KR100936266B1 - The color nonslip paving material for a road and the making method thereof and the paving method thereof - Google Patents

Abstract

PURPOSE: A color nonslip paving material for a road is provided to ensure strong abrasion resistance due to the use of brown molten alumina with high hardness, to maintain vivid color, and to reduce construction cost by reducing coating thickness by improved abrasion resistance. CONSTITUTION: A color nonslip paving material for a road comprises: a non-slip material(10) in which a base material and hardener in a weight ratio of 7:1; and a colored non-slip material(20) in which a binder resin and transparent fused alumina in a weight ratio of 1:10. The binder resin is obtained by mixing a pigment toner and a modified curing agent(MXDA Mannich) in a weight ratio of 4 : 1.

Description

The color nonslip paving material for a road and the making method approximately and the paving method

The present invention relates to a color non-slip packing material for the road to form a vivid color in order to inform the non-slip and dangerous areas of the vehicle by coating on the road, and a manufacturing method and construction method thereof, and more particularly, low price and high hardness By using brown fused alumina, strong abrasion resistance can be formed, and the color non-slip material coated with a curing agent on transparent fused alumina not only maintains vivid color for a long time, but also improves the wear resistance by using fused alumina The present invention relates to a color non-slip pavement for the road, and a manufacturing method and a construction method which can reduce construction costs by reducing the construction cost.

In general, various types of anti-slip compositions are applied to sloped roads and roads around schools to prevent slippage and prevent various accidents by sliding various vehicles or pedestrians on the road. In particular, in order to inspire the driver's alertness in harmony with the surrounding landscape, a variety of bright and colorful coatings are used.

As a conventional construction method for preventing slipping for roads, a method of attaching a slip resistant floor sheet to a road, a method for constructing with a fast curing type of polyurethane, a method using a polyester resin, a method using an acrylic resin, an epoxy resin Although it is being constructed by various methods such as using the method, the method of attaching the non-slip floor sheet to the road and the method using the polyurethane and polyester resin have a weak adhesive force, so that the peeling phenomenon occurs easily after a certain time and needs to be rebuilt. And, the method using the acrylic resin is abrasion resistance is weak and durable, the method using the epoxy resin is excellent in the anti-slip effect and adhesive strength but lacks the ductility there is a problem that occurs when detached with asphalt, overall Manufacturing cost and cost In addition, since some of the above construction methods are made by spraying anti-slip material, the sprayed non-slip material spreads into the air and not only pollutes the surrounding environment, but also the construction method is difficult and the construction period is long. there was.

In addition, the Republic of Korea Patent Publication No. 10-0831095 No. 10-0831095, previously filed by the present inventors in the non-slip material manufacturing method formed by mixing the main material and the curing agent in a constant ratio, bisphenol A-based on the jacket formed at 60 ℃ A liquid epoxy resin 38-42 weight ratio, texanol 4-4.5 weight ratio, amorphous precipitated silica 6-8 weight ratio, barium sulfate 38-42 weight ratio are mixed using a mixer, and the pigment composition 2.2-6.36 weight ratio and viscosity After mixing 5.6 to 6.6 weight ratio of the modifier at the same time, and further mixed with 0.08 to 0.12 weight ratio of the defoaming agent and 0.08 to 0.12 weight ratio of the coupling agent, the resin composition formed by mixing the weight ratio of the main agent and the curing agent in a ratio of 5: 1. The weight ratio of the non-slip material made of any one of the above resin composition and silica, alumina grit, copper slag, iron slag 1 Disclosed is a non-slip material manufacturing method and a non-slip floor construction method using the same.

However, the conventional non-slip material as described above could not cause the driver to be alert because the color is not noticeable, in particular, since the color must be re-installed soon after, the additional cost incurred after construction There was a problem.

In addition, the problem of increasing the construction cost by applying about 3 to 5mm when applying to the road for the non-slip because the hardness of the non-slip agent for slip prevention is not good.

In addition, as described above, since the hardness of the non-slip agent is not high, there is a problem in that breakage of the non-slip material that is constructed frequently requires continuous maintenance and reconstruction.

In order to achieve the above object, 2.5 to 2.8 parts by weight of natural cellulose fiber as a thickener and 25 to 28 parts by weight of glycidyl ester as a reactive diluent with respect to 25 to 28 parts by weight of bisphenol A epoxy resin, which is a binder containing 1.8 to 1.9% of chlorine. 2.8 parts by weight and 19 to 22 parts by weight of barite powder as filler for resin and 24 to 26 parts by weight of silica sand as nonslip agent, 19 to 22 parts by weight of brown fused alumina, 0.2 to 0.25 parts by weight of antifoaming agent and epoxy silane as silane coupling agent 0.1 to 0.15 parts by weight of a bisphenol A epoxy resin for producing a toner as a toner: a reactive diluent and a pigment for color expression, in which the weight ratio of the composition is formed by mixing so that the ratio of 1-2 is 1: 1. 0.8-1.2% of phosphorus low molecular unsaturated polycarboxylic acid polyester solution and low molecular acid polyester unsaturated polyamine amide salt solution, respectively 2 to 2.5 parts by weight of the prepared color paste was prepared to prepare a main body, and a non-slip material mixed with the main body and the curing agent in a weight ratio of 7: 1, a bisphenol A epoxy resin and a pigment for color expression: 1 A pigment toner prepared by mixing in a weight ratio, a binder resin mixed with a pigment toner and a modified binder (MXDA Mannich) in a weight ratio of 4: 1 is prepared, and the binder resin and the transparent molten alumina in a weight ratio of 1:10. It is a feature of the present invention to consist of a mixed color nonslip material.

The color non-slip pavement material of the present invention and its manufacturing method and construction method can be used even in winter by using bisphenol A epoxy containing chlorine to maintain the liquid state even at low temperatures, and low price The use of high hardness brown fused alumina can form strong wear resistance.

In addition, by using bisphenol A epoxy, which is the same binder as the non-slip material, when the color non-slip material is sprayed after applying the non-slip material, the adhesion between the non-slip material and the color non-slip material can be maintained for a long time, in particular, transparent Color non-slip material produced by coating pigments of various colors on the molten alumina with a hardener is applied to the surface of the anti-slip material, which not only makes the driver noticeable, but also the color of the part of the surface of the transparent molten alumina. Even if this peels off, the color of the backside is reflected by the peeled off part of the transparent molten alumina, so that the vivid color can be maintained for a long time.

In addition, it is a useful invention that can achieve the same anti-slip effect, even if the coating thickness of 2 to 3mm by using a molten alumina of high hardness can be obtained, reducing the cost.

Hereinafter, the configuration of the present invention in more detail.

The present invention is divided into a non-slip material (10) made of a main agent and a hardener and a color non-slip material (20) for reducing the cost by improving the clarity and wear resistance of the color.

First, the anti-slip material 10 is 2.5 to 2.8 parts by weight of natural cellulose fiber as a thickener and 25 to 28 parts by weight of bisphenol A epoxy resin, which is a binder containing 1.8 to 1.9% chlorine, and glycidyl ester 2.5 as a reactive diluent. 2.8 parts by weight and 19 to 22 parts by weight of barite powder as filler for resin and 24 to 26 parts by weight of silica sand as nonslip agent, 19 to 22 parts by weight of brown fused alumina, 0.2 to 0.25 parts by weight of antifoaming agent and epoxy as silane coupling agent. 0.1 to 0.15 parts by weight of silane and a toner, a bisphenol A epoxy resin for producing a toner: a reactive diluent and a pigment for color expression, respectively, in a weight ratio of 1 to 2: 1, respectively. Color paper prepared by adding 0.8 ~ 1.2% of low molecular unsaturated polycarboxylic acid polyester solution and low molecular acid polyester unsaturated polyamine amide salt solution, respectively. To prepare a main body by mixing 2 to 2.5 parts by weight of the stratum, and prepared by mixing the main body and the curing agent in a weight ratio of 7: 1,

The color non-slip material 20 is a pigment toner prepared by mixing a bisphenol A epoxy resin with a pigment for color expression in a weight ratio of 1: 1, and a modified toner (MXDA Mannich) which is the pigment toner and a binder in a weight ratio of 4: 1. To prepare a mixed binder resin, by mixing the binder resin and the transparent molten alumina in a weight ratio of 1: 10 to prepare a color non-slip material (20),

When the non-slip material 10 is applied at a thickness of 2 to 3 mm per 1 m 2, the color non-slip material 20 is formed at a ratio of 100 to 200 g per 1 m 2.

When the binder bisphenol A liquid epoxy resin is processed by mixing various fillers, it is crystallized in a semi-solid state within a few days when the air temperature is 0 ℃ or less, and when used in the liquid to be reduced to a liquid state to be maintained at 40 ℃ or more for several hours, used in winter Although it is difficult to solve the problem, in the present invention, by using 25 to 28 parts by weight of bisphenol A epoxy resin containing 1.8 to 1.9% of chlorine, the liquefaction temperature is formed to be lowered, so that it can be easily used even in winter. The bisphenol A epoxy resin used was Epoto YD-115CA manufactured by Kukdo Chemical Co., Ltd.

Natural cellulose fiber, the thickener, is a natural insoluble cellulose obtained from wood (for example, willow) and was used as an asbestos substitute material, and 30 to 50% of the amount of asbestos can exhibit the same effect as asbestos.

This natural cellulose is insoluble in water and organic solvents, resistant to dilute acids and alkalis, and is physiologically toxic.

In the present invention, 2.5 to 2.8 parts by weight of natural cellulose fibers pulverized in a fiber state are mixed with 25 to 28 parts by weight of chlorine-containing bisphenol A epoxy resin to form a three-dimensional structure with a strong cross-linking effect, thereby providing abrasion resistance. The thickening effect according to the sedimentation prevention of silica sand or fused alumina can be obtained, so that the uneven shape is easily formed, and the crack prevention effect is also generated.

The natural cellulose fiber pulverized in the fiber state is preferably used having a length of 1000㎛, 45㎛ thickness.

Glycidyl ester, a reaction diluent, is a reactive diluent of a typical epoxy resin, and has an epoxy equivalent (g / ey) of 240 to 265, a viscosity of 5 to 20 (25 ° C Cps) and a specific gravity (20 ° C) of 0.970 to 0.975. It has less irritation and smell and lower toxicity than Glycidyl Ether) or AGE (Allyl Glycidyl Ether). It is compatible with bisphenol A epoxy resin and has good dilution effect. It plays a similar role in controlling and acts to prevent degradation of water resistance and durability without changing the overall physical properties while reacting with the curing agent.

In the present invention, 2.5 to 2.8 parts by weight of glycidyl ether is added to and mixed with 25 to 28 parts by weight of bisphenol A epoxy resin containing chlorine, but when added to less than 2.5 parts by weight, ductility does not occur and hardness is increased. On the contrary, if it exceeds 2.8 parts by weight, the physical properties become soft, and the overall physical property change occurs and the adhesion decreases.

As the filler for resin, the barite powder has a specific gravity of 4.3 and is resistant to dilute acid and alkali, and is not dissolved by water, an organic solvent and an acid, and has good alkali resistance.

In the present invention, a filler for resin is used to impart viscosity to form irregularities with natural cellulose fibers, and 2.5 to 2.8 parts by weight of natural cellulose fiber is added to 25 to 28 parts by weight of bisphenol A epoxy resin containing chlorine. In the white powder state in which the barite is ground and demineralized by mixing, the particle size is 43 to 46 μm, but more preferably, the particle size is 45 μm (325 mesh).

As the non-slip agent, silica sand and brown molten alumina are materials for preventing slip, and in the present invention, 24 to 26 parts by weight of silica sand and 19 to 22 parts by weight of brown molten alumina are added to 25 to 28 parts by weight of bisphenol A epoxy resin containing chlorine. Mix.

The silica sand is used as a white powder having a particle size of 1mm or less, and brown molten aluminium is also used to have a particle size of 1mm.

In general, roads are often sprayed with calcium chloride to prevent slippage caused by snow falling in winter, and acid rain due to environmental pollution is also frequent.

The molten alumina in the present invention is not easily damaged by the above-mentioned disaster due to wear resistance and alkali resistance, and in particular, as shown in the following [Table 1], even with a small amount of high hardness, sufficient anti-slip resistance is caused by wear resistance. The effect can be obtained.

TABLE 1

The antifoaming agent is to destroy bubbles generated in the color non-slip material 10 for roads, and in the present invention, a polysiloxane solution (incompatible material), which is a silicone-based antifoaming agent that provides excellent antifoaming property even in a small amount, is used. 0.2 to 0.25 parts by weight of the antifoaming agent is added to and mixed with 25 to 28 parts by weight of the bisphenol A epoxy resin containing. In order to obtain the best antifoaming effect, it is preferable to add the antifoaming agent before the dispersing step.

The silane coupling agent, epoxy silane, has two or more different reactors in its molecule, one of which is a reactor (methoxy group, epoxy, etc.) that chemically bonds with an inorganic material (such as asphalt or gravel, sand, and glass metal). The other is a reactor (vinyl group, epoxy group, amino group, methacryl group, mercapdo group, etc.) which is combined with organic materials (various synthetic resins such as epoxy, phenol, and meramine).

In other words, in the present invention, 0.1 to 0.15 parts by weight of epoxy silane is added and mixed with 28 to 28 parts by weight of bisphenol A epoxy resin containing chlorine. When the invention is installed on the road to act to strongly adhere to the porous plate made of concrete, asphalt and metal, so that the present invention does not occur peeling phenomenon after time.

The color paste, a toner, is a bisphenol A epoxy resin containing chlorine for preparing a toner: a low molecular weight polyunsaturated polyunsaturated wet dispersant based on the total weight of a composition mixed with a weight ratio of a reactive diluent and a pigment for color expression. It is prepared by adding 0.8 to 1.2% of a carboxylic acid polyester solution and a low molecular weight polyester unsaturated polyamine amide salt solution, respectively. In the present invention, color pastes 2 to 2.5 to 25 to 28 parts by weight of bisphenol A epoxy resin containing chlorine Add and mix the weight ratio.

Here, when the pigment of the said color paste is an organic pigment, 44-46 weight part of organic pigments, 9-9.5 weight part of reactive diluents, and moisture with respect to 44-46 weight part of bisphenol A epoxy resins containing chlorine for manufacturing a toner 0.44 to 0.46 parts by weight of a dispersant, and when it is an inorganic pigment, 49 to 50 parts by weight of an inorganic pigment and 0.44 to 0.46 parts by weight of a wet dispersant based on 49 to 50 parts by weight of a bisphenol A epoxy resin containing chlorine.

In addition, the wet dispersant is to disperse the pigments mixed with inorganic pigments and organic pigments, so as not to reaggregate, to accelerate the rate at which the aggregates of the pigments are wetted in the resin solution, and to improve the stability of the pigment dispersion. .

In the present invention, 0.8 to 1.2% of the low molecular weight unsaturated polycarboxylic acid polyester solution and the low molecular weight acidic polyester unsaturated polyamide salt solution were added to the total weight of the bisphenol A epoxy resin, the reaction stone diluent, and the pigment. .

The curing agent is used by mixing 3 to 6 parts by weight of the curing accelerator with respect to 94 to 96 parts by weight of the modified curing agent (MXDA Mannich).

The modified hardener exhibits sufficient hardened material properties by itself, and has good chemical resistance weather resistance, which is sufficient hardening time even when used for summer and spring and autumn, and can be used for two hours at 25 ° C., but it is a hardening accelerator as in the present invention. When phosphorus 2, 4, 6 tri (dimethylaminomethyl) phenol is mixed with 3 to 6 parts by weight of a curing accelerator with respect to 94 to 96 parts by weight of a curing agent, the vehicle passes after 3 to 4 hours at 10 ° C. and 1 hour at 30 ° C. This is possible.

On the other hand, the color non-slip material (20) is coated with a color to a transparent alumina with high wear resistance and hardness using a binder, after applying the non-slip material (10) on the road by spraying to increase the anti-slip efficiency while increasing the driver's alert To form a vivid color so as to stimulate the hardening agent, the curing agent by mixing 94 ~ 96 parts by weight of the modified curing agent (MXDA Mannich) and 3 to 6 parts by weight of 2, 4, 6 tri (dimethylaminomethyl) phenol which is a curing accelerator Manufacture.

Here, the pigments used for the non-slip material 10 and the color non-slip material 20 are as shown in Table 2 below.

TABLE 2

The present invention refrains from using cement, urethane, polyester, etc., in which pigment dispersion is not properly performed as in the prior art, and blends one or more pigments with various kinds of pigments as described above in a peripheral view or a vivid color desired by a user. It is possible to form a variety of colors.

Hereinafter, the manufacturing method of the color non-slip pavement according to the present invention is as follows.

25 to 28 parts by weight of a bisphenol A epoxy resin, which is a binder containing 1.8 to 1.9% of chlorine as a binder at a jacket temperature of 60 to 90 ° C., and 2.5 to 2.8 parts by weight of natural cellulose fiber having a thickness of 1,000 μm and a thickness of 45 μm. The mixture was added and dispersed in a primary mixer for 3 to 5 minutes, and then 2.5 to 2.8 parts by weight of glycidyl ester as a reactive diluent was added, followed by a secondary mixer to lower the viscosity, followed by grinding and classifying barite as a resin filler. 19 to 22 parts by weight of barite powder having a particle size of 43 to 46 µm was added and dispersed by a third mixer for 3 to 5 minutes, followed by 24 to 26 parts by weight of silica sand having a particle size of 1 mm or less as a white powder having a purity of 99% or more. 19 to 22 parts by weight of brown molten alumina having a particle size of 1 mm or less and 4 to 4 minutes in a state of quaternary mixer, 0.2 to 0.25 parts by weight of an antifoaming agent and 0.1 to 0.15 parts by weight of epoxy silane as a silane coupling agent. Low molecular weight unsaturated polycarboxylic acid polyester solution, low molecular weight acid polyester, and wet dispersion agent to the total weight of the composition containing 1 ~ 2: 1 by weight of reactive diluent and pigment for color expression, respectively. 0.8 to 1.2% of each unsaturated polyamine amide salt solution was added to the mixture, and then, 2 to 2.5 parts by weight of color paste, which was prepared by dispersing three times on three rollers, was mixed for 5 to 4 minutes to prepare a subject.

Here, when the said color paste is an organic pigment, 44-46 weight part of organic pigments, 9-9.5 weight part of reactive diluents, and a wet dispersant 0.44 with respect to 44-46 weight part of bisphenol A epoxy resins containing chlorine for toner manufacture when it is an organic pigment. After mixing with 0.46 parts by weight, the mixture is dispersed three times with three rollers, and in the case of inorganic pigments, 49-50 parts by weight of inorganic pigments and wet to 49-50 parts by weight of bisphenol A epoxy resin containing chlorine. 0.44 to 0.46 parts by weight of a dispersant is added and mixed, followed by dispersing three times on three rollers to produce the same.

Next, 94 to 96 parts by weight of a modified hardening agent (MXDA Mannich) and 3 to 6 parts by weight of 2, 4, and 6 tri (dimethylaminomethyl) phenol, which are curing accelerators, were mixed to prepare a curing agent, and then the main body and the curing agent prepared above, respectively. To prepare a non-slip material 10 is mixed in a weight ratio of 7: 1:

Here, the anti-slip material (10) is used to mix the master and the curing agent prepared in each field before the construction of 7: 1, in particular, after mixing the main agent and the curing agent 5 to 10 minutes before use It is preferable.

The color non-slip material 20 mixed with the non-slip material 10 is a bisphenol A epoxy resin and a pigment for color expression as 1: 1, respectively, and is added to the three rollers together with a pigment dispersant, and then 2-3. Disperse times to prepare a pigment toner, and the dispersed pigment toner and a binder modifier (MXDA Mannich) in a weight ratio of 4: 1 to prepare a binder resin, the binder resin and the transparent molten alumina of 1: 10 Prepared by mixing in a blender in weight ratio for 5 to 10 minutes and then drying,

When the non-slip material 10 is applied at a thickness of 2 to 3 mm per 1 m 2, the color non-slip material 20 is sprayed onto the surface of the non-slip material 10 applied to the road at a rate of 100 to 200 g per 1 m 2. It is preferable to form.

Looking at the construction method of the color non-slip pavement material of the present invention as follows.

First, remove oil, moisture, and other foreign matter from the construction surface. If the construction surface is concrete, cure for 2 weeks or more in the summer and 3 weeks or more in the winter, and then attach the adhesive masking tape according to the shape to be applied to the construction surface. do.

Next, the main body, the hardening agent, and the color non-slip material 20 of the anti-slip material 10 are manufactured.

First, look at the manufacturing process of the non-slip material,

25 to 28 parts by weight of a bisphenol A epoxy resin, which is a binder containing 1.8 to 1.9% of chlorine relative to the total weight of bisphenol A epoxy resin as a binder at a jacket temperature of 60 to 90 ° C., and a thickener having a thickness of 1,000 μm and a thickness of 45 μm. 2.5 to 2.8 parts by weight of cellulose fibers were added and dispersed in a primary mixer for 3 to 5 minutes, and then 2.5 to 2.8 parts by weight of glycidyl ester as a reactive diluent was added and the mixture was lowered to lower the viscosity, and barite was used as a filler for resin. 19-22 parts by weight of barite powder with a particle size of 43-46 μm was added to the white powder demineralized by pulverization, followed by a third mixer for 3 to 5 minutes to disperse. White powder having a purity of 99% or more as a non-slip agent was 1 mm in particle size. 0.2 to 0.25 parts by weight of a defoamer and a silane coupler in a state of mixing 4 to 26 parts by weight of siliceous sand or less and 19 to 22 parts by weight of brown molten alumina having a particle size of 1 mm or less and mixing for 4 to 5 minutes. The bisphenol A epoxy resin, the reactive diluent and the pigment may be added to a composition in which a reactive diluent and a pigment for color expression are mixed at a weight ratio of 0.1 to 0.15 parts by weight of the epoxy silane and the bisphenol A epoxy resin, respectively. The low molecular weight unsaturated polycarboxylic acid polyester solution and the low molecular acid polyester unsaturated polyamine amide salt solution, which are the wet dispersant to the total weight of the mixed composition, were added 0.8 to 1.2%, respectively, and mixed by dispersing three times on three rollers. 2 to 2.5 parts by weight of color paste, which is a toner, was poured into a fifth mixer for 4 to 6 minutes to prepare a main body.

A curing agent is prepared by mixing 94 to 96 parts by weight of a modified curing agent (MXDA Mannich) and 3 to 6 parts by weight of 2, 4, and 6 tri (dimethylaminomethyl) phenol, which are curing accelerators.

The anti-slip material 10 is prepared by mixing the main material and the curing agent in a weight ratio of 7: 1.

In addition, a bisphenol A epoxy resin and a pigment for color expression are set to 1: 1, and the pigment toner is prepared by dispersing it in three rollers with a pigment dispersant two to three times to prepare a pigment toner. (MXDA Mannich) by mixing the weight ratio of 4: 1 to prepare a binder resin, the binder resin and the transparent molten alumina in a weight ratio of 1: 10 to a mixer in a blender for 5 to 10 minutes and dried to produce a color The non-slip material 20 is produced.

Then, apply the non-slip composition evenly to the construction surface with a metal trowel or a rubber spatula to a thickness of 2 to 3mm, and then put a large washer and a small washer on the shaft in order to form an uneven roller or a common tooth Forming the bottom surface by forming a non-slip material (10) evenly laid on the construction surface in the form of unevenness using a rubber or steel scrap.

At this time, the non-slip material 10 should be used within 5 to 10 minutes after manufacture.

Then, before the non-slip material 10 is initially cured (within 5 minutes at 25 ℃), after spraying the color non-slip material 20 100 ~ 200g per 1 m 2 by a conventional spraying method, the anti-slip material Before (10) is hardened, remove the adhesive masking tape to complete the construction method.

At this time, when the color paste is an organic pigment, 44 to 46 parts by weight of an organic pigment, 9 to 9.5 parts by weight of a reactive diluent, and a wet dispersant, based on 44 to 46 parts by weight of a bisphenol A epoxy resin containing chlorine for producing a toner. 0.44 to 0.46 parts by weight of a mixer, which is then dispersed three times with three rollers. If the color paste is an inorganic pigment, 49 to 50 parts by weight of bisphenol A epoxy resin containing chlorine for preparing toner 49-50 parts by weight of the inorganic pigment and 0.44 to 0.46 parts by weight of the wet dispersant were mixed and mixed, and then dispersed three times on three rollers.

1 is a flow chart illustrating a construction method of the color non-slip pavement for roads according to the present invention.

Figure 2 is a state diagram showing the construction method of the color non-slip pavement for road according to the present invention.

◈Description of code for main parts of drawing

10: non-slip material 20: color non-slip material

50: color non-slip pavement for road

Claims (10)

2.5 to 2.8 parts by weight of natural cellulose fiber as a thickener and 2.5 to 2.8 parts by weight of glycidyl ester as a reactive diluent and a filler for resin as a thickener with respect to 25 to 28 parts by weight of bisphenol A epoxy resin which is a binder containing 1.8 to 1.9% of chlorine. 19 to 22 parts by weight of barite powder, 24 to 26 parts by weight of silica sand as a non-slip agent, 19 to 22 parts by weight of brown fused alumina, 0.2 to 0.25 parts by weight of antifoaming agent, 0.1 to 0.15 part by weight of epoxy silane as silane coupling agent, and toner A bisphenol A epoxy resin for preparing a toner: a low molecular weight unsaturated polycarboxylic poly, which is a wet dispersion agent based on the total weight of a composition formed by mixing a weight ratio of a reactive diluent and a pigment for color expression in a ratio of 1 to 2: 1, respectively. Color paste 2 to 2.5 prepared by adding 0.8 to 1.2% of an ester solution and a low molecular acid polyester unsaturated polyamine amide salt solution, respectively. 1 and a non-slip material 10 mixed in a weight ratio of: the amount of parts and mixed to prepare a subject, wherein the base resin, the curing agent, the 7 A pigment toner prepared by mixing a bisphenol A epoxy resin and a pigment for color expression in a weight ratio of 1: 1, and a binder resin obtained by mixing the pigment toner and a binder modified resin (MXDA Mannich) in a weight ratio of 4: 1, Color non-slip pavement, characterized in that the binder resin and the transparent molten alumina made of a color non-slip material 20 mixed in a weight ratio of 1: 10. The method of claim 1, wherein the natural cellulose fiber has a length of 1,000㎛, the thickness of 45㎛ non-slip pavement, characterized in that the thickness. The color slippery pavement for roads according to claim 1, wherein the barite is a white powder obtained by grinding and classifying barite, and having a particle size of 43 to 46 µm. The color slippery pavement for roads according to claim 1, wherein the silica is white powder having a purity of 99% or more and a particle size of 1 mm or less. The method of claim 1, wherein the brown molten alumina of the non-slip material 10 and the transparent molten alumina of the color nonslip material 20 have a hardness of 12, a Knoop hardness of 1700 to 2500 and a particle size of 1 mm or less. Color non-slip pavement for roads. The color of the road according to claim 1, wherein the curing agent is a mixture of 94 to 96 parts by weight of a modified curing agent (MXDA Mannich) and 3 to 6 parts by weight of 2, 4, and 6 tri (dimethylaminomethyl) phenol, which are curing accelerators. Non-slip packaging. The non-slip material 10 and the color non-slip material 20 according to claim 1, wherein the color non-slip material 20 is 1 m 2 when the non-slip material 10 is applied at a thickness of 2 to 3 mm per 1 m 2. Color anti-skid pavement, characterized by being formed at a ratio of 100 to 200 g per sugar. 25 to 28 parts by weight of a bisphenol A epoxy resin, which is a binder containing 1.8 to 1.9% of chlorine as a binder at a jacket temperature of 60 to 90 ° C., and 2.5 to 2.8 parts by weight of natural cellulose fiber having a thickness of 1,000 μm and a thickness of 45 μm. The mixture was added and dispersed in a primary mixer for 3 to 5 minutes, and then 2.5 to 2.8 parts by weight of glycidyl ester as a reactive diluent was added, followed by a secondary mixer to lower the viscosity, followed by grinding and classifying barite as a resin filler. 19 to 22 parts by weight of barite powder having a particle size of 43 to 46 µm was added and dispersed by a third mixer for 3 to 5 minutes, followed by 24 to 26 parts by weight of silica sand having a particle size of 1 mm or less as a white powder having a purity of 99% or more. 19 to 22 parts by weight of brown molten alumina having a particle size of 1 mm or less and 4 to 4 minutes in a state of quaternary mixer, 0.2 to 0.25 parts by weight of an antifoaming agent and 0.1 to 0.15 weight of epoxy silane as a silane coupling agent. As a toner, bisphenol A epoxy resin: a low molecular weight unsaturated polycarboxylic acid polyester solution and a low molecular acid poly, which are a wet dispersion agent to the total weight of a composition in which the weight ratio of the reactive diluent and the pigment for color expression are mixed in a ratio of 1 to 2: 1, respectively. 0.8 to 1.2% of the ester and unsaturated polyamine amide salt solution were added respectively to the mixer, and then, 2 to 2.5 parts by weight of color paste, a toner prepared by dispersing three times on three rollers, was mixed for 5 to 4 minutes to prepare a main body. and, A curing agent is prepared by mixing 94 to 96 parts by weight of a modified curing agent (MXDA Mannich) and 3 to 6 parts by weight of 2, 4, and 6 tri (dimethylaminomethyl) phenol, which are curing accelerators. The anti-slip material 10 is prepared by mixing the main material and the curing agent in a weight ratio of 7: 1, The color non-slip material 20 used in the non-slip material 10 is mixed with a bisphenol A epoxy resin and a pigment for color expression in a ratio of 1: 1. A pigment toner is prepared by dispersing, and the dispersed pigment toner is mixed with a modified binder (MXDA Mannich) in a weight ratio of 4: 1 to prepare a binder resin, and the binder resin and the transparent molten alumina are weight ratio of 1:10. A method for producing color slippery pavement for roads, which is characterized in that it is put into a mixer and dried after mixing for 5 to 10 minutes. The non-slip material 10 and the color non-slip material 20 according to claim 8, wherein the color non-slip material 20 is 1 m 2 when the non-slip material 10 is applied to a thickness of 2 to 3 mm per 1 m 2. A method for producing color slippery pavement for roads, characterized by being formed at a ratio of 100 to 200 g per sugar. Remove oil, water and other foreign matter from the construction surface, and if the construction surface is concrete, cure it for 2 weeks or more in the summer and 3 weeks or more in the winter, and then attach and mark the adhesive masking tape according to the shape to be installed on the construction surface. 25 to 28 parts by weight of a bisphenol A epoxy resin, which is a binder containing 1.8 to 1.9% of chlorine as a binder at a jacket temperature of 60 to 90 ° C., and 2.5 to 2.8 parts by weight of natural cellulose fiber having a thickness of 1,000 μm and a thickness of 45 μm. The mixture was added and dispersed in a primary mixer for 3 to 5 minutes, and then 2.5 to 2.8 parts by weight of glycidyl ester as a reactive diluent was added, followed by a secondary mixer to lower the viscosity, followed by grinding and classifying barite as a resin filler. 19 to 22 parts by weight of barite powder having a particle size of 43 to 46 µm was added and dispersed by a third mixer for 3 to 5 minutes, followed by 24 to 26 parts by weight of silica sand having a particle size of 1 mm or less as a white powder having a purity of 99% or more. 19 to 22 parts by weight of brown molten alumina having a particle size of 1 mm or less and 4 to 4 minutes in a state of quaternary mixer, 0.2 to 0.25 parts by weight of an antifoaming agent and 0.1 to 0.15 parts by weight of epoxy silane as a silane coupling agent. And bisphenol A epoxy resin: a low molecular weight unsaturated polycarboxylic acid polyester solution and a low molecular acid polyester unsaturated polyamine amide, which are a wet dispersion agent to the total weight of the composition in which the weight ratio of the diluent and the pigment for color expression are mixed in a ratio of 1 to 2: 1, respectively. 0.8 to 1.2% of the salt solution was added to each mixer, and then dispersed three times on three rollers. Toner was prepared by mixing 2 to 2.5 parts by weight of color paste, and mixing it for 5 to 5 minutes to prepare a main body. A curing agent is prepared by mixing 94 to 96 parts by weight of a modified curing agent (MXDA Mannich) and 3 to 6 parts by weight of 2, 4, and 6 tri (dimethylaminomethyl) phenol, which are curing accelerators. After manufacturing the anti-slip material 10 mixed with the main agent and the curing agent in a weight ratio of 7: 1, the anti-slip composition is evenly applied to the thickness of 2-3 mm with a iron trowel or a rubber spatula on the construction surface and then large diameter Compaction work by forming a non-slip material (10) evenly installed on the construction surface by using a washer and a roller with a small diameter in order to form a concave-convex shape or a regular toothed rubber or steel Before the non-slip composition is initially cured (within 5 minutes at 25 ℃), the bisphenol A epoxy resin and the pigment for color expression is 1: 1 and added to the three rollers with a pigment dispersant. 2 to 3 times to prepare a pigment toner, and the dispersed pigment toner and a binder modified modifier (MXDA Mannich) in a weight ratio of 4: 1 to prepare a binder resin, the vine After the resin and the transparent molten alumina were added to the blender at a weight ratio of 1: 10, the mixer was mixed for 5 to 10 minutes, dried, and then sprayed with 100 to 200 g per 1 m 2 of the non-slip composition. A method for constructing a non-slip pavement for roads, characterized in that the adhesive masking tape is removed before curing.

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