CN102532968A - Anti-skid road zebra crossing paint and preparation method thereof - Google Patents
Anti-skid road zebra crossing paint and preparation method thereof Download PDFInfo
- Publication number
- CN102532968A CN102532968A CN2010105781409A CN201010578140A CN102532968A CN 102532968 A CN102532968 A CN 102532968A CN 2010105781409 A CN2010105781409 A CN 2010105781409A CN 201010578140 A CN201010578140 A CN 201010578140A CN 102532968 A CN102532968 A CN 102532968A
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- CN
- China
- Prior art keywords
- zebra crossing
- parts
- road zebra
- coating
- road
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241000283070 Equus zebra Species 0.000 title claims abstract description 37
- 239000003973 paint Substances 0.000 title claims abstract description 8
- 238000002360 preparation method Methods 0.000 title claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000011521 glass Substances 0.000 claims abstract description 17
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000012634 fragment Substances 0.000 claims abstract description 10
- 239000003822 epoxy resin Substances 0.000 claims abstract description 8
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960001124 trientine Drugs 0.000 claims abstract description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 5
- 239000002270 dispersing agent Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims description 24
- 239000011248 coating agent Substances 0.000 claims description 23
- 239000002002 slurry Substances 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 6
- DGSDBJMBHCQYGN-UHFFFAOYSA-M sodium;2-ethylhexyl sulfate Chemical compound [Na+].CCCCC(CC)COS([O-])(=O)=O DGSDBJMBHCQYGN-UHFFFAOYSA-M 0.000 claims description 5
- 239000001038 titanium pigment Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 238000004513 sizing Methods 0.000 abstract 2
- CQDDDLREQHQBRR-UHFFFAOYSA-N 1-cyanoethyl prop-2-enoate Chemical compound N#CC(C)OC(=O)C=C CQDDDLREQHQBRR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 239000011247 coating layer Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- DGSDBJMBHCQYGN-UHFFFAOYSA-N sodium;2-ethylhexyl hydrogen sulfate Chemical compound [Na+].CCCCC(CC)COS(O)(=O)=O DGSDBJMBHCQYGN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 238000005286 illumination Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Road Paving Structures (AREA)
- Road Signs Or Road Markings (AREA)
Abstract
The invention provides a road zebra crossing paint. The road zebra crossing paint comprises a sizing material and a curing agent, wherein the sizing material comprises the following components in parts by weight: 100 parts of a water-based acrylic emulsion, 10 to 20 parts of bisphenol A type epoxy resin, 0.5 to 1 part of 2-ethylhexyl sodium sulfate, 20 to 25 parts of titanium dioxide, 0.2 to 0.5 part of a dispersing agent, 2 to 5 parts of glass beads, 40 to 50 parts of glass fragments and 20 to 30 parts of water; and the curing agent comprises the following components in parts by weight: 100 parts of organic silicon modified acrylic resin, 20 to 30 parts of alpha-cyano-ethyl acrylate and 30 to 40 parts of triethylene tetramine. A coating layer prepared from the road zebra crossing paint which is provided by the invention has excellent anti-skid property and an eye-catching luminescent effect.
Description
Technical field
The present invention relates to a kind of anti-skidding road zebra crossing coating and preparation method thereof.
Background technology
At present, the coating that is used for brushing road zebra crossing has had certain anti-skid factor, but with respect to the asphalt road road surface, it is much level and smooth that road zebra crossing is wanted, and the automobile in advancing at a high speed even hold on the exsiccant road zebra crossing also can skid; Rainy day, it is more sliding to become.In addition, also there is relation on the anti-skidding and road surface of road zebra crossing, the road surface that some perviousness are bad, and coating " floating " easily in the above will be smooth a lot.If leave water stain in a large number, greasy dirt, mud etc. on the zebra stripes, it is more sliding to become.
In addition, though present employed road pattern sign coating has possessed certain reflecting effect, in the dark area that does not have the street lamp irradiation, its illumination effect is very unobvious, brings certain potential safety hazard for the driver and the pedestrian that passes by on one's way of night running.
Summary of the invention
The objective of the invention is to overcome the deficiency of above prior art, provide a kind of non-skid property and reflecting effect good road zebra crossing coating.
The technical scheme that the present invention adopts is:
A kind of road zebra crossing coating is characterized in that, comprises slurry and solidifying agent, wherein,
Said slurry comprises the component of following weight part:
100 parts of aqueous acrylic emulsions
Bisphenol A type epoxy resin 10-20 part
Sodium 2-ethylhexyl sulfate 0.5-1 part
White titanium pigment 20-25 part
Dispersion agent 0.2-0.5 part
Granulated glass sphere 2-5 part
Glass fragment 40-50 part
Water 20-30 part;
Said solidifying agent comprises the component of following weight part:
100 parts of organosilicon modified crylic acid resins
ECA 20-30 part
Triethylene tetramine 30-40 part.
Said granulated glass sphere is the glass granules with smooth surface, and its particle diameter is at 1-3mm.
The bottom surface of said glass fragment is a circular flat, and end face is sphere shape, and its bottom surface diameter is 1.5-2cm, and it highly is 2-3mm.
The molecular weight of said aqueous acrylic emulsion is greater than 200000, and acid number can be through commercially available acquisition at 50-55mg KOH/g.
The model of said bisphenol A type epoxy resin is DYD-127, like the strange DYD-127 type bisphenol A type epoxy resin produced of chemical industry ltd in Dalian.
The model of said dispersion agent is E-1308, like the E-1308 type dispersion agent of Hai'an, Jiangsu petrochemical industry ltd production.
The EA400 type organosilicon modified crylic acid resin that said organosilicon modified crylic acid resin selects for use Sanmu Group Co., Ltd., Jiangsu to produce.
Said slurry and solidifying agent be storage separately, mixes during use to get final product.Preferable, the weight ratio of said slurry and solidifying agent is 1-2: 1.
The present invention also further discloses the preparation method of above-mentioned road zebra crossing coating, it is characterized in that:
The preparation method of said slurry comprises the steps: by proportioning, earlier with water, white titanium pigment, sodium 2-ethylhexyl sulfate and dispersant and after being uniformly dispersed, adds other components and stirs;
The preparation method of said solidifying agent comprises the steps: by proportioning, organosilicon modified crylic acid resin, ECA and triethylene tetramine, and stirring obtains solidifying agent.
The present invention also further discloses a kind of road zebra crossing, by obtaining behind the road zebra crossing paint spay-coating as stated.
Preferable, the thickness of said road zebra crossing is 1-1.5mm.
The present invention adds glass fragment and bisphenol A type epoxy resin in road zebra crossing coating, and adopts the solidifying agent of special formulation simultaneously, can make firm being bonded in the zebra stripes coating of glass fragment.Because the height of glass fragment is greater than the thickness of zebra stripes coating, the coatingsurface that therefore makes is rough and uneven in surface, has improved the non-skid property of zebra stripes coatings greatly.In addition, because the reflection action of glass fragment, its reflective distance is even make zebra stripes also can have eye-catching illumination effect in the rainy day.
Embodiment
Further set forth the present invention below in conjunction with embodiment.Should be understood that these embodiment only are used to explain the present invention, and unrestricted scope of the present invention.
The weight part proportioning of each component is as shown in table 1 among the embodiment 1-4:
Wherein: it is the product of R-20B that aqueous acrylic emulsion is selected Haikechuan industry and trade ltd model for use; Bisphenol A type epoxy resin is selected the very DYD-127 of chemical industry ltd production of Dalian for use; The E-1308 type dispersion agent that dispersion agent selects for use Hai'an, Jiangsu petrochemical industry ltd to produce; The EA400 type organosilicon modified crylic acid resin that organosilicon modified crylic acid resin selects for use Sanmu Group Co., Ltd., Jiangsu to produce.The particle diameter of granulated glass sphere is at 1-3mm.The bottom surface of glass fragment is a circular flat, and end face is sphere shape, and its bottom surface diameter is 1.5-2cm, and it highly is 2-3mm.
Table 1
The preparation of slurry: by proportioning, earlier water, white titanium pigment, sodium 2-ethylhexyl sulfate and dispersion agent are added the paint cylinder, 1200 rev/mins at a high speed, disperseed 10 minutes; Adding remaining component then stirs and obtains slurry.
The preparation method of said solidifying agent comprises the steps: by proportioning, organosilicon modified crylic acid resin, ECA and triethylene tetramine, and stirring obtains solidifying agent.
After road zebra crossing is mixed by slurry material and solidifying agent, adopt conventional road zebra crossing spraying method to prepare.
With reference to transportation industry standard " pavement marking paint " JT/T 280-2004 coating is carried out performance test, the result is (Comparative Examples is the zebra stripes coating that generally uses on the present road surface) as follows:
Table 2
Claims (10)
1. a road zebra crossing coating is characterized in that, comprises slurry and solidifying agent, and wherein, said slurry comprises the component of following weight part:
100 parts of aqueous acrylic emulsions
Bisphenol A type epoxy resin 10-20 part
Sodium 2-ethylhexyl sulfate 0.5-1 part
White titanium pigment 20-25 part
Dispersion agent 0.2-0.5 part
Granulated glass sphere 2-5 part
Glass fragment 40-50 part
Water 20-30 part;
Said solidifying agent comprises the component of following weight part:
100 parts of organosilicon modified crylic acid resins
ECA 20-30 part
Triethylene tetramine v 30-40 part.
2. road zebra crossing coating as claimed in claim 1 is characterized in that, the particle diameter of said granulated glass sphere is 1-3mm.
3. road zebra crossing coating as claimed in claim 1 is characterized in that, the bottom surface of said glass fragment is a circular flat, and end face is sphere shape, and its bottom surface diameter is 1.5-2cm, and it highly is 2-3mm.
4. road zebra crossing coating as claimed in claim 1 is characterized in that, the model of said bisphenol A type epoxy resin is DYD-127.
5. road zebra crossing coating as claimed in claim 1 is characterized in that, the model of said dispersion agent is E-1308.
6. road zebra crossing coating as claimed in claim 1 is characterized in that, the model of said organosilicon modified crylic acid resin is EA400.
7. like arbitrary described road zebra crossing coating among the claim 1-6, it is characterized in that the weight ratio of said slurry and solidifying agent is (1-2): 1.
8. like the preparation method of arbitrary described road zebra crossing coating among the claim 1-7, it is characterized in that:
The preparation method of said slurry comprises the steps: by proportioning, earlier with water, white titanium pigment, sodium 2-ethylhexyl sulfate and dispersant and after being uniformly dispersed, adds other components and stirs;
The preparation method of said solidifying agent comprises the steps: by proportioning, organosilicon modified crylic acid resin, ECA and triethylene tetramine, and stirring obtains solidifying agent.
9. road zebra crossing is by as obtaining behind arbitrary described road zebra crossing paint spay-coating among the claim 1-7.
10. road zebra crossing as claimed in claim 9 is characterized in that, the thickness of said road zebra crossing is 1-1.5mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010578140 CN102532968B (en) | 2010-12-08 | 2010-12-08 | Anti-skid road zebra crossing paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010578140 CN102532968B (en) | 2010-12-08 | 2010-12-08 | Anti-skid road zebra crossing paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102532968A true CN102532968A (en) | 2012-07-04 |
| CN102532968B CN102532968B (en) | 2013-07-31 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010578140 Expired - Fee Related CN102532968B (en) | 2010-12-08 | 2010-12-08 | Anti-skid road zebra crossing paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102532968B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104710911A (en) * | 2015-03-08 | 2015-06-17 | 宁波高新区夏远科技有限公司 | Skid-resistant coating for towel rail and preparation method of skid-resistant coating |
| CN105176085A (en) * | 2015-09-25 | 2015-12-23 | 苏州莱特复合材料有限公司 | Composite for manufacturing automobile steering wheel and preparation method of composite |
| CN105295656A (en) * | 2015-11-25 | 2016-02-03 | 济南昊泽环保科技有限公司 | Skid-resistant coating and preparation method thereof |
| CN105860703A (en) * | 2016-04-21 | 2016-08-17 | 苏州群力防滑材料有限公司 | Antiskid composition with waterproof property |
| CN108059861A (en) * | 2017-12-13 | 2018-05-22 | 许飞扬 | Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance and preparation method thereof |
| CN109777267A (en) * | 2018-12-21 | 2019-05-21 | 朱晶霞 | A kind of road zebra crossing paint |
| CN110093083A (en) * | 2019-06-04 | 2019-08-06 | 浙江农林大学 | Reflective type modified acroleic acid quick-drying road mark paint and its preparation method and application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0874011A1 (en) * | 1997-04-22 | 1998-10-28 | Rohm And Haas Company | Wear-resistant traffic marking composition |
| CN1229110A (en) * | 1998-01-30 | 1999-09-22 | 默克专利股份有限公司 | Interference pigments having blue mass tone |
| CN101063019A (en) * | 2006-04-28 | 2007-10-31 | 郭接宁 | Aqueous long-acting reflecting road traffic marking paint |
| CN101125992A (en) * | 2007-09-18 | 2008-02-20 | 朱辰 | Water-based road guide line coating |
-
2010
- 2010-12-08 CN CN 201010578140 patent/CN102532968B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0874011A1 (en) * | 1997-04-22 | 1998-10-28 | Rohm And Haas Company | Wear-resistant traffic marking composition |
| CN1229110A (en) * | 1998-01-30 | 1999-09-22 | 默克专利股份有限公司 | Interference pigments having blue mass tone |
| CN101063019A (en) * | 2006-04-28 | 2007-10-31 | 郭接宁 | Aqueous long-acting reflecting road traffic marking paint |
| CN101125992A (en) * | 2007-09-18 | 2008-02-20 | 朱辰 | Water-based road guide line coating |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104710911A (en) * | 2015-03-08 | 2015-06-17 | 宁波高新区夏远科技有限公司 | Skid-resistant coating for towel rail and preparation method of skid-resistant coating |
| CN104710911B (en) * | 2015-03-08 | 2017-05-03 | 宁波高新区夏远科技有限公司 | Skid-resistant coating for towel rail and preparation method of skid-resistant coating |
| CN105176085A (en) * | 2015-09-25 | 2015-12-23 | 苏州莱特复合材料有限公司 | Composite for manufacturing automobile steering wheel and preparation method of composite |
| CN105295656A (en) * | 2015-11-25 | 2016-02-03 | 济南昊泽环保科技有限公司 | Skid-resistant coating and preparation method thereof |
| CN105860703A (en) * | 2016-04-21 | 2016-08-17 | 苏州群力防滑材料有限公司 | Antiskid composition with waterproof property |
| CN108059861A (en) * | 2017-12-13 | 2018-05-22 | 许飞扬 | Zebra stripes coating a kind of anti-skidding hydrophobic and with long-acting Thaw performance and preparation method thereof |
| CN109777267A (en) * | 2018-12-21 | 2019-05-21 | 朱晶霞 | A kind of road zebra crossing paint |
| CN110093083A (en) * | 2019-06-04 | 2019-08-06 | 浙江农林大学 | Reflective type modified acroleic acid quick-drying road mark paint and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102532968B (en) | 2013-07-31 |
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