CN103525258A - UV (ultraviolet) curing transparent priming paint and preparation method thereof - Google Patents
UV (ultraviolet) curing transparent priming paint and preparation method thereof Download PDFInfo
- Publication number
- CN103525258A CN103525258A CN201310456933.7A CN201310456933A CN103525258A CN 103525258 A CN103525258 A CN 103525258A CN 201310456933 A CN201310456933 A CN 201310456933A CN 103525258 A CN103525258 A CN 103525258A
- Authority
- CN
- China
- Prior art keywords
- parts
- priming paint
- add
- preparation
- stir
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses UV curing transparent priming paint which comprises raw materials in parts by weight as follows: 30-35 parts of epoxy acrylate, 10-15 parts of acetic ether, 2-3 parts of polytetrafluoroethylene, 30-35 parts of urethane acrylate, 2-3 parts of allyloxy nonyl phenoxy propyl alcohol polyoxyethylene ether, 10-12 parts of tripropylene glycol diacrylate, 1-2 parts of phenyl glycidyl ether, 5-10 parts of propylene glycol methyl ether acetate, 2-5 parts of polydimethylsiloxane, 4-5 parts of a photoinitiator 1173, 1-2 parts of N-methylol acrylamide, 2-3 parts of polyethylene glycol, 1-2 parts of stannous chloride and 4-5 parts of a dispersing auxiliary. The provided priming paint utilizes epoxy acrylate, thereby having high curing speed and good water resistance, hot water resistance, drug resistance, cohesiveness and toughness; besides, the dispersing auxiliary is adopted by the priming paint, so that the priming paint has the characteristics of high curing speed and flat formed film; and the prepared paint is free of activation period, has good abundance ratio, high drying speed, high production efficiency and few organic volatile matters and is simple and convenient to construct.
Description
Technical field
The invention belongs to paint field, relate in particular to a kind of UV photocuring transparent priming and preparation method thereof.
Background technology
Development along with market economy, there is great variety in paint field, wherein UV coating has the advantages such as curing speed is fast, energy-conservation, ambient cure, superior performance, environmental protection, on it, ray velocity is fast, rete luminance brightness is high, and dry rear face is firm heat-resisting, and refractive power is effective, make ground produce strong main body sense, be widely used in the fields such as chemical industry, machinery, electronics light industry, communication.Due to its environment-friendly advantage, UV solidifies and to have obtained the strong support of relevant environment rules and the close attention of industry member, and UV radiation curing material is in market requirement rapid growth, and UV Radiation-curing system is just with multiple technologies combination, to overcome some defect, meet actual application.Now in printing industry; the packing that can make UV obtains some special effects: high glossiness, good ink protection feature, the slipping that can add control and rub resistance, low smell or do not have smell, low extract maybe cannot detect extract, and the provide protection to ink.
Current UV solidify material is various, but still in various degree exist some problems, such as: Organic pollutants, xanthochromia, explosive look, not low temperature resistant, the series of problems such as cost is high, corrosion-resistant, all need to continue improvement for different purposes, reduce production costs, expand purposes.
Summary of the invention
The object of the present invention is to provide a kind of UV photocuring transparent priming and preparation method thereof, this coating has that sticking power is good, hardness is high, the good advantage of levelling.
Technical scheme of the present invention is as follows:
A photocuring transparent priming, is characterized in that being made by the raw material of following weight part: epoxy acrylate 30-35, vinyl acetic monomer 10-15, tetrafluoroethylene 2-3, urethane acrylate 30-35, allyloxy Nonylphenoxy propyl alcohol Soxylat A 25-7 2-3, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2,1-Methoxy-2-propyl acetate 5-10, polydimethylsiloxane 2-5, light trigger 1173 4-5, N hydroxymethyl acrylamide 1-2, polyoxyethylene glycol 2-3, tin protochloride 1-2, dispersing auxiliary 4-5;
Described dispersing auxiliary is made by the raw material of following weight part: attapulgite 7-9, jade 2-3, xitix 1-2, Silane coupling agent KH550 1-2, propylene glycol phenylate 3-4, peroxidized t-butyl perbenzoate 0.2-0.3, vinylbenzene 1-2, dipropylene glycol 1-2, TriMethylolPropane(TMP) 2-3, ethyl acetate 22-25; Preparation method puts into calcining furnace by attapulgite, jade, at 670-700 ℃, calcines 3-4 hour, takes out, and puts into 10-15% hydrochloric acid soln and is ground to 20-40 μ m slurry, and the material pH value of sizing mixing is for neutral, and spraying is dry; Vinylbenzene, dipropylene glycol, TriMethylolPropane(TMP), ethyl acetate are mixed, be heated to 40-50 ℃, add peroxidized t-butyl perbenzoate, stir 40-50 minute; Then, add other composition, continue to be warming up to 70-80 ℃, add attapulgite, jade powder and other remaining component, stirring reaction 1-2 hour, obtains.
The preparation method of described UV photocuring transparent priming, it is characterized in that comprising the following steps: other composition except light trigger 1173 is mixed, be heated to 50-60 ℃, under 600-700 rev/min, stir 10-20 minute, cool to 40 ℃ and add again below light trigger 1173, continue to stir 15-20 minute, obtain.
Beneficial effect of the present invention
Priming paint provided by the invention, has been used epoxy acrylate, has quick solidifying, excellent water tolerance, hot water resistance, resistance physical property, cohesiveness, toughness; In addition this priming paint has been used dispersing auxiliary, has quick solidifying, the feature that film forming is smooth; The paint preparing without pot-life, fullness ratio is good, rate of drying is fast, production efficiency is high, organic volatile is few, it is simple and convenient to construct.
Embodiment
A photocuring transparent priming, by following weight part (kilogram) raw material make: epoxy acrylate 33, vinyl acetic monomer 13, tetrafluoroethylene 2, urethane acrylate 32, allyloxy Nonylphenoxy propyl alcohol Soxylat A 25-7 2, tri (propylene glycol) diacrylate 11, phenyl glycidyl ether 1.5,1-Methoxy-2-propyl acetate 7, polydimethylsiloxane 4, light trigger 1,173 4, N hydroxymethyl acrylamide 1.5, polyoxyethylene glycol 2.6, tin protochloride 1.5, dispersing auxiliary 4;
Described dispersing auxiliary by following weight part (kilogram) raw material make: attapulgite 8, jade 2, xitix 1, Silane coupling agent KH550 1, propylene glycol phenylate 3, peroxidized t-butyl perbenzoate 0.2, vinylbenzene 1, dipropylene glycol 1, TriMethylolPropane(TMP) 2, ethyl acetate 23; Preparation method puts into calcining furnace by attapulgite, jade, calcines 3.6 hours at 690 ℃, takes out, and puts into 13% hydrochloric acid soln and is ground to 30 μ m slurries, and the material pH value of sizing mixing is for neutral, and spraying is dry; Vinylbenzene, dipropylene glycol, TriMethylolPropane(TMP), ethyl acetate are mixed, be heated to 45 ℃, add peroxidized t-butyl perbenzoate, stir 46 minutes; Then, add other composition, continue to be warming up to 74 ℃, add attapulgite, jade powder and other remaining component, stirring reaction 1.5 hours, obtains.
The preparation method of described UV photocuring transparent priming, comprises the following steps: other composition except light trigger 1173 is mixed, be heated to 50-60 ℃, under 600-700 rev/min, stir 10-20 minute, cool to 32 ℃ and add again light trigger 1173, continue to stir 15-20 minute, obtain.
This UV photocuring transparent priming can adopt the form of construction work of roller coating, showering, spraying to construct.The primer painting making by above scheme sticking power on plank is all better than secondary, resistance to 75% ethanol is more than 24 hours, alkaline-resisting 24 hours above, acidproof more than 48 hours, the cold cycling that tolerates subzero 40 degree and 40 degree does not ftracture for 10 times, resistance to 15% salt solution is more than 60 hours, hardness can regulate between 3H at 2HB, and abrasion resistance index turns above 3000.
Claims (2)
1. a UV photocuring transparent priming, is characterized in that being made by the raw material of following weight part: epoxy acrylate 30-35, vinyl acetic monomer 10-15, tetrafluoroethylene 2-3, urethane acrylate 30-35, allyloxy Nonylphenoxy propyl alcohol Soxylat A 25-7 2-3, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2,1-Methoxy-2-propyl acetate 5-10, polydimethylsiloxane 2-5, light trigger 1173 4-5, N hydroxymethyl acrylamide 1-2, polyoxyethylene glycol 2-3, tin protochloride 1-2, dispersing auxiliary 4-5;
Described dispersing auxiliary is made by the raw material of following weight part: attapulgite 7-9, jade 2-3, xitix 1-2, Silane coupling agent KH550 1-2, propylene glycol phenylate 3-4, peroxidized t-butyl perbenzoate 0.2-0.3, vinylbenzene 1-2, dipropylene glycol 1-2, TriMethylolPropane(TMP) 2-3, ethyl acetate 22-25; Preparation method puts into calcining furnace by attapulgite, jade, at 670-700 ℃, calcines 3-4 hour, takes out, and puts into 10-15% hydrochloric acid soln and is ground to 20-40 μ m slurry, and the material pH value of sizing mixing is for neutral, and spraying is dry; Vinylbenzene, dipropylene glycol, TriMethylolPropane(TMP), ethyl acetate are mixed, be heated to 40-50 ℃, add peroxidized t-butyl perbenzoate, stir 40-50 minute; Then, add other composition, continue to be warming up to 70-80 ℃, add attapulgite, jade powder and other remaining component, stirring reaction 1-2 hour, obtains.
2. the preparation method of UV photocuring transparent priming according to claim 1, it is characterized in that comprising the following steps: other composition except light trigger 1173 is mixed, be heated to 50-60 ℃, under 600-700 rev/min, stir 10-20 minute, cool to 40 ℃ and add again below light trigger 1173, continue to stir 15-20 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310456933.7A CN103525258A (en) | 2013-09-30 | 2013-09-30 | UV (ultraviolet) curing transparent priming paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310456933.7A CN103525258A (en) | 2013-09-30 | 2013-09-30 | UV (ultraviolet) curing transparent priming paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103525258A true CN103525258A (en) | 2014-01-22 |
Family
ID=49927623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310456933.7A Pending CN103525258A (en) | 2013-09-30 | 2013-09-30 | UV (ultraviolet) curing transparent priming paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103525258A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105482655A (en) * | 2016-01-19 | 2016-04-13 | 卓达新材料科技集团有限公司 | UV (ultraviolet) building coating with high adhesive force and preparation method of coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101544869A (en) * | 2008-03-27 | 2009-09-30 | 上海富臣化工有限公司 | Packless ultraviolet curing transparent priming lacquer for woodenware |
| CN102732133A (en) * | 2012-06-29 | 2012-10-17 | 惠州市长润发涂料有限公司 | Anti-sagging spraying prime coat |
| CN102952455A (en) * | 2012-11-21 | 2013-03-06 | 深圳市广田环保涂料有限公司 | Ultraviolet light curing transparent priming paint and preparation method and use method thereof |
-
2013
- 2013-09-30 CN CN201310456933.7A patent/CN103525258A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101544869A (en) * | 2008-03-27 | 2009-09-30 | 上海富臣化工有限公司 | Packless ultraviolet curing transparent priming lacquer for woodenware |
| CN102732133A (en) * | 2012-06-29 | 2012-10-17 | 惠州市长润发涂料有限公司 | Anti-sagging spraying prime coat |
| CN102952455A (en) * | 2012-11-21 | 2013-03-06 | 深圳市广田环保涂料有限公司 | Ultraviolet light curing transparent priming paint and preparation method and use method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105482655A (en) * | 2016-01-19 | 2016-04-13 | 卓达新材料科技集团有限公司 | UV (ultraviolet) building coating with high adhesive force and preparation method of coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102925052B (en) | Double-curing vacuum plating UV (Ultraviolet) coating finish | |
| CN101353545B (en) | UV curing antibiotic coating and preparation thereof | |
| CN102977748B (en) | A kind of not containing the UV furniture spray paint light top coat top coat of volatile organic solvent | |
| CN103555188A (en) | UV (ultraviolet) photocuring paint and preparation method thereof | |
| CN106147527A (en) | A kind of aqueous epoxy coating used for building exterior wall | |
| CN103525261A (en) | UV (ultraviolet) polishing and priming-free UV coating and preparation method thereof | |
| CN103525272A (en) | Flame-retardant UV curing coating and preparation method thereof | |
| CN103525274A (en) | UV (ultraviolet) curing hardware coating and preparation method thereof | |
| CN102206436A (en) | Vacuum-plating ultraviolet curing intermediate paint | |
| CN103525264A (en) | Ultraviolet (UV) cured paint and preparation method thereof | |
| CN103525265A (en) | UV (ultraviolet)-photocuring paint and preparation method thereof | |
| CN103525258A (en) | UV (ultraviolet) curing transparent priming paint and preparation method thereof | |
| CN103526632A (en) | Priming-free ultraviolet (UV) coating for paper and preparation method of coating | |
| CN107880698A (en) | A kind of acrylic acid environmental protection enamel paint | |
| CN103525257A (en) | Stone surface crystallization ultraviolet photocurable coating and preparation method thereof | |
| CN103525291A (en) | Conductivity type UV (ultraviolet) curing paint and preparation method thereof | |
| CN103540241A (en) | Ultraviolet-curing primer wood coating and preparation method thereof | |
| CN103525288A (en) | Ultraviolet curing coating for coating plastic surface and preparation method thereof | |
| CN103525289A (en) | Insulating UV (ultraviolet) varnish and preparation method thereof | |
| CN103525262A (en) | UV (ultraviolet) curing coating with functions of light energy absorption and heat conduction and preparation method of coating | |
| CN103525286A (en) | UV gloss paint for priming on metal surface and preparation method thereof | |
| CN103525290A (en) | Wear-resistant ultraviolet (UV) photo-curing coating and preparation method thereof | |
| CN103571324B (en) | A kind of colored UV photo-cured coating and preparation method thereof | |
| CN103525273A (en) | UV (ultraviolet) coating with water drop effect and preparation method thereof | |
| CN103525263A (en) | Gildable gravure line ultraviolet (UV) gloss oil and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140122 |