CN105331279B - A kind of waterborne UV coating and preparation method thereof - Google Patents
A kind of waterborne UV coating and preparation method thereof Download PDFInfo
- Publication number
- CN105331279B CN105331279B CN201510937909.4A CN201510937909A CN105331279B CN 105331279 B CN105331279 B CN 105331279B CN 201510937909 A CN201510937909 A CN 201510937909A CN 105331279 B CN105331279 B CN 105331279B
- Authority
- CN
- China
- Prior art keywords
- coating
- waterborne
- levelling agent
- epoxy
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000011248 coating agent Substances 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 239000004593 Epoxy Substances 0.000 claims abstract description 20
- -1 epoxy acrylate Chemical compound 0.000 claims abstract description 16
- NBVXSUQYWXRMNV-UHFFFAOYSA-N Fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004814 polyurethane Substances 0.000 claims abstract description 13
- 229920002635 polyurethane Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- FGVGQIHNLRMVRI-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;oxirene-2-carboxylic acid Chemical group OC(=O)C1=CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 FGVGQIHNLRMVRI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 5
- 239000012456 homogeneous solution Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Natural products CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 2
- 229940106691 bisphenol A Drugs 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- LXCIHXPVYQKJAG-UHFFFAOYSA-N N-[aziridin-1-yl-(2-methylaziridin-1-yl)phosphoryl]-N-prop-2-enylprop-2-en-1-amine Chemical compound CC1CN1P(=O)(N(CC=C)CC=C)N1CC1 LXCIHXPVYQKJAG-UHFFFAOYSA-N 0.000 claims 1
- JZTLWHBTNKUQME-UHFFFAOYSA-N ethyl carbamate;prop-1-ene Chemical group CC=C.CCOC(N)=O JZTLWHBTNKUQME-UHFFFAOYSA-N 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 238000007711 solidification Methods 0.000 abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000002209 hydrophobic Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 4
- 238000007792 addition Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
A kind of waterborne UV coating and preparation method thereof, the waterborne UV coating is made up of the raw material of following mass percent：Urethane acrylate 25%~35%, epoxy acrylate 20%~30%, aqueous hyperbranched polyurethane 5%~10%, fluorocarbon resin 5%~10%, light trigger 5%~15%, dispersant 2%~5%, auxiliary agent 2%~10%.The urethane acrylate is fluorochemical urethane acrylate, and the epoxy acrylate is bisphenol A epoxy acrylate and the mixture of aliphatic epoxy tetraacrylate；The auxiliary agent is the mixture of silicone levelling agent and fluorine-carbon modified class levelling agent.The preparation method of the waterborne UV coating, technique is simple, and the coating of preparation has good adhesion property and hydrophobic, water resistance, its curing rate is faster compared with traditional UV coating, it is to avoid the generation of bubble in solidification process；Meanwhile, anticorrosive, the ageing-resistant and acid-proof alkaline of the coating is also obviously improved, and is the surface coating of a kind of ideal metal and woodenware.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of waterborne UV coating and preparation method thereof.
Background technology
Photocureable coating（UV coating）It is a kind of efficient, new coating of energy-saving and environmental protection, traditional UV coating is dilute using activity
Agent regulation rheology is released, causes coating that there is strong impulse smell, and harmful effect is produced to the physical property of film.Relatively
In traditional UV coating, waterborne UV coating not only realizes low VOC, and is had no irritating odor in solidification process, to constructor and
Terminal user is without actual bodily harm.So the oligomer of high relative molecular mass can be used in waterborne radiation curable coating to replace living
Property diluent so as to overcoming this shortcoming.But UV coating still has some shortcomings now, such as：（1）Base should not be coated with
Because its adhesive force is undesirable after material, and coating, coating is easy to fall off；（2）Anticorrosive, ageing-resistant and acid-proof alkaline is poor, no
Widely used requirement can be reached.
The content of the invention
In view of the above-mentioned problems, the present invention provide it is a kind of there is good adhesion and paintability, it is relatively strong anticorrosive, ageing-resistant
With the waterborne UV coating of acid-proof alkaline and preparation method thereof.
To realize the above-mentioned purpose of the present invention, the present invention provides a kind of waterborne UV coating, is by following mass percent
Raw material composition：Urethane acrylate 25%~35%, epoxy acrylate 20%~30%, aqueous hyperbranched polyurethane 5%~
10%th, fluorocarbon resin 5%~10%, light trigger 5%~15%, dispersant 2%~5%, auxiliary agent 2%~10%.
The present invention also provides a kind of preparation method of waterborne UV coating, comprises the following steps.
Step 1, by mass percentage by 25%~35% urethane acrylate, 20%~30% epoxy acrylate and
5%~10% aqueous hyperbranched polyurethane is added in the container specified, and is carried out 2~5h of mechanical agitation, is filled these three materials
Divide mixing, the fluorocarbon resin powder and 2%~5% dispersant for then adding 5%~10% carry out 5~10h of mechanical agitation again,
So that fluorocarbon resin powder is dispersed in the solution, homogeneous solution is obtained.
Step 2, by 5%~15% light trigger and 2%~10% auxiliary agent, be added in step 1 gained homogeneous solution, continue
1~2h is stirred, until stirring, UV coating is produced.
The urethane acrylate is fluorochemical urethane acrylate.
The epoxy acrylate is bisphenol A epoxy acrylate and the mixture of aliphatic epoxy tetraacrylate, institute
The mass ratio for stating bisphenol A epoxy acrylate and aliphatic epoxy tetraacrylate is 4:5~9.
The light trigger is alpha, alpha-dimethyl epoxide-α-phenyl acetophenone, the oxidation of 2,4,6- trimethylbenzoy-diphenies
One kind in phosphine, 2- hydroxy-2-methyls -1- [4- (2- hydroxyl-oxethyls) phenyl] -1- acetone, alpha-hydroxyalkyl benzophenone.
The auxiliary agent is levelling agent, and the levelling agent is the mixing of silicone levelling agent and fluorine-carbon modified class levelling agent
The mass ratio of thing, the silicone levelling agent and fluorine-carbon modified class levelling agent is 5:2~4.
Beneficial effects of the present invention compared with prior art.
Waterborne UV coating that the present invention is provided and preparation method thereof, using fluorochemical urethane acrylate so that coating has
Have a higher water resistance and alcohol resistance, levelability preferably, curing rate also substantially accelerate, while the surface of coating is more after solidification
It is smooth；Meanwhile, the addition of the mixture of bisphenol-A epoxy acrylic resin and aliphatic epoxy tetraacrylate, not only causing should
Waterborne UV coating is substantially strengthened the adhesive force of matrix, and stress of aliphatic acrylate when alleviating curing of coating is received
Contracting, pliability, impact resistance to film play obvious action；The addition of aqueous hyperbranched polyurethane is effectively improved to be contained admittedly
Amount and the glossiness and richness of paint film；The addition of fluorocarbon resin causes the shortcoming of tradition UV coating loss of properties on agings to obtain
It is obviously improved, so that not only curing rate is faster for the waterborne UV coating, it is to avoid the generation of bubble in solidification process, and
It is the surface coating of a kind of ideal metal and woodenware with stronger anticorrosive, ageing-resistant and acid-proof alkaline.
Embodiment
The present invention is further described with reference to specific embodiment.
Embodiment 1.
The present embodiment provides a kind of waterborne UV coating, is made up of the raw material of following mass percent：Polyurethane propylene
Acid esters 30%, epoxy acrylate 25%, aqueous hyperbranched polyurethane 10%, fluorocarbon resin 10%, light trigger 15%, dispersant 5%,
Auxiliary agent 5%.
The urethane acrylate is fluorochemical urethane acrylate；The epoxy acrylate is mass ratio 4:6
The mixture of bisphenol A epoxy acrylate and aliphatic epoxy tetraacrylate；The auxiliary agent is mass ratio 5:3 organic silicon
The mixture of levelling agent and fluorine-carbon modified class levelling agent；The light trigger is alpha, alpha-dimethyl epoxide-α-phenyl acetophenone.
The present embodiment also provides a kind of preparation method of waterborne UV coating, comprises the following steps.
Step 1, by mass percentage by 30% fluorochemical urethane acrylate, 25% epoxy acrylate and 10%
Aqueous hyperbranched polyurethane is added in the container specified, and is carried out mechanical agitation 4h, is sufficiently mixed these three materials, Ran Houzai
The fluorocarbon resin powder and 5% dispersant for adding 10% carry out mechanical agitation 10h again so that fluorocarbon resin powder is dispersed
In the solution, homogeneous solution is obtained.
Step 2, by 15% alpha, alpha-dimethyl epoxide-α-phenyl acetophenone and 5% auxiliary agent, be added to step 1 gained homogeneous solution
In, continue to stir 2h, until stirring, produce UV coating.
Embodiment 2.
The present embodiment provides a kind of waterborne UV coating, is made up of the raw material of following mass percent：Polyurethane propylene
Acid esters 35%, epoxy acrylate 23%, aqueous hyperbranched polyurethane 7%, fluorocarbon resin 10%, light trigger 12%, dispersant 3%,
Auxiliary agent 10%.
Embodiment 3.
The present embodiment provides a kind of waterborne UV coating, is made up of the raw material of following mass percent：Polyurethane propylene
Acid esters 28%, epoxy acrylate 30%, aqueous hyperbranched polyurethane 7%, fluorocarbon resin 8%, light trigger 13%, dispersant 4%, help
Agent 10%.
Claims (4)
1. a kind of waterborne UV coating, it is characterised in that be made up of the raw material of following mass percent：Fluorochemical urethane propylene
The mixture 20%~30% of acid esters 25%~35%, bisphenol A epoxy acrylate and aliphatic epoxy tetraacrylate, aqueous over-expense
Change polyurethane 5%~10%, fluorocarbon resin 5%~10%, light trigger 5%~15%, dispersant 2%~5%, levelling agent 2%~10%；Institute
The mass ratio for stating bisphenol A epoxy acrylate and aliphatic epoxy tetraacrylate is 4:5~9.
2. waterborne UV coating as claimed in claim 1, it is characterised in that the light trigger is alpha, alpha-dimethyl epoxide-α-phenyl
Acetophenone, 2,4,6- trimethylbenzoy-diphenies phosphine oxide, 2- hydroxy-2-methyls -1- [4- (2- hydroxyl-oxethyls) benzene
Base] -1- acetone, one kind in alpha-hydroxyalkyl benzophenone.
3. waterborne UV coating as claimed in claim 1, it is characterised in that the levelling agent is silicone levelling agent and fluorine carbon
The mass ratio of the mixture of modified class levelling agent, the silicone levelling agent and fluorine-carbon modified class levelling agent is 5:2~4.
4. the preparation method of waterborne UV coating as claimed in claim 1, it is characterised in that comprise the following steps：
Step 1, by mass percentage by 25%~35% fluorochemical urethane acrylate, 20%~30% bisphenol-A epoxy propylene
Acid esters and the mixture and 5%~10% aqueous hyperbranched polyurethane of aliphatic epoxy tetraacrylate are added to the container specified
In, 2~5h of mechanical agitation is carried out, these three materials is sufficiently mixed, then adds 5%~10% fluorocarbon resin and 2%~5%
Dispersant carry out 5~10h of mechanical agitation again so that fluorocarbon resin is dispersed in the solution, obtains homogeneous solution；
Step 2, by 5%~15% light trigger and 2%~10% levelling agent, be added in step 1 gained homogeneous solution, continue to stir
1~2h is mixed, until stirring, UV coating is produced.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510937909.4A CN105331279B (en) | 2015-12-16 | 2015-12-16 | A kind of waterborne UV coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510937909.4A CN105331279B (en) | 2015-12-16 | 2015-12-16 | A kind of waterborne UV coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105331279A CN105331279A (en) | 2016-02-17 |
| CN105331279B true CN105331279B (en) | 2017-07-28 |
Family
ID=55282054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510937909.4A Active CN105331279B (en) | 2015-12-16 | 2015-12-16 | A kind of waterborne UV coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105331279B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107353804A (en) * | 2016-05-09 | 2017-11-17 | 中国林业科学研究院木材工业研究所 | A kind of environment-friendly type woodwork coating and preparation method thereof |
| CN107353805A (en) * | 2016-05-09 | 2017-11-17 | 中国林业科学研究院木材工业研究所 | A kind of water-based UV woodwork coatings and preparation method thereof |
| CN107903800A (en) * | 2017-10-31 | 2018-04-13 | 北京展辰新材料有限公司 | A kind of water-based UV varnish of large arch dam and preparation method and application |
| CN108587416B (en) * | 2018-05-08 | 2020-04-17 | 中科广化（重庆）新材料研究院有限公司 | Fluorine-containing prepolymer modified waterborne epoxy (methyl) acrylate composite UV (ultraviolet) curing coating and preparation and application thereof |
| CN109054562A (en) * | 2018-07-13 | 2018-12-21 | 安徽康瑞高科新材料技术工程有限公司 | A kind of waterborne UV coating and preparation method thereof |
| CN109749619B (en) * | 2018-12-28 | 2021-06-08 | 东来涂料技术（上海）股份有限公司 | Super-hydrophobic and stain-resistant water-based UV coating and preparation method thereof |
| WO2022088124A1 (en) * | 2020-10-30 | 2022-05-05 | 河北比尔尼克新材料科技股份有限公司 | Water-based fluorocarbon paint, preparation method therefor and use thereof |
| CN115260826A (en) * | 2022-09-26 | 2022-11-01 | 佛山市西伦化工有限公司 | Liquid photosensitive line ink and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418147A (en) * | 2008-12-11 | 2009-04-29 | 中国科学院长春应用化学研究所 | Waterborne ultraviolet-heat dual curing coating composite and preparation method thereof |
| CN101654570B (en) * | 2009-09-24 | 2011-05-04 | 中国海洋石油总公司 | Water-based ultraviolet curing coating |
| EP2365036A1 (en) * | 2010-03-12 | 2011-09-14 | Cytec Surface Specialties, S.A. | Radiation curable aqueous coating compositions |
| CN103160186A (en) * | 2011-12-13 | 2013-06-19 | 江苏钜儒电子有限公司 | Plastic surface aqueous photocurable coating |
| CN102702957B (en) * | 2012-06-21 | 2014-04-02 | 南京工业大学 | Water-based uv-curable composite paint for glass fiber insulating sleeve, and preparation method thereof |
| CN102766397A (en) * | 2012-07-03 | 2012-11-07 | 江苏天辅星光学材料有限公司 | Aqueous UV (Ultraviolet) coating |
-
2015
- 2015-12-16 CN CN201510937909.4A patent/CN105331279B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105331279A (en) | 2016-02-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105331279B (en) | A kind of waterborne UV coating and preparation method thereof | |
| CN101177553A (en) | Composite ultraviolet solidified aqueous coating and preparation method thereof | |
| CN107312134A (en) | A kind of dual cross-linking aqueous epoxy/polyacrylate hybridisation emulsion of room temperature and preparation method thereof | |
| CN104497814A (en) | Aldehyde-ketone resin modified unsaturated polyester primer and preparation method thereof | |
| CN109535960A (en) | Anticorrosive paint, corrosion-inhibiting coating and preparation method thereof | |
| WO2019127442A1 (en) | Aqueous coating and preparation method therefor | |
| CN107011770A (en) | A kind of self-drying paint aqueous epoxy resins and preparation method and application | |
| CN110183946A (en) | A kind of EB is coating material solidified, preparation method and applications | |
| CN102719188B (en) | Hydrophilic aluminum foil coating with integrated bottom and top and preparation method thereof | |
| JPWO2005010095A1 (en) | Two-component plastisol composition and method of use thereof | |
| CN109180877A (en) | Plastic paint waterborne epoxy modified acrylic resin and preparation method thereof | |
| CN106634085A (en) | Low-odor ultraviolet light polymerization acrylic coating and preparation technique thereof | |
| CN102675530A (en) | Novel aqueous acrylic acid modified alicyclic epoxy emulsion and preparation method thereof | |
| CN103589295A (en) | Leveling-free ultraviolet curing primer | |
| CN103849299A (en) | Electrostatic spraying PE op-coat paint | |
| CN101235245A (en) | Method for preparing silicone-acrylate dope | |
| CN106752723A (en) | A kind of water-base epoxy antiseptic varnish and preparation method thereof | |
| RU2017123116A (en) | POWDER MIXTURE CONTAINING ORGANIC PEROXIDE | |
| WO2015127794A1 (en) | Photocuring coating and preparation method therefor | |
| CN103421415A (en) | Ultraviolet light curing hydrophilic aluminum foil paint and preparation method thereof | |
| CN107641468A (en) | A kind of water proof fire retardant powdery paints and preparation method thereof | |
| CN107353804A (en) | A kind of environment-friendly type woodwork coating and preparation method thereof | |
| CN103589302A (en) | Low-odor ultraviolet curing primer | |
| JP4633998B2 (en) | Acrylic lightweight curable composition | |
| CN110423496A (en) | Low-light curing and anticorrosive coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 110141 Yao village, Yuhong Township, Yuhong District, Liaoning, Shenyang Applicant after: Shenyang Shunfeng New Materials Co., Ltd Address before: 110141 Yao village, Yuhong Township, Yuhong District, Liaoning, Shenyang Applicant before: Shenyang Shunfeng Metro Building Materials Co., Ltd. |
|
| COR | Change of bibliographic data | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 110141 Yao village, Yuhong Township, Yuhong District, Liaoning, Shenyang Patentee after: Liaoning Shunfeng New Material Technology Co.,Ltd. Address before: 110141 Yao village, Yuhong Township, Yuhong District, Liaoning, Shenyang Patentee before: SHENYANG SHUNFENG NEW MATERIAL Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder |