CN103131318A - UV paint for building sheet material - Google Patents

UV paint for building sheet material Download PDF

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Publication number
CN103131318A
CN103131318A CN2011103774000A CN201110377400A CN103131318A CN 103131318 A CN103131318 A CN 103131318A CN 2011103774000 A CN2011103774000 A CN 2011103774000A CN 201110377400 A CN201110377400 A CN 201110377400A CN 103131318 A CN103131318 A CN 103131318A
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agent
component
building board
paints
pigment
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CN2011103774000A
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孙月静
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Abstract

The invention provides UV paint for a building sheet material. The UV paint has high color fidelity, discolors difficultly, and has high hardness, good wear resistance, high paint surface skid resistance and staining resistance, and a certain antibacterial effect. The invention also provides a preparation method and a use method of the UV paint for a building sheet material. The UV paint has high color fidelity, discolors difficultly, and has high hardness, good wear resistance and high skid resistance. After being added with nano-silver powder, the UV paint has a certain antibacterial effect and can be used in a room.

Description

A kind of building board paints with UV
Technical field
The invention belongs to the building decoration field, relate to a kind of building board and paint with UV, particularly a kind of calcium silicate board spraying is painted with UV.
Background technology
Along with the raising of expanding economy and living standards of the people, people improve constantly the aesthetic conceptions in room, and the decoration of room metope, floor, furniture etc. is more and more emphasized decorative effect and environmental requirement.
UV coating is to utilize uviolizing generation chemical reaction and the coating that hardens, and its main component comprises photosensitive resin, light trigger, auxiliary agent and reactive thinner etc.UV coating, absorbs ultraviolet ray with light trigger and forms free radical as solidifying the energy with ultraviolet ray, causes photosensitive resin and reactive thinner molecule, and then chain polymerization occurs, and makes paint film realize solidification effect.
UV coating have curing speed fast, need not the advantages such as heating, excellent performance, energy-conserving and environment-protective, and the rete luminance brightness is high, after dry face firm heat-resisting, surface that can make ground is very bright, level and smooth, refractive power is effective, make ground produce strong theme sense, be widely used in the industries such as chemical industry, machinery, electronics, building, light industry.
In the market UV paint is mainly used in take plastics, metal, timber as base material, a lot of defectives being arranged,, jaundice variable color not high such as hardness, not wear-resisting, not antibiotic etc.The product that can be used on building board mainly contains single-component tide solidified paint, double-component polyurethane paint, epoxy-based lacquers etc., but all there is defective in above-mentioned three kinds of paints at aspects such as wear resistance, anti-skid, resistances to soiling.
Summary of the invention
In order to solve above-mentioned existing technical problem, a first aspect of the present invention provides a kind of building board to paint with UV, and this UV paints that not only color is true to nature, not easy to change, hardness is high, and wear resistance is good, lacquer painting anti-skid and resistance to soiling are improved, and have certain anti-microbial effect.
In order to solve above-mentioned existing technical problem, a second aspect of the present invention provides the preparation method of a kind of building board with the UV paint.
In order to solve above-mentioned existing technical problem, a third aspect of the present invention provides the using method of a kind of building board with the UV paint.
A first aspect of the present invention for solving the problems of the technologies described above, the invention provides a kind of building board and paints with UV, and its each component and weight percentage are respectively:
Monomer 20-35,
UV resin 40-70,
Light trigger 2-10,
Anti-wear agent 5-20,
Auxiliary agent 1-5,
Anti-settling agent 0.5-2,
Solvent 5-20,
Pigment 0-20,
Nanometer silver powder 0-5.
Preferably, wherein said monomer is at least a in Viscoat 295, two functionality acrylate monomers, six functionality acrylate monomers; Described UV resin is polyurethane acrylic resin or epoxy acrylic resin or mixtures both; Described light trigger is at least a in vapour bar (Ciba) light trigger, acylphosphine oxide photoinitiator, alpha-alcohol ketone photoinitiator; Described anti-settling agent is polycarboxylic acid salt or the modified urea solution of polyamine acid amides.
Preferably, described anti-wear agent is the mixture of A component and B component; Described A component is at least a in aluminium sesquioxide, high circularity glass microballon, low circularity glass microballon and silicon carbide, and described B component is at least a in crystallinity ultrahigh molecular weight polyethylene(UHMWPE) and crystallinity ultrahigh molecular weight polypropylene.
Preferably, described auxiliary agent is the mixing solutions of flow agent, defoamer, dispersion agent, and its weight percentage is respectively:
Flow agent 25%-40%,
Defoamer 20%-35%,
Dispersion agent 20%-40%.
Preferably, described solvent is butylacetate, ethyl acetate, Virahol, ethylene glycol monobutyl ether mixing solutions, and its weight percentage is respectively:
Butylacetate 20%-40%,
Ethyl acetate 20%-35%,
Virahol 20%-35%,
Ethylene glycol monobutyl ether 7%-15%.
Preferably, described pigment comprises at least a in mineral dye, pigment dyestuff, bronze, silver powder, reflective pigment, fluorescent material; The particle diameter of described nanometer silver is 30~50nm.And described nanometer silver powder is absorption or year silver metal ion produced by ion-exchange method on the nano material basis.
The paint that makes in component by above this paint is clear lacquer, and when need preparation dumb light paint, also need add weight percent is the matting agent of 5-15, and described UV resin 40-70 is substituted by UV resin 35-60 and matting agent 5-15.
Preferably, a kind of building board paints with UV, and its each component and weight percentage are respectively:
Monomer 20-35,
UV resin 40-70,
Light trigger 2-10,
Anti-wear agent 5-20,
Auxiliary agent 1-5,
Anti-settling agent 0.5-2,
Solvent 5-20,
Pigment 0-20,
Nanometer silver powder 0-5.
A second aspect of the present invention for solving the problems of the technologies described above, the invention provides a kind of building board with the preparation method of UV paint, comprises the steps:
(1) in proportion with flow agent, defoamer, dispersant together, stir, obtain auxiliary agent;
(2) in proportion butylacetate, ethyl acetate, Virahol, ethylene glycol monobutyl ether are mixed, stir, obtain solvent;
(3) get the UV resin, the monomer that adds corresponding proportion, then add respectively in proportion light trigger, anti-wear agent, anti-settling agent, pigment, nanometer silver powder to add again the auxiliary agent of step (1) and the solvent of step (2), stir with stirrer after mixing, and get final product.
Preferably, wherein said monomer is at least a in Viscoat 295, two functionality acrylate monomers, six functionality acrylate monomers; Described UV resin is polyurethane acrylic resin or epoxy acrylic resin or mixtures both; Described light trigger is at least a in vapour (Ciba) light trigger, acylphosphine oxide photoinitiator, alpha-alcohol ketone photoinitiator; Described anti-settling agent is polycarboxylic acid salt or the modified urea solution of polyamine acid amides.
Preferably, described anti-wear agent is the mixture of A component and B component; Described A component is at least a in aluminium sesquioxide, high circularity glass microballon, low circularity glass microballon and silicon carbide, and described B component is at least a in crystallinity ultrahigh molecular weight polyethylene(UHMWPE) and crystallinity ultrahigh molecular weight polypropylene.
Preferably, described auxiliary agent is the mixing solutions of flow agent, defoamer, dispersion agent, and its weight percentage is respectively:
Flow agent 25%-40%,
Defoamer 20%-35%,
Dispersion agent 20%-40%.
Preferably, described solvent is butylacetate, ethyl acetate, Virahol, ethylene glycol monobutyl ether mixing solutions, and its weight percentage is respectively:
Butylacetate 20%-40%,
Ethyl acetate 20%-35%,
Virahol 20%-35%,
Ethylene glycol monobutyl ether 7%-15%.
Preferably, described pigment comprises at least a in mineral dye, pigment dyestuff, bronze, silver powder, reflective pigment, fluorescent material; The particle diameter of described nanometer silver is 30~50nm.And described nanometer silver powder is absorption or year silver metal ion produced by ion-exchange method on the nano material basis.
A third aspect of the present invention for solving the problems of the technologies described above, the invention provides the using method that a kind of building board paints with UV.
Preferably, a kind of building board is mainly used in being coated with UV paint the various sheet materials that timber, Al-alloy metal plate, other inorganic materials such as stone material, particularly calcium silicate board are made.
Preferably, by the mode of roller coat or spraying, building board is painted with UV and be applied to building board, the building board after spraying is placed several minutes, make lacquer painting nature levelling, and put into the baking box baking; Preferably, storing time is 2-5 minute, and storing temperature is 50-80 ℃, carries out ultraviolet light polymerization finally by the UV stove.
In said components, described starting material are that ordinary method makes or are commercially available.
Compared with prior art; the paint film structure that UV paint of the present invention forms is tough and tensile; can be at wooden, stone material; the building boards such as Al-alloy metal plate, inorganic board surface forms the protective layer of scrape resistant; the anti-skid of lacquer painting also improves a lot simultaneously; in addition, described building board plays certain anti-microbial effect with also having added the nanometer silver powder in the UV paint.Make the wider of application.
Embodiment
Below in conjunction with specific embodiment, such scheme is described further.Should be understood that these embodiment are not limited to limit the scope of the invention for explanation the present invention.The implementation condition that adopts in embodiment can be done further adjustment according to concrete condition.
Embodiment 1 building board paints with UV
Get following raw material by formula:
Figure BSA00000619870800051
During preparation, blending dispersion is even according to a conventional method with above-mentioned raw materials, and it is dissolved fully, and stirring with stirrer after mixing namely gets UV paint of the present invention.
Embodiment 2
2.1 building board paints with UV
Figure BSA00000619870800052
2.2 building board comprises the steps: with the preparation method of UV paint
(1) in proportion with flow agent, defoamer, dispersant together, stir, obtain auxiliary agent;
(2) in proportion butylacetate, ethyl acetate, Virahol, ethylene glycol monobutyl ether are mixed, stir, obtain solvent;
(3) get the UV resin, the monomer that adds corresponding proportion, then add respectively in proportion light trigger, anti-wear agent, anti-settling agent, pigment, nanometer silver powder to add again the auxiliary agent of step (1) and the solvent of step (2), stir with stirrer after mixing, and get final product.
During preparation, blending dispersion is even according to a conventional method with above-mentioned raw materials, and it is dissolved fully, is modulated into UV paint of the present invention.
2.3 the using method that building board paints with UV
Mode by roller coat or spraying is applied to building board for example on calcium silicate board with paint, and the calcium silicate board after spraying is placed several minutes, makes lacquer painting nature levelling, and put into baking box and toast, storing temperature is 60 ℃, and storing time is 3 minutes, carries out ultraviolet light polymerization finally by the UV stove.
The technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.

Claims (15)

1. a building board paints with UV, and its each component and weight percentage are respectively:
Monomer 20-35,
UV resin 40-70,
Light trigger 2-10,
Anti-wear agent 5-20,
Auxiliary agent 1-5,
Anti-settling agent 0.5-2,
Solvent 5-20,
Pigment 0-20,
Nanometer silver powder 0-5.
2. a kind of building board according to claim 1 paints with UV, it is characterized in that, described monomer is at least a in Viscoat 295, two functionality acrylate monomers, six functionality acrylate monomers; Described UV resin is polyurethane acrylic resin or epoxy acrylic resin or mixtures both; Described light trigger is at least a in vapour (Ciba) light trigger, acylphosphine oxide photoinitiator, alpha-alcohol ketone photoinitiator; Described anti-settling agent is polycarboxylic acid salt or the modified urea solution of polyamine acid amides.
3. a kind of building board according to claim 1 paints with UV, it is characterized in that, described anti-wear agent is the mixture of A component and B component; Described A component is at least a in aluminium sesquioxide, high circularity glass microballon, low circularity glass microballon and silicon carbide, and described B component is at least a in crystallinity ultrahigh molecular weight polyethylene(UHMWPE) and crystallinity ultrahigh molecular weight polypropylene.Shared weight percentage is respectively:
A component 50%-80%,
B component 30%-50%,
A, B component directly mix.
4. a kind of building board according to claim 1 paints with UV, it is characterized in that, described auxiliary agent is flow agent, defoamer, dispersant solution, and its weight percentage is respectively:
Flow agent 25%-40%,
Defoamer 20%-35%,
Dispersion agent 20%-40%.
5. a kind of building board according to claim 1 paints with UV, it is characterized in that, described solvent is butylacetate, ethyl acetate, Virahol, ethylene glycol monobutyl ether mixing solutions, and its weight percentage is respectively:
Butylacetate 20%-40%,
Ethyl acetate 20%-35%,
Virahol 20%-35%,
Ethylene glycol monobutyl ether 7%-15%.
6. a kind of building board according to claim 1 paints with UV, it is characterized in that, described pigment comprises at least a in mineral dye, pigment dyestuff, bronze, silver powder, reflective pigment, fluorescent material; The particle diameter of described nanometer silver is 30~50nm.
7. a kind of building board according to claim 1 paints with UV, it is characterized in that, its each component and weight percentage are respectively:
Monomer 20-35,
UV resin 40-70,
Light trigger 2-10,
Anti-wear agent 5-20,
Auxiliary agent 1-5,
Anti-settling agent 0.5-2,
Solvent 5-20,
Pigment 0-20,
Nanometer silver powder 0-5.
8. the described building board of claim 1 with the preparation method that UV paints, comprises the steps:
(1) in proportion with flow agent, defoamer, dispersant together, stir, obtain auxiliary agent;
(2) in proportion butylacetate, ethyl acetate, Virahol, ethylene glycol monobutyl ether are mixed, stir, obtain solvent;
(3) get the UV resin, the monomer that adds corresponding proportion, then add respectively in proportion light trigger, anti-wear agent, anti-settling agent, pigment, nanometer silver powder to add again the auxiliary agent of step (1) and the solvent of step (2), stir with stirrer after mixing, and get final product.
9. preparation method according to claim 8, is characterized in that, described monomer is at least a in Viscoat 295, two functionality acrylate monomers, six functionality acrylate monomers; Described UV resin is polyurethane acrylic resin or epoxy acrylic resin or mixtures both; Described light trigger is at least a in vapour (Ciba) light trigger, acylphosphine oxide photoinitiator, alpha-alcohol ketone photoinitiator; Described anti-settling agent is polycarboxylic acid salt or the modified urea solution of polyamine acid amides.
10. preparation method according to claim 8, is characterized in that, described anti-wear agent is the mixture of A component and B component; Described A component is at least a in aluminium sesquioxide, high circularity glass microballon, low circularity glass microballon and silicon carbide, and described B component is at least a in crystallinity ultrahigh molecular weight polyethylene(UHMWPE) and crystallinity ultrahigh molecular weight polypropylene.Its weight percentage is respectively:
A component 50%-80%,
B component 30%-50%.
11. preparation method according to claim 8 is characterized in that, described auxiliary agent is flow agent, defoamer, dispersant solution, and its weight percentage is respectively:
Flow agent 25%-40%,
Defoamer 20%-35%,
Dispersion agent 20%-40%.
12. preparation method according to claim 8 is characterized in that, described solvent is butylacetate, ethyl acetate, Virahol, ethylene glycol monobutyl ether mixing solutions, and its weight percentage is respectively:
Butylacetate 20%-40%,
Ethyl acetate 20%-35%,
Virahol 20%-35%,
Ethylene glycol monobutyl ether 7%-15%.
13. preparation method according to claim 8 is characterized in that, described pigment comprises at least a in mineral dye, pigment dyestuff, bronze, silver powder, reflective pigment, fluorescent material; The particle diameter of described nanometer silver is 30~50nm.
14. a kind of building board as claimed in claim 1 is mainly used in UV paint the various sheet materials that timber, Al-alloy metal plate, other inorganic materials such as stone material, particularly calcium silicate board are made.
15. purposes according to claim 9 is characterized in that, by the mode of roller coat or spraying, building board is painted with UV and is applied to building board, and the building board after spraying is placed several minutes, makes lacquer painting nature levelling, and puts into the baking box baking; Storing time is 2-5 minute, and storing temperature is 50-80 ℃, carries out ultraviolet light polymerization finally by the UV stove.
CN2011103774000A 2011-11-21 2011-11-21 UV paint for building sheet material Pending CN103131318A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602224A (en) * 2013-11-20 2014-02-26 广东美涂士建材股份有限公司 White solvent-free finish paint as well as preparation method and construction process of white solvent-free finish paint
CN103696546A (en) * 2013-12-17 2014-04-02 佛山澳特板业有限公司 Antibacterial cement type plate and preparation method thereof
CN103865376A (en) * 2014-03-11 2014-06-18 上海长润发涂料有限公司 UV spraying frosted paint
CN104017410A (en) * 2014-06-19 2014-09-03 江苏凯尚节能科技有限公司 Antibacterial composite floor based on nano zinc particles
CN104877553A (en) * 2015-05-29 2015-09-02 苏州德翔装饰工程有限公司 Skid-resistant coating for granite plates and preparation method of skid-resistant coating
CN104927626A (en) * 2015-06-09 2015-09-23 成都纳硕科技有限公司 Ultraviolet curing coating for outer walls
CN105331255A (en) * 2015-12-10 2016-02-17 展辰新材料集团股份有限公司 Ultraviolet curing coating and preparation method thereof
CN107384182A (en) * 2017-08-08 2017-11-24 湖南邦弗特新材料技术有限公司 A kind of outdoor heavy bamboo timber floor and preparation method thereof
CN109401612A (en) * 2018-11-02 2019-03-01 华容县恒兴建材有限公司 Wear-resisting optical curing of UV coating
CN110511653A (en) * 2019-08-07 2019-11-29 佛山市丰瑞新材料科技有限公司 Stone surface inorganic agent and preparation method thereof and method for treatment of surface of stone

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602224A (en) * 2013-11-20 2014-02-26 广东美涂士建材股份有限公司 White solvent-free finish paint as well as preparation method and construction process of white solvent-free finish paint
CN103602224B (en) * 2013-11-20 2016-06-01 广东美涂士建材股份有限公司 A kind of white solvent-free finish paint and its preparation method and construction technology
CN103696546A (en) * 2013-12-17 2014-04-02 佛山澳特板业有限公司 Antibacterial cement type plate and preparation method thereof
CN103865376A (en) * 2014-03-11 2014-06-18 上海长润发涂料有限公司 UV spraying frosted paint
CN104017410A (en) * 2014-06-19 2014-09-03 江苏凯尚节能科技有限公司 Antibacterial composite floor based on nano zinc particles
CN104877553A (en) * 2015-05-29 2015-09-02 苏州德翔装饰工程有限公司 Skid-resistant coating for granite plates and preparation method of skid-resistant coating
CN104927626A (en) * 2015-06-09 2015-09-23 成都纳硕科技有限公司 Ultraviolet curing coating for outer walls
CN105331255A (en) * 2015-12-10 2016-02-17 展辰新材料集团股份有限公司 Ultraviolet curing coating and preparation method thereof
CN107384182A (en) * 2017-08-08 2017-11-24 湖南邦弗特新材料技术有限公司 A kind of outdoor heavy bamboo timber floor and preparation method thereof
CN109401612A (en) * 2018-11-02 2019-03-01 华容县恒兴建材有限公司 Wear-resisting optical curing of UV coating
CN110511653A (en) * 2019-08-07 2019-11-29 佛山市丰瑞新材料科技有限公司 Stone surface inorganic agent and preparation method thereof and method for treatment of surface of stone

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Application publication date: 20130605