CN104497849B - Ultraviolet light polymerization antiskid elastic floor paint and method - Google Patents

Ultraviolet light polymerization antiskid elastic floor paint and method Download PDF

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Publication number
CN104497849B
CN104497849B CN201510005892.9A CN201510005892A CN104497849B CN 104497849 B CN104497849 B CN 104497849B CN 201510005892 A CN201510005892 A CN 201510005892A CN 104497849 B CN104497849 B CN 104497849B
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China
Prior art keywords
ultraviolet light
light polymerization
floor paint
elastic floor
antiskid
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CN201510005892.9A
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CN104497849A (en
Inventor
段利刚
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TONG JOU CHEMICAL INDUSTRIAL (KUNSHAN) Co Ltd
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TONG JOU CHEMICAL INDUSTRIAL (KUNSHAN) Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
    • C09D193/04—Rosin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention relates to a kind of ultraviolet light polymerization antiskid elastic floor paint and method, the paint is made up of the component of following weight percentage：Urethane acrylate 10%~40%；Epoxy acrylate 10%~20%；Modified rosin resin 15~25%, reactive amines 2%~7%；1 hydroxycyclohexylphenyl acetone 2%~7%；Trimethylolpropane trimethacrylate 5%~15%；Tripropylene glycol diacrylate 10%~30%；1,6 hexanediyl ester 2%~10%, elastic powder 3%~5%, face produces tiny weavy grain when paint film of the present invention has larger frictional force and solidification, and lacquer painting is attractive in appearance and provides more preferable coefficient of friction, and further increase lacquer painting frictional force, reaches skidproof effect.Solvent is free of in product, it is environmentally friendly, it is particularly suited for nursing homes, kindergarten's interior decoration.

Description

Ultraviolet light polymerization antiskid elastic floor paint and method
Technical field
The ultraviolet light polymerization antiskid elastic floor paint on floor can be used the present invention relates to a kind of
Background technology
With the continuous improvement and the continuous progress of science and technology of the living standard of people, domestic and international customer demand is used on ground Finish paint on plate possess it is persistently wear-resisting after environmental protection, surface lacquer be difficult the features such as scratching, but traditional wear-resistant paint is often It is solvent based coating, it is more difficult to process, is difficult quick production.And conventional anti skid floor can be by delineating or imprinting concavo-convex on floor The non-slip groove of 2mm~5mm, it is more difficult that this is not only processed, and is not easy to quick production, and decorative effect and unsightly.
The content of the invention
The technical problems to be solved by the invention are to overcome the deficiencies in the prior art, there is provided a kind of UV-curing chemoprevention Sliding resiliently-mounted floor paint and method.
To solve above technical problem, the present invention is adopted the following technical scheme that：A kind of ultraviolet light polymerization antiskid elastic floor Paint, the component composition that it includes weight percentage：Urethane acrylate 10%~40%；Epoxy acrylate 10%~ 20%；Modified rosin resin 15~25%；Reactive amines 2%~7%；1- hydroxycyclohexylphenyls acetone 2%~7%；Three hydroxyl first Base propane triacrylate 5%~15%；Tripropylene glycol diacrylate 10%~30%；1,6- hexanediyl ester 2%~10%；Elastic powder 3%~5%.
On the basis of above-mentioned technical proposal, following attached technical scheme is further included：
Described urethane acrylate is 2 officials or 3 official's urethane acrylates.
Described modified rosin resin is maleic acid modified or phenolic -modified abietic resin.
Described elastic powder is that particle diameter is the elastic polyurethane powder of 4um~40um.
A kind of preparation method of the ultraviolet light polymerization antiskid elastic floor paint, it puts into polyurethane successively in tank diameter Acrylate, epoxy acrylate, modified rosin resin, reactive amines, 1- hydroxycyclohexylphenyls acetone, trimethylolpropane tris Acrylate, tripropylene glycol diacrylate, 1,6- hexanediyl esters, 1000 revs/min of the rotating speed of mixer, stirring 30 minutes, elastic powder is added after above-mentioned material is sufficiently mixed uniformly, in stirring, 1500 revs/min are stirred for obtaining final product for 60 minutes Ultraviolet light polymerization antiskid elastic floor paint.
The ultraviolet light polymerization antiskid elastic floor paint by roll coater be coated with will in plate surface, coating weight is 8~ 20g/m2, then solidify by uv cure machine, solidification energy is 200~600mj/cm2。
Due to using above-mentioned technical proposal, the rosin resin that film is used in the present invention has larger frictional force, while Using reactive amines and 1- hydroxycyclohexylphenyl acetone, cause film top layer different with bottom curing rate, generate below 2mm Elastic weavy grain and salient point, lacquer painting frictional force is further increased by elastic weavy grain and salient point, reaches skidproof effect, while can be with profit Quickly produced with existing floor production line, without doing stiff groove rag in wood surface, embodied timber natural in itself Texture, is free of solvent in beautiful decoration, and product, environmentally friendly, is particularly suited for nursing homes, kindergarten's interior decoration.
Specific embodiment
Embodiment：The present invention provides a kind of specific embodiment of ultraviolet light polymerization antiskid elastic floor paint, its component according to Following different embodiments and the corresponding proportioning of content by weight, refer to table 1：
Table 1
Embodiment one Embodiment two Embodiment three Example IV
Urethane acrylate 15 20 35 40
Epoxy acrylate 20 10 10 10
Modified rosin resin 15 20 25 20
Reactive amines 4 5 3 5
1- hydroxycyclohexylphenyl acetone 5 5 2 2
Trimethylolpropane trimethacrylate 12 5 5 4
Tripropylene glycol diacrylate 15 27 15 13
1,6- hexanediyl ester 10 5 2 2
Elastic powder 4 3 3 4
Formula in above-described embodiment, its specific preparation method is：Put into polyurethane propylene successively in tank diameter Acid esters, epoxy acrylate, modified rosin resin, reactive amines, 1- hydroxycyclohexylphenyls acetone, trimethylolpropane tris propylene Acid esters, tripropylene glycol diacrylate, 1,6- hexanediyl esters, 1000 revs/min of the rotating speed of mixer stir 30 points Clock, make above-mentioned material be sufficiently mixed it is uniform after, add elastic powder in stirring, 1500 revs/min be stirred for obtaining final product for 60 minutes it is ultraviolet Photocuring antiskid elastic floor paint, the performance parameter for being obtained compares with common finish paint, refers to table 2：
Table 2
Thus by ultraviolet light polymerization antiskid elastic floor paint in the present invention, by roll coater be coated with will in plate surface, It is capable of achieving by uv cure machine solidification again, it is possible to quickly produced using existing floor production line.
The present invention is described in detail above, its object is to allow the personage for being familiar with this art to will appreciate that this The content of invention is simultaneously carried out, and it is not intended to limit the scope of the present invention, all Spirit Essence institutes of the invention The equivalent change or modification of work, should all cover within the scope of the present invention.

Claims (6)

1. a kind of ultraviolet light polymerization antiskid elastic floor paint, it is characterised in that it includes following component by weight percentage：Poly- ammonia Ester acrylate 10%~40%；Epoxy acrylate 10%~20%；Modified rosin resin 15~25%；Reactive amines 2%~ 7%；1- hydroxycyclohexylphenyls acetone 2%~7%；Trimethylolpropane trimethacrylate 5%~15%；Tripropylene glycol dipropyl Olefin(e) acid ester 10%~30%；1,6 hexanediol diacrylate 2%~10%；Elastic powder 3%~5%.
2. ultraviolet light polymerization antiskid elastic floor paint according to claim 1, it is characterised in that：Described polyurethane propylene Acid esters is 2 officials or 3 official's urethane acrylates.
3. ultraviolet light polymerization antiskid elastic floor paint according to claim 1, it is characterised in that：Described modified rosin tree Fat is maleic acid modified or phenolic -modified abietic resin.
4. ultraviolet light polymerization antiskid elastic floor paint according to claim 1, it is characterised in that：Described elastic powder is grain Footpath is the elastic polyurethane powder of 4um~40um.
5. a kind of preparation method of the ultraviolet light polymerization antiskid elastic floor paint as described in claim 1 or 2 or 3, it is characterised in that： Put into urethane acrylate, epoxy acrylate, modified rosin resin, reactive amines, 1- hydroxy cyclohexylphenyls successively in tank diameter Base phenylacetone, trimethylolpropane trimethacrylate, tripropylene glycol diacrylate, 1,6- hexanediyl esters, stir 1000 revs/min of the rotating speed of machine is mixed, is stirred 30 minutes, elastic powder is added after above-mentioned material is sufficiently mixed uniformly, in stirring, 1500 revs/min are stirred for obtaining final product within 60 minutes ultraviolet light polymerization antiskid elastic floor paint.
6. the preparation method of ultraviolet light polymerization antiskid elastic floor paint as claimed in claim 5, it is characterised in that：The ultraviolet light Solidification antiskid elastic floor paint coats plate surface by roll coater, and coating weight is 8~20g/m2, then by ultraviolet light polymerization Machine completion of cure, solidification energy is 200~600mj/cm2。
CN201510005892.9A 2015-01-07 2015-01-07 Ultraviolet light polymerization antiskid elastic floor paint and method Active CN104497849B (en)

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Publication number Priority date Publication date Assignee Title
CN105921378A (en) * 2016-04-21 2016-09-07 苏州群力防滑材料有限公司 Manufacturing method for anti-sliding plate
CN106118385B (en) * 2016-08-23 2018-03-27 佛山阳光逸采涂料科技有限公司 A kind of UV LED low energy solidification mahogany furniture coating and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445679A (en) * 2008-12-25 2009-06-03 四川大学 UV-light solidifying paint having decorative effect and preparation method thereof
CN101638554A (en) * 2009-05-06 2010-02-03 佛山市顺德区希贵光固化材料有限公司 Ultraviolet curing coating
CN101851466A (en) * 2010-06-02 2010-10-06 长沙华良涂料有限公司 Antistatic abrasion-resistant UV coating and preparation method thereof
CN102190938A (en) * 2010-03-19 2011-09-21 刘立新 High-wear-resistance antiscratch and antifouling solid wood board ultraviolet (UV) curable coating system
CN103602258A (en) * 2013-12-06 2014-02-26 东周化学工业（昆山）有限公司 Ultraviolet-curing finish coat adhesive

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103709906B (en) * 2014-01-15 2016-08-24 东周化学工业（昆山）有限公司 Ultraviolet light polymerization white finish paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445679A (en) * 2008-12-25 2009-06-03 四川大学 UV-light solidifying paint having decorative effect and preparation method thereof
CN101638554A (en) * 2009-05-06 2010-02-03 佛山市顺德区希贵光固化材料有限公司 Ultraviolet curing coating
CN102190938A (en) * 2010-03-19 2011-09-21 刘立新 High-wear-resistance antiscratch and antifouling solid wood board ultraviolet (UV) curable coating system
CN101851466A (en) * 2010-06-02 2010-10-06 长沙华良涂料有限公司 Antistatic abrasion-resistant UV coating and preparation method thereof
CN103602258A (en) * 2013-12-06 2014-02-26 东周化学工业（昆山）有限公司 Ultraviolet-curing finish coat adhesive

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