CN102719188B - Hydrophilic aluminum foil coating with integrated bottom and top and preparation method thereof - Google Patents
Hydrophilic aluminum foil coating with integrated bottom and top and preparation method thereof Download PDFInfo
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- CN102719188B CN102719188B CN201210192543.9A CN201210192543A CN102719188B CN 102719188 B CN102719188 B CN 102719188B CN 201210192543 A CN201210192543 A CN 201210192543A CN 102719188 B CN102719188 B CN 102719188B
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Abstract
The invention discloses a hydrophilic aluminum foil coating with integrated bottom and top and a preparation method thereof. The coating consists of the following components in percentage by mass: 25-40 percent of hydrophilic acrylic resin, 15-30 percent of polyurethane acrylic resin, 25-45 percent of active diluent mixture and 5-10 percent of photoinitiator; and the coating is cured into a film at one time through ultraviolet irradiation. The hydrophilic acrylic resin is prepared by synthesizing acrylic resin with a solution polymerization method, adding diethanolamine, and neutralizing into a salt; and the hydrophilic aluminum foil coating with integrated bottom and top is obtained by weighing and mixing components proportionally and mechanically stirring uniformly. After a paint film is cured, the continuous hydrophilicity of a coating layer is high, the hardness is moderate, the adhesion force is strong, and wear to a punching die is small. The coating layer is used for providing functions such as corrosion prevention, protection, hydrophilicity and the like for an aluminum foil.
Description
Technical field
The invention belongs to the Application Areas that is applied to hydrophilic aluminium foil coating antiseptic, particularly hydrophilic aluminium foil coating of a kind of bottom surface unification and preparation method thereof.
Technical field
For achieving the above object, the concrete technical scheme of taking is in the present invention:
A hydrophilic aluminium foil coating for bottom surface unification, by mass percentage by component: hydrophilic acrylic resin is 25～40%, polyurethane acrylic resin is 15～30%, and reactive thinner mixture is 25～45%, and light trigger is 5～10% compositions;
Wherein said hydrophilic acrylic resin is by mass percentage by component: methyl methacrylate is 15～30%, Isooctyl acrylate monomer is 10～25%, vinylformic acid is 2.5～7.5%, acrylamide is 1～5%, diethanolamine is 3.6～10.8%, ethylene glycol monobutyl ether is 10～30%, and propyl carbinol is 10～40%, and Diisopropyl azodicarboxylate is 1～5% composition;
Described reactive thinner mixture is 40～60% by polyoxyethylene glycol (400) dimethacrylate by mass percentage, methacryloxyethyl acid isobornyl thiocyanoacetate is 10～25%, propylene glycol diacrylate is 20～30%, pentaerythritol triacrylate is 1～5%, tetrahydrofuran (THF) acrylate is 2～8%, the mixture of the polymerizable multifunctional monomer composition that butyl acrylate is 1～5%.
Described polyurethane acrylic resin is the CN965NS that Sartomer company of the U.S. produces, any in CN983NS and CN966J75NS.
Described light trigger is 2-hydroxy-2-methyl-1-phenyl-1-acetone or 1-hydroxyl-cyclohexyl benzophenone.
For achieving the above object, another technical scheme that the present invention takes is:
A preparation method for the hydrophilic aluminium foil coating of bottom surface unification, comprises the steps:
(1) hydrophilic acrylic resin's preparation
Press proportioning claimed in claim 1 first by methyl methacrylate, Isooctyl acrylate monomer, vinylformic acid, acrylamide mixes, add Diisopropyl azodicarboxylate to be uniformly dissolved and obtain mixed prepolymer, then quantitative ethylene glycol monobutyl ether and propyl carbinol are mixed in reactor and are warming up to 60 ℃～80 ℃, mixed prepolymer is added dropwise in the mixed solvent being formed by ethylene glycol monobutyl ether and propyl carbinol, time for adding is 0.5～1 hour, dropwise and be warming up to 75～100 ℃, react 8～～24 hours, and then be cooled to 50 ℃～60 ℃, add diethanolamine to react again after 0.5～2 hour and vacuumize removal solvent, cooling discharging, obtain hydrophilic acrylic resin,
(2) mixing of reactive thinner
By proportioning claimed in claim 1, each reactive thinner component is weighed, utilize homogenizer to stir the speed of 300～500 revs/min, be directly mixed to get;
(3) preparation of the hydrophilic aluminium foil coating of bottom surface unification
Successively hydrophilic acrylic resin, polyurethane acrylic resin, reactive thinner are added in stirrer by proportioning claimed in claim 1, be under 1500～2500 revs/min, to stir 15～30 minutes at rotating speed, and then add light trigger, under the rotating speed of 1000～2000 revs/min, stir 10～15 minutes, obtain the hydrophilic aluminium foil coating of desired bottom surface unification.
Curing mode of the present invention is: first base material aluminium foil is carried out to pre-treatment, pre-treatment comprises cleans base material aluminium foil surface and base material aluminium foil is carried out to drying and processing with the mixed solution of grease-removing agent and deionized water; After pre-treatment, the coating of preparation is filled with to paint roller, by the rotation of paint roller, coating is coated in to the two surfaces of base material aluminium foil bag uniformly, the coating applying on base material aluminium foil is controlled at 1g/m
2left and right; The high voltage mercury lamp ultraviolet light irradiation that is 1kw through overpower solidifies for 30 seconds, finally can obtain hydrophilic aluminium foil coating.
Advantage of the present invention and beneficial effect are mainly:
1, hydrophilic aluminium foil coating of the present invention, bottom surface unification, solidifies by ultraviolet light irradiation, the complete processing that dry at two ends two of needs of relatively traditional hydrophilic aluminium foil, work simplification and energy saving, in addition, coating has reduced the volatilization of organic solvent, is conducive to environmental protection.
2, the protracted hydrophilicity of the bottom surface unified hydrophilic aluminum foil coating by ultraviolet light irradiation is strong, and hardness is moderate, and sticking power is good, less to the wearing and tearing of punching die, and anticorrosion effect is better.
Background technology
Hydrophilic aluminium foil is the modified aluminium foil material that makes to solidify in pure aluminum foil surface-coated hydrophilic coating by special process.Water of condensation can scatter rapidly on hydrophilic aluminium foil, can not condense into the globule, thereby increases heat exchange area, accelerates cooling and warming speed, also can effectively avoid water of condensation to hinder air flowing and the noise that produces.Based on this, class hydrophilic coating material for aluminium foil requires to have following performance: 1, good wetting ability and resistance to corrosion; 2, good plasticity and to the non-abradability of mould; 3, extremely strong resistance to punching press oiliness, solvent resistance, heat impedance; 4, gas-flow resistance is little.Traditional hydrophilic aluminium foil applying coating, comprises primer coating and hydrophilic surface lacquering, need to have the process of twice application and baking.In addition, traditional hydrophilic aluminium foil coating, in coating process, is mainly by the volatilization of water and organic solvent, and heating film forming is solidified.On the one hand, the volatilization of a large amount of organic solvents is unfavorable for environmental protection; On the other hand, the power consumption that is heating and curing is large, and baking time is longer, and production efficiency declines.
For overcoming the defect of traditional hydrophilic aluminium foil coating.The present invention is by synthesis hydrophilic based acrylic resin, and mixed polyurethane acrylic resin, reactive thinner and light trigger, prepare the hydrophilic aluminium foil coating of a kind of novel bottom surface unification, it solidifies by ultraviolet light irradiation mode, abandon solvent evaporates and pollute to reduce, enhance productivity simultaneously.Coating resin itself is with hydrophilic radical, and paint film has protracted hydrophilicity, and mechanical property is better, and corrosion resistance nature is strong, the complete Application Areas applicable to hydrophilic aluminium foil.
Summary of the invention
The object of the invention is the defect in order to overcome traditional hydrophilic aluminium foil coating, hydrophilic aluminium foil coating of a kind of bottom surface unification and preparation method thereof is provided.
Embodiment:
Below in conjunction with example, the present invention is done to further specific descriptions, but be not limited to this.
Embodiment 1
One, hydrophilic acrylic resin's is synthetic
(1) be equipped with by mass percentage component
Methyl methacrylate 15%,
Isooctyl acrylate monomer 24%,
Vinylformic acid 2.5%,
Acrylamide 1%,
Diethanolamine 3.6%,
Ethylene glycol monobutyl ether 10%,
Propyl carbinol 40%,
Diisopropyl azodicarboxylate 3.9%.
(2) preparation technology
First according to design proportion by methyl methacrylate, Isooctyl acrylate monomer, vinylformic acid, acrylamide mixes, add again Diisopropyl azodicarboxylate to be uniformly dissolved and obtain mixed prepolymer, then quantitative ethylene glycol monobutyl ether and propyl carbinol are mixed in reactor and are warming up to 60 ℃, mixed prepolymer is added dropwise in the mixed solvent being formed by ethylene glycol monobutyl ether and propyl carbinol, time for adding is 1 hour, dropwise and be warming up to 75 ℃, react 24 hours, and then be cooled to 60 ℃, add diethanolamine to react again after 0.5 hour and vacuumize removal solvent, cooling discharging, obtain hydrophilic acrylic resin.
Two, the preparation of reactive thinner mixture
(1) be equipped with by mass percentage component
Polyoxyethylene glycol (400) methacrylic ester 60%,
Methacryloxyethyl acid isobornyl thiocyanoacetate 10%,
Propylene glycol diacrylate 20%,
Pentaerythritol triacrylate 3%,
Tetrahydrofuran (THF) acrylate 6%,
Butyl acrylate 1%.
(2) preparation technology
Reactive thinner blending means is for to weigh each reactive thinner component according to formula rate, and high speed dispersor, with 500 revs/min of stirrings, is directly mixed to get.
Three. the preparation of the hydrophilic aluminium foil coating of bottom surface unification
(1) content is equipped with component by mass percentage
Hydrophilic acrylic resin 25%,
Urethane acrylate (CN965NS) 30%,
Reactive thinner mixture 35%,
2-hydroxy-2-methyl-1-phenyl-1-acetone 10%.
(2) preparation technology
In order, in mixing kettle, add respectively hydrophilic acrylic resin, urethane acrylate (CN965NS), reactive thinner etc., under 1500 revs/min of rotating speeds of high speed dispersion, stir 30 minutes, and then in mixing kettle, add light trigger, under the rotating speed of high speed dispersion and 1000 revs/min, stir 15 minutes, obtain the hydrophilic aluminium foil coating of desired bottom surface unification.
Embodiment 2
One. hydrophilic acrylic resin's is synthetic
(1) be equipped with by mass percentage component
Methyl methacrylate 30%,
Isooctyl acrylate monomer 10%,
Vinylformic acid 5%,
Acrylamide 2.8%,
Diethanolamine 7.2%,
Ethylene glycol monobutyl ether 30%,
Propyl carbinol 10%,
Diisopropyl azodicarboxylate 5%.
(2) preparation technology
First according to design proportion by methyl methacrylate, Isooctyl acrylate monomer, vinylformic acid, acrylamide mixes, add again Diisopropyl azodicarboxylate to be uniformly dissolved and obtain mixed prepolymer, then quantitative ethylene glycol monobutyl ether and propyl carbinol are mixed in reactor and are warming up to 80 ℃, mixed prepolymer is added dropwise in the mixed solvent being formed by ethylene glycol monobutyl ether and propyl carbinol, time for adding is 0.5 hour, dropwise and be warming up to 80 ℃, react 8 hours, and then be cooled to 50 ℃, add diethanolamine to react again after 2 hours and vacuumize removal solvent, cooling discharging, obtain hydrophilic acrylic resin.
Two, the preparation of reactive thinner mixture
(1) be equipped with by mass percentage component
Polyoxyethylene glycol (400) dimethacrylate 40%,
Methacryloxyethyl acid isobornyl thiocyanoacetate 25%,
Propylene glycol diacrylate 25%,
Pentaerythritol triacrylate 5%,
Tetrahydrofuran (THF) acrylate 2%,
Butyl acrylate 3%.
(2) preparation technology
Reactive thinner blending means is for to weigh each reactive thinner component according to formula rate, and 300 revs/min of stirrings of high speed dispersor, are directly mixed to get.
Three. the preparation of hydrophilic aluminium foil photo-cured coating
(1) content is equipped with component by mass percentage
Hydrophilic acrylic resin 40%,
Urethane acrylate (CN983NS) 15%,
Reactive thinner mixture 40%,
1-hydroxyl-cyclohexyl benzophenone 5%.
(2) preparation technology
In order, in mixing kettle, add respectively hydrophilic acrylic resin, polyurethane acrylic resin (CN983NS), reactive thinner etc., high speed dispersion 2500 is walked around, and speed is lower to be stirred 15 minutes, and then add light trigger, under 2000 revs/min of rotating speeds of high speed dispersor, stir 10 minutes, obtain the hydrophilic aluminium foil coating of desired bottom surface unification.
Embodiment 3
One. hydrophilic acrylic resin's is synthetic
(1) be equipped with in mass ratio component
Methyl methacrylate 25%,
Isooctyl acrylate monomer 15%,
Vinylformic acid 7.5%,
Acrylamide 5%,
Diethanolamine 10.8%,
Ethylene glycol monobutyl ether 20%,
Propyl carbinol 15.7%,
Diisopropyl azodicarboxylate 1%.
(2) preparation technology
First according to design proportion by methyl methacrylate, Isooctyl acrylate monomer, vinylformic acid, acrylamide mixes, add again Diisopropyl azodicarboxylate to be uniformly dissolved and obtain mixed prepolymer, then quantitative ethylene glycol monobutyl ether and propyl carbinol are mixed in reactor and are warming up to 70 ℃, mixed prepolymer is added dropwise in the mixed solvent being formed by ethylene glycol monobutyl ether and propyl carbinol, time for adding is 0.8 hour, dropwise and be warming up to 85 ℃, react 12 hours, and then be cooled to 55 ℃, add diethanolamine to react again after 1 hour and vacuumize removal solvent, cooling discharging, obtain hydrophilic acrylic resin.
Two, the preparation of reactive thinner mixture
(1) be equipped with by mass percentage component
Polyoxyethylene glycol (400) methacrylic ester 42%,
Methacryloxyethyl acid isobornyl thiocyanoacetate 14%,
Propylene glycol diacrylate 30%,
Pentaerythritol triacrylate 1%,
Tetrahydrofuran (THF) acrylate 8%,
Butyl acrylate 5%.
(2) preparation technology
Reactive thinner blending means is for to weigh each reactive thinner component according to formula rate, and 400 revs/min of stirrings of high speed dispersor, are directly mixed to get.
Two. the preparation of hydrophilic aluminium foil photo-cured coating
(1) content is equipped with component by mass percentage
Hydrophilic acrylic resin 39%,
Urethane acrylate (CN966J75NS) 28%,
Reactive thinner mixture 25%,
2-hydroxy-2-methyl-1-phenyl-1-acetone 8%.
(2) preparation technology
In order, in mixing kettle, add respectively hydrophilic acrylic resin, polyurethane acrylic resin (CN966J75NS), reactive thinner etc., high speed dispersion 2200 is walked around, and speed is lower to be stirred 17 minutes, and then in mixing kettle, add light trigger, 1900 revs/min of stirrings of high speed dispersor 11 minutes, obtain the hydrophilic aluminium foil coating that desired bottom surface is unified.
Embodiment 4:
One. hydrophilic acrylic resin's is synthetic
(1) be equipped with by mass percentage component
Methyl methacrylate 20%,
Isooctyl acrylate monomer 20%,
Vinylformic acid 5%,
Acrylamide 4.8%,
Diethanolamine 7.2%,
Ethylene glycol monobutyl ether 15%,
Propyl carbinol 25%,
Diisopropyl azodicarboxylate 3%.
(2) preparation technology
First according to design proportion by methyl methacrylate, Isooctyl acrylate monomer, vinylformic acid, acrylamide mixes, add again Diisopropyl azodicarboxylate to be uniformly dissolved and obtain mixed prepolymer, then quantitative ethylene glycol monobutyl ether and propyl carbinol are mixed in reactor and are warming up to 75 ℃, mixed prepolymer is added dropwise in the mixed solvent being formed by ethylene glycol monobutyl ether and propyl carbinol, time for adding is 1 hour, dropwise and be warming up to 90 ℃, react 12 hours, and then be cooled to 60 ℃, add diethanolamine to react again after 1 hour and vacuumize removal solvent, cooling discharging, obtain hydrophilic acrylic resin.
Two, the preparation of reactive thinner mixture
(1) be equipped with by mass percentage component
Polyoxyethylene glycol (400) methacrylic ester 55%,
Methacryloxyethyl acid isobornyl thiocyanoacetate 12%,
Propylene glycol diacrylate 22%,
Pentaerythritol triacrylate 3%,
Tetrahydrofuran (THF) acrylate 5%,
Butyl acrylate 3%.
(2) preparation technology
Reactive thinner blending means is for to weigh each reactive thinner component according to formula rate, and 450 revs/min of stirrings of high speed dispersor, are directly mixed to get.
Three. the preparation of hydrophilic aluminium foil photo-cured coating
(1) content is equipped with component by mass percentage
Hydrophilic acrylic resin 28%,
Urethane acrylate (CN965NS) 21%,
Reactive thinner mixture 45%,
2-hydroxy-2-methyl-1-phenyl-1-acetone 6%.
(2) preparation technology
In order, in mixing kettle, add respectively hydrophilic acrylic resin, polyurethane acroleic acid fat (CN965NS), reactive thinner etc., high speed dispersion 2000 is walked around, and speed is lower to be stirred 16 minutes, and then in mixing kettle, add light trigger, 2000 revs/min of stirrings of high speed dispersor 12 minutes, obtain the hydrophilic aluminium foil coating that desired bottom surface is unified.
Film curing and Performance Ratio thereof be:
First its solidification process is to prepare base material aluminium foil, and this base material aluminium foil is light paper tinsel.Base material aluminium foil is carried out to pre-treatment, and described pre-treatment comprises cleans base material aluminium foil surface and base material aluminium foil is carried out to drying and processing with the mixed solution of grease-removing agent and deionized water.After pre-treatment, coating is filled with to paint roller, by the rotation of paint roller, coating is coated in to the two surfaces of base material aluminium foil bag uniformly upper, the coating applying on base material aluminium foil is controlled at 1g/m
2left and right.The high voltage mercury lamp ultraviolet light irradiation that is 1kw through overpower solidifies for 30 seconds, forms hydrophilic aluminium foil coating.Its performance is as follows:
Claims (4)
1. a hydrophilic aluminium foil coating for bottom surface unification, by mass percentage by component: hydrophilic acrylic resin is 25～40%, polyurethane acrylic resin is 15～30%, and reactive thinner mixture is 25～45%, and light trigger is 5～10% compositions;
Wherein said hydrophilic acrylic resin is by mass percentage by component: methyl methacrylate is 15～30%, Isooctyl acrylate monomer is 10～25%, vinylformic acid is 2.5～7.5%, acrylamide is 1～5%, diethanolamine is 3.6～10.8%, ethylene glycol monobutyl ether is 10～30%, and propyl carbinol is 10～40%, and Diisopropyl azodicarboxylate is 1～5% composition, and press proportioning first by methyl methacrylate, Isooctyl acrylate monomer, vinylformic acid, acrylamide mixes, add Diisopropyl azodicarboxylate to be uniformly dissolved and obtain mixed prepolymer, then quantitative ethylene glycol monobutyl ether and propyl carbinol are mixed in reactor and are warming up to 60 ℃～80 ℃, mixed prepolymer is added dropwise in the mixed solvent being formed by ethylene glycol monobutyl ether and propyl carbinol, time for adding is 0.5～1 hour, dropwise and be warming up to 75～100 ℃, react 8～24 hours, and then be cooled to 50 ℃～60 ℃, add diethanolamine to react again after 0.5～2 hour and vacuumize removal solvent, cooling discharging, obtain hydrophilic acrylic resin,
Described reactive thinner mixture is 40～60% by polyoxyethylene glycol (400) dimethacrylate by mass percentage, isobornyl methacrylate is 10～25%, propylene glycol diacrylate is 20～30%, pentaerythritol triacrylate is 1～5%, tetrahydrofuran (THF) acrylate is 2～8%, the mixture of the polymerizable multifunctional monomer composition that butyl acrylate is 1～5%.
2. by the hydrophilic aluminium foil coating of a kind of bottom surface unification claimed in claim 1, it is characterized in that, described polyurethane acrylic resin is the CN965NS that Sartomer company of the U.S. produces, any in CN983NS and CN966J75NS.
3. by the hydrophilic aluminium foil coating of a kind of bottom surface unification claimed in claim 1, it is characterized in that: described light trigger is 2-hydroxy-2-methyl-1-phenyl-1-acetone or 1-hydroxyl-cyclohexyl benzophenone.
4. by a preparation method for the hydrophilic aluminium foil coating of bottom surface claimed in claim 1 unification, it is characterized in that comprising the steps:
(1) hydrophilic acrylic resin's preparation
Press proportioning claimed in claim 1 first by methyl methacrylate, Isooctyl acrylate monomer, vinylformic acid, acrylamide mixes, add Diisopropyl azodicarboxylate to be uniformly dissolved and obtain mixed prepolymer, then quantitative ethylene glycol monobutyl ether and propyl carbinol are mixed in reactor and are warming up to 60 ℃～80 ℃, mixed prepolymer is added dropwise in the mixed solvent being formed by ethylene glycol monobutyl ether and propyl carbinol, time for adding is 0.5～1 hour, dropwise and be warming up to 75～100 ℃, react 8～24 hours, and then be cooled to 50 ℃～60 ℃, add diethanolamine to react again after 0.5～2 hour and vacuumize removal solvent, cooling discharging, obtain hydrophilic acrylic resin,
(2) mixing of reactive thinner
By proportioning claimed in claim 1, each reactive thinner component is weighed, utilize homogenizer to stir the speed of 300～500 revs/min, be directly mixed to get;
(3) preparation of the hydrophilic aluminium foil coating of bottom surface unification
Successively hydrophilic acrylic resin, polyurethane acrylic resin, reactive thinner are added in stirrer by proportioning claimed in claim 1, be under 1500～2500 revs/min, to stir 15～30 minutes at rotating speed, and then add light trigger, under the rotating speed of 1000～2000 revs/min, stir 10～15 minutes, obtain the hydrophilic aluminium foil coating of desired bottom surface unification.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210192543.9A CN102719188B (en) | 2012-06-12 | 2012-06-12 | Hydrophilic aluminum foil coating with integrated bottom and top and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210192543.9A CN102719188B (en) | 2012-06-12 | 2012-06-12 | Hydrophilic aluminum foil coating with integrated bottom and top and preparation method thereof |
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| CN102719188A CN102719188A (en) | 2012-10-10 |
| CN102719188B true CN102719188B (en) | 2014-07-02 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102876200B (en) * | 2012-11-05 | 2015-06-10 | 江苏科技大学 | Hydrophilic aluminum foil coating and method for preparing and curing same |
| CN103045068B (en) * | 2012-12-10 | 2015-09-30 | 江苏中金玛泰医药包装有限公司 | A kind of aluminium foil use coating-forming agent and preparation method thereof |
| CN106299380B (en) * | 2016-08-24 | 2019-11-01 | 合肥国轩高科动力能源有限公司 | A kind of ultraviolet light solidification carbon-coated aluminum foils collector and preparation method |
| CN107134547B (en) * | 2017-04-01 | 2020-05-19 | 乐凯胶片股份有限公司 | Novel aluminum-plastic flexible packaging film for lithium ion battery |
| CN108864376B (en) * | 2018-06-15 | 2021-01-05 | 韶关瑞和环保科技有限公司 | Water-soluble acrylic resin and preparation method thereof, and hydrophilic coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001055540A (en) * | 1999-08-20 | 2001-02-27 | Nippon Polyurethane Ind Co Ltd | Polyurethane-based primer |
| CN101659785A (en) * | 2009-01-14 | 2010-03-03 | 佛山市顺德区德美油墨化工有限公司 | High-functionality water-based UV resin composition with 100% solid content and preparation method thereof |
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2012
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001055540A (en) * | 1999-08-20 | 2001-02-27 | Nippon Polyurethane Ind Co Ltd | Polyurethane-based primer |
| CN101659785A (en) * | 2009-01-14 | 2010-03-03 | 佛山市顺德区德美油墨化工有限公司 | High-functionality water-based UV resin composition with 100% solid content and preparation method thereof |
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