CN107880698A - A kind of acrylic acid environmental protection enamel paint - Google Patents
A kind of acrylic acid environmental protection enamel paint Download PDFInfo
- Publication number
- CN107880698A CN107880698A CN201711295294.5A CN201711295294A CN107880698A CN 107880698 A CN107880698 A CN 107880698A CN 201711295294 A CN201711295294 A CN 201711295294A CN 107880698 A CN107880698 A CN 107880698A
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- China
- Prior art keywords
- acrylic acid
- parts
- environmental protection
- enamel paint
- acid environmental
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/23—Magnetisable or magnetic paints or lacquers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of acrylic acid environmental protection enamel paint, belong to coating material production technical field.The acrylic acid environmental protection enamel paint of the present invention, including following raw material：Carboxyl acrylic resin, glycerine, filler, nano-kaolinite and nano montmorillonite mixed thing, levelling agent, dispersant, thickener, wetting agent, pigment, deionized water.The acrylic acid environmental protection enamel paint of the present invention is by preparing made of the series of steps such as acrylic resin, configuration, mixing.The acrylic acid environmental protection enamel paint of the present invention, raw material sources are extensive, proportioning science, have the advantages of viscosity amount of increase is small, friction resistant power is good, environmentally friendly.
Description
Technical field
The invention belongs to coating material production technical field, and in particular to a kind of acrylic acid environmental protection enamel paint.
Background technology
Acrylic paint has fabulous weatherability, very high mechanical performance, is a kind of coating that have developed rapidly.Acrylic paint
Self-drying acrylic paint can be divided into（Thermoplastics type）With crosslinking curing type acrylic paint（Heat curing-type）, the former belongs to nonconvertible painting
Material, the latter belong to convertion coating.Self-drying acrylic coating is mainly used in building coating, plastic paint, electronic paint, road
Line coatings etc., have that surface drying is rapid, is easy to construction, protection and decorative effect clear advantage.Shortcoming is that solid content is not easy
Too high, hardness, elasticity are not easy to take into account, and once construction can not obtain very thick film, and film fullness is not ideal enough.Crosslinking is solid
Change type acrylic coating mainly has acrylic-amino paint, acrylic polyurethane coating, acrylic acid alkyd paint, radiation curing acrylic acid to apply
The kinds such as material.It is widely used in car paint, electric appliance paint, woodwork coating, building coating etc..Crosslinking curing type acrylic acid applies
Material typically all has very high solid content, and an application can obtain very thick film, and good mechanical performance, can be made
High-weatherability, high richness, high resiliency, the coating of high rigidity.Shortcoming is two-component coating, cumbersome, many kinds of constructing
Also need to be heating and curing or radiation curing, higher is required to environmental condition, is typically necessary preferable equipment, more skilled painting
Fill skill.
Acrylic enamel is by acrylic resin, adds the polished addition organic solvent preparation of various pigment and plasticizer
Form.It is mainly used in chinaware, ceramic tile surface protection.In recent years, with the continuous lifting of customer demand, acrylic enamel by
In its cost is low, protection is good, persistence is good the advantages that, extensively liked by consumer.The associated formula technology of acrylic enamel
It is evolving.
The content of the invention
The invention provides a kind of acrylic acid environmental protection enamel paint, with solve acrylic enamel persistence is poor, preparation technology excessively
Complicated, solvent not environmentally the problem of.
The present invention uses following technical scheme：A kind of acrylic acid environmental protection enamel paint, by following weight than raw material prepare：Carboxyl
35 ~ 50 parts of acrylic resin, 9 ~ 17 parts of glycerine, 8 ~ 22 parts of filler, nano-kaolinite and nano montmorillonite mixed thing 15 ~ 28
Part, 2 ~ 10 parts of levelling agent, 3 ~ 11 parts of dispersant, 2 ~ 9 parts of thickener, 2.5 ~ 8.5 parts of wetting agent, 6 ~ 15 parts of pigment, deionized water
32 ~ 46 parts.
The filler is mica powder or wollastonite.
Described thickener is one kind in HEC, PEO, HPAM.
The levelling agent is one kind in acrylic ester type levelling agent.
The wetting agent is the wetting agent that BASF AG's production model is Hydropalat 875.
The dispersant is polyethylene glycol 200 or polyethylene glycol 400.
The preparation method of the carboxyl acrylic resin is as follows：Toluene and butyl methacrylate are pressed 1:1.5 mixing, add
Enter into reactor, heating stirring；After water temperature rises to 80 DEG C, by styrene by evenly mixing, methyl methacrylate,
Acrylic acid, AIBN at the uniform velocity instill mixed solution, are added dropwise under 80 DEG C of constant temperature in 2h, continue to react 4h, stop heating and are
Obtain carboxyl acrylic resin.
The acrylic acid environmental protection enamel paint of the present invention, raw material sources extensively, proportioning science, have that viscosity amount of increase is small, friction resistant power
The advantages of good, environmentally friendly.
Embodiment
Below by more specific embodiment, the present invention will be described.For ease of more fully understanding the present invention, by following
Example is illustrated, and these examples belong to protection scope of the present invention, but do not limit the scope of the invention.
The acrylic acid environmental protection enamel paint of the present invention of embodiment 1, by following weight than raw material prepare：35 parts of acrylic resin,
9 parts of glycerine, filler（Mica powder）8 parts, nano-kaolinite and 15 parts of nano montmorillonite mixed thing, acrylic ester type levelling agent 2
Part, 3 parts of dispersant polyethylene glycol 200, thickener HEC2 parts, 8752.5 parts of wetting agent Hydropalat, 6 parts of pigment, go from
Sub- 32 parts of water；Preparation method is as follows：
（1）It will be added to after the mixed solution of toluene and butyl methacrylate in reactor, heating stirring；Treat that water temperature rises to 80
After DEG C, styrene by evenly mixing, methyl methacrylate, acrylic acid, AIBN are at the uniform velocity instilled into mixed solution, at 80 DEG C
It is added dropwise under constant temperature in 2h, continues to react 4h, stop heating, produce carboxyl acrylic resin；It is each by said ratio metering
Component；
（2）Carboxyl acrylic resin is added in reactor, polyethylene glycol, mica powder, nano-kaolinite is sequentially added and receives
Rice montmorillonite mixed thing, levelling agent, dispersant, HEC, wetting agent, pigment, deionized water, temperature are warming up to as 50 DEG C, in rotating speed
To be sufficiently stirred 3h under 300RPM rotating speeds；After obtained homogeneous mixture of material is cooled to room temperature, 300 eye mesh screens are crossed.
The acrylic acid environmental protection enamel paint of the present invention of embodiment 2, by following weight than raw material prepare：50 parts of acrylic resin,
17 parts of glycerine, filler（Wollastonite）22 parts, nano-kaolinite and 28 parts of nano montmorillonite mixed thing, acrylic ester type levelling agent
10 parts, 11 parts of dispersant polyethylene glycol 200, thickener HPAM9 parts, 8758.5 parts of wetting agent Hydropalat, 15 parts of pigment,
46 parts of deionized water；Preparation method is as follows：
（1）It will be added to after the mixed solution of toluene and butyl methacrylate in reactor, heating stirring；Treat that water temperature rises to 80
After DEG C, styrene by evenly mixing, methyl methacrylate, acrylic acid, AIBN are at the uniform velocity instilled into mixed solution, in 80 DEG C of perseverances
It is added dropwise under temperature in 2h, continues to react 4h, stopping, which is heated, produces carboxyl acrylic resin；Each component is measured by said ratio；
（2）Obtained carboxyl acrylic resin is added in reactor, sequentially adds polyethylene glycol, filler, nano-kaolinite
With nano montmorillonite mixed thing, levelling agent, dispersant, PEO, wetting agent, pigment, deionized water, temperature is warming up to as 70 DEG C,
Rotating speed is to be sufficiently stirred 2h under 400RPM rotating speeds；After obtained homogeneous mixture of material is cooled to room temperature, 300 eye mesh screens are crossed.
The acrylic acid environmental protection enamel paint of the present invention of embodiment 3, by following weight than raw material prepare：42 parts of acrylic resin,
12 parts of glycerine, filler（Mica powder）15 parts, nano-kaolinite and 22 parts of nano montmorillonite mixed thing, acrylic ester type levelling agent
7 parts, 6 parts of dispersant, 6 parts of thickener PEO, 875 5.5 parts of wetting agent Hydropalat, 9 parts of pigment, 40 parts of deionized water；
Preparation method is as follows：
（1）It will be added to after the mixed solution of toluene and butyl methacrylate in reactor, heating stirring；Treat that water temperature rises to 80
After DEG C, styrene by evenly mixing, methyl methacrylate, acrylic acid, AIBN are at the uniform velocity instilled into mixed solution, at 80 DEG C
It is added dropwise under constant temperature in 2h, continues to react 4h, stopping, which is heated, produces carboxyl acrylic resin；Each group is measured by said ratio
Point；
（2）Obtained carboxyl acrylic resin is added in reactor, sequentially adds polyethylene glycol, mica powder, nanometer kaolinite
Stone and nano montmorillonite mixed thing, levelling agent, dispersant, HPAM, wetting agent, pigment, deionized water, temperature is warming up to as 60
DEG C, it is sufficiently stirred 2.5h in the case where rotating speed is 350RPM rotating speeds；After obtained homogeneous mixture of material is cooled to room temperature, 250 are crossed
Eye mesh screen.
Claims (7)
- A kind of 1. acrylic acid environmental protection enamel paint, it is characterised in that by following weight than raw material prepare：Carboxyl acrylic resin 35 ~ 50 parts, 9 ~ 17 parts of glycerine, 8 ~ 22 parts of filler, nano-kaolinite and 15 ~ 28 parts of nano montmorillonite mixed thing, levelling agent 2 ~ 10 Part, 3 ~ 11 parts of dispersant, 2 ~ 9 parts of thickener, 2.5 ~ 8.5 parts of wetting agent, 6 ~ 15 parts of pigment, 32 ~ 46 parts of deionized water.
- 2. acrylic acid environmental protection enamel paint according to claim 1, it is characterised in that the filler is mica powder or wollastonite.
- 3. acrylic acid environmental protection enamel paint according to claim 1, it is characterised in that described thickener is HEC, PEO, HPAM In one kind.
- 4. acrylic acid environmental protection enamel paint according to claim 1, it is characterised in that the levelling agent is acrylic ester type levelling One kind in agent.
- 5. acrylic acid environmental protection enamel paint according to claim 1, it is characterised in that the wetting agent produces for BASF AG Model Hydropalat 875 wetting agent.
- 6. according to the acrylic acid environmental protection enamel paint described in claim 1, it is characterised in that the dispersant is polyethylene glycol 200 or gathered Ethylene glycol 400.
- 7. acrylic acid environmental protection enamel paint according to claim 1, it is characterised in that the preparation side of the carboxyl acrylic resin Method is as follows：Toluene and butyl methacrylate are pressed 1:1.5 mixing, are added in reactor, heating stirring；Treat that water temperature rises to 80 After DEG C, styrene by evenly mixing, methyl methacrylate, acrylic acid, AIBN are at the uniform velocity instilled into mixed solution, at 80 DEG C It is added dropwise under constant temperature in 2h, continues to react 4h, stopping, which is heated, produces carboxyl acrylic resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711295294.5A CN107880698A (en) | 2017-12-08 | 2017-12-08 | A kind of acrylic acid environmental protection enamel paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711295294.5A CN107880698A (en) | 2017-12-08 | 2017-12-08 | A kind of acrylic acid environmental protection enamel paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107880698A true CN107880698A (en) | 2018-04-06 |
Family
ID=61773289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711295294.5A Withdrawn CN107880698A (en) | 2017-12-08 | 2017-12-08 | A kind of acrylic acid environmental protection enamel paint |
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| CN (1) | CN107880698A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624171A (en) * | 2018-05-25 | 2018-10-09 | 吕军 | A kind of enamel paint formula for unmanned plane covering |
| CN108795266A (en) * | 2018-05-25 | 2018-11-13 | 吕军 | A kind of unmanned plane acrylic acid environmental protection enamel paint |
| CN112500756A (en) * | 2020-11-18 | 2021-03-16 | 雅图高新材料股份有限公司 | Solvent type low-VOC (volatile organic compound) Daba intermediate coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101987936A (en) * | 2010-12-09 | 2011-03-23 | 上海电动工具研究所 | Single-component water-soluble insulated enamel paint and preparation method thereof |
| CN104559549A (en) * | 2013-10-25 | 2015-04-29 | 青岛德固建筑材料有限公司 | Enamel paint |
-
2017
- 2017-12-08 CN CN201711295294.5A patent/CN107880698A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101987936A (en) * | 2010-12-09 | 2011-03-23 | 上海电动工具研究所 | Single-component water-soluble insulated enamel paint and preparation method thereof |
| CN104559549A (en) * | 2013-10-25 | 2015-04-29 | 青岛德固建筑材料有限公司 | Enamel paint |
Non-Patent Citations (1)
| Title |
|---|
| 王锡娇: "《涂料与颜料标准应用手册（上册）》", 30 April 2005, 军事谊文出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624171A (en) * | 2018-05-25 | 2018-10-09 | 吕军 | A kind of enamel paint formula for unmanned plane covering |
| CN108795266A (en) * | 2018-05-25 | 2018-11-13 | 吕军 | A kind of unmanned plane acrylic acid environmental protection enamel paint |
| CN112500756A (en) * | 2020-11-18 | 2021-03-16 | 雅图高新材料股份有限公司 | Solvent type low-VOC (volatile organic compound) Daba intermediate coating and preparation method thereof |
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180406 |
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