CN108059861A - Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance and preparation method thereof - Google Patents
Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance and preparation method thereof Download PDFInfo
- Publication number
- CN108059861A CN108059861A CN201711325324.2A CN201711325324A CN108059861A CN 108059861 A CN108059861 A CN 108059861A CN 201711325324 A CN201711325324 A CN 201711325324A CN 108059861 A CN108059861 A CN 108059861A
- Authority
- CN
- China
- Prior art keywords
- parts
- zebra stripes
- coating
- powder
- acting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance, including slurry and curing agent.The component of the slurry and the mass fraction proportioning of each component are：120 150 parts of aqueous acrylic emulsion, 20 30 parts of bisphenol A type epoxy resin, 58 parts of 2 ethylhexyl sulfate, 20 25 parts of titanium dioxide, 25 parts of dispersant, 23 parts of aqueous wetting agent, 23 parts of levelling agent, 58 parts of modified manometer silicon dioxide powder, 58 parts of powder of ice-melt snow, 35 parts of luminescent powder, 58 parts of quartz sand, 20 40 parts of water；The component of the curing agent and the mass fraction proportioning of each component are：100 parts of organosilicon modified crylic acid resin, 20 30 parts of α cyanacrylates, 30 40 parts of triethylene tetramine.The zebra stripes coating of the present invention has anti-skidding, hydrophobic and Thaw performance, in sleety weather, can prevent zebra stripes coating surface from stockpiling sleet, so as to prevent that vehicle from skidding when passing by zebra stripes or pedestrian falls down.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to zebra stripes a kind of anti-skidding hydrophobic and with long-acting Thaw performance
Coating and preparation method thereof.
Background technology
The coating for being used for brushing road zebra crossing in the prior art has had certain anti-skid factor, in zebra stripes coating table
When face is dried, there is certain non-skid property, but when running into sleety weather, zebra stripes coating surface can rainy or snow, rain or
The presence of snow so that zebra stripes coating surface is wet and slippery, the phenomenon that being had skidded so as to cause the vehicle in traveling, the people of walking
Particularly in autumn and winter, old man occurs often for the phenomenon that sliding into when going across the road because zebra stripes non-skid property difference causes
That falls down happens.In addition, existing zebra stripes do not have luminous effect, it is easy to not see spot when night, light was weaker
So as to cause pedestrian when through lateral road accident occurs for horse line, it is, therefore, desirable to provide a kind of have hydrophobic, snow melt and noctilucence
The anti-skidding zebra stripes coating of performance.
The content of the invention
In view of the problems of the existing technology, it is the present invention is directed to propose a kind of anti-skidding hydrophobic and with long-acting Thaw performance
Zebra stripes coating and preparation method thereof, in sleety weather, can prevent zebra stripes coating surface from stockpiling sleet, so as to prevent
The situation that vehicle skids when passing by zebra stripes or pedestrian falls down occurs.
In order to achieve the goal above, the technical solution adopted by the present invention is：One kind is anti-skidding hydrophobic and with long-acting snow melt
The zebra stripes coating of energy, including slurry and curing agent.
The component of the slurry and the mass fraction proportioning of each component are：120-150 parts of aqueous acrylic emulsion, bisphenol-A
20-30 parts of type epoxy resin, 5-8 parts of sodium 2-ethylhexyl sulfate, 20-25 parts of titanium dioxide, 2-5 parts of dispersant, aqueous wetting agent
2-3 parts, it is 2-3 parts of levelling agent, 5-8 parts of modified manometer silicon dioxide powder, 5-8 part of powder of ice-melt snow, 3-5 parts of luminescent powder, quartzy
5-8 parts of sand, 20-40 parts of water；
The component of the curing agent and the mass fraction proportioning of each component are：100 parts of organosilicon modified crylic acid resin, α-
20-30 parts of cyanacrylate, 30-40 parts of triethylene tetramine.
Preferably, the molecular weight of the aqueous acrylic emulsion is more than 200000, and acid value is in 50-55mgKOH/g.
Preferably, the synthetic method of the modified manometer silicon dioxide powder is：Ethyl orthosilicate is with absolute ethyl alcohol in room
Temperature is lower to be mixed 10min, then the mixed solution of distilled water and ammonium hydroxide is added dropwise, and is added dropwise again after stirring 2h strongly at 60 DEG C
Methyltriethoxysilane continues after stirring 1h, and room temperature ageing 1-2d, being subsequently placed in 2d in 60 DEG C of baking ovens makes evaporation of the solvent, obtains
To the nano silica powder of surface hydrophobicity.
Preferably, the quality parts ratio of the synthesis material of the modified manometer silicon dioxide powder is ethyl orthosilicate:Nothing
Water-ethanol:Durability.
To sum up, compared with prior art, the invention has the advantages that：
1. the zebra stripes coating of the present invention includes slurry and curing agent, slurry and curing agent are separately stored, are used in mixed way, make
It is good with the performance that is adhesively fixed on ground with convenience, extend the service life of zebra stripes coating.
2. the zebra stripes coating of the present invention has hydrophobic Thaw performance, shorten nano-silica by being added in formulation for coating material
SiClx powder adds the hydrophobic performance of coating, and the contact angle of coating and water is 165 ° -175 °, and roll angle is 2-5 °, coating
Hydrophobic performance is excellent, and coating surface does not have ponding presence；Powder is avenged by adding ice-melt in formulation for coating material, passes through macromolecule
Thin-film material wraps up snow melt substance, makes snow melt material sustained-release effect more preferable, extends the snow melt time of zebra stripes coating,
Road can be maintained from ice-melt snow function 1 year or more, it, can first after snowfall suitable for the more area of northern sleety weather
Time makes snow melt, and coordinates the hydrophobic performance of modified manometer silicon dioxide powder, dries zebra stripes coating surface, avoids rain
Snow causes coating surface is wet and slippery vehicle slip or pedestrian is caused to fall down.And also increasing in coating composition has quartz sand, Neng Gouzeng
The non-skid property of strong coating, so as to further prevent vehicle slip or what pedestrian fell down happens.
3. the zebra stripes coating of the present invention has noctilucence effect, by adding in luminescent powder in coating composition so that coating
Noctilucence is sent when night, light was poor, it is watchful so as to play the role of to pedestrian.
Specific embodiment
The present invention is described in further detail with reference to specific embodiment.
Embodiment 1
Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance, including slurry and curing agent.
The component of the slurry and the mass fraction proportioning of each component are：130 parts of aqueous acrylic emulsion, bisphenol-A type ring
25 parts of oxygen resin, 6 parts of sodium 2-ethylhexyl sulfate, 24 parts of titanium dioxide, 3 parts of dispersant, 2.5 parts of aqueous wetting agent, levelling agent 2.5
Part, 6 parts of modified manometer silicon dioxide powder, 6 parts of powder of ice-melt snow, 4 parts of luminescent powder, 6 parts of quartz sand, 30 parts of water；
The component of the curing agent and the mass fraction proportioning of each component are：100 parts of organosilicon modified crylic acid resin, α-
25 parts of cyanacrylate, 35 parts of triethylene tetramine.
The molecular weight of the aqueous acrylic emulsion is 300000, acid value 50mgKOH/g.
The synthetic method of the modified manometer silicon dioxide powder is：The ethyl orthosilicate of 2 mass parts and 60 mass parts
10min is mixed in absolute ethyl alcohol at room temperature, then the mixed solution of 8 mass parts distilled water and 2 mass parts ammonium hydroxide is added dropwise, 60
The methyltriethoxysilane that 12 mass parts are added dropwise after 2h again is stirred at DEG C strongly, is continued after stirring 1h, room temperature ageing
1.5d, being subsequently placed in 2d in 60 DEG C of baking ovens makes evaporation of the solvent, obtains the nano silica powder of surface hydrophobicity.
The synthetic method of ice-melt snow powder is：The obtained sodium chloride that will sieve uses in bottom spray fluidized-bed coating machine
Ethyl cellulose solution is uniformly wrapped in its surface by the method for bottom spray coating, is sieved after dry, is added 0.5 mass parts grape
The ice-melt snow powder that sodium saccharate obtains；The ethyl cellulose solution is that the ethyl cellulose of 5 mass parts is added to 100 mass
The second ammonium hydroxide of part:Distilled water:Methyltriethoxysilane=1:30:(2-5):1:(4-8).
Preferably, the synthetic method of the ice-melt snow powder is：Obtained snow melt substance will be sieved in bottom spray fluid bed bag
Coating material solution is uniformly wrapped in by its surface using the method for bottom spray coating in clothing machine, sieves after dry, adds addition
The ice-melt snow powder that agent obtains；The coating material solution is that the coating material of 3-10 mass parts is added to 90-130 mass parts
Solvent in, stirring at normal temperature uniformly stands what is obtained for 24 hours afterwards.
Preferably, the snow melt substance is sodium chloride, calcium chloride, magnesium chloride or potassium acetate.
Preferably, the coating material is ethyl cellulose, acrylic resin or the polyethylene in hydrophobic coating agent
Butyral；The etoh solvent.
Preferably, the additive is sodium gluconate, sodium nitrite or sodium metasilicate；Prepare melting for 10-50 mass parts
The additive of ice and snow powder addition is 0.5-2 mass parts.
Above-mentioned anti-skidding hydrophobic and with long-acting Thaw performance the preparation method of zebra stripes coating is：
The preparation method of the slurry includes the following steps：It is matched by constituent mass number, first by water, titanium dioxide, 2- second
Base sodium hexy1 sulfate, dispersant, aqueous wetting agent, levelling agent, modified manometer silicon dioxide powder, ice-melt snow powder, luminescent powder,
It quartz sand and mixes and after being uniformly dispersed, adds in aqueous acrylic emulsion and bisphenol A type epoxy resin stirs evenly, starched
Material；
The preparation method of the curing agent includes the following steps：It is matched by constituent mass number, by organic-silicon-modified propylene
Acid resin, α-cyanoacrylate and triethylene tetramine are uniformly mixing to obtain curing agent.
Preferably, the slurry and curing agent are stored separately, and when use is uniformly mixed, and when slurry and curing agent mix
Mass ratio is (1-2): 1.
Anti-skidding hydrophobic and with long-acting Thaw performance the component mechanism of action of zebra stripes coating of the present invention is：
The zebra stripes coating of the present invention adds in modified manometer silicon dioxide powder, ice-melt in conventional zebra stripes coating composition
Snow powder, luminescent powder and quartz sand, modified manometer silicon dioxide powder are made it have excellent by being modified to silica
Ultra-hydrophobicity so that the contact angle of coating and water be 165 ° -175 °, roll angle be 2-5 ° so that zebra stripes coating
Surface does not have ponding presence.Ice-melt snow powder is wrapped up snow melt substance by high molecular film material, makes snow melt substance
Slow release effect is more preferable, extends the snow melt time of zebra stripes coating, and road can be maintained to be suitable for from ice-melt snow function 1 year or more
The more area of northern sleety weather, can make snow melt at the first time after snowfall, and coordinate modified manometer silicon dioxide powder
The hydrophobic performance of body dries zebra stripes coating surface, sleet is avoided to cause coating surface is wet and slippery to cause vehicle slip or pedestrian
It falls down.Luminescent powder adds the noctilucence effect of coating, watchful so as to play the role of when night, light was poor to pedestrian.Stone
Sand enhances the non-skid property of zebra stripes coating.Dispersant can shorten nano silica powder, ice-melt snow powder and night
The jitter time of the components such as light powder is uniform, the stability of strengthening slurry.The present invention is used cooperatively by slurry and curing agent, is cured
Adhesive effect is good, can avenge powder to the ice-melt in slurry and quartz sand plays good solidification, and by slurry
Middle addition aqueous wetting agent, aqueous wetting agent can reduce the surface tension of system, improve wetting of the coating to ground, improve attached
Put forth effort, so as to enhance in coating alcohol, stirring at normal temperature uniformly stands what is obtained for 24 hours afterwards.
Above-mentioned anti-skidding hydrophobic and with long-acting Thaw performance the preparation method of zebra stripes coating is：
The preparation method of the slurry includes the following steps：It is matched by constituent mass number, first by water, titanium dioxide, 2- second
Base sodium hexy1 sulfate, dispersant, aqueous wetting agent, levelling agent, modified manometer silicon dioxide powder, ice-melt snow powder, luminescent powder,
It quartz sand and mixes and after being uniformly dispersed, adds in aqueous acrylic emulsion and bisphenol A type epoxy resin stirs evenly, starched
Material；
The preparation method of the curing agent includes the following steps：It is matched by constituent mass number, by organic-silicon-modified propylene
Acid resin, α-cyanoacrylate and triethylene tetramine are uniformly mixing to obtain curing agent.
The slurry and curing agent are stored separately, and when use is uniformly mixed, and mass ratio when slurry and curing agent mix
For 1.5: 1.
Embodiment 2
Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance, including slurry and curing agent.
The component of the slurry and the mass fraction proportioning of each component are：120 parts of aqueous acrylic emulsion, bisphenol-A type ring
30 parts of oxygen resin, 8 parts of sodium 2-ethylhexyl sulfate, 25 parts of titanium dioxide, 5 parts of dispersant, 3 parts of aqueous wetting agent, 3 parts of levelling agent,
5 parts of modified manometer silicon dioxide powder, 8 parts of powder of ice-melt snow, 5 parts of luminescent powder, 5 parts of quartz sand, 40 parts of water；
The component of the curing agent and the mass fraction proportioning of each component are：100 parts of organosilicon modified crylic acid resin, α-
20 parts of cyanacrylate, 40 parts of triethylene tetramine.
The molecular weight of the aqueous acrylic emulsion is 300000, acid value 55mgKOH/g.
The synthetic method of the modified manometer silicon dioxide powder is：The ethyl orthosilicate of 2 mass parts and 60 mass parts
10min is mixed in absolute ethyl alcohol at room temperature, then the mixed solution of 10 mass parts distilled water and 2 mass parts ammonium hydroxide is added dropwise,
The methyltriethoxysilane that 8 mass parts are added dropwise after 2h again is stirred at 60 DEG C strongly, is continued after stirring 1h, room temperature ageing
2d, being subsequently placed in 2d in 60 DEG C of baking ovens makes evaporation of the solvent, obtains the nano silica powder of surface hydrophobicity.
The synthetic method of ice-melt snow powder is：The obtained calcium chloride that will sieve uses in bottom spray fluidized-bed coating machine
Acrylic resin soln is uniformly wrapped in its surface by the method for bottom spray coating, is sieved after dry, is added 2 mass parts nitrous acid
The ice-melt snow powder that sodium obtains；The acrylic resin soln is that the acrylic resin of 10 mass parts is added to 130 mass parts
Ethyl alcohol in, stirring at normal temperature uniformly stands what is obtained for 24 hours afterwards.
Above-mentioned anti-skidding hydrophobic and with long-acting Thaw performance the preparation method of zebra stripes coating is：
The preparation method of the slurry includes the following steps：It is matched by constituent mass number, first by water, titanium dioxide, 2- second
Base sodium hexy1 sulfate, dispersant, aqueous wetting agent, levelling agent, modified manometer silicon dioxide powder, ice-melt snow powder, luminescent powder,
It quartz sand and mixes and after being uniformly dispersed, adds in aqueous acrylic emulsion and bisphenol A type epoxy resin stirs evenly, starched
Material；
The preparation method of the curing agent includes the following steps：It is matched by constituent mass number, by organic-silicon-modified propylene
Acid resin, α-cyanoacrylate and triethylene tetramine are uniformly mixing to obtain curing agent.
The slurry and curing agent are stored separately, and when use is uniformly mixed, and mass ratio when slurry and curing agent mix
For 2: 1.
Embodiment 3
Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance, including slurry and curing agent.
The component of the slurry and the mass fraction proportioning of each component are：150 parts of aqueous acrylic emulsion, bisphenol-A type ring
20 parts of oxygen resin, 5 parts of sodium 2-ethylhexyl sulfate, 20 parts of titanium dioxide, 5 parts of dispersant, 2 parts of aqueous wetting agent, 2 parts of levelling agent,
8 parts of modified manometer silicon dioxide powder, 8 parts of powder of ice-melt snow, 3 parts of luminescent powder, 8 parts of quartz sand, 20 parts of water；
The component of the curing agent and the mass fraction proportioning of each component are：100 parts of organosilicon modified crylic acid resin, α-
30 parts of cyanacrylate, 30 parts of triethylene tetramine.
The molecular weight of the aqueous acrylic emulsion is 300000, acid value 52mgKOH/g.
The synthetic method of the modified manometer silicon dioxide powder is：The ethyl orthosilicate of 2 mass parts and 60 mass parts
10min is mixed in absolute ethyl alcohol at room temperature, then the mixed solution of 4 mass parts distilled water and 2 mass parts ammonium hydroxide is added dropwise, 60
The methyltriethoxysilane that 16 mass parts are added dropwise after 2h again is stirred at DEG C strongly, is continued after stirring 1.5h, room temperature ageing
1.5d, being subsequently placed in 2d in 60 DEG C of baking ovens makes evaporation of the solvent, obtains the nano silica powder of surface hydrophobicity.
The synthetic method of ice-melt snow powder is：The obtained magnesium chloride that will sieve uses in bottom spray fluidized-bed coating machine
Polyvinyl butyral solution is uniformly wrapped in its surface by the method for bottom spray coating, is sieved after dry, is added 1.5 mass parts
The ice-melt snow powder that sodium metasilicate obtains；The polyvinyl butyral solution is to be added to the ethyl cellulose of 5 mass parts
In the ethyl alcohol of 100 mass parts, stirring at normal temperature uniformly stands what is obtained for 24 hours afterwards.
Above-mentioned anti-skidding hydrophobic and with long-acting Thaw performance the preparation method of zebra stripes coating is：
The preparation method of the slurry includes the following steps：It is matched by constituent mass number, first by water, titanium dioxide, 2- second
Base sodium hexy1 sulfate, dispersant, aqueous wetting agent, levelling agent, modified manometer silicon dioxide powder, ice-melt snow powder, luminescent powder,
It quartz sand and mixes and after being uniformly dispersed, adds in aqueous acrylic emulsion and bisphenol A type epoxy resin stirs evenly, starched
Material；
The preparation method of the curing agent includes the following steps：It is matched by constituent mass number, by organic-silicon-modified propylene
Acid resin, α-cyanoacrylate and triethylene tetramine are uniformly mixing to obtain curing agent.
The slurry and curing agent are stored separately, and when use is uniformly mixed, and mass ratio when slurry and curing agent mix
For 1: 1.
Take what is used in the prior art to heat road white line coating as a comparison case along logical board, with reference to transportation industry mark
It is accurate《Pavement marking paint》JT/T 280-2004 to the coating that the coating of the coating of comparative example and above-described embodiment 1 to 3 is formed into
Row test, test event includes skid resistance, wearability, hydrophobicity, snow melt and noctilucence, as shown in table 1 below in test result.
1 coating test result of table
By above-mentioned test result, by zebra stripes coating made from the formula and preparation method of the present invention with it is existing
The coating of technology is compared, and abrasion loss is less than comparative example, therefore wear-resisting property is excellent；Pass through the formula and preparation method system of the present invention
The zebra stripes coating BPN values obtained are more than comparative example, and antiskid is had excellent performance；And compared with comparative example, coating of the invention, which has, to be dredged
Aqueous, snow melt and noctilucence, this is not available for comparative example, thus the zebra stripes coating of the present invention can snow melt it is hydrophobic,
Coating surface drying is kept, so as to enhance non-skid property, it is wet under sleety weather to solve zebra stripes coating in the prior art
The situation slided and vehicle slip, pedestrian is caused to be fallen down.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to limit the invention,
Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, still may be used
To modify to the technical solution recorded in foregoing embodiments or carry out equivalent substitution to which part technical characteristic.
Within the spirit and principles of the invention, any modifications, equivalent replacements and improvements are made should be included in the present invention's
Within protection domain.
Claims (10)
1. zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance, including slurry and curing agent, which is characterized in that
The component of the slurry and the mass fraction proportioning of each component are：120-150 parts of aqueous acrylic emulsion, bisphenol-A type ring
20-30 parts of oxygen resin, 5-8 parts of sodium 2-ethylhexyl sulfate, 20-25 parts of titanium dioxide, 2-5 parts of dispersant, aqueous wetting agent 2-3
Part, 2-3 parts of levelling agent, 5-8 parts of modified manometer silicon dioxide powder, 5-8 parts of powder of ice-melt snow, 3-5 parts of luminescent powder, quartz sand 5-
8 parts, 20-40 parts of water；
The component of the curing agent and the mass fraction proportioning of each component are：100 parts of organosilicon modified crylic acid resin, alpha-cyano
20-30 parts of ethyl acrylate, 30-40 parts of triethylene tetramine.
2. zebra stripes coating according to claim 1 anti-skidding hydrophobic and with long-acting Thaw performance, which is characterized in that institute
The molecular weight for stating aqueous acrylic emulsion is more than 200000, and acid value is in 50-55mgKOH/g.
3. zebra stripes coating according to claim 1 anti-skidding hydrophobic and with long-acting Thaw performance, which is characterized in that institute
The synthetic method for stating modified manometer silicon dioxide powder is：10min is mixed with absolute ethyl alcohol in ethyl orthosilicate at room temperature,
The mixed solution of distilled water and ammonium hydroxide is added dropwise again, methyltriethoxysilane is added dropwise again after stirring 2h strongly at 60 DEG C,
Continue after stirring 1h, room temperature ageing 1-2d, being subsequently placed in 2d in 60 DEG C of baking ovens makes evaporation of the solvent, obtains the nanometer two of surface hydrophobicity
Silica powder.
4. zebra stripes coating according to claim 3 anti-skidding hydrophobic and with long-acting Thaw performance, which is characterized in that institute
The quality parts ratio for stating the synthesis material of modified manometer silicon dioxide powder is ethyl orthosilicate:Absolute ethyl alcohol:Ammonium hydroxide:Distillation
Water:Methyltriethoxysilane=1:30:(2-5):1:(4-8).
5. zebra stripes coating according to claim 1 anti-skidding hydrophobic and with long-acting Thaw performance, which is characterized in that institute
State ice-melt snow powder synthetic method be：The obtained snow melt substance that will sieve is sprayed in fluidized-bed coating machine the bottom of at using bottom spray coating
Method coating material solution is uniformly wrapped in its surface, sieve after dry, add the ice-melt snow powder that additive obtains；
The coating material solution is added to the coating material of 3-10 mass parts in the solvent of 90-130 mass parts, and stirring at normal temperature is equal
Stand what is obtained for 24 hours after even.
6. zebra stripes coating according to claim 5 anti-skidding hydrophobic and with long-acting Thaw performance, which is characterized in that institute
Snow melt substance is stated as sodium chloride, calcium chloride, magnesium chloride or potassium acetate.
7. zebra stripes coating according to claim 5 anti-skidding hydrophobic and with long-acting Thaw performance, which is characterized in that institute
Coating material is stated as ethyl cellulose, acrylic resin or the polyvinyl butyral in hydrophobic coating agent；The solvent
Ethyl alcohol.
8. zebra stripes coating according to claim 5 anti-skidding hydrophobic and with long-acting Thaw performance, which is characterized in that institute
Additive is stated as sodium gluconate, sodium nitrite or sodium metasilicate；Prepare the addition of the ice-melt snow powder addition of 10-50 mass parts
Agent is 0.5-2 mass parts.
9. the preparation side of anti-skidding hydrophobic and with long-acting Thaw performance the zebra stripes coating as described in any in claim 1-8
Method, it is characterised in that：
The preparation method of the slurry includes the following steps：It is matched by constituent mass number, first by water, titanium dioxide, 2- ethyl hexyls
Base sodium sulphate, dispersant, aqueous wetting agent, levelling agent, modified manometer silicon dioxide powder, ice-melt snow powder, luminescent powder, quartz
It sand and mixes and after being uniformly dispersed, adds in aqueous acrylic emulsion and bisphenol A type epoxy resin stirs evenly, obtain slurry；
The preparation method of the curing agent includes the following steps：It is matched by constituent mass number, by organosilicon-modified acrylic tree
Fat, α-cyanoacrylate and triethylene tetramine are uniformly mixing to obtain curing agent.
10. zebra stripes coating anti-skidding hydrophobic according to claim 1-9 any one of them and with long-acting Thaw performance, special
Sign is that the slurry and curing agent are stored separately, and when use is uniformly mixed, and mass ratio when slurry and curing agent mix is
(1-2)∶1。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711325324.2A CN108059861A (en) | 2017-12-13 | 2017-12-13 | Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711325324.2A CN108059861A (en) | 2017-12-13 | 2017-12-13 | Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108059861A true CN108059861A (en) | 2018-05-22 |
Family
ID=62138303
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711325324.2A Pending CN108059861A (en) | 2017-12-13 | 2017-12-13 | Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108059861A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109044655A (en) * | 2018-06-25 | 2018-12-21 | 常州市第二人民医院 | A kind of multi-functional disposition bed of Emergence |
| CN109294391A (en) * | 2018-08-15 | 2019-02-01 | 句容协鑫集成科技有限公司 | A kind of solar photovoltaic cell backplane adhesive |
| CN109777267A (en) * | 2018-12-21 | 2019-05-21 | 朱晶霞 | A kind of road zebra crossing paint |
| CN109825140A (en) * | 2019-03-09 | 2019-05-31 | 华北水利水电大学 | Environment-friendly high-efficiency snow melt road surface coating material and its preparation method and application |
| CN109880522A (en) * | 2019-03-05 | 2019-06-14 | 澜猫（天津）新材料科技有限公司 | A kind of super-hydrophobic PRTV(RTV) based composites and preparation method thereof, application method |
| CN109943177A (en) * | 2019-03-21 | 2019-06-28 | 华北水利水电大学 | Environment-friendly high-efficiency melting ice coating material and its preparation method and application |
| CN113604118A (en) * | 2021-06-29 | 2021-11-05 | 四川省公路规划勘察设计研究院有限公司 | Durable anti-freezing coating and preparation method thereof |
| CN114907749A (en) * | 2022-06-07 | 2022-08-16 | 广州中桥能源科技有限公司 | Material for preventing natural gas gasifier from frosting and freezing and preparation method thereof |
| CN115581015A (en) * | 2022-12-08 | 2023-01-06 | 山东超链智能科技有限公司 | Intelligent control device for elevator |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532968A (en) * | 2010-12-08 | 2012-07-04 | 上海控江中学附属民办学校 | Anti-skid road zebra crossing paint and preparation method thereof |
| CN104629580A (en) * | 2015-01-28 | 2015-05-20 | 西安中交万里新材料有限公司 | Long-acting environment-friendly ice-snow melting pavement coating and preparation method and using method of thereof |
| CN106147527A (en) * | 2016-07-19 | 2016-11-23 | 安徽圣德建材科技有限公司 | A kind of aqueous epoxy coating used for building exterior wall |
| CN107022279A (en) * | 2017-05-18 | 2017-08-08 | 福州大学 | A kind of preparation method of the wear-resisting super hydrophobic composite coating of high transparency |
-
2017
- 2017-12-13 CN CN201711325324.2A patent/CN108059861A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532968A (en) * | 2010-12-08 | 2012-07-04 | 上海控江中学附属民办学校 | Anti-skid road zebra crossing paint and preparation method thereof |
| CN104629580A (en) * | 2015-01-28 | 2015-05-20 | 西安中交万里新材料有限公司 | Long-acting environment-friendly ice-snow melting pavement coating and preparation method and using method of thereof |
| CN106147527A (en) * | 2016-07-19 | 2016-11-23 | 安徽圣德建材科技有限公司 | A kind of aqueous epoxy coating used for building exterior wall |
| CN107022279A (en) * | 2017-05-18 | 2017-08-08 | 福州大学 | A kind of preparation method of the wear-resisting super hydrophobic composite coating of high transparency |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109044655A (en) * | 2018-06-25 | 2018-12-21 | 常州市第二人民医院 | A kind of multi-functional disposition bed of Emergence |
| CN109294391A (en) * | 2018-08-15 | 2019-02-01 | 句容协鑫集成科技有限公司 | A kind of solar photovoltaic cell backplane adhesive |
| CN109777267A (en) * | 2018-12-21 | 2019-05-21 | 朱晶霞 | A kind of road zebra crossing paint |
| CN109880522A (en) * | 2019-03-05 | 2019-06-14 | 澜猫（天津）新材料科技有限公司 | A kind of super-hydrophobic PRTV(RTV) based composites and preparation method thereof, application method |
| CN109825140A (en) * | 2019-03-09 | 2019-05-31 | 华北水利水电大学 | Environment-friendly high-efficiency snow melt road surface coating material and its preparation method and application |
| CN109943177A (en) * | 2019-03-21 | 2019-06-28 | 华北水利水电大学 | Environment-friendly high-efficiency melting ice coating material and its preparation method and application |
| CN113604118A (en) * | 2021-06-29 | 2021-11-05 | 四川省公路规划勘察设计研究院有限公司 | Durable anti-freezing coating and preparation method thereof |
| CN114907749A (en) * | 2022-06-07 | 2022-08-16 | 广州中桥能源科技有限公司 | Material for preventing natural gas gasifier from frosting and freezing and preparation method thereof |
| CN115581015A (en) * | 2022-12-08 | 2023-01-06 | 山东超链智能科技有限公司 | Intelligent control device for elevator |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108059861A (en) | Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance and preparation method thereof | |
| CN104164819B (en) | The anti-skid surface of hydrophobic ice-melt and construction method thereof | |
| CN106634310B (en) | A kind of environment-friendly type aqueous marking paint and preparation method thereof | |
| KR100510845B1 (en) | Method of promoting the drying of water-based road marking paints and paints | |
| WO2012129742A1 (en) | Eco-friendly road surface coating material for thawing ice and snow and methods of preparing and using the same | |
| KR100935912B1 (en) | A System for anti-skid pavement of road using polymer cement mortar | |
| KR101261565B1 (en) | The Non-Slip Paint and Its Maikng Method | |
| CN102532968B (en) | Anti-skid road zebra crossing paint and preparation method thereof | |
| KR101449677B1 (en) | Elastic floor coatings for sports utility pavement | |
| CN103965757A (en) | Solvent-free bicomponent road marking paint | |
| US20150166883A1 (en) | Photoluminescent compositions and uses thereof | |
| CN108049277A (en) | Coloured silk slurry sealing and its method for being paved on road surface | |
| CN105295656A (en) | Skid-resistant coating and preparation method thereof | |
| CN112980266A (en) | Water-based self-luminous reflective rain and night marking coating and preparation method thereof, road marking and construction method thereof | |
| ES2947517T3 (en) | Water-based latex paint compositions for road marking | |
| CN110130172B (en) | Anti-freezing composite surface refining method for asphalt pavement | |
| CN106281187A (en) | Base material and graining layer bonding PUR glue and production technology thereof | |
| JP4159322B2 (en) | Water-based paint composition | |
| CN106830759B (en) | Hydrophobic anti-freeze antiskid layer material of one kind and preparation method thereof | |
| CN107032691A (en) | A kind of true mineral varnish of extra-weather-proof dry powder and its application method | |
| KR102110603B1 (en) | Non-Slip Road Flooring Maaterial For Forming Unevenness And Method For Producing The Same | |
| JPH0617563B2 (en) | Road marking method | |
| JPH03503431A (en) | Soil bed stabilization method | |
| JP2005008782A (en) | Asphalt emulsion composition | |
| KR101050393B1 (en) | Pavement block for surface strengthening and manufacturing method of pavement block for surface strengthening |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180522 |