CN106147527A - A kind of aqueous epoxy coating used for building exterior wall - Google Patents

A kind of aqueous epoxy coating used for building exterior wall Download PDF

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Publication number
CN106147527A
CN106147527A CN201610573932.4A CN201610573932A CN106147527A CN 106147527 A CN106147527 A CN 106147527A CN 201610573932 A CN201610573932 A CN 201610573932A CN 106147527 A CN106147527 A CN 106147527A
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CN
China
Prior art keywords
parts
exterior wall
aqueous
building exterior
epoxy resin
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Pending
Application number
CN201610573932.4A
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Chinese (zh)
Inventor
邱华岭
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ANHUI SHENGDE BUILDING MATERIAL TECHNOLOGY Co Ltd
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ANHUI SHENGDE BUILDING MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201610573932.4A priority Critical patent/CN106147527A/en
Publication of CN106147527A publication Critical patent/CN106147527A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of aqueous epoxy coating used for building exterior wall, its raw material includes by weight: bisphenol A type epoxy resin 20 40 parts, aqueous acrylic modified epoxy resin 2 14 parts, styrene-acrylic emulsion 5 15 parts, tripolycyanamide 26 parts, coalescents 13 parts, Pulvis Talci 2 10 parts, activated carbon 5 15 parts, hollow glass microballoon 2 10 parts, calcinated argil 14 parts, aluminium silicate 28 parts, nano silicon 14 parts, zinc phosphate 27 parts, sodium hydroxide 16 parts, 13 parts of glacial acetic acid, polyvinyl alcohol 2 10 parts, anti-settling agent 12 parts, preservative 12 parts, defoamer 12 parts, 20 50 parts of water.The aqueous epoxy coating used for building exterior wall that the present invention proposes, gained coating heat stability, water resistance are good, and good toughness, and hardness is high.

Description

A kind of aqueous epoxy coating used for building exterior wall
Technical field
The present invention relates to exterior coating technical field, particularly relate to a kind of aqueous epoxy coating used for building exterior wall.
Background technology
At present solvent-borne type is coated with coating and mostly contain organic solvent, as easy as rolling off a log volatilization in coating process, and severe contamination is greatly Gas, destroys ecological environment, and nowadays environmental conservation increasingly comes into one's own, and water paint will replace traditional solvent-borne type and be coated with Material, in coating used for building exterior wall, is widely used owing to aqueous epoxy coating adhesive force is good, shrinkage factor is low, but generally speaking The heat stability of aqueous epoxy coating, waterproof, toughness and hardness and oiliness epoxy coating also have quite poor away from, how to prepare one Kind of heat stability, water resistance are good, and good toughness, and the aqueous epoxy coating that hardness is high becomes and the technology of solution is presently required asks Topic.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of aqueous epoxy coating used for building exterior wall, institute Coating heat stability, water resistance are good, and good toughness, hardness is high.
The one aqueous epoxy coating used for building exterior wall that the present invention proposes, its raw material includes by weight: bisphenol type epoxy Resin 20-40 part, aqueous acrylic modified epoxy resin 2-14 part, styrene-acrylic emulsion 5-15 part, tripolycyanamide 2-6 part, film forming helps Agent 1-3 part, Pulvis Talci 2-10 part, activated carbon 5-15 part, hollow glass microballoon 2-10 part, calcinated argil 1-4 part, aluminium silicate 2-8 Part, nano silicon 1-4 part, zinc phosphate 2-7 part, sodium hydroxide 1-6 part, glacial acetic acid 1-3 part, polyvinyl alcohol 2-10 part is anti- Heavy agent 1-2 part, preservative 1-2 part, defoamer 1-2 part, water 20-50 part.
Preferably, bisphenol A type epoxy resin, aqueous acrylic modified epoxy resin, the weight ratio of styrene-acrylic emulsion are 25- 35:5-10:8-12.
Preferably, Pulvis Talci, activated carbon, hollow glass microballoon, calcinated argil, aluminium silicate, nano silicon, zinc phosphate Weight ratio be 4-8:8-12:4-8:2-3:4-6:2-3:4-5.
Preferably, sodium hydroxide, glacial acetic acid, the weight ratio of polyvinyl alcohol are 3-5:1.5-2.5:4-8.
Preferably, anti-settling agent, preservative, the weight ratio of defoamer are 1.5-1.8:1.5-1.8:1.2-1.5.
Preferably, its raw material includes by weight: bisphenol A type epoxy resin 25-35 part, aqueous acrylic modified asphalt mixtures modified by epoxy resin Fat 5-10 part, styrene-acrylic emulsion 8-12 part, tripolycyanamide 3-5 part, coalescents 1.5-2.5 part, Pulvis Talci 4-8 part, activated carbon 8- 12 parts, hollow glass microballoon 4-8 part, calcinated argil 2-3 part, aluminium silicate 4-6 part, nano silicon 2-3 part, zinc phosphate 4-5 Part, sodium hydroxide 3-5 part, glacial acetic acid 1.5-2.5 part, polyvinyl alcohol 4-8 part, anti-settling agent 1.5-1.8 part, preservative 1.5-1.8 Part, defoamer 1.2-1.5 part, water 30-40 part.
In the present invention, use bisphenol A type epoxy resin, aqueous acrylic modified epoxy resin, styrene-acrylic emulsion synergism, Each other compatibility is good, and can supply a gap each other, heat-resisting, corrosion-resistant, ageing-resistant performance is excellent, in tripolycyanamide, film forming Under the effect of auxiliary agent after film-forming, film layer is closely knit, and good toughness is the most easy to crack, and sodium hydroxide, glacial acetic acid, polyvinyl alcohol can Effectively molecular weight after regulation solidification, on the premise of ensureing toughness, hardness is moderate, and the Pulvis Talci added, activated carbon, hollow glass Glass microsphere, calcinated argil, aluminium silicate, nano silicon, zinc phosphate mating reaction, thermally-stabilised fabulous, and excellent in mechanical performance, Wherein activated carbon is internal fabulous to rest materials adsorptivity containing a large amount of cavitys, and hollow glass microballoon hydrophobicity is good, and can have Effect strengthens dispersibility between rest materials, activated carbon and hollow glass microballoon synergism, and goods water resistance is good, and divides each other Dissipating closely knit, with bisphenol A type epoxy resin, aqueous acrylic modified epoxy resin, styrene-acrylic emulsion effect, toughness is with hardness the most relatively Good, water resistance is excellent, and heat stability is fabulous.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
The one aqueous epoxy coating used for building exterior wall that the present invention proposes, its raw material includes by weight: bisphenol type epoxy Resin 20 parts, aqueous acrylic modified epoxy resin 14 parts, styrene-acrylic emulsion 5 parts, tripolycyanamide 6 parts, coalescents 1 part, Talcum 10 parts of powder, activated carbon 5 parts, hollow glass microballoon 10 parts, calcinated argil 1 part, aluminium silicate 8 parts, nano silicon 1 part, phosphoric acid 7 parts of zinc, sodium hydroxide 1 part, 3 parts of glacial acetic acid, polyvinyl alcohol 2 parts, anti-settling agent 2 parts, preservative 1 part, defoamer 2 parts, 20 parts of water.
Embodiment 2
The one aqueous epoxy coating used for building exterior wall that the present invention proposes, its raw material includes by weight: bisphenol type epoxy Resin 40 parts, aqueous acrylic modified epoxy resin 2 parts, styrene-acrylic emulsion 15 parts, tripolycyanamide 2 parts, coalescents 3 parts, Talcum 2 parts of powder, activated carbon 15 parts, hollow glass microballoon 2 parts, calcinated argil 4 parts, aluminium silicate 2 parts, nano silicon 4 parts, zinc phosphate 2 parts, sodium hydroxide 6 parts, 1 part of glacial acetic acid, polyvinyl alcohol 10 parts, anti-settling agent 1 part, preservative 2 parts, defoamer 1 part, 50 parts of water.
Embodiment 3
The one aqueous epoxy coating used for building exterior wall that the present invention proposes, its raw material includes by weight: bisphenol type epoxy Resin 25 parts, aqueous acrylic modified epoxy resin 10 parts, styrene-acrylic emulsion 8 parts, tripolycyanamide 5 parts, coalescents 1.5 parts is sliding Stone powder 8 parts, activated carbon 8 parts, hollow glass microballoon 8 parts, calcinated argil 2 parts, aluminium silicate 6 parts, nano silicon 2 parts, phosphoric acid 5 parts of zinc, sodium hydroxide 3 parts, 2.5 parts of glacial acetic acid, polyvinyl alcohol 4 parts, anti-settling agent 1.8 parts, preservative 1.5 parts, defoamer 1.5 Part, 30 parts of water.
Embodiment 4
The one aqueous epoxy coating used for building exterior wall that the present invention proposes, its raw material includes by weight: bisphenol type epoxy Resin 35 parts, aqueous acrylic modified epoxy resin 5 parts, styrene-acrylic emulsion 12 parts, tripolycyanamide 3 parts, coalescents 2.5 parts is sliding Stone powder 4 parts, activated carbon 12 parts, hollow glass microballoon 4 parts, calcinated argil 3 parts, aluminium silicate 4 parts, nano silicon 3 parts, phosphoric acid 4 parts of zinc, sodium hydroxide 5 parts, 1.5 parts of glacial acetic acid, polyvinyl alcohol 8 parts, anti-settling agent 1.5 parts, preservative 1.8 parts, defoamer 1.2 Part, 40 parts of water.
Embodiment 5
The one aqueous epoxy coating used for building exterior wall that the present invention proposes, its raw material includes by weight: bisphenol type epoxy Resin 30 parts, aqueous acrylic modified epoxy resin 8 parts, styrene-acrylic emulsion 10 parts, tripolycyanamide 4 parts, coalescents 2 parts, Talcum 6 parts of powder, activated carbon 10 parts, hollow glass microballoon 6 parts, calcinated argil 2.5 parts, aluminium silicate 5 parts, nano silicon 2.5 parts, phosphorus 4.5 parts of zinc of acid, sodium hydroxide 4 parts, 2 parts of glacial acetic acid, polyvinyl alcohol 6 parts, anti-settling agent 1.6 parts, preservative 1.7 parts, defoamer 1.3 Part, 35 parts of water.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (6)

1. an aqueous epoxy coating used for building exterior wall, it is characterised in that its raw material includes by weight: bisphenol type epoxy tree Fat 20-40 part, aqueous acrylic modified epoxy resin 2-14 part, styrene-acrylic emulsion 5-15 part, tripolycyanamide 2-6 part, coalescents 1-3 part, Pulvis Talci 2-10 part, activated carbon 5-15 part, hollow glass microballoon 2-10 part, calcinated argil 1-4 part, aluminium silicate 2-8 part, Nano silicon 1-4 part, zinc phosphate 2-7 part, sodium hydroxide 1-6 part, glacial acetic acid 1-3 part, polyvinyl alcohol 2-10 part, anti-settling agent 1-2 part, preservative 1-2 part, defoamer 1-2 part, water 20-50 part.
Aqueous epoxy coating the most used for building exterior wall, it is characterised in that bisphenol A type epoxy resin, aqueous Acrylic modified epoxy resin, the weight ratio of styrene-acrylic emulsion are 25-35:5-10:8-12.
Aqueous epoxy coating used for building exterior wall the most according to claim 1 or claim 2, it is characterised in that Pulvis Talci, activated carbon, in Empty glass microsphere, calcinated argil, aluminium silicate, nano silicon, the weight ratio of zinc phosphate are 4-8:8-12:4-8:2-3:4-6: 2-3:4-5.
4. according to aqueous epoxy coating used for building exterior wall described in any one of claim 1-3, it is characterised in that sodium hydroxide, ice Acetic acid, the weight ratio of polyvinyl alcohol are 3-5:1.5-2.5:4-8.
5. according to aqueous epoxy coating used for building exterior wall described in any one of claim 1-4, it is characterised in that anti-settling agent, anticorrosion Agent, the weight ratio of defoamer are 1.5-1.8:1.5-1.8:1.2-1.5.
6. according to aqueous epoxy coating used for building exterior wall described in any one of claim 1-5, it is characterised in that its raw material is by weight Part includes: bisphenol A type epoxy resin 25-35 part, aqueous acrylic modified epoxy resin 5-10 part, styrene-acrylic emulsion 8-12 part, three Poly cyanamid 3-5 part, coalescents 1.5-2.5 part, Pulvis Talci 4-8 part, activated carbon 8-12 part, hollow glass microballoon 4-8 part, calcining Potter's clay 2-3 part, aluminium silicate 4-6 part, nano silicon 2-3 part, zinc phosphate 4-5 part, sodium hydroxide 3-5 part, glacial acetic acid 1.5- 2.5 parts, polyvinyl alcohol 4-8 part, anti-settling agent 1.5-1.8 part, preservative 1.5-1.8 part, defoamer 1.2-1.5 part, water 30-40 Part.
CN201610573932.4A 2016-07-19 2016-07-19 A kind of aqueous epoxy coating used for building exterior wall Pending CN106147527A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163792A (en) * 2017-06-22 2017-09-15 芜湖航天特种电缆厂股份有限公司 Cable insulation coating compositions and preparation method thereof
CN108059861A (en) * 2017-12-13 2018-05-22 许飞扬 Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance and preparation method thereof
CN108410305A (en) * 2018-04-13 2018-08-17 王俊玲 A kind of coating with fireproof heat insulating sound insulation function
CN108587413A (en) * 2018-05-30 2018-09-28 安徽润晟建设有限公司 A kind of exterior wall waterborne epoxy coatings
CN108641552A (en) * 2018-05-30 2018-10-12 安徽润晟建设有限公司 A kind of high adhesion force waterborne epoxy coatings preparation method
CN109913049A (en) * 2019-03-15 2019-06-21 天津市青龙建筑安装工程有限公司 A kind of Environment-friendlyexterior exterior wall paint and its construction technology
CN111662600A (en) * 2019-05-17 2020-09-15 亚科维亚(福建)科技有限公司 Anti-highlight orthographic projection coating and orthographic projection screen

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101434771A (en) * 2007-11-15 2009-05-20 于士井 Waterproof anticracking construction exterior wall paint
CN101475767A (en) * 2006-03-31 2009-07-08 中国科学院过程工程研究所 Coating for collecting formaldehyde
JP2012021135A (en) * 2010-06-18 2012-02-02 Nippon Shokubai Co Ltd Aqueous resin composition for rustproof coating material
CN103342947A (en) * 2013-07-04 2013-10-09 滁州格锐矿业有限责任公司 Novel two-dimensional nano paint
CN105062262A (en) * 2015-08-05 2015-11-18 天长市开林化工有限公司 Building interior wall special-purpose antibacterial mildew-resistant emulsion paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101475767A (en) * 2006-03-31 2009-07-08 中国科学院过程工程研究所 Coating for collecting formaldehyde
CN101434771A (en) * 2007-11-15 2009-05-20 于士井 Waterproof anticracking construction exterior wall paint
JP2012021135A (en) * 2010-06-18 2012-02-02 Nippon Shokubai Co Ltd Aqueous resin composition for rustproof coating material
CN103342947A (en) * 2013-07-04 2013-10-09 滁州格锐矿业有限责任公司 Novel two-dimensional nano paint
CN105062262A (en) * 2015-08-05 2015-11-18 天长市开林化工有限公司 Building interior wall special-purpose antibacterial mildew-resistant emulsion paint

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163792A (en) * 2017-06-22 2017-09-15 芜湖航天特种电缆厂股份有限公司 Cable insulation coating compositions and preparation method thereof
CN108059861A (en) * 2017-12-13 2018-05-22 许飞扬 Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance and preparation method thereof
CN108410305A (en) * 2018-04-13 2018-08-17 王俊玲 A kind of coating with fireproof heat insulating sound insulation function
CN108587413A (en) * 2018-05-30 2018-09-28 安徽润晟建设有限公司 A kind of exterior wall waterborne epoxy coatings
CN108641552A (en) * 2018-05-30 2018-10-12 安徽润晟建设有限公司 A kind of high adhesion force waterborne epoxy coatings preparation method
CN109913049A (en) * 2019-03-15 2019-06-21 天津市青龙建筑安装工程有限公司 A kind of Environment-friendlyexterior exterior wall paint and its construction technology
CN111662600A (en) * 2019-05-17 2020-09-15 亚科维亚(福建)科技有限公司 Anti-highlight orthographic projection coating and orthographic projection screen

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Application publication date: 20161123