, was prepared according to the method of nano UV curable antimicrobial Wood of claim 7, wherein: step ① ho diluent is monofunctional diluent, diluent or difunctional, or trifunctional diluent, or the mixture monofunctional diluent and difunctional diluents, or a mixture of monofunctional diluent and trifunctional diluents, or a mixture of difunctional diluent and trifunctional diluents, or a monofunctional diluent and difunctional diluent and tris diluent mixture functional group; ho step ① of the inorganic nano-antibacterial penalty of inorganic nano silver antibacterial agent, an inorganic nano zinc contained one or two antibacterial agents; inorganic nano-fillers in the step ① nanosilica, Bitterness nano zinc, one or two or three nano-anatase titanium dioxide; ho step ② of the epoxy acrylate hope bis a epoxy acrylate, brominated bisphenol a epoxy acrylate, polyol alcohol-modified epoxy acrylate, fatty acid modified building ring one or two or three or four kinds of acrylate; urethane acrylate ho flushed in step ② aromatic 氨酯丙烯酸酯、脂肪族聚氨酶丙烯酸酯中的一种或两种;歩骤③中的光引发剂为二苯甲酮和叔胺的混合物、2-羟基-2-甲基-l-苯基-l-丙酮、1-羟基一环己基苯酮中的一种或两种或二种。 Urethane acrylate, aliphatic urethane acrylate enzyme one or two; ho step ③ the photoinitiator is a mixture of benzophenone and a tertiary amine, 2-hydroxy-2-methyl -l- acetone -l- phenyl, a 1-hydroxycyclohexyl phenyl ketone or of one or both of two kinds.
9、 根据权利要求7所述的紫外光固化纳米抗菌木器漆的制备方法,其特征在于: 步骤①中的单官能团稀释剂为:丙烯酸丁酯、甲基丙烯酸丁酯、丙烯酸乙酯、甲基丙烯酸乙酯、丙烯酸甲酯、甲基丙^&酸甲酯、丙烯酸縮水甘油酯、甲基丙烯酸縮水甘油酯、 丙烯酸羟ZJ旨、甲基丙烯酸羟乙酯、丙烯酸羟丙酯、甲基丙烯酸羟丙酯、或N-乙烯吡烷酮:歩骤(D中的双官能团稀释剂为:邻苯二甲酸二乙二醇二丙烯酸酯、邻苯二甲酸三丙二醇二丙烯酸酯、二丙二醇二丙烯酸酯、三丙二醇二丙烯酸酯、新戊二醇二丙烯酸酯、 丙氧基化新戊二醇二丙烯酸酯、1,6-己二醇二丙烯酸酯、1,4-丁二醇二丙烯酸酯、乙氧基化双酚A二丙烯酸酯、二乙二醇二丙烯酸酯、或三乙二醇二丙烯酸酯:歩骤①中的三官能团稀释剂为:三羟甲基丙烷三丙烯酸酯、乙氧基化三羟甲基丙烷三丙烯酸 9, prepared according to claim nanometer UV curable antimicrobial method of claim 7 Wood claims, characterized in that: the step ① monofunctional diluent is from: butyl acrylate, butyl methacrylate, ethyl acrylate, methyl ethyl acrylate, methyl acrylate, methyl propionate, methyl & ^, glycidyl acrylate, glycidyl methacrylate, hydroxyethyl acrylate, ZJ purpose, hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, propyl, or N- vinyl pyrrolidone-pyrazole: ho step (D difunctional diluent is from: phthalic acid diethylene glycol diacrylate phthalate, tripropylene glycol diacrylate, dipropylene glycol diacrylate , tripropylene glycol diacrylate, neopentyl glycol diacrylate, propoxylated neopentyl glycol diacrylate, 1,6-hexanediol diacrylate, 1,4-butanediol diacrylate, b ethoxylated bisphenol a diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate or: ho trifunctional diluent in step ① are: trimethylolpropane triacrylate, ethoxylated trimethylol propane triacrylate 、季戊四醇三丙烯酸酯、或丙氧基化甘油三丙烯酸酯。 , Pentaerythritol triacrylate, or propoxylated glycerol triacrylate.
CN 200610152183 2006-09-18 2006-09-18 Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof CN100462414C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200610152183 CN100462414C (en) 2006-09-18 2006-09-18 Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200610152183 CN100462414C (en) 2006-09-18 2006-09-18 Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof

Publications (2)

Publication Number Publication Date
CN1927971A CN1927971A (en) 2007-03-14
CN100462414C true CN100462414C (en) 2009-02-18

Family

ID=37858114

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200610152183 CN100462414C (en) 2006-09-18 2006-09-18 Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN100462414C (en)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280154B (en) 2007-04-06 2010-10-13 上海海优威电子技术有限公司 Ultraviolet curing vacuum metallizing coating
CN101353545B (en) 2008-08-26 2010-06-23 苏州市明大高分子科技材料有限公司 UV curing antibiotic coating and preparation thereof
CN102190938B (en) * 2010-03-19 2013-04-10 刘立新 High-wear-resistance antiscratch and antifouling solid wood board ultraviolet (UV) curable coating system
CN102234480A (en) * 2010-04-20 2011-11-09 东莞市佩琦涂料有限公司 Ultraviolet light solidified antibiosis paint
CN102002316A (en) * 2010-12-03 2011-04-06 广东盈然木业有限公司 UV-water-wet finish paint and floor produced thereby
CN102775889B (en) * 2012-07-17 2014-12-31 华南理工大学 Ultraviolet-curing light oil for plastic top-coat and preparation method thereof
CN103073964A (en) * 2012-11-23 2013-05-01 高凡 Preparation method of novel nano modified antibiosis aqueous woodenware paint
CN103059669A (en) * 2012-11-23 2013-04-24 高凡 Novel nano modified antimicrobial water-based woodware paint
CN103497668A (en) * 2013-09-16 2014-01-08 成都优品涂料有限公司 Ultraviolet curing stain-resistant and wear-resistant negative ion wood lacquer and preparation method thereof
CN103589296B (en) * 2013-10-24 2016-09-07 惠州市长润发涂料有限公司 One kind of anti-yellowing white primer uv wood
CN103666223B (en) * 2013-12-12 2016-05-11 李正新 Nano-modified anti-yellowing UV paint
CN103805052A (en) * 2014-02-13 2014-05-21 芜湖市宝艺游乐科技设备有限公司 High-temperature-resistant UV-curing paint and preparation method thereof
KR101964092B1 (en) * 2014-08-01 2019-04-02 (주)엘지하우시스 Hard coating composition containing polytetrafluoroethylene, hard coating layer and flooring including the same
CN104312419B (en) * 2014-10-16 2016-06-29 山西大学 UV-curable coating and a method for preparing a glass having antibacterial function
CN104293168A (en) * 2014-10-28 2015-01-21 成都纳硕科技有限公司 VOC-free deodorization ultraviolet-curing coating for wood building material
CN104277518A (en) * 2014-10-28 2015-01-14 成都纳硕科技有限公司 High-leveling abrasion-resistant ultraviolet-curable coating material for solid wood floors
CN104277708A (en) * 2014-10-28 2015-01-14 成都纳硕科技有限公司 Ultraviolet curing coating with low chromatic number, high gloss and high hardness for woodware
CN104277676A (en) * 2014-10-30 2015-01-14 成都优品涂料有限公司 UV (ultraviolet) paint with 3D (three-dimensional) effect and preparation method thereof
CN104277546A (en) * 2014-10-30 2015-01-14 成都优品涂料有限公司 UV wood lacquer jelly-type transparent earth-invigorating putty and preparation method thereof
CN104530959A (en) * 2014-12-11 2015-04-22 惠州市长润发涂料有限公司 Anti-sinking UV transparent primer
CN104497737A (en) * 2014-12-15 2015-04-08 广东梅雁吉祥水电股份有限公司 Multifunctional anti-bacteria coating composition and preparation method thereof
CN104497803A (en) * 2014-12-17 2015-04-08 北京百慕航材高科技股份有限公司 Coating, carbon fiber silent arrow shaft and preparation method of carbon fiber silent arrow shaft
CN104910757B (en) * 2015-05-11 2017-05-03 广德美涂士化工有限公司 A heat-resistant UV-curable coatings
CN104877547A (en) * 2015-05-15 2015-09-02 成都纳硕科技有限公司 Ultraviolet-light curing antibacterial, antiseptic and antistatic coating for metals
CN104927627A (en) * 2015-06-09 2015-09-23 成都纳硕科技有限公司 Bacterium-resistant UV curing furniture coating
CN106317997A (en) * 2015-06-22 2017-01-11 泰州市华丽塑料有限公司 Nano-TiO2 modified UV coating and production method thereof
CN106318134A (en) * 2015-06-22 2017-01-11 泰州市华丽塑料有限公司 Carbon nanotube/TiO2 modified UV resin coating with antistatic and antibacterial functions
CN105400385B (en) * 2015-11-27 2019-02-15 宁波双人新材料有限公司 A kind of photocuring wear-resistant paint and preparation method thereof with anti-microbial property
CN107057543A (en) * 2016-12-24 2017-08-18 句容亿格纳米材料厂 Nanometer photo-curing coating for nonmetal plate, and preparation method and application thereof
CN107163830B (en) * 2017-07-19 2019-04-02 安徽三品技术服务有限公司 A kind of wear-resisting sterilization floor paint
CN107936817A (en) * 2017-11-13 2018-04-20 惠州市李唐科技发展有限公司 Nanometer waterproof thermal insulation consolidation fluid and use method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1196370A (en) 1997-04-02 1998-10-21 三星电管株式会社 Coating composition for cathode ray tube and method of coating same
CN1297973A (en) 2000-06-07 2001-06-06 湖南亚大化工建材有限公司 Ultraviolet cured paint
CN1554717A (en) 2003-12-26 2004-12-15 南京海泰纳米材料有限公司 Nano technology modified ultraviolet solidified woodware paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1196370A (en) 1997-04-02 1998-10-21 三星电管株式会社 Coating composition for cathode ray tube and method of coating same
CN1297973A (en) 2000-06-07 2001-06-06 湖南亚大化工建材有限公司 Ultraviolet cured paint
CN1554717A (en) 2003-12-26 2004-12-15 南京海泰纳米材料有限公司 Nano technology modified ultraviolet solidified woodware paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
紫外光固化环氧-丙烯酸酯/聚氨酯-丙烯酸酯复合型水性涂料的研制. 汪存东.涂料工业,第35卷第2期. 2005

Also Published As

Publication number Publication date
CN1927971A (en) 2007-03-14

Similar Documents

Publication Publication Date Title
CN101486863B (en) Environment friendly waterborne paint and preparation thereof
CN100558834C (en) Green powdered paint and its prepn
CN101215438B (en) Anti-soiling aging-resisting stainless steel paint and preparation method thereof
CN101486861B (en) Environment friendly antibacterial waterborne paint and preparation thereof
JP3486919B2 (en) Glass flakes having antimicrobial
CN104387816A (en) Multifunctional inorganic diatom ooze coating and preparation method thereof
CN101100583B (en) High-adhesion ultraviolet radiation polyurethane double-solidifying carpentry paint and preparation method thereof
CN101029204A (en) Multifunctional water woodenware pigment and its production
CN101353545B (en) UV curing antibiotic coating and preparation thereof
CN101016431A (en) Nano antibacterial water woodenware paint and preparing method thereof
CN101705048A (en) Highly transparent unsaturated polyester primer and preparation method as well as use method thereof
CN101921521A (en) Nano-titanium water-based coating having long-acting resistance to formaldehyde
CN1244651C (en) Nano titanium dioxide composite water-based building paint having high weathering-resistance
CN103756523A (en) Antibacterial mildew-resistant powder coating, and preparation method thereof
CN102702889A (en) Anti-bacterial water-based paint and preparation method thereof
CN100387666C (en) Nanometre Ag antibacterial aqueous woodware paint and its preparation method
CN1554717A (en) Nano technology modified ultraviolet solidified woodware paint
CN1580144A (en) Environmenttally friendly water-based transparent putty for woodenware
CN102206461B (en) Waterborne UV coating
CN101985541B (en) Polyurethane coating and preparation method thereof
CN102190936A (en) Swelling-preventing polyacrylate dispersion/SiO2 hybrid aqueous wood coating
CN102220062B (en) Aqueous UV curing coating and preparation method thereof
CN101633817B (en) Aqueous UV plastic coating
CN1118525C (en) Antibacterial antimildew surface decorative material and its application method
CN102888180A (en) Antimicrobial ultraviolet-curing paint and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
C10 Request of examination as to substance
C14 Granted
C17 Cessation of patent right