CN104497849B - Ultraviolet light polymerization antiskid elastic floor paint and method - Google Patents

Ultraviolet light polymerization antiskid elastic floor paint and method Download PDF

Info

Publication number
CN104497849B
CN104497849B CN201510005892.9A CN201510005892A CN104497849B CN 104497849 B CN104497849 B CN 104497849B CN 201510005892 A CN201510005892 A CN 201510005892A CN 104497849 B CN104497849 B CN 104497849B
Authority
CN
China
Prior art keywords
ultraviolet light
light polymerization
floor paint
elastic floor
antiskid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201510005892.9A
Other languages
Chinese (zh)
Other versions
CN104497849A (en
Inventor
段利刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TONG JOU CHEMICAL INDUSTRIAL (KUNSHAN) Co Ltd
Original Assignee
TONG JOU CHEMICAL INDUSTRIAL (KUNSHAN) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TONG JOU CHEMICAL INDUSTRIAL (KUNSHAN) Co Ltd filed Critical TONG JOU CHEMICAL INDUSTRIAL (KUNSHAN) Co Ltd
Priority to CN201510005892.9A priority Critical patent/CN104497849B/en
Publication of CN104497849A publication Critical patent/CN104497849A/en
Application granted granted Critical
Publication of CN104497849B publication Critical patent/CN104497849B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D193/00Coating compositions based on natural resins; Coating compositions based on derivatives thereof
    • C09D193/04Rosin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention relates to a kind of ultraviolet light polymerization antiskid elastic floor paint and method, the paint is made up of the component of following weight percentage:Urethane acrylate 10%~40%;Epoxy acrylate 10%~20%;Modified rosin resin 15~25%, reactive amines 2%~7%;1 hydroxycyclohexylphenyl acetone 2%~7%;Trimethylolpropane trimethacrylate 5%~15%;Tripropylene glycol diacrylate 10%~30%;1,6 hexanediyl ester 2%~10%, elastic powder 3%~5%, face produces tiny weavy grain when paint film of the present invention has larger frictional force and solidification, and lacquer painting is attractive in appearance and provides more preferable coefficient of friction, and further increase lacquer painting frictional force, reaches skidproof effect.Solvent is free of in product, it is environmentally friendly, it is particularly suited for nursing homes, kindergarten's interior decoration.

Description

Ultraviolet light polymerization antiskid elastic floor paint and method
Technical field
The ultraviolet light polymerization antiskid elastic floor paint on floor can be used the present invention relates to a kind of
Background technology
With the continuous improvement and the continuous progress of science and technology of the living standard of people, domestic and international customer demand is used on ground Finish paint on plate possess it is persistently wear-resisting after environmental protection, surface lacquer be difficult the features such as scratching, but traditional wear-resistant paint is often It is solvent based coating, it is more difficult to process, is difficult quick production.And conventional anti skid floor can be by delineating or imprinting concavo-convex on floor The non-slip groove of 2mm~5mm, it is more difficult that this is not only processed, and is not easy to quick production, and decorative effect and unsightly.
The content of the invention
The technical problems to be solved by the invention are to overcome the deficiencies in the prior art, there is provided a kind of UV-curing chemoprevention Sliding resiliently-mounted floor paint and method.
To solve above technical problem, the present invention is adopted the following technical scheme that:A kind of ultraviolet light polymerization antiskid elastic floor Paint, the component composition that it includes weight percentage:Urethane acrylate 10%~40%;Epoxy acrylate 10%~ 20%;Modified rosin resin 15~25%;Reactive amines 2%~7%;1- hydroxycyclohexylphenyls acetone 2%~7%;Three hydroxyl first Base propane triacrylate 5%~15%;Tripropylene glycol diacrylate 10%~30%;1,6- hexanediyl ester 2%~10%;Elastic powder 3%~5%.
On the basis of above-mentioned technical proposal, following attached technical scheme is further included:
Described urethane acrylate is 2 officials or 3 official's urethane acrylates.
Described modified rosin resin is maleic acid modified or phenolic -modified abietic resin.
Described elastic powder is that particle diameter is the elastic polyurethane powder of 4um~40um.
A kind of preparation method of the ultraviolet light polymerization antiskid elastic floor paint, it puts into polyurethane successively in tank diameter Acrylate, epoxy acrylate, modified rosin resin, reactive amines, 1- hydroxycyclohexylphenyls acetone, trimethylolpropane tris Acrylate, tripropylene glycol diacrylate, 1,6- hexanediyl esters, 1000 revs/min of the rotating speed of mixer, stirring 30 minutes, elastic powder is added after above-mentioned material is sufficiently mixed uniformly, in stirring, 1500 revs/min are stirred for obtaining final product for 60 minutes Ultraviolet light polymerization antiskid elastic floor paint.
The ultraviolet light polymerization antiskid elastic floor paint by roll coater be coated with will in plate surface, coating weight is 8~ 20g/m2, then solidify by uv cure machine, solidification energy is 200~600mj/cm2
Due to using above-mentioned technical proposal, the rosin resin that film is used in the present invention has larger frictional force, while Using reactive amines and 1- hydroxycyclohexylphenyl acetone, cause film top layer different with bottom curing rate, generate below 2mm Elastic weavy grain and salient point, lacquer painting frictional force is further increased by elastic weavy grain and salient point, reaches skidproof effect, while can be with profit Quickly produced with existing floor production line, without doing stiff groove rag in wood surface, embodied timber natural in itself Texture, is free of solvent in beautiful decoration, and product, environmentally friendly, is particularly suited for nursing homes, kindergarten's interior decoration.
Specific embodiment
Embodiment:The present invention provides a kind of specific embodiment of ultraviolet light polymerization antiskid elastic floor paint, its component according to Following different embodiments and the corresponding proportioning of content by weight, refer to table 1:
Table 1
Embodiment one Embodiment two Embodiment three Example IV
Urethane acrylate 15 20 35 40
Epoxy acrylate 20 10 10 10
Modified rosin resin 15 20 25 20
Reactive amines 4 5 3 5
1- hydroxycyclohexylphenyl acetone 5 5 2 2
Trimethylolpropane trimethacrylate 12 5 5 4
Tripropylene glycol diacrylate 15 27 15 13
1,6- hexanediyl ester 10 5 2 2
Elastic powder 4 3 3 4
Formula in above-described embodiment, its specific preparation method is:Put into polyurethane propylene successively in tank diameter Acid esters, epoxy acrylate, modified rosin resin, reactive amines, 1- hydroxycyclohexylphenyls acetone, trimethylolpropane tris propylene Acid esters, tripropylene glycol diacrylate, 1,6- hexanediyl esters, 1000 revs/min of the rotating speed of mixer stir 30 points Clock, make above-mentioned material be sufficiently mixed it is uniform after, add elastic powder in stirring, 1500 revs/min be stirred for obtaining final product for 60 minutes it is ultraviolet Photocuring antiskid elastic floor paint, the performance parameter for being obtained compares with common finish paint, refers to table 2:
Table 2
Thus by ultraviolet light polymerization antiskid elastic floor paint in the present invention, by roll coater be coated with will in plate surface, It is capable of achieving by uv cure machine solidification again, it is possible to quickly produced using existing floor production line.
The present invention is described in detail above, its object is to allow the personage for being familiar with this art to will appreciate that this The content of invention is simultaneously carried out, and it is not intended to limit the scope of the present invention, all Spirit Essence institutes of the invention The equivalent change or modification of work, should all cover within the scope of the present invention.

Claims (6)

1. a kind of ultraviolet light polymerization antiskid elastic floor paint, it is characterised in that it includes following component by weight percentage:Poly- ammonia Ester acrylate 10%~40%;Epoxy acrylate 10%~20%;Modified rosin resin 15~25%;Reactive amines 2%~ 7%;1- hydroxycyclohexylphenyls acetone 2%~7%;Trimethylolpropane trimethacrylate 5%~15%;Tripropylene glycol dipropyl Olefin(e) acid ester 10%~30%;1,6 hexanediol diacrylate 2%~10%;Elastic powder 3%~5%.
2. ultraviolet light polymerization antiskid elastic floor paint according to claim 1, it is characterised in that:Described polyurethane propylene Acid esters is 2 officials or 3 official's urethane acrylates.
3. ultraviolet light polymerization antiskid elastic floor paint according to claim 1, it is characterised in that:Described modified rosin tree Fat is maleic acid modified or phenolic -modified abietic resin.
4. ultraviolet light polymerization antiskid elastic floor paint according to claim 1, it is characterised in that:Described elastic powder is grain Footpath is the elastic polyurethane powder of 4um~40um.
5. a kind of preparation method of the ultraviolet light polymerization antiskid elastic floor paint as described in claim 1 or 2 or 3, it is characterised in that: Put into urethane acrylate, epoxy acrylate, modified rosin resin, reactive amines, 1- hydroxy cyclohexylphenyls successively in tank diameter Base phenylacetone, trimethylolpropane trimethacrylate, tripropylene glycol diacrylate, 1,6- hexanediyl esters, stir 1000 revs/min of the rotating speed of machine is mixed, is stirred 30 minutes, elastic powder is added after above-mentioned material is sufficiently mixed uniformly, in stirring, 1500 revs/min are stirred for obtaining final product within 60 minutes ultraviolet light polymerization antiskid elastic floor paint.
6. the preparation method of ultraviolet light polymerization antiskid elastic floor paint as claimed in claim 5, it is characterised in that:The ultraviolet light Solidification antiskid elastic floor paint coats plate surface by roll coater, and coating weight is 8~20g/m2, then by ultraviolet light polymerization Machine completion of cure, solidification energy is 200~600mj/cm2
CN201510005892.9A 2015-01-07 2015-01-07 Ultraviolet light polymerization antiskid elastic floor paint and method Active CN104497849B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510005892.9A CN104497849B (en) 2015-01-07 2015-01-07 Ultraviolet light polymerization antiskid elastic floor paint and method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510005892.9A CN104497849B (en) 2015-01-07 2015-01-07 Ultraviolet light polymerization antiskid elastic floor paint and method

Publications (2)

Publication Number Publication Date
CN104497849A CN104497849A (en) 2015-04-08
CN104497849B true CN104497849B (en) 2017-05-31

Family

ID=52939310

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510005892.9A Active CN104497849B (en) 2015-01-07 2015-01-07 Ultraviolet light polymerization antiskid elastic floor paint and method

Country Status (1)

Country Link
CN (1) CN104497849B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105921378A (en) * 2016-04-21 2016-09-07 苏州群力防滑材料有限公司 Manufacturing method for anti-sliding plate
CN106118385B (en) * 2016-08-23 2018-03-27 佛山阳光逸采涂料科技有限公司 A kind of UV LED low energy solidification mahogany furniture coating and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445679A (en) * 2008-12-25 2009-06-03 四川大学 UV-light solidifying paint having decorative effect and preparation method thereof
CN101638554A (en) * 2009-05-06 2010-02-03 佛山市顺德区希贵光固化材料有限公司 Ultraviolet curing coating
CN101851466A (en) * 2010-06-02 2010-10-06 长沙华良涂料有限公司 Antistatic abrasion-resistant UV coating and preparation method thereof
CN102190938A (en) * 2010-03-19 2011-09-21 刘立新 High-wear-resistance antiscratch and antifouling solid wood board ultraviolet (UV) curable coating system
CN103602258A (en) * 2013-12-06 2014-02-26 东周化学工业(昆山)有限公司 Ultraviolet-curing finish coat adhesive

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103709906B (en) * 2014-01-15 2016-08-24 东周化学工业(昆山)有限公司 Ultraviolet light polymerization white finish paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445679A (en) * 2008-12-25 2009-06-03 四川大学 UV-light solidifying paint having decorative effect and preparation method thereof
CN101638554A (en) * 2009-05-06 2010-02-03 佛山市顺德区希贵光固化材料有限公司 Ultraviolet curing coating
CN102190938A (en) * 2010-03-19 2011-09-21 刘立新 High-wear-resistance antiscratch and antifouling solid wood board ultraviolet (UV) curable coating system
CN101851466A (en) * 2010-06-02 2010-10-06 长沙华良涂料有限公司 Antistatic abrasion-resistant UV coating and preparation method thereof
CN103602258A (en) * 2013-12-06 2014-02-26 东周化学工业(昆山)有限公司 Ultraviolet-curing finish coat adhesive

Also Published As

Publication number Publication date
CN104497849A (en) 2015-04-08

Similar Documents

Publication Publication Date Title
CN103958213B (en) A kind of method of printing on wall or floor panel
CN102080440B (en) Concave-convex obvious texture solid floor and manufacturing method thereof
CN102587616B (en) Energy-saving and environment-friendly floor with low energy consumption and preparation method and using method of floor
CN103694862A (en) UV (Ultraviolet) curing white primer for laser roller painting of woodware and preparation and application methods thereof
CN104497849B (en) Ultraviolet light polymerization antiskid elastic floor paint and method
CN107384182B (en) Outdoor heavy bamboo-wood floor and preparation method thereof
CN201753515U (en) Ultraviolet light curing direct-printing ink simulation wood grain floor
CN105419623B (en) A kind of multifunctional aqueous UV varnish and its preparation and application method
CN103317580B (en) Production method of high-hardness and high-wear-resistance solid wood composite floor
CN104031548A (en) Finish paint with pitted surface effect and preparation method thereof
CN104493940A (en) Veneer UV-painting (ultraviolet painting) method
CN102535814B (en) Fluorescent floor, preparation method and using method thereof
CN102816467A (en) Release paint for artificial leather and release paper prepared by utilizing release paint
CN102430504A (en) Construction method for preventing paint film of ultraviolet curing paint from blushing
CN104476646A (en) Method for spraying PUR+UV paint on wood veneer
CN103802416B (en) High bright wear-resisting building materials and ornaments film and production method thereof
CN201972358U (en) Moistened floor
CN105820720A (en) UV curing coating for PVC material coating process and preparation method for UV curing material
CN104559620A (en) PU matte color repairing golden oil and preparation process thereof
CN201162328Y (en) Novel wooden floor
CN203611633U (en) Ultraviolet photocuring coating decorative board
CN101474934A (en) Method for producing artificial grain on surface of house article
CN201865299U (en) Concave-convex grain solid wood floor
CN107987684A (en) Can not sanding recoating woodenware with high attachment UV environment-friendly spray coating based white primers
CN202039535U (en) Composite floor sheet

Legal Events

Date Code Title Description
PB01 Publication
C06 Publication
SE01 Entry into force of request for substantive examination
C10 Entry into substantive examination
GR01 Patent grant
GR01 Patent grant